Engineering Commons^™

Investigating The Effect Of Electrolyte Concentration And Charging Protocol On Materials Utilization In Rechargeable Zinc Manganese Dioxide Batteries, Snehal H. Kolhekar

Dissertations and Theses

Achieving a highly cyclable, high energy density battery with MnO₂ cathodes encounters many obstacles. Chief among these is the inability of the widely-used γ-MnO₂ polymorph to retain its structural integrity when cycled to near full one-electron discharge capacity, which is about 280mAh/g for commercially available electrolytic manganese dioxide (EMD). In this one-electron range, discharge occurs by proton insertion producing Mn⁺³ which then reverts to γ-MnO₂ on charging. In the first part of the thesis, we investigate the root cause of failure of MnO₂ cathodes under deep cycling in the one-electron discharge range and establish a …

Voltage Security Optimization For Power Transmission Systems, Tamer Ibrahim

Dissertations and Theses

This project proposes an optimization approach for day-ahead reactive power planning to ensure voltage security in transmission networks. The problem is formulated as a voltage-secure multi-period optimal reactive power dispatch (MP-ORPD) problem. The optimization approach searches for optimal set-points of dynamic and static reactive power (var) resources. Specifically, the output includes set-points for switching shunts, transformer taps, and voltage magnitudes at the regulated buses. The primary goal is to maximize the dynamic reactive power reserve of the system, by minimizing the reactive power supplied by synchronous generators. The secondary goal is to minimize changes in the settings of switching shunts …

Development Of A Biaxial Testing System For Research Of Soft Tissue Biomechanics Using Laboratory Models, Tariq Shameen

Dissertations and Theses

The rupture of the cap tissue layer of a fibroatheroma in human coronary vessels is considered the key event leading to the formation of a thrombus and myocardial infarction, resulting in more than half a million deaths in the US every year. In this study, we are interested in investigating the biomechanics of different elastomer materials that can be used as laboratory models to replicate coronary arteries’ ultimate tensile stress (0.2 - 2.08 MPa). To this end, we developed a biomechanical testing system that allows us to characterize the material properties of small samples with high accuracy and precision. We …

The Diffuse Bounce Back Lattice Boltzmann Method And Its Applications On The Study Of Fluid-Particle Interactions, Geng Liu

Dissertations and Theses

Fluid-structure interaction is very broadly seen and widely used in many industrial, engineering and environmental processes. The lattice Boltzmann method has been preferred for simulating particulate flows due to its advantages of easy implementation, micro- and mesoscopic physical insights and parallel algorithm. Both sharp and diffuse boundary treatments are studied to recover curved and moving boundaries on structured orthogonal grids for the lattice Boltzmann method. These methods can describe curved boundaries more accurately and more smoothly than the naive staircase approximation. However, to improve the order of velocity accuracy and to reduce the fluctuation of force, either interpolation or additional …

Transition To Turbulence And Relaminarization Of Pulsatile Pipe Flows, Joan Gomez

Dissertations and Theses

The instability and transition to turbulence and its evolution in pulsatile pipe flows involving both, reverse and no-reverse flows, is the primary focus of this experimental work. A piston driven by a programable DC servo motor was used to set up a water flow system and provide the pulsation characteristics. Time-resolved particle image velocimetry data were acquired in a refractive index matching setup by using a continuous wave laser and a high-frame-rate digital camera. The position of the piston was continuously recorded by a laser proximity sensor. Different experiments were carried out with Reynolds numbers in the range of 535 …

Degradation Issues And Stabilization Strategies Of Protonic Ceramic Electrolysis Cells For Steam Electrolysis, Hanrui Su, Yun Hang Hu

Michigan Tech Publications, Part 1

Protonic ceramic electrolysis cells (PCECs) are attractive electrochemical devices for converting electrical energy to chemicals due to their high conversion efficiency, favorable thermodynamics, fast kinetics, and inexpensive materials. Compared with conventional oxygen ion-conducting solid oxide electrolysis cells, PCECs operate at a lower operating temperature and a favorable operation mode, thus expecting high durability. However, the degradation of PCECs is still significant, hampering their development. In this review, the typical degradations of PCECs are summarized, with emphasis on the chemical stability of the electrolytes and the air electrode materials. Moreover, the degradation mechanism and influencing factors are assessed deeply. Finally, the …

Mid-Infrared Laser Absorption Spectroscopy And Ignition Delay Time Measurements Of Advanced Renewable Fuels At High Pressure In A Shock Tube, Erik Ninnemann

