Bioresource and Agricultural Engineering Commons^™

Microbial Reduction Of Uranium Under Iron- And Sulfate-Reducing Conditions: Effect Of Amended Goethite On Microbial Community Composition And Dynamics, H.S. Moon, L. Mcguinness, Ravi K. Kukkadapu, A.D. Peacock, John Komlos, L.J. Kerkhof, P.E. Long, Peter R. Jaffe

United States Department of Energy: Publications

There is a growing need for a better understanding of the biogeochemical dynamics involved in microbial U(VI) reduction due to an increasing interest in using biostimulation via electron donor addition as a means to remediate uranium contaminated sites. U (VI) reduction has been observed to be maximized during iron-reducing conditions and to decrease upon commencement of sulfate-reducing conditions. There are many unknowns regarding the impact of iron/sulfate biogeochemistry on U(VI) reduction. This includes Fe(III) availability as well as the microbial community changes, including the activity of iron-reducers during the uranium biostimulation period even after sulfate reduction becomes dominant. Column experiments …

Confinement Resonances In Photoionization Of Xe@C+60, A. L. D. Kilcoyne, A. Aguilar, A. Muller, S. Schippers, C. Cisneros, G. Alna’Washi, N. B. Aryal, K. K. Baral, D. A. Esteves, C. M. Thomas, R. A. Phaneuf

United States Department of Energy: Publications

Experimental evidence is presented for confinement resonances associated with photoabsorption by a Xe atom in a C₆₀ cage. The giant 4d resonance in photoionization of Xe is predicted to be redistributed into four components due to multipath interference of photoelectron waves reflected by the cage. The measurements were made in the photon energy range 60–150 eV by merging a beam of synchrotron radiation with a mass/charge selected Xe@C⁺₆₀ ion beam. The phenomenon was observed in the Xe@C³⁺₅₈ product ion channel.

Valence-Shell Photoionization Of The Chlorinelike Ca3+ Ion, Ghassan A. Alna’Washi, M. Lu, M. Habibi, R. A. Phaneuf, A. L. D. Kilcoyne, A. S. Schlachter, C. Cisneros, B. M. Mclaughlin

United States Department of Energy: Publications

Absolute photoionization measurements were performed for a mixture of ²P^o_3/2 ground-state and ²P^o_1/2 metastable-state Ca³⁺ ions over the photon energy range 65.7–104.6 eV by merging an ion beam with a beam of monochromatized synchrotron radiation. The ionization threshold energy of the ²P^o_3/2 ground state was measured to be 67.063 ± 0.015 eV, which is 0.207 eV lower than the value tabulated in the NIST database. Most of the observed resonances associated with multiple Rydberg series of autoionizing states have been assigned spectroscopically using the quantum defect form of the Rydberg …

Nebraska Water And Energy Flux Measurement, Modeling, And Research Network (Nebflux), Suat Irmak

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Surface energy and water vapor fluxes play a critical role in understanding the response of agro‐ecosystems to changes in environmental and atmospheric parameters. These fluxes play a crucial role in exploring the dynamics of water and energy use efficiencies of these systems. Quantification of the fluxes is also necessary for assessing the impact of land use and management changes on water balances. Accomplishing these goals requires measurement of water vapor and energy exchanges between various vegetation surfaces and microclimates for long‐enough periods to understand the behavior and dynamics involved with the flux transfer so that robust models can be developed …

Testing Of Interactions Between Coal Ash Leachates And Rock Materials For Mine Backfill Evaluations, Colin R. Ward, David French, Leanne Stephenson, Ken Riley, Zhongsheng Li

Coal Combustion and Gasification Products Journal Archive

A series of laboratory-based leaching tests has been developed to evaluate the chemical interaction between ash, water and different mine-site rock materials, as a basis for assessing the potential environmental impact of using coal ash as backfill in coal mines. Two different test protocols were used: a two-stage serial batch testing program in which leachate from representative ash samples were allowed to interact separately with relevant rock materials under laboratory conditions, and a single-stage mixed batch testing program in which 50:50 mixtures of the same ashes and rock samples were extracted with water following a similar procedure to leaching tests …

Laboratory Performance Of A Mass Flow Sensor For Dry Edible Bean Harvesters, Rodrigo S. Zandonadi, Timothy S. Stombaugh, Scott A. Shearer, Daniel M. Queiroz, Michael P. Sama

Biosystems and Agricultural Engineering Faculty Publications

Due to the importance of yield monitoring, researchers have been developing systems for crops such as tomatoes, forage, sugar cane, citrus, and coffee. A yield monitoring system for pull type dry edible beans harvester has not yet been developed. The goal of this project was to design and test a drive torque measurement device on a clean grain bucket elevator of a dry bean harvester, and evaluate its potential to be used as a mass flow sensor. Tests were conducted in the Yield Monitor Test Facility (YMTF) of University of Kentucky following the recommendation of ASABE Standard S578 (2007) The …

Handbook Of Bioentrepreneurship (Book Review), Joseph R. Bell

New England Journal of Entrepreneurship

Book review by Joseph R. Bell.

Patzelt, Holger and Thomas Brenner, eds. Handbook of Bioentrepreneurship. New York: Springer, 2008. ISBN 9780387483436

The Handbook of Bioentrepreneurship represents volume 4 in the International Handbook Series on Entrepreneurship.This book is a collection of articles covering the rapidly evolving biotechnology industry.

Chemistry Of Coal And Coal Combustion Products From Kentucky Power Plants: Results From The 2007 Sampling, With Emphasis On Selenium, James C. Hower, Thomas L. Robl, Gerald A. Thomas, Shelley D. Hopps, Margaret Grider

Coal Combustion and Gasification Products Journal Archive

Kentucky produced over 8 Mt of coal combustion products (CCPs) in 2006, with 30% of the CCPs being utilized, a significant increase from our 1996 and 2001 surveys. As much of the increase is related to increased utilization of flue-gas desulfurization (FGD) gypsum, the increased production of FGD gypsum coincident with the commissioning of new FGD units and the saturation of the (currently) weak market for new construction, the percentage of utilization may decrease by the time of the next planned survey (2011). The concentration of volatile trace elements in the feed coal and in the pulverizer reject, while associated …

An Investigation Of The Behavior Of Raw Calcareous Fly Ash In Mortar Mixtures, Ioanna Papayianni, Eleftherios K. Anastasiou

Coal Combustion and Gasification Products Journal Archive

The behavior of unprocessed calcareous fly ash in cement mortar mixtures is often questionable and unpredictable and that is one of the difficulties in confining these fly ashes within the limits of standards. This work aims at correlating the material characteristics with its behavior in mortar mixtures. An effort is made to understand how three of the reactive constituents; lime (CaO), silica (SiO2), and sulfates (SO3), affect strength and volume stability. Two raw calcareous fly ashes of different composition emanating from the Ptolemaida area, Greece, were systematically tested to define their profile as cementitious agents that could be incorporated in …

Coal Fired Power Station Ash Products And Eu Regulation, Lindon K.A. Sear

Coal Combustion and Gasification Products Journal Archive

The UK has a long history of the use of coal fired power station ash products in a range of applications in construction. These range from use in concrete as a cementitious material through to its use as a fill material in embankments. While there have been no environmental problems associated with these uses, environmental regulations emanating from the European Union (EU) are increasingly impacting on the use of these materials. Unfortunately it is not a single set of regulations that are being applied, but three separate and apparently disconnected initiatives; these are Registration, Evaluation and Authorisation of Chemicals (REACH), …

Enriched Coal Ash Utilization For Augmenting Production Of Rice Under Acid Lateritic Soil, S. Karmakar, B.N. Mittra, B.C. Ghosh

Coal Combustion and Gasification Products Journal Archive

The use of industrial wastes such as fly ash (FA) or rice husk ash (RHA), along with paper factory sludge (PFS), farmyard manure (FYM), and chemical fertilizers (CF), under integrated nutrient management, was studied in acid lateritic soil on rice. Application of combined fertilization sources increased growth, yield attributes, and yield (up to 92.3 and 9.7% over control and CF, respectively) of wet season rice. The uptake of N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, and Co was increased under combined fertilization sources. The study also indicated that such integrated plant nutrition system improved physico-chemical properties of soil …

Erosive Wear In Pipelines At Pneumatic Conveying Of Fine Silicon-Containing Materials, Viacheslav Y. Putilov, Vijay K. Agarwal, Irina V. Putilova

Coal Combustion and Gasification Products Journal Archive

Erosive wear is a major operational problem in conveying of hard abrasive bulk materials like silica sand, fly ash, coal dust, etc., in pneumatic conveying systems. Erosion results in emergency downtime of pneumatic conveying installations of ash and slag removal and dust-preparation systems at TPPs caused by holes in pipelines. That leads to worsening of technical, economic, and ecological parameters of thermal power plants as a whole. In MPEI, a model of estimating erosion of rectilinear and curvilinear sections of pneumatic conveying pipelines has been developed. To validate the estimating model developed in the MPEI, experimental investigations in the Indian …

