Engineering Commons^™

Microwave-Assisted Carbon Nanotube Growth From Methane On Surface Catalyst Exsolving Perovskite Oxide, Angela M. Deibel

Graduate Theses, Dissertations, and Problem Reports (ETD)

The novel method of using a perovskite exsolution catalyst, strontium titanium nickel oxide (STNO), proved capable of simultaneously producing carbon nanotubes (CNTs) and CO_x-free hydrogen during methane decomposition under microwave irradiation. An optimization of common perovskite materials was conducted for microwave-responsiveness with the results reported in this study. Out of the materials screened, strontium titanium nickel oxide (STNO) was the best candidate to achieve an acceptable methane conversion rate as well as a decent responsiveness to microwave. STNO was further optimized through Ni content, reduction dwell time, and reduction temperature to produce the best methane conversion and CNT …

Face Recognition With Attention Mechanisms, Qiangchang Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Face recognition has been widely used in people’s daily lives due to its contactless process and high accuracy. Existing works can be divided into two categories: global and local approaches. The mainstream global approaches usually extract features on whole faces. However, global faces tend to suffer from dramatic appearance changes under the scenarios of large pose variations, heavy occlusions, and so on. On the other hand, since some local patches may remain similar, they can play an important role in such scenarios. Existing local approaches mainly rely on cropping local patches around facial landmarks and then extracting corresponding local representations. …

A Narrative Inquiry Into Veterans In Engineering, Miracle David Solley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Much research has been conducted on student veterans, in general; however, research on student veterans in engineering majors is very sparse. There is national recognition of the importance of student veterans in science, technology, engineering, and mathematics (STEM) fields as evidenced in the passage in 2020 of a bill investigating the lack of veteran students in these fields. This study adds to the literature by answering the following two research questions: What are the experiences of veteran engineering students? How has military service impacted those experiences? Twelve students and five professors from a Doctoral University: Very High Research Activity in …

Nano-, Encapsulated Manganese Oxide (Nemo) Particles For Mri Enhancement In Microfluidic Tumor Models, Kasey Alexis Freshwater

Graduate Theses, Dissertations, and Problem Reports (ETD)

Breast cancer is among the deadliest cancers in women, with approximately 2.3 million new cases and 685,000 deaths reported globally in 2020 alone. Magnetic Resonance Imaging (MRI) is commonly used to diagnose, stage, and develop treatment plans for patients predisposed to breast cancer. However, current MRI-based screening of breast cancer has high false-positive rates up to 25%, leading to unnecessary invasive follow-up screening and testing. The gold-standard intravenous gadolinium (Gd)-based contrast agents (GBCAs) account for false-positive rates because they are always “ON”, providing a constant MRI signal that highlights both benign and malignant tumors. The work detailed in this thesis …

Examining The Relationship Among Perceived Academic Climate, Belongingness, And Engineering Identity, Sumaia Ali Raisa

Graduate Theses, Dissertations, and Problem Reports (ETD)

An attempt to cultivate an inclusive learning environment in engineering is trending as a response to women's underrepresentation and a lower retention rate than men undergraduates. This study was situated in such an undergraduate engineering program where interventions were embedded in the course curriculum focusing on cultivating an inclusive engineering identity. Following a sociocultural perspective, the present study aimed to examine the relation of engineering identity with perceived academic climate, sense of belonging, and gender among two engineering cohorts (before covid and during covid context). A total of 482 first-year engineering undergraduates' survey responses were analyzed in this study using …

Reinforcement Learning For Process Control: Applications To Energy Systems, Elijah Ballard Hedrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

Reinforcement learning (RL) is a machine learning method that has recently seen significant research activity owing to its successes in the areas of robotics and gameplaying (Silver et al., 2017). However, significant challenges exist in the extension of these control methods to process control problems, where state and input signals are nearly always continuous and more stringent performance guarantees are required. The goal of this work is to explore ways that modern RL algorithms can be adapted to handle process control problems; avenues for this work include using RL with existing controllers such as model predictive control (MPC) and adapting …

Low-Temperature Hot Corrosion Of Boilers In The Coal-Fired Power Plant, Artem Gavrilev

Graduate Theses, Dissertations, and Problem Reports (ETD)

Hot corrosion of materials has remained a relevant topic since its introduction in the second half of the 20th century as gas turbine engines suffered severe corrosion during operation over seawater. Hot corrosion is observed in a multitude of high temperature components, such as gas turbines, power plants, refineries, fluidized bed combustion systems, pipelines, and industrial waste incinerators.

