Engineering Commons^™

Ceria Nanostructured Catalysts For Conversion Of Methanol And Carbon Dioxide To Dimethyl Carbonate, Jawad Hassan A Al Drwish

Masters Theses

"In this study, three different shapes of ceria (CeO₂) nanostructures (e.g., nanooctahedra, nanocubes and nanorods) were synthesized via the hydrothermal method and screened for carbonylation reaction. Of these three shapes of nanostructures, the nanorod was doped with metals such as Ca, Ni, Cu, and Co by wet impregnation method. All materials were characterized by XRD, NH₃/CO₂-TPD, XRF, FTIR and N₂ physorption to determine the crystal size and phases, acid-base properties, metal loading, and surface properties. The obtained materials were employed as catalysts for the activation of Carbon Dioxide (CO₂) and methanol …

Cyclic Axial Compression Behavior Of Concrete-Filled Hybrid Large Rupture Strain Frp Tubes, Monika Nain

Masters Theses

"This study introduces an experimental investigation of the behavior of concrete filled fiber reinforced polymer (FRP) tubes (CFFTs) under cyclic axial compression. The FRP used in this study were either small rupture strain FRP (SRS-FRP) or large rupture strain FRP (LRS-FRP). This paper also presents the first-ever experimental study on the behavior of concrete confined using hybrid LRS-FRP and SRS-FRP. LRS-FRP included PEN (polyethylene napthalate) and PET (polyethylene terephthalate) where both of them having ultimate axial strain larger than 5%, and low stiffness. SRP-FRP included carbon and glass FRP having small rupture strains, smaller than 2%, and high stiffness. The …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Epithelium Detection And Cervical Intraepithelial Neoplasia Classification In Digitized Histology Images, Sri Venkata Ravitej Addanki

Masters Theses

“Cervical cancer is one of the most deadly cancers faced by women. It is the second leading cause of cancer death in women aged 20 to 39 years. In order to detect cancer at early stages, pathologists analyze the epithelium region from the cervical histology images. These histology images have a pre-cervical cancer condition called cervical intraepithelial neoplasia (CIN) determined by pathologists. This study deals with automating the process of epithelium detection and epithelium CIN classification in digitized histology images. For epithelium detection, the objective is to detect epithelium regions in microscopy images from non-epithelium regions and background. convolutional neural …

Numerical And Experimental Analysis Of Local Buckling Of Axially Loaded Steel Tubes Confined By Concrete And Frp, Nicholas Colbert

Masters Theses

“The hollow core Fiber-Reinforced-Polymer (FRP) concrete circular-steel (HC-FCS) column consists of an outer circular fiber reinforced polymer (FRP) tube, an inner thin-walled circular steel tube concentrically aligned, and a concrete shell between them. Research has been performed on the performance of the member as a whole, but to date, there has been no investigation into the behavior of the steel tube confined in the column. 17 small-scale columns were tested under axisymmetric axial compressions applied directly to the steel tube under displacement control. The conducted parametric study examined the effects of diameter-to-thickness (D/t) ratio, concrete unconfined compressive strength, FRP thickness, …

Thermal Curing Efficiency Of Geopolymer Mortars, Simon Peter Sargon

Masters Theses

”Missouri is the fourth largest coal consumer in the U.S. with coal-fired power plants generate 81.3% of the electricity in the state which generate about 2.7 million tons of coal combustion residuals (CCRs) annually. The CCR, including fly ash, disposal issue is not limited to Missouri, rather it is a national issue with CCRs being the second largest waste stream in the U.S. Ninety million tons of fly ash are stored in landfills and ash ponds annually. Hence, using this waste product effectively is necessary. One of the emerging applications of fly ash is to use it as binder in …

Multiscale Approaches Toward Advanced Lithium-Ion Battery: From Nano To Meso Scale, Susmita Sarkar

Masters Theses

“Battery performance and its degradation are determined by various aspects such as the transport of ions and electrons through heterogeneous internal structures composed of constituent particles, kinetic reactions at the interfaces, and a corresponding interplay between mechanical, chemical, and thermal responses. Further, modern battery materials require a variety of engineering processes such as coating, doping and mixing. As a result, in order to fully understand the behavior of the battery material and improve battery performance, it is necessary to understand and control the individual particle behavior and then connect it to the electrode. This study elucidated the physical phenomena associated …

