Engineering Commons^™

Use Of Biochar And Zeolite For Landfill Leachate Treatment: Experimental Studies And Reuse Potential Assessment, Thanh Thieu Lam

USF Tampa Graduate Theses and Dissertations

Leachate is a highly colored liquid waste product of landfills that contains high concentrations of ammonia nitrogen (NH4+-N), refractory organic matter, and heavy metals. It is commonly disposed to local publicly owned treatment works (POTWs). With these potent characteristics, it interferes with the physical, biological, and chemical treatment processes within POTWs. Sequencing batch biofilm reactors (SBBR) and hybrid subsurface flow constructed wetlands (CW) have been used in the past to treat landfill leachate, but their design and performance can still be optimized. Addition of low-cost adsorbent materials to SBBRs and CWs, such as biochar and zeolite, have the potential to …

Community Assessment Of Water Perceptions And Household Point-Of-Use Treatment Methods In Madagascar, Isabella Rose Silverman

USF Tampa Graduate Theses and Dissertations

One in four people around the world do not have access to safe drinking water, which means that two billion people globally lack access. In high-income countries, 0.02% of yearly deaths are attributed to unsafe water sources; however, an alarming 10.6% of deaths occur in Madagascar, for the same reason.

To achieve Sustainable Development Goal 6: Ensure access to water and sanitation for all, a collaboration between public health and engineering is critical. Within the public health sector, social marketing is commonly utilized to address a problem by using commercial marketing principles to change behavior for the good of society. …

Laboratory Examination Of Lead Weights Harvested From Pitcher Pumps In Eastern Madagascar, Madelyn Wilson

USF Tampa Graduate Theses and Dissertations

Previous sampling campaigns in Tamatave, Madagascar, conducted by the University of South Florida (USF) have identified lead contamination in drinking water sourced from self-supply pitcher pumps. The pitcher pump piston and foot valves were identified as the primary source of lead contamination since they are often manufactured from recycled lead acid batteries. The previous field sampling technique consisted of collecting an aliquot of a 10-15-liter composite sample from the pitcher pump for dissolved lead analysis; however, this technique (1) neglects the contribution of particulate lead, (2) does not properly account for the effects of water stagnation inside the pitcher pump …

Using Fuzzy Clustering Of User Perception To Determine The Number Of Level-Of-Service Categories For Bus Rapid Transit, Yueying Huo, Jinhua Zhao, Xiaojuan Li, Chen Guo

Journal of Public Transportation

The concept of level of service (LOS) is meant to reflect user perception of the quality of service provided by a transportation facility or service. Although the LOS of bus rapid transit (BRT) has received considerable attention, the number of levels of service of BRT that a user can perceive still remains unclear. Therefore, in this paper, we address this issue using fuzzy clustering of user perception. User perception is defined as a six-dimension vector of the perceived arrival time, perceived waiting time, bus speed perception, passenger load perception, perceived departure time, and overall perception. A smartphone-based transit travel survey …

A Novel Reduced-Order Method For Analysis Of Hyperspectral Images, Yanming Zhang, Lijun Jiang

Electrical and Computer Engineering Faculty Research & Creative Works

Hyperspectral imaging technology has been broadly applied in remote sensing because it collects echoed signals from across the electromagnetic (EM) spectrum and provides fruitfully helpful information. However, the processing or transformation of high-data-volume hyperspectral images, also viewed as snapshots varying with the EM spectrum, burdens the hardware resources, especially for the high spectral resolution and spatial resolution cases. To tackle this challenge, a novel reduced-order method based on the dynamic mode decomposition (DMD) algorithm is presented here to analyze hyperspectral images. The method decomposes the spatial-spectral hyperspectral images in terms of spatial dynamic modes and corresponding spectral patterns. Then, these …

Electrochemical Synthesis Of P-(Β-Hydroxyethyl Sulfone) Aniline, Hao Guo, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang

Journal of Electrochemistry

Para-ester is the most important intermediate for the preparation of ethylene sulfone type reactive dyes, which is usually used in the dyeing of cellulose fibers and synthetic fibers. P-(β-hydroxyethyl sulfone) aniline is an important intermediate for the synthesis of para-ester. In this paper, p-(β-hydroxyethyl sulfone) aniline was prepared by electrochemical method, having the advantages of simple process, mild reaction condition, less environmental pollution, easy reaction control and so on. It has strong development potential and industrial application prospect. The electrochemical reduction of p-nitrophenyl-β-hydroxyethyl sulfone on a lead plate electrode to prepare p-(β-hydroxyethyl …

Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang

Journal of Electrochemistry

Glassy carbon electrode (GCE) is a common basic electrode for various electrochemical sensors, and the detection properties are determined by its interfacial characteristics. In this paper, we established an equivalent circuit including electrolyte resistance (R_el), charge transport resistance (R_ct), diffusion impedance (R_di, C_di), electrochemical (oxidation/reduction) reaction impedance (R_R, C_R), surface adsorption impedance (R_ads , C_ads), double-layer capacitance (C_DL), and derived the mathematical expression for the equivalent circuit. The R_el and C_DL are contributed by inactive …

Development Of Small-Scale Power Supplies For Wearable Medical Diagnostic Devices, Donny Stiner

USF Tampa Graduate Theses and Dissertations

As devices continue the trend of becoming increasingly smaller in scale to allowfor wearability, the power supply modules driving these technologies will in turn become reduced in size as well. This progression will call for advanced techniques to fabricate power supplies on wearable device platforms which still permit the circuit to operate effectively. One such crucial technique, which is discussed in this thesis, is the implementation of power saving measures to increase battery lifespan on wearable devices.

Equipment found in the medical field today can be quite bulky and requireinconvenient means of transportation and take up an excessive amount of …

Trilateration-Based Localization In Known Environments With Object Detection, Valeria M. Salas Pacheco

USF Tampa Graduate Theses and Dissertations

Many strategies for localization have been proposed, the majority of which rely on distance calculations and estimates. The proposed approach is a method that combines image-based single-camera localization techniques and the principle of trilateration to perform localization in a known indoor environment. By using a camera, the proposed system can detect custom objects using object detection in an indoor environment and calculate an approximation of the camera’s position. To recognize the location, previous information such as the size of the environment and the coordinates and sizes of the objects in the environment are given as input to the system together …

Fundamentals Of Electrochemical Impedance Spectroscopy For Macrohomogeneous Porous Electrodes, Xiang Li, Qiu-An Huang, Wei-Heng Li, Yu-Xuan Bai, Jia Wang, Yang Liu, Yu-Feng Zhao, Juan Wang, Jiu-Jun Zhang

Journal of Electrochemistry

Electrochemical impedance spectroscopy (EIS) can be used to diagnose charge transfer reactions and mass transport in porous electrodes. The charge transfer reactions include interfacial charge accumulation and charge conduction as well as electrochemical reaction. In this paper, the complex phasor method is developed under the macrohomogeneous assumption to build an impedance model of porous electrodes for clarifying several vague expressions in the traditional approaches. The following researches are carried out: (1) Identifying characteristic parameters for the porous electrodes, including electrode electronic conductivity σ₁, electrolyte ionic conductivity σ₂, interface charge transfer conductivity g_ct, unit area …

Janus-Tinbco2 For Hydrogen Evolution Reaction With High Conductivity And Catalytic Activity, Li-Li Xu, Dong-Yan Ren, Xiao-Feng Zhao, Yong Yi

Journal of Electrochemistry

Exploring the potential hydrogen evolution reaction (HER) catalysts with the high activity and high conductivity has always been a hot spot in the research of renewable energy development. Ti₂C, as one of the 2D-MXene, has excellent properties relating to many active sites, mechanical stability, conductivity, etc., and has become a potential HER catalyst. However, the modification of the surface of Ti₂C by terminal O will reduce the conductivity, thereby limiting the transport of electrons between the valence band and the conduction band. In this study, an electric double layer Janus-TiNbCO₂ was constructed by Nb doping. …

