Chemical Engineering Commons^™

The Synthesis, Characteristics And Performance Of Cnt Composites As Anodic Materials In Litium-Ion Battery, Quan-Feng Dong, Ming-Sen Zheng, Zhen-Cai Huang, Ming-Gang Jin, Ya-Ding Zhan, Zu-Geng Lin

Journal of Electrochemistry

As an anodic material for lithium ion battery the carbon nano-tube (CNT) and some compounds based on tin have ever been investigated intensively. The fruited progress has not been made yet, however. In this paper the composites of CNT and Sn/SnO₂ were synthesized employing two methods and characterized by SEM and XRD. And the electrochemical performance of the composites was investigated.

The Effect Of Oxidant On Structure And Properties Of Pan/Ptfe Conducting Composite Membrane, Chang-Yuan Tao, Jing Chen, Jun Du, Cai-Xin Sun

Journal of Electrochemistry

The PAn/PTFE conducting composite membrane was prepared by means of in-situ permeating chemical polymerization, with (NH₄)₂S₂O₈ and Na₃VO₄ being used as an oxidant respectively. The polymerization-growth behavior of the aniline by using different oxidant was compared. In addition, the oxidant effect on the structure and properties of conducting composite membrane was discussed. The results of SEM micrographs, pore size distribution and electrochemical methods suggested that using either oxidants could also induce the product with small pore size and dense pore structure. Compared with (NH₄)₂S₂O …

The Preparation And Performance Of The Aqueous Matrix For Molten Carbonate Fuel Cells, Hua-Xin Lin, Mo-Jie Ceng, Bao-Lian Yi

Journal of Electrochemistry

PVA matrix of MCFC was prepared from the α-LiAlO₂ powder, and polyvinylalcohol(PVA), Compared with the conventional PVB matrix, higher porosity, higher thermal weight loss and smaller maximum pore diameter were achieved for PVA matrix. Single cell was assembled with PVA matrix. At reaction gas pressure of 0.9 MPa, under reaction gas utilization of 20%, at 300 and 428.57 mA·cm^-2, the cell voltage was 0.849 and 0.739 V respectively, and the output power density was 254.7 and 316.7 mW·cm^-2 respectively, which are higher than those of the cell assembled with PVB matrix. During thermal cycles, the cell …

Study Of 2d And 3d Optical Beam Induced Voltage Imaging Using Photoresistor Sensor, Warsito Warsito, Sri Wahyu Suciyati, Susi Harnani, Akhmad Dzakwan

Makara Journal of Technology

Study of 2D and 3D Optical Beam Induced Voltage Imaging Using Photoresistor Sensor. This article shows a method to study OBIV (optical beam induced voltage) imagerie system, that usually employ a laser scanning microscopy system. The OBIV imagerie system developed use a photoresistor sensor as a sample and simultaneously it can be used for analyzing its inhomogeneity response. Resolution of the system is still low, about 350μm due to high value of incident light diameter. The results inform that photoresistor sensors gave an optimum response if the incident light hits the center of sensible zone.

Water Quality Of Rivers And Ponds On Dki Jakarta, Diana Hendrawan

Makara Journal of Technology

Water Quality of Rivers and Ponds on DKI Jakarta. Thirteen big rivers, some small rivers, and 40 ponds spread over districts at Jakarta city are potential to support human being life. As the population is growing and the usage of stream water is increasing, the condition and quality of rivers and ponds are changing. Crowd housing can affect rivers and ponds pollution, as the people awareness about clean and healthy environment is less. Stream water pollution assessment can be done by counting the effect of pollutant to life of stream water organisms. This assessment unit could be classified into physics, …

Time Domain Characterization Of 1-2 Ghz Circular-Ended Bowtie Antenna Using Normalizad Impulse Response, Joko Suryana, Andriyan B. Suksmono, Tati R. Mengko

Makara Journal of Technology

Time Domain Characterization of 1-2 GHz Circular-ended Bowtie Antenna Using Normalizad Impulse Response. Frequency domain analysis is a powerful and compact tool for characterizing the antenna parameters such as gain, radiation pattern and the impedance as a function of frequency. However, if time or space is a major concern, such as in the GPR appication, the time domain analysis would be a very important tool due to their unique capability for determining the echo delay and range profile of target image. In this paper, we will describe the classical theory of system characterization in time domain, and then also propose …