Laser-Aided Additive Manufacturing Of Glass, John Michael Hostetler

Masters Theses

“This thesis presents various approaches for the laser-aided additive manufacturing of glass. First, a technique is investigated to create free-form, low to zero coefficient of thermal expansion structures out of silica-gel. A CO₂ laser was coupled through a gantry system and focused onto a binder-free silica-gel powder bed (15-40 μm particles). Prior to writing each layer, powder is dispensed by sifting it onto the build platform as opposed to a conventional wiper system, avoiding contacting and potentially damaging sensitive parts. After deposition, the parts are annealed in a furnace to increase their strength. The influence of various process parameters …

Building Information Modeling (Bim) Impact On Construction Performance, David D. John

College of Graduate Studies: Theses & Dissertations

This study is designed to address the need for having a measure for Construction Performance on BIM-assisted construction projects. Through this study a new Construction Key Performance Indicator (CKPI) matrix is identified and created by the author. The CKPI could be used to assess BIM-assisted projects. Utilizing a sequential mixed methodology approach, academic and practitioner perspectives are assessed. A qualitative content analysis and quantitative descriptive analysis based on demographics are conducted to establish a better understanding of BIM and Construction Performance. The academic perspective is used to assess the relevance of BIMM and CKPI indicators, and the practitioner perspective is …

Geometric Optimization Of A Heaving Point Absorber Wave Energy Converter, Ian Riley

College of Graduate Studies: Theses & Dissertations

Wave energy shows significant potential for development into a competitive renewable energy source. Non-renewable resources are finite and contribute to adverse effects on the environment. Development of wave energy conversion devices that use heave motion as the primary driver for converting wave energy into electrical potential is explored through optimizing the geometry of an axisymmetric partially submerged buoy in deep water. The governing equations of motion and hydrodynamic forces are solved for in one degree of freedom using ANSYS Aqwa. An external PTO device is simulated to induce power capture in the system. Four different geometric shapes are tested and …

Structural And Aerodynamic Design, Procedure And Analysis Of A Small V-Shaped Vertical Axis Wind Turbine, Odari J. Whyte

College of Graduate Studies: Theses & Dissertations

Over the last two decades there has been a renewed interest in Vertical Axis Wind Turbines. This turbine configuration though unpopular for large-scale generation has found a niche market in the way of offshore energy harvesting. However, offshore wind has its challenges. In this thesis a detailed comprehensive study of a proposed V-shaped vertical axis turbine rotor is performed in order to examine its structural and aerodynamic characteristics. The design met and exceeded the safety parameters establish for test bed operation, showing a factor of safety of 1.87 with regard to fatigue stress response. A satisfactory fatigue stress design life …

Mazetec: A Scenario-Based Learning Platform, Daniel Bietz

College of Graduate Studies: Theses & Dissertations

This work presents Mazetec, a scenario-based learning platform for delivering non-linear scenarios format asynchronously. It enables subject matter experts to create interactive, state-dependent case studies or courses with branching logic for online learning and knowledge testing. Mazetec is a complex web application designed to deliver decision-based or case-based educational scenarios and simulations in a time-limited, non-linear format. There are many e-learning systems in the open source and commercial markets, but while these systems may have similar functions, we have found none that are both domain independent and able to deliver state-dependent content asynchronous and non-linearly. Mazetec can serve as …

Digital Forensic Tools & Cloud-Based Machine Learning For Analyzing Crime Data, Majeed Kayode Raji

College of Graduate Studies: Theses & Dissertations

Digital forensics is a branch of forensic science in which we can recreate past events using forensic tools for legal measure. Also, the increase in the availability of mobile devices has led to their use in criminal activities. Moreover, the rate at which data is being generated has been on the increase which has led to big data problems. With cloud computing, data can now be stored, processed and analyzed as they are generated. This thesis documents consists of three studies related to data analysis. The first study involves analyzing data from an android smartphone while making a comparison between …

Designing And Testing 3-D Printed Wafer-Box With Embedded Pzt Sensors To Identify The Shape Effect On Energy Harvesting, Ahmad Jami Safayet