Application Of Ti/Ruo2-Iro2-Sno2-Sb2O5 Anode In Rural Drinking Water Disinfection, Jing-Ru Guo, Xue-Jiao Zhang, Shuai Liao, Xue-Ming Chen

Journal of Electrochemistry

Sodium hypochlorite disinfection has many advantages, including reliable operation, low cost, easily available raw materials. It is, therefore, suitable for disinfection of drinking water in remote rural areas. The service life and chlorine evolution efficiency of the anode are the main factors restricting the performance of the sodium hypochlorite generator. The special conditions of frequent shutdown and low electrolyte concentration in the rural drinking water application also put forward high requirements on the performance of the anode. In this study, Ti/RuO₂-IrO₂-SnO₂-Sb₂O₅,a new-type and efficient chlorine evolution anode, was prepared by …

Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu

Journal of Electrochemistry

In recent years, the nickel-based phosphide has drawn great attention because of its low intercalation/deintercalation platform and lower polarization compared to sulfides and oxides as anodes for next-generation high-energy lithium-ion batteries. The Ni₂P anode can deliver high theoretical specific capacity of 542 mAh·g^-1, but it subject to a conversion reaction mechanism, which make them unsuitable for commercial applications. The agglomeration of Ni₂P nanoparticles during material fabrication and the structural deterioration of electrode associated with large volume change during charge-discharge process lead to poor cycle stability and low utilization of active materials. Meanwhile, the low …

Preparation Of Modified Titanium Based Pbo2 Electrode And Its Rapid Detection Of Cod, Qi Sun, Yan-He Han, Xiao-Lu Fu

Journal of Electrochemistry

In the traditional Ti/β-PbO₂ electrode, the crystal lattice difference between β-PbO₂ and Ti matrix is large, and the prepared electrode is easy to fall off and has a short service life. It needs to be modified in actual use. Based on the advantages of α-PbO₂ material and Ag material in terms of adhesion and conductivity, respectively, the above two materials are selected as the intermediate layer of Ti/β-PbO₂ electrode to improve electrode performance. In this paper, by preparing Ti/α/β-PbO₂ and Ti/Ag/β-PbO₂ electrodes …

Pair Distribution Function Analysis And Electrochemical Performance Of Mesoporous Carbon Nanomaterials Synthesized Through Koh And Zncl2 Activation, Talam E. Kibona, Sarah Frisco, Maxwell W. Terban

Tanzania Journal of Science

Mesoporous carbon has been synthesized by activating carbonized biogas slurry residues with ZnCl2 and KOH simultaneously. The carbon to activating agent mass ratios were kept at 1:4, while the ZnCl2 to KOH mass ratio varied from 4:0, 3:1, 2:2, 1:3, to 0:4. The highest BET specific surface area of 361 m2 g-1, micropore surface area of 231 m2 g‒1, mesopore surface area of 125 m2 g‒1, and total pore volume of 0.23 cm3 g‒1 which amounted to 78% mesopore content, were obtained for the sample with 3:1 ZnCl2 to KOH mass ratio. Scanning electron microscope (SEM) images were acquired to …

Advances In Nanomaterials Sciences And Nanotechnology For Sustainable Development: A Review, Gervas E. Assey, Wilhelm S. Malasi

Tanzania Journal of Science

The fields of materials sciences have great opportunities to address the challenges of sustainable development of modern societies. The sub-disciplines of materials sciences of interest in this review are nanomaterials sciences and nanotechnology. Nanomaterials possess one external dimension measuring 1-100 nm. They have larger surface area for the same mass than their bulk materials. They are more reactive with effects on their electrical, optical and magnetic properties. Thus, nanomaterials are promising for sustainable development in the areas of energy, water, chemicals, electronics, medical and pharmaceutical industries, CO2 mitigation and agriculture. To this end, this review explores the advances in nanomaterials …

Minimum Cut-Sets For The Identification Of Critical Water Distribution Network Segments, Xiliang Mao