3d Modelling With Linear Approaches Using Geometric Primitives, Mochammad Zuliansyah

Makara Journal of Technology

In this paper, we study linear approaches for 3D model acquisition from non-calibrated images. First, the intrinsic and extrinsic camera calibration is taken into consideration. In particular, we study the use of a specific calibration primitive: the parallelepiped. Parallelepipeds are frequently present in man-made environments and naturally encode the affine structure of the scene. Any information about their euclidean structure (angles or ratios of edge lengths), possibly combined with information about camera parameters is useful to obtain the euclidean reconstruction. We propose an elegant formalism to incorporate such information, in which camera parameters are dual to parallelepiped parameters, i.e. any …

Dipole Magnetization Effect To Kerosene Characteristics, Mochamad Chalid, Nelson Saksono, Adiwar Adiwar, Nono Darsono

Makara Journal of Technology

Dipole Magnetization Effect to Kerosene Characteristics. Investigation of kerosene characteristics has been done by ex-situ dipole magnetization. The results show that magnetization technique can be able to influence kerosene characteristics. Polarity and viscosity of the kerosene are observed by measuring refractive index and viscosity. An hour of 4330 Gauss flux magnetic will increase refractive index from 1.447 to 1.449 and decrease the viscosity from 1.278 to 1.256. Those changing support de-clustering occurrence and polarity increment of kerosene molecule. Gas chromatography and infrared result show that those changing do not alter kerosene structure and composition.

Synthesis Dibenzyl Terephthalate Through Depolimerization Of Poly (Ethylene Terephthalate) As Alternative Of Waste Plastics Recycling, Suwardi Suwardi, Crys Fajar Partana, Agus Salim, Dyah Anitasari

Makara Journal of Technology

Synthesis Dibenzyl Terephthalate Through Depolimerization of Poly(ethylene terephthalate) as Alternative of Waste Plastics Recycling. Synthesis dibenzyl terephathalate were done through PET degradation by refluxing in benzyl alcohol at 145oC temperature for 20, 24, and 28 hours in the presence of zinc acetate catalyst. The result of degradation was purified by recristalization in methanol and then melting point (mp), FTIR, 1H NMR spectra, and TLC spot were determined. The melting point of product degradation for 28 hours was 98-99 oC. Based FTIR spectra known that compunds of product degradation have OH, C=O, C-O, CH, monosubstituted benzene, disubstituted benzene groups, while on …

Flexi Radio Base Station (Rbs) Performance Analysis Of Voice And Trafic On Kota 2 Jakarta Barat Base Station Control (Bsc), Mushfar Ferdian, Fitri Yuli Zulkifli

Makara Journal of Technology

Flexi Radio Base Station (RBS) Performance Analysis of Voice and Trafic on Kota 2 Jakarta Barat Base Station Control (BSC). The CDMA 2000 technology uses circuit switch method to handle voice traffic and packet switch method to handle data traffic between the user and RBS (Radio Base Station). These two parameters can be used to measure performance of the network generally, so it is necessary to optimize them. This paper analyze the performance of RBS by measuring its parameters such as set up failure ratio, drop ratio, and occupancy. Furthermore, the traffic increment is calculated too in order to provide …

Research On Phenol Wastewater Treatment By Electrochemical Oxidation, Tian-Cheng Li, Shen-Lin Zhu

Journal of Electrochemistry

Electrochemical oxidation is an effective technology for the phenol wastewater treatment, and the anode properties are important to the electrochemical oxidationefficiency. The over-potentials of oxygen evolution have been measured for thestainless steel, feasible graphite and SnO₂/Ti anode respectively. Moreover, the synthetic phenol wastewater was treated by the electrochemical oxidation with the stainless steel or feasible graphite anodes. The experimental results showed that the order of the over-potential is SnO₂/Ti > graphite > stainless steel; meanwhile, the COD values of purified water were approaching to or less than 100 mg·L^-1, and the phenol concentrations in the purified …

Influence Of Rare Earth Oxide On The Performance Of Secondary Zinc Electrodes, Xian-Ling Meng, Hua-Bin Yang, Jun-Hong Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

