Bioresource and Agricultural Engineering Commons^™

Techno-Economic Feasibility Of Polyhydroxybutyrate (Phb) Production From Corn Stover, Jey-R Ventura, Ruby Lynn Ventura

The Philippine Agricultural Scientist

This research evaluated the techno-economic feasibility of polyhydroxybutyrate (PHB) production using corn stover as a substrate for the fermentation process. The target PHB plant production was set at 1000 t PHB per yr, with a daily production of about 3 t PHB. The required corn stover biomass was around 12 000 t per yr. The economic analysis of this study suggested that 91.13 M US$ is needed to put up the targeted plant production capacity, with 94% of the total investment to be allotted to the direct fixed capital cost. Annual operating cost was rated at 4.71 M US$ per …

Techno-Economic Feasibility Of Electrifying Food Markets In Nigeria With Biogas Hybrid Mini-Grids, Demi Temitope Ogunwo

Cal Poly Humboldt theses and projects

This thesis explored the feasibility of electrifying a food market in an urban city in Nigeria with a hybrid biogas-powered mini-grid. Under the Energizing Economies Initiative of the Rural Electrification Agency of Nigeria, nine markets in the country currently receive constant access to electricity via hybrid mini-grid systems. As a majority of these systems are diesel-solar-battery systems, this thesis explored the use of biogas generators as a substitute for diesel generators in hybrid mini-grids for food markets. A fruit and vegetable market in Ketu, Lagos was used as a case study for the research. The research for this thesis was …

Exploration Of The Sludge Biodiesel Pathway, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater sludge is an overlooked source of fat, oil, and grease (FOG) that could be converted into biodiesel. The United States produces about 8 million tons of sludge per year. The disposal cost for this amount of sludge is about 2 billion US dollars. The widespread availability and low cost of sludge compared to other biodiesel raw materials make it an economical choice for a renewable fuel. Using sludge as a raw material can produce 25 to 30 mg per gram of fatty acid methyl ester (FAME); the main component of biodiesel. Sludge biodiesel has the potential of transforming a …

Rational Design Of Advanced Functional Materials For Electrochemical Devices, Shun Lu

Electronic Theses and Dissertations

In recent years, there has been a fast-growing trend in developing urea (CO(NH2)2) as a substitute H2 carrier in energy conversion due to its high energy density, nontoxicity, stability, and nonflammability. Urea, a byproduct in the metabolism of proteins and a frequent contaminant in wastewater, is an abundant compound that has demonstrated favorable characteristics as a hydrogen-rich fuel source with 6.7 wt % gravimetric hydrogen content. Also, there is 2-2.5 wt % urea from mammal urine; therefore, 0.5 million ton of additional fuels will be produced per year just from human urine (240 million ton each year). Electrochemical oxidation has …

Biomass-Derived Electrode Materials And Sustainable Processes For Supercapacitors, Katelyn M. Shell

Theses and Dissertations

Biomass is one of the most abundant natural resources and has been used as a source of energy for thousands of years. Biomass as a precursor for energy storage materials is still relatively novel and faces several obstacles before becoming commonly used in today’s electrical devices. Currently, energy storage devices, such as batteries, capacitors, and supercapacitors, utilize petroleum-derived graphitic carbons for anodes, generating a need for more sustainable materials. Biomass, as a carbon-rich source for electrode materials, presents a viable and economically feasible alternative due to the prevalent lignocellulosic compounds: lignin, cellulose, and hemicellulose. Preliminary studies on the solid residues …

Potential Energy Generation From Agricultural Residue In Indonesia, Adrian Rizqi Irhamna

International Programs

Indonesia has great potential of biomass sources from their agricultural residue, which can potentially be used for alternative energy generation. This preliminary research explores the most suitable technology for energy generation from agricultural residue and its challenge for application in Indonesia. The study showed that biomass utilization via the direct combustion process is recommended for energy generation. It is also reported that the pretreatment process of drying and washing, are required to increase the fuel quality and plant efficiency.

Development Of Novel Catalysts For Hydrogen Gas Production From Biomass Compounds, Boanerges Bamaca

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Hydrothermal biomass gasification technologies (sub- and supercritical water gasification and aqueous-phase reforming) have considerable economic, environmental, and technical advantages over other energy-extensive technologies (e.g. natural gas reforming) for hydrogen gas production. However, lack of economically feasible and highly active catalysts is a main challenge that impedes upscaling of these technologies for hydrogen gas production.