College of Graduate Studies: Theses & Dissertations

Piezoelectric energy has been recently paid attention in the field of alternative energy. Day by day the traditional energy sources including Coal tar and oils are becoming scarce. People are heading to an alternative energy source to meet the future energy demand. Piezoelectric energy is one of the competitive energy sources compared to the conventional renewable energy sources including solar, wind, and geothermal power and so on. This energy production method bears enormous research potential because it can be used as the roadway for a new method of power generation. This research project aimed to identify which shaped wafer-box produced …

Reduced Exhaust Emissions Through Blending N-Butanol With Ultra Low Sulfur Diesel And Synthetic Paraffinic Kerosene In Reactivity Controlled Compression Ignition Combustion, Remi Gaubert

College of Graduate Studies: Theses & Dissertations

Increasing restrictions on the emitted exhaust emissions in diesel engines are becoming a more challenging task than in previous years. An electronic common rail fuel injection system and a port fuel injection (PFI) system were developed for an experimental engine to research dual fuel combustion. The experimental research was conducted at 1500 rpm and 4, 5, and 6 bar indicated mean effective pressure (IMEP). n-Butanol was port fuel injected at a 60% by mass fraction coupled with direct injection (DI) of three fuels, including ultra-low sulfur diesel (ULSD RCCI), a 50-50 wt-% blend of ULSD and butanol (ULSD-Bu RCCI), and …

Synthesis And Behavior Characterization Of Multi-Scale Hierarchical Structured Composites, Jacob M. Mayfield

College of Graduate Studies: Theses & Dissertations

The purpose of the synthesis of a multi-scale hierarchical composite material was to create a material with a high specific strength, a low mass, and high strength material. To achieve this the material categorization of the Formlabs Tough V2 resin was conducted. The resin was used in the construction of a bio-mimicry diamond lattice structure. The structure was subjected to compression testing to characterize the material properties. The Tough V2 resin structure combined with cellulose created a multi-scaled material on Macro and Micro levels to show the bio-inspired design to increase the material properties in a favorable manor. The Tough …

Application Of Machine Learning On Fracture Interference, Dennis Wayne Chamberlain Jr.

Graduate Theses, Dissertations, and Problem Reports (ETD)

A method has been developed that locates and determines well-to-well hydraulic fracture interference (frac-hit) in shale plays using hard data. This method uses Artificial Neural Networks (ANN) with designated parameters and target outputs in conjunction with graphs of gas flowrate, tubing pressure, and cumulative gas prediction. The method was created to address the significant increase in frac-hit occurrences due to the infill wells being completed in shale plays. The production data of the well is first cleaned to eliminate outliers in the initial timeframe of the well and periods of no production so that the ANN model can be accurately …

Automated Cleaning Of Identity Label Noise In A Large-Scale Face Dataset Using A Face Image Quality Control, Mohamad Al Jazaery

Graduate Theses, Dissertations, and Problem Reports (ETD)

For face recognition, some very large-scale datasets are publicly available in recent years which are usually collected from the internet using search engines, and thus have many faces with wrong identity labels (outliers). Additionally, the face images in these datasets have different qualities. Since the low quality face images are hard to identify, current automated identity label cleaning methods are not able to detect the identity label error in the low quality faces. Therefore, we propose a novel approach for cleaning the identity label error more low quality faces. Our face identity labels cleaned by our method can train better …

On Designing An Ecg-Based Intelligent System: Utilizing The Heart’S Electrical Activity To Recognize Humans And Detect Arrhythmia, Sara Saeed Abdeldayem

Graduate Theses, Dissertations, and Problem Reports (ETD)

The electrocardiogram (ECG) signal is the bioelectrical signal that reflects the heart's activity. It has been extensively used as a diagnostic tool since it holds information about the cardiac health condition. However, recent researches have shown that it exhibits an inter-subject variability property. Therefore, it can be used as a biometric-based modality for either identification or verification purposes. Nevertheless, some of the challenges are faced while employing such a signal. For instance, ECG signal is prone to noise, accordingly, noise filters should be designed to remove the noise while keeping the signal properties. Moreover, factors such as medications, health condition, …

Resilience Modeling Of Surface Transportation System In Mixed Traffic Environment, Shofiq Ahmed

Graduate Theses, Dissertations, and Problem Reports (ETD)