Influence of La(OH)₃ or Ce(OH)₃ in secondary zinc electrode was investigated by the cyclic voltammetry, potentiodynamic polarizationand potentiostatic polarization tests and influence of La₂O₃ or CeO₂ in the charge/discharge performance of Zn/Ni battery was studied by galvanostatic charge/discharge experiment. The results showed that the film of rare earth hydroxide prevented the zincate species from transferring toward solution, enhanced hydrogen overpotential and decreased thecorrosion current density (i_corr), and therefore inhibited zinc corrosion. The potentiostatic polarization results at100mV overpotential showed that La(OH)₃ or Ce(OH)₃ oated on the zinc electrode effectively suppressed the …

Interphase Exchange Coupling In Fe/Sm-Co Bilayers With Gradient Fe Thickness, Ming-Hui Yu, Jason R. Hattrick-Simpers, Ichiro Takeuchi, Jing Li, Z. L. Wang, J. P. Liu, S. E. Lofland, Somdev Tyagi, J. W. Freeland, D. Giubertoni, M. Bersani, M. Anderle

Faculty Publications

We have fabricated Fe∕Sm–Co bilayers with gradient Fe thicknesses in order to systematically study the dependence of exchange coupling on the thickness of the Fe layer. The Fe layer was deposited at two different temperatures (150 and 300°C) to study the effect of deposition temperature on the exchange coupling. Magneto-optical Kerr effect and x-ray magnetic circular dichroism (XMCD) have been employed as nondestructive rapid characterization tools to map the magnetic properties of the gradient samples. Systematic enhancement in exchange coupling between the soft layer and the hard layer is observed as the soft layer thickness is decreased. Separate exchange couplings …

Tunable Multiferroic Properties In Nanocomposite Pbtio3-Cofe2O4 Epitaxial Thin Films, M. Murakami, K.-S. Chang, M. A. Aronova, C.-L. Lin, Ming H. Yu, Jason R. Hattrick-Simpers, M. Wuttig, I. Takeuchi, C. Gao, B. Hu, S. E. Lofland, L. A. Knauss, L. A. Bendersky

Faculty Publications

We report on the synthesis of PbTiO₃–CoFe₂O₄ multiferroic nanocomposites and continuous tuning of their ferroelectric and magnetic properties as a function of the average composition on thin-film composition spreads. The highest dielectric constant and nonlinear dielectric signal was observed at (PbTiO₃)₈₅–(CoFe₂O₄)₁₅, where robust magnetism was also observed. Transmission electron microscopy revealed a pancake-shaped epitaxial nanostructure of PbTiO₃ on the order of 30 nm embedded in the matrix of CoFe₂O₄ at this composition. Composition dependent ferroics properties observed here indicate that there …

Indium Growth On Si(100)-2 X 1 By Femtosecond Pulsed Laser Deposition, M. A. Hafez, M. S. Hegazy, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Indium was grown on Si (100) -2×1 at room temperature by femtosecond pulsed laser deposition. Reflection high-energy electron diffraction (RHEED) was performed in situ to study film morphology and in-plane lattice spacing. Indium was found to grow on Si (100) -2×1 by the Stranski-Krastanov mode. The initial two-dimensional In layer formed in the In-2×1 structure with a lattice constant of 3.65 Å. The full-width at half-maximum (FWHM) of the specular peak decreased during the growth, indicating an increase of the In islands size. Further In growth on the initial In-2×1 layer showed the formation of hexagonal, elongated, and hemispherical islands …

Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto

Makara Journal of Technology

Fuel Injection System for One Cylinder Motor Cycle Engine. Fuel injection has been developed for many years. But its common application is limited on car’s engine. With many reason fuel injection systems in motorcycle one cylinder engine has not been widely used yet. Fuel Injection System allows the amount of fuel, injected to be controlled appropriate to engine parameters such as engine speed, amount of air inducted to cylinder, temperature, for each cycle, over the entire engine operating conditions. This fuel injection research is done to find out the Volumetric Efficiency of the intake manifold system, the amount of fuel …

Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo

Makara Journal of Technology

Influence of Connection Placement to the Behavior of Precast Concrete Exterior Beam-Column Joint. This paper presents an experimental study on the influence of connection placement to the behaviour of exterior beamcolumn joint of precast concrete structure under semi cyclic loading. Four half-scale beam-column specimens were investigated. Three beam-columns were jointed through connection that are placed in beam-column joint region and the forth is connected at the plastic hinge potensial region of the beam. Crack patterns, strength, stiffness and ductility of the test specimens have been evaluated. The test result indicated that all beam-column specimens show good ductility behavior.

Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan

Makara Journal of Technology

Optic Properties on AgGaSe2 Polycristal Fabrication. Polycristal AgGaSe2, is compound (I-III-VI2) a semiconductor as basic material for thin film for solar cell. Polycristal was succesfully grown using Bridgmann Method, heated on sequential temperature treatment until 850°C and cooled down slowly until room temperature. Results observed were in the form of ingot (bars) with more or less 3 cm length and 13 mm in diameter. By using X-Ray Fefraction, composition obtained of each element (weight %) was Ag = 29,3996 %, Ga = 36,8123 % and Se = 30,29 % while using X-Ray Difraction lattice parameter obtained/calculated a = 4,4112 Å, …

Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty

Makara Journal of Technology

Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered Vehicles Flue Gas. Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel soot that can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension of catalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along the catalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic condition based on a kinetic study that …

The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo

Makara Journal of Technology

The Effects of Influent Debit on Hydrodynamic Characteristic of Bojongsoang Facultative Pond: Without Wind Effects. The performance of facultative pond in Bojongsoang WWTP have reported to be unstable. One of the cause of the unstable performance is the hydrodynamic characteristics that not met the criterion. The improper hydrodynamic characteristics are included the existence of dead-zone, the short-circuiting, and the turbulence due to eddy current. The study was to analyze the effect of the influent debit variation on the hydrodynamic characteristics of the pond using mathematical model. The two-dimensional hydrodynamic model was built from two hydrodynamic equations which are continuity and …

Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang

Journal of Electrochemistry

The electrochemical behaviours of DDAB-Hb-PME were studied in this paper. The (apparent) surface concentration of Hb was enhanced greatly by using the powder microelectrode (technique). NO reacts with Hb and absorbs on the surface of the modified carbon powder. Therefore, the output of the electrode was enhanced greatly by employing PME with higher reaction surface (area). The sensitivity of DDAB-Hb-PME is 3.1 mA/μmol·L^-1·cm², which is much larger than the values obtained with the traditional electrodes. The detection limit is 9 nmol·L^-1 and the linear response range is 9～100 nmol·L^-1.

Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma

Journal of Electrochemistry

The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …

Effect Of Fe3+ Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang

Journal of Electrochemistry

Photo-catalytic titanium dioxide film in nano crystalline has been prepared by electrochemical oxidation process and adding different amount of ferric ion into the electrolyte during the anodic oxidation.The effects of Fe³⁺ dopen on absorption spectra and photo-catalytic of the titanium dioxide films have been studied. It shows that the Fe³⁺ dopen caused the red shife of the absorption edge for the incoming light and exhibited the improved photocatalytic reactivity.

Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang

Journal of Electrochemistry

The feasibility of employing aluminum in KOH ethanol solution as a battery anode system was discussed. Weight loss measurement showed that the corrosion rate of Al is low enough to be used in sealed batteries. Through the measurements done by anodic polarization, EIS and galvanostatic discharge, it was found that Al is electrochemical active in a wide potential range in this system, and its discharge mechanism is similar to that of Al in aqueous solution. The discharge potential increased rapidly after a period of time, which might be caused by the discharge products depositing on the electrode surface.

Preparation And Photo-Catalyst Properties Of The α-Fe2O3-Tio2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen

Journal of Electrochemistry

Three new nano thin films of α-Fe₂O_3, TiO₂ and α-Fe₂O₃-TiO₂ by doping their powder with sodium alginate polymer were prepared. Surface structure and catalytic activities of the films were characterized by FTIR, XRD, PL, TEM and I-V techniques. The results of UV-visible absorption showed that the methylene blue was mineralized in aqueous of α-Fe₂O₃/SA, TiO₂/SA and (α-(Fe₂O₃))-TiO₂ /SA upon radiation with ultra violet light. α-Fe₂O₃ enhanced their photo-decolorized-activities by doping 15% TiO₂.