USF Tampa Graduate Theses and Dissertations

To ensure adequate performance of water distribution networks, utilities must identify critical segments within the network that will adversely affect users when failures occur. Currently, time consuming hydraulic simulations are used for such criticality analyses. A method can be of great benefit for utilities if it can easily evaluate the criticality of water distribution network segments. This research applies topology-based methods for the preliminary screening of critical segments. This study evaluated the connectivity between sources and each demand segment in water distribution networks using minimum cut-sets. Through topological analysis, the minimum cut -set between the source node and each demand …

Multi-Material Hybrid Additive And Subtractive Manufacturing Of Photonic Devices, Roger Brandon Tipton

USF Tampa Graduate Theses and Dissertations

Optoelectronics focuses on the application of electronic devices that utilize forms of electromagnetic radiation including visible light and other wavelengths including ultraviolet and infrared. Optoelectronics typically include devices that emit light and detect light. Devices created using this technology include light-emitting diodes, laser diodes, photoresistors, photodiodes, solar cells, phototransistors, and fiber optics. Fiber optic interconnects are interesting devices in that they are used in conjunction with optoelectronic devices to transmit information between individual optoelectronic components.

Optoelectronics are typically produced by traditional lithography methods including etching, writing, and printing on rigid silicon substrates for fabricating devices. Other techniques like glass or …

Design Of Acoustic Wave Sensor System For Detection Of Btex In Gas Phase, Veselinka Mitevska

USF Tampa Graduate Theses and Dissertations

Benzene, toluene, ethylbenzene, and xylene are classified as volatile organic compounds (VOC), which if present at higher concentrations can cause acute and/or chronic health effects. To protect people from VOCs, the occupational safety and health agency (OSHA) established short term and eight-hour workday exposure limits. The short time levels of exposure for BTEX materials are 5 ppm, 150 ppm, 125 ppm, and 150 ppm, for benzene, toluene, ethylbenzene, and xylene respectively. The eight-hour workday exposure for these same materials are 1 ppm for benzene, 200 ppm for toluene, 100 ppm for ethylbenzene and 100 ppm for xylene. Although there are …

Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

Direct methanol fuel cell (DMFC), which directly converts the chemical energy of methanol fuel into electrical energy, has the advantages of high energy conversion efficiency, environmental friendliness, and abundance of fuel sources. DMFC is considered as the promising substitutes in the field of portable devices, military applications, and stationary power stations, while the broad application is severely hindered by the sluggish kinetic of methanol oxidation reaction (MOR) in the anode and the high cost of platinum (Pt)-based anodic electrocatalysts. Herein, a series of carbon supported Pt_xCu_y (Pt_xCu_y/C) binary metal electrocatalysts, featured with high …

Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu

Journal of Electrochemistry

Glyoxylic acid with the dual characteristics of acid and aldehyde is an important chemical raw material and organic synthesis intermediate, which is extensively used in the perfumery, pharmaceutical and fine chemical industries. A family of symmetric quaternary ammonium hydroxides (QAHs) with different alkyl chain lengths was used as the additives in generating glyoxylic acid from oxalic acid electroreduction reaction (OAER). The effects of alkyl chain length on OAER and the corresponding side reaction, i.e., hydrogen evolution reaction (HER), were investigated. Linear sweep voltammetric (LSV) results showed that the adsorption of the additives suppressed more on the HER than that on …

A Review Of Mobile Apps For Chronic Kidney Disease Patients, Clarisse Zigan, Carl Russell Iii, Kirsten Wozniak, Kshaunish Soni

The Journal of Purdue Undergraduate Research

No abstract provided.

Collision Tracking And Brain Mapping, Carl Russell Iii

The Journal of Purdue Undergraduate Research

No abstract provided.

Continuous Liquid-Liquid Extraction Of Lomustine Synthesis, Devna Grover

The Journal of Purdue Undergraduate Research

No abstract provided.