Evaluation Of The Variables That Influence Mercury Capture In Solid Sorbents, M. Antonia Lopez-Anton, Patricia Abad-Valle, Mercedes Diaz-Somoano, M. Rosa Martinez-Tarazona

Coal Combustion and Gasification Products Journal Archive

Newly obtained results on mercury retention in fly ashes and activated carbons during coal combustion are compared with previous findings. The influence of different variables on mercury capture, including the composition and nature of the sorbents, the composition of the flue gas and the mercury species in gas phase is investigated. Coal-fired utility boilers are currently the largest single-known source of mercury emissions. According to the USEPA’s Information Collection Request (ICR), on average, only 40% of the mercury entering a coal-fired power plant is captured, while 60% is emitted into the atmosphere. Several solid materials, including activated carbons, are considered …

Mechanical Performance Of Pavement Geomaterials Stabilized With Fly Ash In Field Applications, Lin Li, Tuncer B. Edil, Craig H. Benson

Coal Combustion and Gasification Products Journal Archive

This paper describes an evaluation of the mechanical performance of fly ash stabilized materials. Soft clay soil, asphaltic recycled pavement material (RPM), and road-surface gravel (RSG) were stabilized using Class C and off-specification fly ashes to create working platforms or stabilized base courses for construction of flexible and rigid pavements at six sites in Wisconsin and Minnesota. California bearing ratio (CBR), resilient modulus (Mr) tests, and unconfined compression (qu) tests were conducted on the subgrade soil, RPM, and RSG alone and on mixtures prepared in the field and the laboratory to evaluate improvements in bearing resistance and stiffness. Fly ash …

Manufactured Coal Ash Aggregates For Aqueous Tnt Sorption, Sangchul Hwang, Victor Hernandez

Coal Combustion and Gasification Products Journal Archive

No abstract provided.

Mineralogy And Leaching Characteristics Of Coal Ash From A Major Brazilian Power Plant, Luis F.O. Silva, Colin R. Ward, James C. Hower, Maria Izquierdo, Frans Waanders, Marcos L.S. Oliveira, Zhongsheng Li, Rachel S. Hatch, Xavier Querol

Coal Combustion and Gasification Products Journal Archive

The feed coals, fly ashes and bottom ashes collected from seven different units in a major Brazilian PF power plant have been subjected to comprehensive mineralogical, geochemical, and petrographic studies, to investigate the links between feed coal and ash characteristics. Ashes from two of the units were collected while the coal was being co-fired with oil as part of the boiler start-up procedure, allowing the impact of oil co-firing on ash characteristics also to be evaluated. High proportions of unburnt carbon and high proportions of retained sulphur were found in the fly ashes produced during oil co-firing, probably reflecting less …

Precipitation Of Germanium From Coal Fly Ash Leachates, Fatima Arroyo, Constantino Fernandez-Pereira, Pilar Coca

Coal Combustion and Gasification Products Journal Archive

The valorization of a coal gasification fly ash was studied by leaching the fly ash using different aqueous solutions followed by the subsequent precipitation of the germanium solubilized from the ash. Experimental investigations were focused on the precipitation of a germanium2catechol (CAT) complex with cetyl trimethyl ammonium bromide (CTAB). The influences of pH and amounts of CTAB and CAT on the precipitation yield were investigated. To this aim, a central composite rotatable design and ANOVA Design Expert 7.0.3 Wiley software were employed for experimental design and analysis of the results. Thus, the independent and combined effects of pH, CAT/Ge and …

The Effect Of Drag-Reducing Additives On The Rheological Properties Of Fly Ash-Water Suspensions At Varying Temperature Environment, H.K. Naik, M.K. Mishra, Rao Karanam U.M.

Coal Combustion and Gasification Products Journal Archive

Fly ash transportation and disposal is a major problem in India. Presently fly ash is being transported as lean slurry in pipe lines requiring about 80 to 85% of water which, in turn, consumes more energy input. The objective of the present study is to evaluate the rheological characteristics of fly ash slurry at varying temperatures with and without an additive to facilitate smooth flow in the pipelines. Six fly ash slurry samples were prepared from the fly ash obtained from a thermal power plant situated in the southern part of India. The main constituents of the slurry were fly …

Waste Stabilization/Solidification (S/S) Of Eaf Dust Using Fly Ash-Based Geopolymers. Influence Of Carbonation On The Stabilized Solids, Y. Luna Galiano, C. Fernandez Pereira, J. Vale