The goal of this study was to develop innovative, economically feasible and active heterogeneous supported metal catalysts for hydrothermal processes for producing hydrogen gas from biomass-derived compounds. Because of its stable structure and chemical inertness, graphene was used as catalyst support. Graphene supported metal catalysts were …

Uumanned Aerial Vehicle Data Analysis For High-Throughput Plant Phenotyping, Jiating Li

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

The continuing population is placing unprecedented demands on worldwide crop yield production and quality. Improving genomic selection for breeding process is one essential aspect for solving this dilemma. Benefitted from the advances in high-throughput genotyping, researchers already gained better understanding of genetic traits. However, given the comparatively lower efficiency in current phenotyping technique, the significance of phenotypic traits has still not fully exploited in genomic selection. Therefore, improving HTPP efficiency has become an urgent task for researchers. As one of the platforms utilized for collecting HTPP data, unmanned aerial vehicle (UAV) allows high quality data to be collected within short …

Investigation Of Organic Solvents’ Effects On Kenaf (Hibiscus Cannabinus L.) Biomass Conversion In Subcritical Water, Bahar Meryemoglu, Arif Hasanoglu, Mehtap Kurtulus, Sibel Irmak

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Kenaf biomass was hydrolyzed under subcritical water conditions in the presence of various organic solvents. The solvents tested were tetrahydrofuran (THF), acetone, xylene (mixed isomers) and methanol. The organic compounds released into hydrolysates, total organic contents, water-soluble total phenols, and the molecular weight distributions of the polysaccharides in the hydrolysates, solid residues leftover after hydrolysis and gaseous products formed during the solubilization process were determined. The results showed that organic solvents significantly enhanced the dissolution of kenaf biomass (methanol < (omp)xylene ≤ acetone ~ tetrahydrofuran). The hydrolysis percentage was found to be between 75-82% depending on the type of the solvent. Hydrolysis yield and total organic carbons released into hydrolysates highly differed when the solubilization process was performed under carbon dioxide pressure and this effect considerably varied based on the type of solvent used in hydrolysis process. The main gas product formed during hydrolysis process was carbon dioxide with ~80% composition. Morphological measurements of the solid biomass residues left after hydrolysis showed substantial degradations with increasing number of pores on the biomass surfaces.

Characteristics Of Activated Carbons Produced From Herbaceous Biomass Feedstock, Oluwatosin Jerry Oginni

Graduate Theses, Dissertations, and Problem Reports (ETD)

Energy security and environmental protection are at the forefront of research due to the forecasted depletion of fossil fuel reserves and the growing concern of its adverse environmental impacts. The use of renewable sources for energy applications has centered on the use of biomass feedstocks and this include from herbaceous, woody, agricultural waste, forest residues and municipal wastes. The thermochemical conversion (pyrolysis) of these biomass feedstocks has potential to produce liquid fuel, a solid residue (biochar) and non-condensable gas. The biochar is primarily composed of renewable porous carbon and other inorganic compounds. The biochar is used for soil amendment, adsorption …

Hydraulic Properties Of Baled Switchgrass And Miscanthus, Drew F. Schiavone, Michael D. Montross

Biosystems and Agricultural Engineering Faculty Publications

This study characterized the hydraulic properties within baled switchgrass ( Panicum virgatum L., variety Alamo) and miscanthus (Miscanthus x giganteus), thereby enabling a better understanding of moisture changes in baled biomass during on-farm storage and/or high-solids bioconversion. Fully saturated bales were drained by gravity, and the moisture content was determined over 60 h. The average initial moisture content ranged between 55.9% and 71.9% (w.b.) for switchgrass and between 60.5% and 73.9% (w.b.) for miscanthus bales depending on the dry bale density. As the bale drained by gravity, rapid leaching of water was observed within the first 0.1 h, …

Designing And Development Of A Photobioreactor For Optimizing The Growth Of Micro Algae And Studying Its Growth Parameters, Sarmila Katuwal

Electronic Theses and Dissertations

This thesis presents the estimated value of materials required to grow 1g of biomass and the analysis of the light intensity with respect to flow path and flow rate. This thesis aims to design the sparger for a flat plate Photobioreactor, study the flow patterns at different flow rate of air flow and check the performance of flat plate PBR by growing the cyanobacteria. The estimated value to produce 1g of biomass (C_44.6H₇O₂₅N_7.68P_0.9S_0.3) was 0.099g of N, 0.493g of C, 0.160 g of Na, 0.026 g of P, …

Development Of Heterogeneous Catalysts For Upgrading Biomass Pyrolysis Bio-Oils Into Advanced Biofuels, Shouyun Cheng