Electronic Theses and Dissertations, 2020-2023

The United States government has set 2050 as the target for net-zero greenhouse gas emissions due to their increasing levels and the subsequent rise in global temperatures. To meet this target, there has been renewed interest in the combustion of high-energy biofuels that could combat these issues. Thus, the Department of Energy started the Co-Optimization of Fuels and Engines program to find bioderived blendstocks that can harmonize with current and future generation engines to increase power and efficiency, all while reducing overall emissions. As part of this program, it is crucial to understand the combustion of these fuels at the …

Analysis Of Miniaturized, Circularly Polarized Antennas For Bidirectional Propagation, Mason C. Moore

College of Graduate Studies: Theses & Dissertations

Size reduction is necessary to fit the recent demand for small sized communication systems in consumer electronics. Wireless communication systems rely on antennas for long range transmission of signals, so size reduced antennas have been sought after in recent years. Also, not many antennas are designed for use in bidirectional scenarios like subways, tunnels, bridges, etc. Three sized reduced antennas with circular polarization are presented for use in bidirectional communication systems. An electrically small pattern reconfigurable array, an electrically small two-sided printed cross dipole, and a size reduced printed wideband antenna are introduced within this thesis. All antennas’ results are …

Reclamation Of Fused Silica From Investment Shells Used For Casting Steel, Samuel L. Holt

College of Graduate Studies: Theses & Dissertations

Fused silica is widely used for investment casting shell molds. Fused silica shells are discarded after being used for casting one time. This is due to the transformation of fused silica to beta cristobalite above 1652℉ (900℃). To reduce cost and waste of investment casting foundries, this study is exploring a method to inhibit transformation of fused silica and reclaim it from high temperature investment casting shells. This research has employed firing to minimalize fused silica transformation to cristobalite. The phase transformation is minimalized due to sintering and coarsening of the particles during firing. Coarsening reduces surface area to volume …

Current Status Of Design And Construction Of Piles With A Pilot Hole On Rock, Charles C. Crowner

College of Graduate Studies: Theses & Dissertations

Driven piles at project sites get their load bearing capacity from side friction along the driven lengths as well as from end resistance. Pilot holes is a pile driving assistance method used to aid driving displacement piles through hard/ dense layers and rock. These pilot holes can be a size smaller or larger than the pile that is to be installed. The pilot hole is first drilled down to a specific depth. The use of a pilot hole reduces the “end bearing” and “side resistance” within the drilled zone and aids the driving of the pile. This process also complicates …

The Digitization Of Court Processes In African Regional And Subregional Judicial Institutions, Frederic Drabo

Walden Dissertations and Doctoral Studies

Despite information technology (IT) officers’ multiple efforts to develop reliable and efficient electronic justice (e-justice) systems, digitizing court processes still presents several quality challenges associated with IT infrastructure and literacy issues. Grounded in the principles of total quality management, the purpose of this qualitative multiple case study was to identify strategies and best practices IT officers in African regional economic communities (REC) use for digitizing regional and subregional court processes to improve African e-justice systems. The participants included four IT officers working as assistant computer system analysts (ACSA), computer system analysts (CSA), and heads of IT (HIT) in regional and …

Strategies For Catalyzing Clinicians’ Support Of Telemedicine Programs In Rural Communities, Jonathan Liwag

Walden Dissertations and Doctoral Studies

Clinicians’ failure to accept contemporary technology has been a critical barrier to telemedicine program adoption. Staff technical challenges and resistance to change can affect technology return on investment, which concerns telemedicine program leaders. Grounded in Davis’s technology acceptance model, the purpose of this qualitative, descriptive single case study was to explore strategies used by program leaders in the Marianas Islands who successfully gained clinicians’ acceptance of contemporary technology. The participants were 5 program leaders recommended by their institution because of their leadership role and telemedicine technologies experience. Data were collected from 4 face-to-face and 1 audio teleconference interview with the …

Design And Deployment Of A Mobile Learning Cloud Network To Facilitate Open Educational Resources For Asynchronous Learning, Joselito Christian Paulus M. Villanueva, Mark Anthony V. Melendres, Catherine Genevieve B. Lagunzad, Nathaniel Joseph C. Libatique

Biology Faculty Publications

This paper describes the design and deployment of a mobile cloud network that facilitates open educational resource content distribution. The setup utilized clustered single board computers as content, communication and monitoring servers. It was installed in a Public High School where stakeholders, using their mobile devices, were given access to preloaded content via wireless local area network. Initial tests of the mobile cloud showed good network performance. Teachers were randomly selected to evaluate the content validity and delivery of the OER content. Results show that the quality of the network’s OER content is very satisfactory. This implementation shows the advantage …