Layer-By-Layer Nanoassembly Combined With Microfabrication Techniques For Microelectronics And Microelectromechanical Systems, Jingshi Shi

Doctoral Dissertations

The objective of this work is to investigate the combination of layer-by-layer self-assembly with microfabrication technology and its applications in microelectronics and MEMS.

One can assemble, on a standard silicon wafer, needed multilayers containing different nanoparticles and polymers and then apply various micromanufacturing techniques to form microdevices with nanostructured elements.

Alternate layer-by-layer self-assembly of linear polyions and colloidal silica at elevated temperatures have been firstly studied by QCM and SEM. LbL self-assembly and photolithography were combined to fabricate an indium resistor. The RTA method was employed in the fabrication. Hot-embossing technique as a reasonably fast and moderately expensive technique was …

Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma, You-Qun Chu, Ying-Hong Zhu, Zhi-Hua Xu

Journal of Electrochemistry

The tungsten carbide (WC) electrode was constructed by using polyterafluoroethylene as binder. The electrochemical behavior of nitrobenzene on the WC electrode in acidic solution was investigated by cyclic voltammetry, linear scan method and chronoamperometry. Experimental results showed that WC electrode had good activity for the electrochemical reduction of nitrobenzene, and the electrode process was controlled by diffusion and electrochemical stepssimultaneously. The apparent active energy of the electrode process is 23.7kJ⋅mol^-1, while the active energy of the electrochemicalstep is 10.91kJ⋅mol^-1.

Solid State Synthesis And Electrocatalysis Of Pt/Moo3 For The Oxidation Of Methanol, Qing Wang, Yi-Ming Zhou, Yang Shao, Yi-Gang Ji, Juan Xu, Ya-Wen Tang, Tian-Hong Lu, Tao Shen

Journal of Electrochemistry

The electrocatalyst, Pt/MoO₃ synthesized by solid state reaction, was used for the oxidation of methanol in direct methanol fuel cells. The X-Ray diffraction and cyclic voltammetry were employed to investigate the performance of the material. It was shown that the typical diffraction peaks for Pt appeared in XRD. And a good electrocatalysis for methanol oxidation was observed. The peak potential of the methanol oxidation appeared at ca. 0.63V(vs.SCE) and the peak current density for the oxidation was 78.1 mA⋅cm^-2.

Study On An Intermediate Temperature Planar Solid Oxide Fuel Cell, Shao-Rong Wang, Wen-Xia Chen, Ting-Lian Wen, Jia-Di Cao, Zhi-Yi Lv, Da-Qian Wang

Journal of Electrochemistry

Tape cast method was applied to prepare green sheets of Ni/YSZ anode supported YSZ thin film. After isostatic pressure treatment and cosintering, the YSZ film on the Ni/YSZ anode was gas-tight dense, and 15~30 μm thick. The area of the composite film was over 100 cm². A Ce_0.8Sm_0.2O_1.9 (CSO) interlayer was sintered on to the YSZ electrolyte film to protect La_0.6Sr_0.4CoO₃ (LSCO) cathode from reaction with YSZ at high temperatures. The LSCO cathode layer was screen printed onto the CSO interlayer and sintered at 1200 ℃ for 3 …

Fabrication Of Solid Oxide Fuel Cells And Analysis Of Their Structure And Performance, Nai-Tao Yang, Bo Meng, Ru-Jun Yu, Xiao-Yao Tan

Journal of Electrochemistry

An intermediate temperature solid oxide fuel cell (IT-SOFC) was fabricated by co-copressing-sintering methods, and the electrolyte of Ce_0.8Gd_0.2O_1.9 (CGO) and cathode materials of La_0.6Sr_0.4Co_0.2Fe_0.8O_3-α (LSCF) were prepared by sol-gel method. The effect of preparation methods on the microstructure of the prepared fuel cells was analyzed by SEM . It shows that the cells prepared by the co-pressing/co-sintering method possess a dense electrolyte layer and a compact interface between electrolyte and anode but a curved configuration, while those prepared by the colloidal technique have a flat configuration …