Coal Combustion and Gasification Products Journal Archive

The effect of the curing in a carbonated ambient of the solids obtained after the stabilization/solidification (S/S) of metallurgical waste using geopolymerization technology is described in this paper. The electric arc furnace (EAF) dust to stabilize contains hazardous metals such as Pb, Cd, Cr, or Zn. Different geopolymeric agents such as potassium hydroxide, potassium silicate, metakaolin, and blast furnace slag have been used. Mixtures of EAF waste with these geopolymeric materials and class F fly ash as main silica and alumina source have been processed. Samples were submitted to an accelerated carbonation test. Compressive strength tests and different leaching tests …

Variations In Fly Ash Composition With Sampling Location: Case Study From A Portuguese Power Plant, B. Valentim, A. Guedes, D. Flores, C.R. Ward, J.C. Hower

Coal Combustion and Gasification Products Journal Archive

Fly ash (FA) is a heterogeneous and complex material resulting from coal combustion in thermoelectric power plants (TPP). Therefore, different types of coals, worldwide, produce FAs with different compositions. However, the location of the FA sampling system, inside the TPP, is also important to the composition of the FA produced at each location. A case study of FA from a Portuguese TPP, using several coal and FA characterization techniques (particle size analysis, proximate and ultimate analyses, XRF, SEM/ESEM/EDS, Optical microscopy, XRD, inferred chemistry, and AAS), has shown that FA chemical classification, mineralogy and phase-mineral classification, and trace elements (Cr, Cu, …

Zeolite Synthesised From Fused Coal Fly Ash At Low Temperature Using Seawater For Crystallization, Claudia Belviso, Francesco Cavalcante, Antonio Lettino, Saverio Fiore

Coal Combustion and Gasification Products Journal Archive

A sample of coal fly ash from an Italian thermoelectric power plant was used in order to synthesize zeolite by hydrothermal activation after a pre-treatment fusion with NaOH. The experiments involved were performed at different temperatures of crystallization, ranging from 35 up to 60uC, with seawater and distilled water, separately, during hydrothermal process. A comparison between the results obtained from the use of the different kinds of water showed that at low temperature (35–40 uC) the synthesis yield of zeolite X is higher using seawater as crystallizing agent than using distilled water. This implies a possible application for seawater in …

Low-Cost Obstacle Detection Sensor Array For Unmanned Agricultural Vehicles, Santosh Pitla, Joe D. Luck, Scott A. Shearer

Department of Agricultural and Biological Systems Engineering: Presentations and White Papers

Mobile robots deployed for agricultural applications must operate in harsh environments where they encounter a variety of both moveable and immovable obstacles. Typically, robots utilize vision sensors to learn about the environment in which they are working. In this study, a low-cost infra-red (IR) sensor array was developed to act as an obstacle detection aid for an unmanned agricultural vehicle (UAgV). The IR sensor array developed consists of six IR sensors mounted on two orthogonal steel plates. The array of sensors was continuously oscillated about the yaw-axis to traverse a 200° field of view in front of the UAgV. Three …

2010 Nebraska Water Monitoring Programs Report, Marty Link

Nebraska Department of Environmental Quality: Reports

The Nebraska Department of Environmental Quality (NDEQ) is charged with monitoring, assessing, and to the extent possible, managing the state’s water resources. The purpose of this work is to protect and maintain good quality water and encourage or execute activities to improve poor water quality. Monitoring is done on the over 18,000 miles of flowing rivers and streams, our greater than 280,000 acres of surface water in lakes and reservoirs, and the vast storage of groundwater in Nebraska’s aquifers.

Validation Of A Model For Static And Dynamic Recrystallization In Metals, Arthur Brown, Douglas Bammann

United States Department of Energy: Publications

In this paper, modifications are proposed to a phenomenological plasticity model to account for the evolution of recrystallization and the resultant softening behavior. The novel model includes internal state variables representing dislocation density and the spacing between geometrically necessary subgrain boundaries. In order to capture both single and multiple peak recrystallization, the model tracks the evolution of recrystallized volume fractions for multiple cycles of recrystallization, and has a set of state variables for each volume fraction. A rule of mixtures is used to determine the average stress. The model is capable of capturing static recrystallization as well as both single …

Fractionation Of Oxygen Isotopes In Phosphate During Its Interactions With Iron Oxides, Deb P. Jaisi, Ruth E. Blake, Ravi K. Kukkadapu

United States Department of Energy: Publications

Iron (III) oxides are ubiquitous in near-surface soils and sediments and interact strongly with dissolved phosphates via sorption, co-precipitation, mineral transformation and redox-cycling reactions. Iron oxide phases are thus, an important reservoir for dissolved phosphate, and phosphate bound to iron oxides may reflect dissolved phosphate sources as well as carry a history of the biogeochemical cycling of phosphorus (P). It has recently been demonstrated that dissolved inorganic phosphate (DIP) in rivers, lakes, estuaries and the open ocean can be used to distinguish different P sources and biological reaction pathways in the ratio of ¹⁸O/¹⁶O (δ¹⁸O …

Role Of Outer-Membrane Cytochromes Mtrc And Omca In The Biomineralization Of Ferrihydrite By Shewanella Oneidensis Mr-1, C. L. Reardon, Alice Dohnalkova, P. Nachimuthu, David Kennedy, D. A. Saffarini, B. W. Arey, L. Shi, Zheming Wang, D. Moore, J. S. Mclean, D. Moyles, M. J. Marshall, John M. Zachara, James K. Fredrickson, A. S. Beliaev

United States Department of Energy: Publications

In an effort to improve the understanding of electron transfer mechanisms at the microbe–mineral interface, Shewanella oneidensis MR-1 mutants with in-frame deletions of outer-membrane cytochromes (OMCs), MtrC and OmcA, were characterized for the ability to reduce ferrihydrite (FH) using a suite of microscopic, spectroscopic, and biochemical techniques. Analysis of purified recombinant proteins demonstrated that both cytochromes undergo rapid electron exchange with FH in vitro with MtrC displaying faster transfer rates than OmcA. Immunomicroscopy with cytochrome-specific antibodies revealed that MtrC co-localizes with iron solids on the cell surface while OmcA exhibits a more diffuse distribution over the cell surface. After 3-day …

Hydraulic Geometry Relationships And Regional Curves For The Inner And Outer Bluegrass Regions Of Kentucky, Ruth Roseann Brockman

University of Kentucky Master's Theses

Hydraulic geometry relationships and regional curves are used in natural channel design to assist engineers, biologists, and fluvial geomorphologists in the efforts undertaken to ameliorate previous activities that have diminished, impaired or destroyed the structure and function of stream systems. Bankfull channel characteristics were assessed for 14 United States Geological Survey (USGS) gaged sites in the Inner Bluegrass and 15 USGS gaged sites in the Outer Bluegrass Regions of Kentucky. Hydraulic geometry relationships and regional curves were developed for the aforementioned regions.

Analysis of the regression relationships showed that bankfull discharge is a good explanatory variable for bankfull parameters such …

Testing Fuel Efficiency Of Tractors With Both Continuously Variable And Standard Geared Transmissions, Christopher N. Howard

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

A John Deere 8295R IVT tractor with a continuously variable transmission (CVT) and a John Deere 8295R PowerShift (PST) tractor (Waterloo, Iowa) with a standard geared transmission (GT) were tested for fuel consumption at three different travel speeds with six different load levels applied per speed. The JD 8295R PST tractor was tested both at full throttle (FT) and shifted up two gears and throttled back (SUTB) to achieve the same travel speed as at full throttle conditions. The three speeds tested corresponded to the maximum speeds achieved in 6th, 8th and 10th gear for the JD 8295R PST tractor …

Nebraska Agricultural Water Management Demonstration Network (Nawmdn): Integrating Research And Extension/Outreach, Suat Irmak, Jennifer M. Rees, Gary L. Zoubek, Brandy S. Van Dewalle, William R. Rathje, Rodney Debuhr, Dan Leininger, Darrel D. Siekman, James W. Schneider, Andrew P. Christiansen

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Maximizing the net benefits of irrigated plant production through appropriately designed agricultural water management programs is of growing importance in Nebraska, and other western and Midwestern states, because many areas are involved in management and policy changes to conserve irrigation water. In Nebraska, farmers are being challenged to practice conservation methods and use water resources more efficiently while meeting plant water requirements and maintaining high yields. Another challenge Nebraska experiences in it's approximately 3.5‐million‐ha irrigated lands is limited adoption of newer technologies/tools to help farmers better manage irrigation, conserve water and energy, and increase plant water use efficiency. In 2005, …

Water And Nutrient Balances Of Vegetative Treatment Systems For Feedlots In South Dakota, Daniel T. Ostrem

Electronic Theses and Dissertations

Vegetative treatment systems (VTS) are a possible alternative to storage basins for managing feedlot runoff but have not been researched in South Dakota. This study was conducted to evaluate the performance of VTS within South Dakota. The performance was evaluated by determining water and mass balances on each vegetative treatment area (VTA). The balances were determined by measuring all inflow, outflow, evapotranspiration, precipitation, and both soil and water nutrient concentrations within the VTA. Twelve site years have been completed in researching VTS from four feed lots in South Dakota. Seven of the twelve site-years VTS were able to prevent water …