Simulating Ejecta Blown Off The Lunar Surface Due To Landing Spacecraft Using The Mercury N-Body Integrator, Isabel Rivera

Electronic Theses and Dissertations, 2020-2023

The experiences of the Apollo lunar landings revealed the danger lunar dust can pose to surrounding hardware, outposts, and orbiting spacecraft. Future lunar missions such as the Artemis program will require more information about the trajectories of ejecta blown by landers to protect orbiting spacecraft such as the Lunar Gateway. In this paper, we simulate lunar lander ejecta trajectories using the Mercury N-body integrator. We placed cones of test particles on the Moon at the North Pole, South Pole, and Equator with various ejection speeds and angles. The results show that particles ejected at speeds near the Moon's escape velocity …

Seismic Soil-Structure Interaction Effects In Tall Buildings Considering Nonlinear-Inelastic Behaviors, Jaime Mercado

Electronic Theses and Dissertations, 2020-2023

Soil-structure interaction (SSI) effects are relevant for the seismic analysis of tall buildings on shallow foundations since the dynamic behavior of structures is highly affected by the interaction between the superstructure and supporting soils. As part of earthquake-resistant designs of buildings, considering SSI effects in the analysis provides more realistic estimates of its performance during a seismic event, particularly when both the structure and soil undergo large demands that can compromise serviceability. Oversimplifications of structural or soil modeling in the analysis introduces variability and biases in the computed seismic response. The main goal of this dissertation is to investigate the …

Understanding Forearm Muscle Coordination In Children, Miguel Gonzalez

Electronic Theses and Dissertations, 2020-2023

A combination of surface electromyography (EMG) and pattern recognition algorithms have led to improvements in the functionality of upper limb prosthetics. This method of control relies on user's ability to repeatedly generate consistent muscle contractions. Research in EMG based control of prosthesis has mainly utilized adult subjects who have fully developed neuromuscular control. Little is known about children's ability to generate consistent EMG signals necessary to control artificial limbs with multiple degrees of freedom. To address this gap, two experiments were designed to validate and benchmark an experimental protocol that quantifies the ability to coordinate forearm muscle contractions in able-bodied …

Solidification Cracking In Binary Al-Cu Alloys Additively Manufactured Through Laser Powder Bed Fusion, Keegan Muller

Electronic Theses and Dissertations, 2020-2023

Laser Powder Bed Fusion (LPBF) is an additive manufacturing technique with growing relevance in industry. However, alloys with a high susceptibility to micro-cracking during solidification cannot be feasibly manufactured through LPBF, such as in selected high-strength Al-alloys. The cracking susceptibility (CS) of Al-alloys varies with composition, so modeling CS with respect to composition is crucial in designing compatible alloys for LPBF. In a theoretical modeling of solidification cracking based on the Scheil equation, the relative CS is taken as the maximum value of |dT/d(fs^1/2)| when solidification is near completion. However, experimental observations of the crack density in Al-alloys suggest that …

Optimizing Peer Selection Among Internet Service Providers (Isps), Shahzeb Mustafa

Electronic Theses and Dissertations, 2020-2023

Connections among Internet Service Providers (ISPs) form the backbone of the Internet. This enables communications across the globe. ISPs are represented as Autonomous Systems (ASes) in the global Internet and inter-ISP traffic exchange takes place via inter-AS links, which are formed based on inter-ISP connections and agreements. In addition to customer-provider agreements, a crucial type of inter-ISP agreement is peering. ISP administrators use various platforms like AP-NIC and NANOG networking events for establishing new peering connections in accordance with their business and technical needs. Such methods are often inefficient and slow, potentially resulting in missed opportunities or sub-optimal routes. The …

Neural Signatures Of Human Perception Of Effort And Comfort In Isometric Arm Force Exertions By Males, Raul Fernandez Sumano

Electronic Theses and Dissertations, 2020-2023

Understanding the brain's electrical activity provides objective evidence of different psychophysical phenomena related to manual handling tasks. The primary objective of this research was to assess the neural signatures of human physical efforts and perceived comfort in isometric arm exertions. Two experiments were conducted with male participants (n=20) who applied isometric forces at 1) different levels of exertion and 2) different levels of physical comfort. EEG signals, the rate of perceived exertion (RPE), and the rate of perceived physical comfort (RPC) have been recorded. The results showed statistically significant differences in EEG's power spectral density (PSD) at different brain regions …

The Critical Role Of Dynamic Surface Tension Of Surfactants On The Impact Dynamics Of Water Droplets, Amir Esmaeili, Reza Mohammadi

Graduate Research Posters

Due to their time-dependent surface tension, the addition of surface-active agents or surfactants to water for specific applications has made controlling the impact dynamics of these droplets a complex phenomenon. This work investigates the influence of the molecular weight, concentration, and ionic nature of the surfactants as well as the substrate surface characteristics on the impact dynamics of surfactant-laden droplets using a high-speed camera at 10000 frames per second. Sodium dodecyl sulfate, hexadecyltrimethylammonium bromide, and n-decanoyl-n-methylglucamine were used as anionic, cationic, and nonionic surfactants, respectively. We used hydrophilic glass slides, hydrophobic polytetrafluoroethylene, and superhydrophobic alkyl ketene dimer (AKD) as substrates. …

Natural Gas Conversion To Value-Added Chemicals By Microwave Catalytic Processes, Brandon Robinson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ethane is the second-largest component in natural gas and is typically separated out to minimize condensation in the pipelines. The technical difficulties and cost associated with the transportation and the storage of ethane have led companies to start burning natural gas to produce power or flaring which attributes to the global CO₂ emission problem. The conversion of ethane to higher-value liquid products is of increasing importance so that the natural gas can be safely utilized and cost-effectively transported. Existing commercial technologies used to convert ethane to liquid chemical products are typically based on the indirect syngas route, such as …

Distributed Cross-Community Collaboration For The Cloud-Based Energy Management Service, Yu-Wen Chen, J. Morris Chang

Publications and Research

Customers’ participation is a critical factor for inte-grating the distributed energy resources via demand response and demand-side management programs, especially when customers become prosumers. Incentives need to be delivered by the energy management service to attract prosumers to operate their distributed energy resources and electricity loads grid-friendly actively. The cloud-based energy management service enables virtual trading for customers within the same community to minimize cost and smooth the fluctuation. With the potential fast-growing number of service providers and customers, the needs exist for efficiently collaborating across multiple service providers and customers. This paper proposes the distributed cross-community collaboration (XCC) for …

Toward An Interactive, Patient-Specific, Vr-Based Obstetrics Simulator, Michel A. Audette, Marco Parente, Dulce Oliveira, Sreekanth Arikatla, Alfred Abuhamad, Rumit Singh Kakar, Mark Scerbo, Lucia Tabacu, John Conery, Christopher Macgowan, Renato Natal Jorge

Electrical & Computer Engineering Faculty Publications

This paper presents a nascent collaborative effort to achieve a Virtual Reality (VR)-based, real-time, haptics-driven patient-specific obstetrics simulator. The high-level architecture and preliminary results are presented here; the latter are based on offline birthing simulation developed by team in conjunction with open-source visualization tools. The cornerstones of this simulator will be high-fidelity generic offline birthing simulation, an anatomy-to-image nonrigid registration pipeline exploiting fetal MRI, the open-source interactive medical simulation toolkit IMSTK augmented by high-throughput deep learning-based soft tissue deformation, open-source musculoskeletal dynamics simulation platform SimTk for representing fetal motion. The initial emphasis will be on shoulder dystocia. The two main …

Electroosmotic Flow Of Viscoelastic Fluid Through A Constriction Microchannel, Jianyu Ji, Shizhi Qian, Zhaohui Liu

Mechanical & Aerospace Engineering Faculty Publications

Electroosmotic flow (EOF) has been widely used in various biochemical microfluidic applications, many of which use viscoelastic non-Newtonian fluid. This study numerically investigates the EOF of viscoelastic fluid through a 10:1 constriction microfluidic channel connecting two reservoirs on either side. The flow is modelled by the Oldroyd-B (OB) model coupled with the Poisson–Boltzmann model. EOF of polyacrylamide (PAA) solution is studied as a function of the PAA concentration and the applied electric field. In contrast to steady EOF of Newtonian fluid, the EOF of PAA solution becomes unstable when the applied electric field (PAA concentration) exceeds a critical value for …

(Quinolin-8-Yl) Tin Synthons In Transmetalation Reactions With Transition Metals Yield Multimetallic Organometallic Molecules And Clusters, Arjun Chandra Bhowmick

Dissertations and Theses

Transition metal (Hg, Ag, Pd, Ni, Sn, Cu) complexes and clusters form from the reaction of metal salts and QSnX (Q = quinolin-8-yl; X = Q or Cl) synthons. Our original intent was the use of Q2Hg, Q2Sn, or QSnCl as an ambiphilic ligand; however, we observed an apparent redox-trans metalation reaction in most of the cases. Bimetallic Hg-Ag complexes were prepared using Q2Hg as an ambiphilic ligand. Heterobimetallic (Ni-Sn and Pd-Sn) complexes were obtained from the reaction of NiCl2 (or PdCl2) with in situ generated QSnCl. Geometry and electronic configuration of the complexes were investigated using DFT methods. The …

Detection Of 2,4,6-Trinitrotoluene Using A Colorimetric Gold Nanoparticle Air Cassette Filter, Andrea I. Ferrer Vega

Master of Science in Forensic Science Directed Research Projects

Trinitrotoluene (TNT) is an explosive commonly used during military and terrorist activities. Current methods to identify this compound require sampling, transport and analysis at a forensic lab using analytical instrumentation. However, on-site detection is needed to assist efforts to prevent detonation. Gold nanoparticles have been used as sensors throughout the years due to their versatility and surface enhanced Raman scattering properties in the presence of an analyte and low limits of detection. By taking advantage of the Meisenheimer complex that TNT forms in the presence of amines, it is possible to determine its presence at picogram levels. Subsequently, adhering amine …

Simulation Of Particle Transport In A Multi-Component Flow With A High Viscosity Ratio Driven By Slender Structures, Michael Roeing-Donna

Graduate Research Theses & Dissertations

Simulating particle transport in multi-component fluid flows driven by slender structures is important but challenging, especially when dealing with large viscosity ratios. In this thesis, a general multi-physics model is introduced to handle multi-component fluid flows, slender beating structures, immersed particles/droplets, and their interactions. This multi-physics model has been validated with analytical solutions and other published experimental and numerical results for the mean mucous velocity. The validated model is used to study particle transport in nasal mucous layer, the interplay between cilia and fluid flow. The model shows that mucous-pericilairy layer interface and mucous-air interface remain a constant height throughout …

Development Of Prototype Rf Front-End Electronics For Linear Accelerator Beam Position Monitoring System, Edward Matthew Siebert

Graduate Research Theses & Dissertations

Beam Position Monitoring (BPM) systems are utilized extensively in particle accelerator facilities as a diagnostic tool to ascertain quantitative aspects of an accelerated charge-beam such as spatial position and intensity of the beam as it is accelerated to greater velocities and levels of kinetic energy within said accelerating machine. A critical aspect of a BPM system is the Radio Frequency Front End (RFFE) electronic circuitry that receives the incoming raw BPM signal and performs signal-conditioning such that its frequency spectrum is transformed from radio frequency (RF) to non-RF and digitization of the transformed signal by downstream components can successfully occur. …

Experimental Exploration Of Shared Magnetic Phases Between Diverse Systems Of Iron-Pnictide Superconductors, Ryan Scott Stadel

Graduate Research Theses & Dissertations

The exciting field of iron-pnictide superconductors offers unique opportunities for studying the relationship between magnetism and unconventional superconductivity. This is vital to developing an understanding of the microscopic origin of high-temperature superconductivity, which is itself an important step in harnessing such a potentially revolutionary technology.

Polycrystalline and crystalline samples are synthesized over a diverse collection of related iron-pnictide systems including (Ca,Sr,Ba)1-xNaxFe2As2, Ba(Fe1-xCox)2As2 (122s), and LaFeAs1-xPxO, and TbFeAs1-xPxO (1111s). These compounds are characterized through various types of neutron and x-ray diffraction on multiple instruments, as well as muon spin resonance, and magnetic susceptibility measurements.

A thorough investigation into the conditions under …

Modeling Study Of Electrocoagulation System For Treating Wastewater, Swachwa Dey

Graduate Research Theses & Dissertations

Effective treatment of wastewater from households, communities, and industries is vital to preserve our environment. Chemical treatment to add coagulants into the wastewater is the most popular treatment method, but due to the high operating cost and secondary contamination issue, a novel method to solve those issues is required. In this study, we revisited the electro-coagulation (EC) system which has promising features of low system/operating cost and environment friendly process. EC was actively developed once, but due to the low efficiency and scaling-up issues, it could not be fully utilized. In this study, physics-based mathematical model was developed to elucidate …