Hot corrosion experiments in the laboratory have been conducted under constant temperatures of interest, while in the actual working conditions of coal-fired power plants, boiler tubes are cooled down via water cooling from a relatively high fireside temperature, e.g., 1000°C. To investigate …

Ecological Restoration Of Lead/Zinc/Copper Mine Tailings: Phytomanagement And Amendment Strategies To Enhance Substrate Functionality And Biomass Production, Mariam K. Al-Lami

Doctoral Dissertations

“The extreme physiochemical characteristics of mine tailings inhibit microbial processes and natural plant growth. Consequently, vast and numerous tailings sites remain barren for decades and highly susceptible to wind and water erosion. Phytostabilization is a cost-effective and ecologically productive remediation approach; however, tailings revegetation is generally challenging and must often be assisted with appropriate soil amendments. Amendments applied individually in greenhouse studies discussed herein revealed notable improvement in bioenergy crops growth only with biosolids treatments. Recalcitrant carbon amendments (biochar and humus) showed notable impact only on tailings physichochemical and hydraulic properties. Nevertheless, biosolids may not support sustained vegetation due to …

The Utilization And Loss Of Available Energy In Aerospace Systems, Mohammad Abbas

Doctoral Dissertations

“Theoretical principles and analytical methodology for the control volume-based energy availability methodology for aerospace vehicles are developed; applications are made to jet-propelled and rocket-propelled vehicles as well as to stand-alone engine systems. Energy availability utilization characteristics of a modeled turbojet engine are studied across a wide range of operating conditions of throttle setting, flight altitude, and flight Mach number. The method is also extended to consider jet-powered vehicles. Fundamental principles regarding entropy generation and energy availability are developed, including directly linking entropy generation and maximum range and endurance of a powered aircraft. Theory and application of the energy utilization methodology …

Effects Of Vacancies And Electron Temperature On The Electron Phonon Coupling In Cubic Silicon Carbide And Their Connection To The Inelastic Thermal Spike, Salah Al-Smairat

Doctoral Dissertations

“The electron-phonon interaction is an important interaction in many solids as it influences transport phenomena and related quantities such as the electrical and thermal conductivities, especially in nuclear and space applications. The importance of the electron-phonon interaction in primary damage production in 3C-SiC is the subject of this research.

The electron-phonon coupling factor was calculated using a hybrid Density Functional Perturbation Theory - Classical Electron Gas model. The coupling factor was calculated as a function of electron temperature in pristine and defective 3C-SiC, and relaxed defective cells. The electron-phonon coupling is found to depend strongly on the electronic temperature and …

Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster

Doctoral Dissertations

“The role of cobalt in trivalent chromium passivations (TCPs) to improve corrosion resistance of γ-ZnNi coated steel and aluminum is based on its effect on hexavalent chromium content in the passive layer. Investigations of both a cobalt-containing and cobalt-free TCP on SAE 1008 steel indicated that both passivations protect well for up to 1000 hours in neutral salt spray exposure (SSE). A repetition on Al 6061-T6 alloy indicated that TCP performed much better than cobalt-free TCP implicating the underlying substrate. Optical and electron micrographs indicated physical changes such as crack thickness, crack density, passivation porosity, and passivation thickness existed between …

Characterization And Utilization Of Alkali-Activated Concrete For Sustainable Infrastructures, Eslam Gomaa

Doctoral Dissertations

“This study has investigated the feasibility of using locally available fly ashes (FAs) to synthesize alkali-activated concrete (AAC) for different structural and repair applications. Using AAC made of 100% FA reduces global CO2 emissions, saves energy, and decreases raw material consumption during the production process of ordinary Portland cement. Class C FAs, sourced from Labadie, Jeffery City, Kansas City, Thomas Hill, and Sikeston power plants in the state of Missouri, were used to synthesize the AAC. Sodium silicate (SS), Na2SiO3, and sodium hydroxide (SH), NaOH were used as the alkali activators. Slag, crumb rubber, and air-entraining admixture were used as …

Modeling Strategy For Emi Filter And Flyback Transformer, Ruijie He

Doctoral Dissertations

“The switch-mode power supply is key to miniaturizing power adapters. However, the switching nature of the circuit introduces issues in conducted emissions. In a flyback converter, the transformer serves as the path for common mode current flowing from the primary side to the secondary side. Different winding technologies have been invented and implemented to reduce the capacitance between the primary side and the secondary side. But the repeatability of the winding is still poor due to the fluctuations of the winding machine. Thus, the resulting conducted emission has a fluctuation that can lead to failure in the compliance tests. EMI …

Innovative Approach To Use Guayule Resin As A Bio-Based Asphalt Alternative, Ahmed Hemida

Doctoral Dissertations

"Asphalt cement will not last long as the world encounters a diminishment in crude oil. Novel resources can contribute to replacing asphalt with the sustainable, flexible pavement. This study presented guayule resin (guayule) as an innovative bio-based asphalt alternative. Ground tire rubber was used as an asphalt enhancer. To judge the guayule's contribution, guayule-based binders were investigated and compared to control asphalt and asphalt-rubber binders. Binders were assessed according to comprehensive Superpave criteria and advanced rheological tests. Component analysis was performed to link the microscale level with the macroscale level. To validate the novel binder, satisfying mix performance tests were …

The Kanarra Fold-Thrust System -- The Leading Edge Of The Sevier Fold-Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Doctoral Dissertations

“The Jurassic to Eocene Sevier fold-thrust belt is the subject of continued scientific curiosity in tectonics, stratigraphy, and industry. Understanding its development in southwest Utah is hindered in part due to the multiple origins proposed for the Kanarra anticline, a major leading edge structure -- a drag fold along the Hurricane fault, Laramide monocline, Sevier fault propagation fold, or a combination of these -- which have confused its tectonic significance and regional context. This confusion results from the structural complexity of its exposed eastern limb, as well as displacement and burial of its crest and western limb beneath Neogene sediments …

Characterizing And Modeling Methods For Power Converters, Anfeng Huang

Doctoral Dissertations

“Stable power delivery is becoming increasingly important in modern electronic devices, especially in applications with stringent requirements of its form factor. With the evolution of technology, the switching frequency in a power converter is pushed to a higher frequency range, e.g., several MHz or even higher, to decrease its size. However, the loss generated in the converter increases drastically due to the high switching frequency. In addition, a wide-band feedback controller is required to accommodate the high switching frequency in the converter. We focus on the characterization or modeling of the feedback control circuits and critical components in a switching …

Numerical Simulation Study Of Gel Treatment For Conformance Control From Lab To Field, Jianqiao Leng

Doctoral Dissertations

“Gel treatment has been widely applied to control reservoir conformance and thus improve the sweep efficiency of injection fluids. Quite a few numerical simulations have been conducted to investigate the factors impacting gel treatment and assist to optimize treatment design and predict the performance. However, there exists significant barrier between the simulation approaches and lab experiments. In this study, two comprehensive reviews have been conducted to identify the gaps between lab and current simulations for in-situ polymer treatment and preformed particle gel treatment, separately.

Based on the identified gaps, the effect of a few major factors which are very important …

Depression Of Pyrite In Polymetallic Sulfide Flotation Using Chitosan-Grafted-Polyacrylamide Polymers, Keitumetse Cathrine Monyake

Doctoral Dissertations

“In this work, Chitosan-grafted-Polyacrylamides (Chi-g-PAMs) were studied, for the first time, as selective depressants of pyrite in the flotation of base metal sulfides. Fundamental studies of the adsorption behavior of Chi-g-PAM on model sulfide minerals indicated that Chi-g-PAM was more selective to pyrite’s surfaces as compared to base metal sulfides. Results suggested that the adsorption of Chi-g-PAM at pyrite-water interface was a chemisorption in nature which involved the amine, amide, and hydroxyl groups of Chi-g-PAM. Batch flotation studies of complex sulfide ore of Mississippi Valley Type (MVT) showed that Chi-g-PAM outperformed other pyrite’s depressants at producing less pyrite-diluted concentrates. Statistical …