Multiphase Energetic Experiments: Application Of Multiple Object Tracking, Sarah Davis Finch

The Journal of Purdue Undergraduate Research

The process of using computer vision for multiple-objects tracking is incredibly complex. Thus, simulated data was created to mimic the complexities of more realistic data. These test cases would isolate a few of the inaccuracies of real data and allow the researchers to determine what factor of said data is the most detrimental to the object-tracking process. Due to the large quantity of factors at play, Cotter’s method was used to analyze the significance of each factor. The number of detections and the number of centroids were the main dependent results that were utilized to analyze the data. The overall …

Visualizing Bacteriophage Evolution Through Sequence And Structural Phylogeny Of Lysin A And Terminase Proteins: An Analysis Of Protein Structure Across Phage Clusters, Maansi Asthana, Alyssa Easton, Julia Mollenhauer, Sean Renwick, Anita Golpalrathnam

The Journal of Purdue Undergraduate Research

Understanding how genes evolve and persist is a critical part of viral genomics. Bacteriophages can provide unique insight about viral evolution because of their abundance and largely unexplored history. Traditionally, phylogenetic trees have used DNA sequence comparison to visualize evolutionary paths between organisms. However, DNA sequence similarity does not reflect key alterations to protein structure and therefore how the protein performs its function. Phylogenetic trees based on predicted protein structure could provide an alternative lens through which to view evolutionary paths. From each of the 10 largest clusters included in the Actinobacteriophage Database, three mycobacteriophage genomes were selected. Lysin A …

Dataset Of Concurrent Eeg, Ecg, And Behavior With Multiple Doses Of Transcranial Electrical Stimulation, Nigel Gebodh, Zeinab Esmaeilpour, Abhishek Datta, Marom Bikson

Publications and Research

We present a dataset combining human-participant high-density electroencephalography (EEG) with physiological and continuous behavioral metrics during transcranial electrical stimulation (tES). Data include within participant application of nine High-Definition tES (HD-tES) types, targeting three cortical regions (frontal, motor, parietal) with three stimulation waveforms (DC, 5 Hz, 30 Hz); more than 783 total stimulation trials over 62 sessions with EEG, physiological (ECG, EOG), and continuous behavioral vigilance/alertness metrics. Experiment 1 and 2 consisted of participants performing a continuous vigilance/alertness task over three 70-minute and two 70.5-minute sessions, respectively. Demographic data were collected, as well as self-reported wellness questionnaires before and after each …

Phenolic, Carotenoid And Saccharide Compositions Of Vietnamese Camellia Sinensis Teas And Herbal Teas, Danh C. Vu, Sophie Alvarez

Nebraska Center for Biotechnology: Faculty and Staff Publications

Tea (Camellia sinensis) and herbal tea have been recognized as rich sources of bioactive constituents with the ability to exert antioxidant actions. The aims of this study were to analyze phenolic, carotenoid and saccharide contents in a set of Vietnamese tea and herbal tea and compare the results with those of green and black teas marketed in the U.S. In total, 27 phenolics, six carotenoids and chlorophylls, and three saccharides were quantitatively identified. Catechins, quercetin glycosides and chlorogenic acid were the predominating phenolics in the teas, with the concentrations following the order: jasmine/green teas > oolong tea > black tea. …

Generating Synthetic Training Data For Deep Learning-Based Uav Trajectory Prediction, Brendan T. Morris, Stefan Becker, Ronny Hug, Wolfgang Huebner, Michael Arens

Electrical & Computer Engineering Faculty Research

Deep learning-based models, such as recurrent neural networks (RNNs), have been applied to various sequence learning tasks with great success. Following this, these models are increasingly replacing classic approaches in object tracking applications for motion prediction. On the one hand, these models can capture complex object dynamics with less modeling required, but on the other hand, they depend on a large amount of training data for parameter tuning. Towards this end, we present an approach for generating synthetic trajectory data of unmanned-aerial-vehicles (UAVs) in image space. Since UAVs, or rather quadrotors are dynamical systems, they can not follow arbitrary trajectories. …

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …