Chemical Engineering Commons^™

Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu, Tianpei Zhu

Journal of Electrochemistry

Electrochemical reduction reaction in the course of the titration of Eu(2.2.2) and Eu(2.2) using strong bonding solvent, DMSO, in C₂H₄Cl₂ has been investigated by cyclic voltammetry. The greater the concentration of strong bonding solvent, the more negative the half-wave potentials for the reduction reaction are. The coordination number of Eu(2.2.2) and Eu(2.2) which are 2 and 3 respectively, with DMSO can be calculated, according to the relations between half-wave potentials and the variety of concentration of DMSO.

The Study Of The Growth Processes Of The Oxides On Lead Electrodes In Sulfuric Acid Solution, Hesheng Zhai, Xuguang Chen, Jinkua You, Yong Yang, Zugeng Lin

Journal of Electrochemistry

The growth processes of PbO and PbO₂ on lead electrodes have been investigatedby using in-situ methods that are combined with temporary AC resistance measurment technique and in-situ laser scanning photoelectrochemical microscopy. It is found that a linear relationship existsbetween the electrode resistance(R) and^1/2 after the electrode is oxidized at +0.6 V(vs.Hg/H₂SO₄/35% H₂SO₄) for more than 5 min. This result suggests that the growth of PbO is well distributed during the early stage of oxidation. The study by using laser scanning photoelectrochemical microscopy has further proved this point. The results also …

A Photoelectrochemical Investigation Of Zirconium Oxide Film, Maizhi Yang, Ping Wei, Di Quarto F., Piazza S., Sunseri C.

Journal of Electrochemistry

A photoelectrochemical investigation has been carried out on zirconium initialoxide film and its oxide film grownanodically at constant rate up to different thickness. Both anodicand cathedic photocurrents on the photocurrent spectrum depended on the potential, but had littlerelation with the forming anedic films or measuring solutions. Photocurrent spectrum and photocurrenttransients suggested that the oxide films on zirconium were duplex layers structure. The internal layerwas ZrO₂ and the external layer ZrO₂·(H₂O)_n. The photocurrent included photogenerated carrier ininternal and external oxide films, as well as internal photoinjection process for electrons from thesubstrate metal into the …

Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang

Journal of Electrochemistry

The titanium substrates were bombarded with 1×10¹⁷～5×10¹⁷ ions·cm^-2 ofpalladium at the room temperature. The surface composition of implanted electrode and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene (NB) in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry. The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion, which is the product of one-electronelectroreduction of NB, was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of …

Electroreduction Of Holmium Ion On Iron Electrde In Molten Cholorides, Qiqin Yang, Guankun Liu, Yuzhi Su

Journal of Electrochemistry

The cyclic voltammetry, open circuit potential-time curve after poteritiostatic electrolysis, current-time curve at potential step, X-ray diffraction and electron probe microanalysiswere used to investigate the electrode process of Ho(Ⅲ) reduced on iron electrode in molten chloridesand the phases of surface alloy layer. The Ho-Fe alloys are formed at first, and then the metallic holmium is deposited when Ho(Ⅲ) is reduced on iron electrode. The charge transfer is reversible. The free energies of formation for the four inter metallic compounds of Ho-Fe system, the diffusion coefficients and diffusion activation energy of Ho in alloyed cathode are determined.

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

Design Approach For Small Scale Continuous, Steady State Plants, O Kaunde

Tanzania Journal of Engineering and Technology (TJET)

One of the major steps in the design of a process plant is development of an appiopriate flowsheet. At this step, the technical solutions may be con- sidered in relation to the social and economic factors. In this paper, guide- lines for developing a flowsheet for continuous, steady State process in a developing country environment have been proposed. To illustrate the pro- posed guidelines, a case study involving design of an ethanol distillation plant has been used.

Influence Of Arc Discharge Duration On Turbulent Mass Burning Rate, E Mushi

Tanzania Journal of Engineering and Technology (TJET)

The influence of arc discharge duration on turbulent mass burning rate was investigated for turbulent r.m.s vglocities of u '=1.73 m/s and u'=4.5 nfs. Methane air mixtures were used at equivalence ratios ranging from 0.83 to / .25. Flame size was obtained through schiieren photography while the intensity Of CH chemiluminescence emissions was used to measure mass burning rate. A variable spark duration unit was used for ignition sparks and all the experiments were done in a fan stirred bomb. Discharge duration has no effect when the equivalence ratio is I. For higher values longer duration inoeases the burning rate …

Improved Heat Transfer By Means Of Steam Injection In A Shell & Tube Heat Exchanger, O Kaunde

Tanzania Journal of Engineering and Technology (TJET)

When designing a heat exchanger; one aims at attaining high heat transfer rates SO as to minimise heat transfer area and therefore the overall cost. This paper presents a method of improving the overall heat travsfer coef- ficient of a conventional shell and tube heal exchanger. The method in- volves injecting steam into the process fluid as it enters the heat exchanger thus effecting mixing of fluid as it travels along the exchanger Tests car- • ried out using this technique showed a significant increase in the overall heat transfer coefficient values.

An Alternative Method Of Interfacing A Dc Motor To A Microprocessor For Mo- Tion Control, M Selekwa

Tanzania Journal of Engineering and Technology (TJET)

A Simple and cheap alternative method Of interfacing a permanent mag- net dc motor to a motion control using switch- ing transistor motor drivers is presented. This method involves the use Of very few transistor-transistor logic (TTL) devices and a 555 timer to pro- duce a pulse width modulated (P WM) signal which is required by the mo- ror driver. The motor driver in this case should be of an H-bridge type. Like other methods currently in use, it relieves the MPU of all timing func- tions which are necessary in the generation of P WM signals. The present method, …

Thermodynamics And Transport Proper- Ties Analysis Of Natural Gas From Songosongo In Kilwa- Tanzania, G Mrema

Tanzania Journal of Engineering and Technology (TJET)

Analysis ofthermodynamics and transport properties was carried outfor six natu- ral gas samples from Songosongofield in Kilwa - Tanzania using PRO/II simula- for. Properties of most interest in gas processing (due to their influence on the sales value) such as density, specific gravity, critical parameters, bubble point and dew point, enthalpy, latent heat of vaporisation, molecular weight, boiling point and phase were investigated. In addition composition of the gas was com- pared with that from elsewhere. The gas was assumed to be at a temperature of 30C and a pressme of 150 bar before pressure let down station. Results indicated …

Effects Of Radiative Interactions In Molecular Gases Under Local And Nonlocal Thermodynamic Equilibrium Conditions, Manoj Kumar Jha

Mechanical & Aerospace Engineering Theses & Dissertations

Basic formulations, analyses, and numerical procedures are presented to investigate radiative heat interactions in diatomic and polyatomic gases under local and nonlocal thermodynamic equilibrium conditions. Essential governing equations are presented for both gray and nongray gases. Information is provided on absorption models, relaxation times, and transfer equations. Radiative flux equations are developed which are applicable under local and nonlocal thermodynamic equilibrium conditions.

The problem is solved for fully developed laminar incompressible flows between two parallel plates under the boundary condition of a uniform surface heat flux. For specific applications, three diatomic and three polyatomic gases are considered. The results are …

A Study Of The Effects Of Polyacrylates On Water Retention And Binder Migration Tendencies Of Coatings, Wichan Charoenkitsupat

Masters Theses

Five commercial polyacrylate samples were used to study their effects on viscosity, water holding, and binder migration under non-pressure conditions. The polyacrylates used were different in acid level, degree of crosslinking, and type of polymer (copolymer and terpolymer). A series of coatings was prepared using a number two clay and three styrene-butadiene latexes of similar particle size and T⋁g but different degrees of carboxylation, then the polyacrylates were added at several levels. The coatings were evaluated for rheological properties, water loss rate and binder migration. The results show that with increasing amounts of polyacrylates, the viscosity increased and the water …

Thermal Compatibility Analysis Of The Passive Damping Treatment Proposed For The Space Shuttle Remote Manipulator System (Srms), Mahesh Chowdhary

Mechanical & Aerospace Engineering Theses & Dissertations

The NASA Space Shuttle Remote Manipulator System (SRMS), due to its long reach and light weight construction has significant structural flexibility. Thus any routine use of SRMS often results in large amplitude oscillations with long settling time. A passive damping technique utilizing a constrained viscoelastic layer damping treatment has been proposed to augment the active control of these oscillations in order to enhance the system stability and the end effector positional accuracy. This thesis concerns with the thermal compatibility analysis of the proposed damping treatment. The necessity for thermal compatibility analysis arises from the fact that acceptable damping performance of …

The Fractal Dimension As A Measure Of The Roughness Of Rock Discontinuity Profiles, Y. H. Lee, J. R. Carr, David J. Barr, Charles J. Haas

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An important factor in the analysis of deformation and failure of rock masses along discontinuities is the roughness of the jointing surfaces. The fractal dimension is proposed as a method of objectively quantifying the roughness profile of such discontinuities. With this method much less engineering judgement and experience are required in determining the surface roughness,sb than is required for other methods such as the widely used joint roughness coefficient (JRC) suggested by the International Society for Rock Mechanics [1] (Int. J. Rock. Mech. Min. Sci. & Geomech. Abstr. 15, 319-368, 1978). The fractal dimension, suggested by Mandelbrot [2] (Fractals-Form, Chance …

Simulation Of Fluid Flow In Packed Beds Using A Simplified Model And Network Analysis Technique, Haggai W.K. Sarakikya

Tanzania Journal of Engineering and Technology (TJET)

Abstract

A Study Of The Flow Characteristics In The Core Region Of The Sandia Engineering Reactor, James A. Moeller

Chemical and Biological Engineering ETDs

The core region of a nuclear rector is an extremely compact area with a capability of providing a very high heat output. Regardless of the type of coolant used, the heat transfer characteristics of this region must be adequately designed to prevent any undesirable "hot-spots" from developing. The Sandia Engineering Reactor has one of the most compact cores of any in currently operating nuclear reactors. For this reason it is necessary to investigate fully the heat transfer characteristics of the core. The rate of heat transfer from the fuel elements to the coolant is directly dependent upon the temperature difference …