Mechanical Properties Of Boride Based Ceramics, Alec Murchie

Doctoral Dissertations

“This research focuses on the elevated mechanical properties of diboride based materials at room and elevated temperatures. These materials include a ZrB₂ ceramic, a ZrB₂-WC-SiC ceramic, and a (Hf,Mo,Nb,Ta,W,Zr)B₂ high entropy boride (HEB). The room temperature flexural strength for the ZrB₂ ceramic was 447 MPa and the fracture toughness was 2.3 MPa·m^1/2. The strength decreased to 196 MPa at 1800°C, and then increased to 360 MPa at 2300°C. The fracture toughness increased to 3.1 MPa·m^1/2 at 2200°C. The strength up to 1800°C was likely controlled by a combination of effects: surface damage …

Scale Formation, Properties And De-Scaling In Steelmaking, Richard Osei

Doctoral Dissertations

During continuous castings, reheating, and hot rolling, slab surfaces are exposed to atmospheres containing oxidizing gases which results in scale formation. Inefficient removal of the formed scale during reheating affects product surface quality. The effect of steel composition and operating parameters on scale formation and scale removal efficiencies were investigated. Experimental investigations were carried out using a thermogravimetric (TGA) apparatus designed to replicate the combustion gas atmosphere and temperature in actual industrial slab reheat furnaces. Report on oxidation kinetics, scale structure and properties, and descaling were conducted on laboratory cast and industrial samples. Different characterization techniques were used to analyze …

Characterization Of High Cycle Fatigue And Laser-Aided Machining And Polishing Of Additively Manufactured Materials, Mohammad Masud Parvez

Doctoral Dissertations

“Additive manufacturing (AM) and laser-aided machining and polishing (LAMP) of materials are emerging manufacturing processes both for research and industrial sectors. The AM process can manufacture near-net-shape parts with complex geometries. Meanwhile, the LAMP process integrated with an AM system offers a high processing rate, minimum heat-affected zone, and easily adjustable process parameters during machining and polishing. In mechanical properties characterization of AM metals and alloys, fatigue is a vitally important test method to understand the behavior of materials in cycling loading and unloading circumstances since most mechanical failures of structures are due to fatigue. To characterize AM metal fatigue …

Investigation Of The Thermodynamics Of Iron Phosphate Melts And Stability Of Iron Phosphate Glasses: Effects Of Composition And Iron Redox Ratio, Melodie Linda Schmitt

Doctoral Dissertations

“Iron phosphate glasses with Fe/P = 0.33 - 0.67, O/P = 3.0 - 3.5 and Fe²⁺/ΣFe = 0.16- 0.52 were prepared by altering batch compositions and melt conditions. Thermal analyses indicate polyphosphate glasses with intermediate chain lengths are most stable against devitrification. Heterogeneous crystallization occurs on the glass surface and is dependent on iron valence state, particle size, heating rate, temperature and oxygen availability in the atmosphere. Oxidation of ferrous iron on the glass surface occurs at temperatures as low as Tg, and thus crystallization behavior and stability can be altered via post-melt heat treatments. A novel preparation …

Advances And Applications In High-Dimensional Heuristic Optimization, Samuel Alexander Vanfossan

Doctoral Dissertations

“Applicable to most real-world decision scenarios, multiobjective optimization is an area of multicriteria decision-making that seeks to simultaneously optimize two or more conflicting objectives. In contrast to single-objective scenarios, nontrivial multiobjective optimization problems are characterized by a set of Pareto optimal solutions wherein no solution unanimously optimizes all objectives. Evolutionary algorithms have emerged as a standard approach to determine a set of these Pareto optimal solutions, from which a decision-maker can select a vetted alternative. While easy to implement and having demonstrated great efficacy, these evolutionary approaches have been criticized for their runtime complexity when dealing with many alternatives or …

Characterization And Modeling Of Esd Events, Risk And Protection, Jianchi Zhou

Doctoral Dissertations

“The ESD (Electrostatic discharge) failures have been raising critical reliability problems in electronic devices design. However, not all the ESD scenarios have been specified by the IEC standard and the characterizations of the ESD risk for different scenarios are essential to evaluate the ESD robustness of the devices in the real word.

The insulation of plastic enclosures provides protection against ESD to the electronic system inside. However, seams between plastic parts are often unavoidable. Different plastic arrangements are constructed to investigate the spark length and current derivatives and to understand the ESD spark behavior for geometries having spark lengths longer …

Evaluation Of Recrosslinkable Preformed Particle Gel (Rppg) As A Fluid Loss Control Material During Drilling Operations, Mohamed Saad M. Ahdaya

Doctoral Dissertations

"One of the most intense, expensive, and time-consuming problems during drilling operations is the loss of circulation, which could result in several consequences, including wellbore collapse, fluid inflow, formation damage, environmental issues, and nonproductive time. This research aims to evaluate novel materials that can mitigate lost circulation and overcome the limitation of other materials. In this research, a comprehensive evaluation of a re-crosslinkable preformed particle gel (RPPG) has been conducted to determine the extent to which it can be used to control drilling fluid losses during drilling operations. The RPPG consists of swellable gel particles that can self-crosslink to form …

Novel Sensor Platforms Based On Fabry-Perot Resonators For Applications In Environmental Geophysics, Jing Guo

Doctoral Dissertations

"Fabry-Perot resonator sensors have been widely used for various physical and chemical measurements owing to their unique advantages over traditional sensors such as high measurement resolution, mechanically robust, and distributed sensing capabilities. This dissertation focuses on the development of robust fiber optic microwave sensors based on Fabry-Perot resonator mechanism for real-time applications in environmental geophysics.

Firstly, a novel Extrinsic Fabry-Perot Interferometer (EFPI)-based fiber-optic sensor for force measurement using a pre-buckled beam was demonstrated. The axial displacement is transferred and amplified to a horizontal deflection at the middle of the buckled beam, leading to a relatively significant change in the Fabry-Perot …

Determining Thermal Properties Via Parameter Estimation Of A One-Dimensional, Analytical Model, Lauren B. Tomanek

Doctoral Dissertations

“In thermal applications, thermal conductivity is used to predict how well a material conducts heat. The accuracy of the magnitude of the thermal conductivity becomes increasingly essential to optimize part geometry. Thermal conductivity can vary significantly from the nominal value due to post-processing. The ASTM standards available to measure thermal conductivity are challenging to reproduce because of the insulated and prescribed temperature boundary conditions that are needed. The research introduces two new methods for estimating thermal conductivity that deliver the same accuracy as the existing ASTM standards and are easier to implement. The methods account for losses in the heating …

Advances In Control Of Uncertain Dynamical Systems With Optimal And Adaptive Approaches, Meryem Deniz

Doctoral Dissertations

"This research starts with designing optimal control for uncertain systems, adding the adaptive control input to suppress the uncertainty. It then follows with designing the optimal control for state constraint, designing the optimal nonlinear reference model, designing adaptive control to handle state constraint and uncertainty. Finally, it designs the finite-time controller for uncertain multiagent systems.

It is well known that the design of the control algorithm for an uncertain dynamical system is not trivial. Motivated by this standpoint, this study focuses on optimal and adaptive control approaches with stability and performance guarantees for uncertain sole and multiagent dynamical systems. From …

Distributed Fiber-Optic Temperature Sensors For Applications In The Steel Industry, Muhammad Roman

Doctoral Dissertations

"Steelmaking facilities require continuous temperature measurements throughout the manufacturing process to ensure consistent product quality and high productivity. Motivated by the limitations of conventional temperature sensors, distributed fiber-optic sensors (DFOS) were developed and deployed for various applications in the steel industry. Fiber-optic sensors offer various advantages over conventional sensors, such as the miniaturized size of the optical fiber, immunity to electromagnetic interferences, capability for multiplexing and distributed sensing, and the ability to withstand harsh environments.

Firstly, high-resolution Rayleigh backscattering based DFOS were demonstrated as potential solutions for temperature measurements in steelmaking processes by performing experimental simulations. Additionally, aluminum casting experiments …

Production Of Non-Oriented Electrical Steel Thin Strip Simulating Conditions Of The Direct Twin-Roll Casting Process, Yizhou Du

Doctoral Dissertations

"In this study, a method to cast non-oriented (NGO) electrical steel with conditions of an industrial twin roll thin strip casting (TRSC) process was investigated. A novel vacuum assisted fast cooling (VA) sampling method was developed to produce 2 mm thick strip simulating conditions of an industrial TRSC process. The effects of solidification cooling rate, hot rolling deformation, and annealing time on inclusion distribution, magnetic properties, grain growth, and texture evolution of 3.4 wt.% Si NGO electrical steel with different carbon and sulfur (C&S) levels were analyzed. Samples were thermo-mechanically treated which simulated an industrial TRSC process. After a long …