Electronic Theses and Dissertations

The massive consumption of fossil fuels and associated environmental issues result in an increased interest in alternative resources such as biofuels. The renewable biofuels can be upgraded from bio-oils that are derived from biomass pyrolysis. Catalytic cracking and hydrodeoxygenation (HDO) are two most promising bio-oil upgrading techniques for biofuel production. Heterogeneous catalysts are essential for upgrading bio-oil into hydrocarbon biofuel. Although some progresses have been made, the cost and effectiveness of catalysts still remain challenges. The main objective of this study was to develop efficient heterogeneous catalysts for upgrading bio-oils into advanced hydrocarbon biofuel with low costs. In catalytic cracking, …

Enzymatic Liquefaction Of Untreated Corn Stover, Neal N. Hengge

Open Access Theses

There is an ever increasing need for renewable alternatives to fossil fuels derived from petroleum. This makes feedstocks in the form of lignocellulosic biomass attractive substrates for the production of ethanol and value added chemicals. However, the economics of converting lignocellulosic materials involve high processing costs attributed with pretreatment of the biomass and the use of enzymes for saccharification. Corn stover was obtained for the examination of an upstream processing step to transform the material into a pumpable slurry for subsequent pretreatment and saccharification. Biomass liquefaction was carried out using the enzyme Depol 692L (Biocatalysts, Wales, UK) at 50°C with …

On-Farm Integrated High-Solids Processing System For Biomass, Sue E. Nokes, Bert C. Lynn, Stephen E. Rankin, Barbara L. Knutson, Michael D. Montross, Michael D. Flythe

Biosystems and Agricultural Engineering Faculty Patents

A method for on-farm processing a biomass feedstock into a useful industrial chemicals includes the steps of (a) delignifying the biomass feedstock to produce a delignified biomass, (b) subjecting the deliguified biomass to cellulase production, (c) subjecting the deliguified biomass with attached cellulase to simultaneous cellulolytic and solventogenic reactions to produce useful industrial chemicals (d) collecting and separating the useful industrial chemical from the fermentation broth and (e) collecting the fermentation residues.

Minimizing Ethanol Concentration In Organosolv Pretreatment For The Saccharification Of Loblolly Pine, Nelson B. Heringer

Biological and Agricultural Engineering Undergraduate Honors Theses

Organic solvent pretreatment, commonly known as organosolv, is a method used to prepare biomass for enzymatic hydrolysis for the production of biofuels. This method common uses ethanol as the organic solvent. However, this creates an economic issue with the product stream, as ethanol becomes a product and input. This project sought to explore how decreasing the use of ethanol in organosolv pretreatment affected the recoverability of sugars after enzymatic hydrolysis. Loblolly pine (Pinus taeda L.) was pretreated at 170 °C for 60 minutes in 1% dilute sulfuric acid and an ethanol concentration varying from 65% to 35%. Compositional …

Experimental Investigation Of Fast Pyrolysis Of Arundo Donax In A Novel Paddle Reactor, Chintan Desai

Dissertations, Master's Theses and Master's Reports

The main objective of this research was to show the effectiveness of a novel paddle reactor for fast pyrolysis and study the effect of biomass particle size and reaction temperature of Arundo Donax a type of energy crop on the bio-oil yields. The novel paddle reactor showed effective mixing and heat transfer which were proved with the help of studying the residence time and the heating characteristics of the system respectively. The effect of different biomass particle sizes on the bio-oil yield was not significant, the bio-oil yield was approximately 50% for all the sizes. For Arundo Donax particle sizes …

Design Of Transgenic S. Cerevisiae For Enzymatic Pretreatment, Mark Aronson, Leyla Yamin, Soo Jung Ha, Jenna Rickus, Michael E. Scharf

The Summer Undergraduate Research Fellowship (SURF) Symposium

Biofuels, combustible fuel produced from fermentation of agricultural biomass by microorganisms, represent one of the best possible paths forward for sustainable energy production. However, inefficiencies in biofuel production create barriers that stand in the way of their widespread adoption. One such barrier is the breakdown of lignin, a biopolymer that exists on the edge of plant cell walls which protects the sugars that are used in fermentation. Currently, lignin is broken down in energy-intensive thermal pretreatment processes. A viable alternative is the expression of lignin-degrading enzymes by synthetic microorganisms that work at standard temperatures, eliminating the need for the high-energy …

The Bifunctional Alcohol And Aldehyde Dehydrogenase Gene, Adhe, Is Necessary For Ethanol Production In Clostridium Thermocellum And Thermoanaerobacterium Saccharolyticum, Jonathan Lo, Tianyong Zheng, Shuen Hon, Daniel G. Olson, Lee Lynd

Dartmouth Scholarship

Thermoanaerobacterium saccharolyticum and Clostridium thermocellum are anaerobic thermophilic bacteria being investigated for their ability to produce biofuels from plant biomass. The bifunctional alcohol and aldehyde dehydrogenase gene, adhE, is present in these bacteria and has been known to be important for ethanol formation in other anaerobic alcohol producers. This study explores the inactivation of the adhE gene in C. thermocellum and T. saccharolyticum. Deletion of adhE reduced ethanol production by >95% in both T. saccharolyticum and C. thermocellum, confirming that adhE is necessary for ethanol formation in both organisms. In both adhE deletion strains, fermentation products shifted from ethanol …

Determining Soil Erosion With Varying Corn Stover Cover Factors, Nicole K. Koeninger

Theses and Dissertations--Biosystems and Agricultural Engineering

Since the Dust Bowl, conservation agriculture has become a common practice globally. Because of the rising interest in the use of corn biomass as a feedstock for biofuel production, the effects of corn stover removal on soil erosion were explored. It was hypothesized that selective harvesting strategies would impact soil erosion differently across a variety of slopes. Soil erosion boxes were constructed, and a rainfall simulator with an intensity of 30 mm hr^-1 for 46 min was used to create runoff from slopes of 1, 5, and 10% and three cover factor treatments (no removal and two simulated corn …

Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith

Theses and Dissertations--Biosystems and Agricultural Engineering

Biochars have been created and characterized from a variety livestock manure biomass including poultry, dairy, and swine. However, no research has been conducted on the physical and chemical makeup of biochar pyrolyzed from horse muck. Two horse muck derived biochars containing either straw (HS) or woodchip (HW) bedding were pyrolyzed at 700°C and characterized for their physical and chemical properties. Tests revealed both biochars had high alkalinity, moderate specific conductivity, and low surface area as compared to other biochars in the literature. HS contained more mineral structures than HW. Scanning electron microscopy presented differences in particle shape, size, and presence …

Characterization Of Genetically Modified High Biomass Producing Tobacco Plant, Pankaj Singh Kuhar

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Global warming and peak oil has clouded our energy security. In light of this situation, bioethanol as emerged as one of the most amenable solutions to the problem. However bioethanol has its own shortcomings and transgenics seem imperative to exploit its full potential. A high biomass producing line in transgenic tobacco (Nicotiana tabacum cv. Xanthi) was identified during a routine genetic transformation, termed giant recombinant (GR). To characterize the phenotype of the giant line, growth rate and lignocellulosic composition was analyzed relative to the non-transgenic control line. The GR line accounted for 240% more biomass than the untransformed line …

Comparative Efficiency And Driving Range Of Light- And Heavy-Duty Vehicles Powered With Biomass Energy Stored In Liquid Fuels Or Batteries, Mark Laser, Lee R. R. Lynd

Dartmouth Scholarship

This study addresses the question, "When using cellulosic biomass for vehicular transportation, which field-to-wheels pathway is more efficient: that using biofuels or that using bioelectricity?" In considering the question, the level of assumed technological maturity significantly affects the comparison, as does the intended transportation application. Results from the analysis indicate that for light-duty vehicles, over ranges typical in the United States today (e.g., 560-820 miles), field-to-wheels performance is similar, with some scenarios showing biofuel to be more efficient, and others indicating the two pathways to be essentially the same. Over the current range of heavy-duty vehicles, the field-to-wheels efficiency is …

Design And Use Of An Adjustable Clearance Flailing Knife Biomass Shredder To Mechanically Increase Particle Surface Area, Shawn Gregory Ehlers

Open Access Theses

A flailing knife shredder was designed and tested as an alternative to a hammermill for processing biomass. The machine was comprised of two cylinders with four rungs, each with five free-swinging blades. Each of the two cylinders had adjustable clearance hoods and variable speed drives. Energy usage, output characteristics and device capacities were compared with corn stover processed at moisture contents (MC) of 10%, 35% and 50% wet basis (WB). The hammermill produced a more uniform particle size distribution in comparison to the shredder. Accessibility, indicated by conductivity index, to plant constituents, revealed that the method of treatment was not-significant …

Qualitative And Quantitative Analysis Of Lignocellulosic Biomass Using Infrared Techniques: A Mini-Review, Feng Xu, Jianming Yu, Tesfaye Tesso, Floyd Dowell, Donghai Wang

United States Department of Agriculture-Agricultural Research Service / University of Nebraska-Lincoln: Faculty Publications

Current wet chemical methods for biomass composition analysis using two-step sulfuric acid hydrolysis are time-consuming, labor-intensive, and unable to provide structural information about biomass. Infrared techniques provide fast, low-cost analysis, are non-destructive, and have shown promising results. Chemometric analysis has allowed researchers to perform qualitative and quantitative study of biomass with both near-infrared and mid-infrared spectroscopy. This review summarizes the progress and applications of infrared techniques in biomass study, and compares the infrared and the wet chemical methods for composition analysis. In addition to reviewing recent studies of biomass structure and composition, we also discuss the progress and prospects for …

The Economics And Logistics Of The Dual Harvest Of Grain And Biomass In A Single-Pass, Matthew T. Wold

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Significant interest has developed in using cellulosic resources, especially crop residues, to create biofuels. Collecting these residues in a single-pass of the harvester across the field has the potential to be a low cost option. Two models have been developed; the first characterizes the in-field logistics of single-pass crop residue collection, the second the economics. These models allow the user to easily examine a wide variety of both grain-only and single-pass residue collection harvest cases. A variety of possible residue collection cases have been examined, and their effects both on harvester field capacity and harvest cost compared to grain-only harvest …

Economic And Environmental Sustainability Of Using Bio-Fuels For Small Nebraska Greenhouses, David M. Mabie

Department of Environmental Engineering: Theses and Other Student Research

The primary goal of this paper was to increase profitability in Nebraska greenhouses by using biomass fuels for heating instead of propane. Several different fuels were tested, including whole shelled corn, dry distiller’s grains pelletized, wood pellets and blends between each biomass. The main fuel focus was on whole shelled corn. Bomb calorimetry tests were performed on biomass fuels and their respective ashes. Several furnace and heat exchanger efficiency tests were performed, with cost effectiveness analysis for each fuel type. Emissions data was also collected for each fuel on carbon monoxide, carbon dioxide, nitrous oxides, sulfuric oxides, and particulate matter. …

Corn Stover Availability And Collection Efficiency Using Typical Hay Equipment, Robert M. Prewitt, Michael D. Montross, Scott A. Shearer, Timothy S. Stombaugh, Stephen F. Higgins, Samuel G. Mcneill, Shahab Sokhansanj

Biosystems and Agricultural Engineering Faculty Publications

Corn stover has been identified as a potential feedstock for the production of fermentable sugars and thermochemical processes. The availability and efficiency of typical hay equipment for collecting corn stover has not been well quantified. Corn stover was collected for two years on a central Kentucky farm near Louisville. Six different harvesting treatments, using traditional hay equipment, were used to harvest corn stover. A rotary mower, rotary scythe (flail-type mower with windrow-forming shields), parallel bar rake, and a round baler were utilized. The average stover moisture content prior to grain harvest was above 40%, and field drying was required before …

Economic Analysis Of Cellulase Production Methods For Bio-Ethanol, Jun Zhuang, Mary A. Marchant, Sue E. Nokes, Herbert J. Strobel

Biosystems and Agricultural Engineering Faculty Publications

The cost of cellulase enzymes has limited the feasibility of producing ethanol from fibrous biomass. Traditional submerged fermentation (SmF) was compared to an alternative method of producing cellulase, solid state cultivation (SSC). Results from an economic analysis indicated that the unit costs for cellulase enzyme production were $15.67 (The prices are all 2004 prices in this article, except otherwise stated. We deflated newer prices to 2004 prices using a deflation factor 0.9 per year and inflated older prices to 2004 prices using an inflation factor 1.1.) per kilogram ($/kg) and $40.36/kg, for the SSC and SmF methods, respectively, while the …

Effect Of Stover Fraction On Glucose Production Using Enzymatic Hydrolysis, Czarena L. Crofcheck, Michael D. Montross

Biosystems and Agricultural Engineering Faculty Publications

Corn stover was fractionated into three fractions: cobs, stalks, and leaves and husks. The fractions were dried and ground through a 2 mm screen. Samples of the three fractions and whole corn stover with and without NaOH pretreatment were subjected to enzymatic hydrolysis in order to determine the effect of fractionation on glucose production. The average amounts of glucose released after 60 h of hydrolysis from pretreated cobs, leaves and husks, stalks, and whole stover were 0.50, 0.36, 0.28, and 0.36 g/g dry biomass, respectively. The average amounts of glucose released after 60 h of hydrolysis from nonpretreated cobs, leaves …