Large-scale natural disasters challenge the resilience of surface transportation system. The objective of this research was to develop a resilience model of surface transportation system in mixed-traffic environment considering varying Connected and Automated Vehicle (CAV) penetration scenarios. As deployment of CAVs are expected to improve traffic operations, a resilience model was developed in this research to evaluate the resilience performance of a transportation system with several CAV penetration levels (0%, 25%, 50%, 75% and 100%) for a given budget and recovery time. The proposed resilience quantification model was applied on a roadway network considering several disaster scenarios. The network capacity …

Design And Evaluation Of Novel Attitude Estimation System Using Mems Sensors For Indoor Uas, Joshua Bruce Milam

Graduate Theses, Dissertations, and Problem Reports (ETD)

Most small unmanned aerial systems in use today, employ extended Kalman filter sensor fusion algorithms in order to provide accurate estimations of attitude or orientation. These complex algorithms use measurements from GPS receivers and magnetometer sensors that can be rendered useless in GPS denied environments or areas of significant magnetic interference, such as inside buildings or other structures. The complexity of these algorithms makes them inaccessible for some researchers and hobbyists who wish to code their own attitude estimation algorithms. This complexity is also computationally expensive and requires processors that are powerful enough to operate the algorithms along with any …

Thermal-Fatigue And Thermo-Mechanical Equivalence For Transverse Cracking Evolution In Laminated Composites, Javier Cabrera Barbero

Graduate Theses, Dissertations, and Problem Reports (ETD)

Carbon fiber reinforced plastics (CFRP) are potential materials for many aerospace and aeronautical applications due to their high specif strength/weight and a low coeffcient of thermal expansion (CTE) resulting in a high long-term stability. Among candidate structures, the re-entry reusable launch vehicles (RLV), the fuel oxidant storage and transportation at cryogenic temperature, space satellites, and aircraft structure (frame, wings, etc...) can be highlighted. However, CFRP are prone to internal damage as a result of high residual stresses and thermal fatigue loading. In this study, micro-cracking damage evolution in laminated composites subjected to monotonic cooling and thermal cyclic loads is developed …

Differentiating Human Populations Based On K-Mer Classification Of Hand Bacteria, Thrisha Doppala

Graduate Theses, Dissertations, and Problem Reports (ETD)

Bacterial communities found in and on the human body are not only used in studying human health conditions but are also effective in differentiating individuals due to their distinct profiles. Human palm regions harbor relatively more diverse bacterial communities and are indicative of population groups, life styles, geographic locations, age groups and health conditions. Sequences extracted from hypervariable region V3 of the 16S rRNA bacterial gene of hand bacterial samples from 9 different population groups were classified into Operational Taxonomic Units (OTU) with GreenGenes reference taxonomy using RDP (Ribosomal Database Project) classifier. Frequencies of identified OTUs were used to study …

Investigation Of Combustion Characteristics Of A Heavy-Duty Diesel Engine Retrofitted To Natural Gas Spark Ignition Operation, Jinlong Liu

Graduate Theses, Dissertations, and Problem Reports (ETD)

The conversion of existing diesel engines to natural-gas spark ignition operation by adding a gas injector in the intake manifold for fuel delivery and replacing the diesel fuel injector with a spark plug to initiate and control the combustion process can reduce U.S. dependence on petroleum imports and curtail engine-out emissions. As the conventional diesel combustion chamber (i.e., flat head and bowl-in-piston) creates high turbulence, the engine can operate leaner, which would increase its efficiency and reduce emissions. However, natural gas combustion in such retrofitted engines presents differences compared to that in conventional spark ignited engines. Subsequently, the main goal …

The Nakahara Effect And Its Influence On Solution-Based 3d Printed Films, Daryl Kwakye-Ackah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Motivated by the Nakahara Effect, the influence of altering printing parameters on fragmentation mechanism(s) of directly written titanium dioxide(TiO₂) films is investigated. The Nakahara effect states that a long lasting memory can be introduced into a colloidal system prior to drying, affecting the type of crack pattern formed due to externally applied forces. TiO₂ has important applications due to its interesting semiconducting properties, tunable band gap, photocatalytic properties, biocompatibility, and relative abundance. This is the reason it is used in this project as a model printing ink system.

In this research, two deposition methods (i.e. direct-ink writing …

Development Of Bioreactors For Comparative Study Of Naturalattenuation, Biostimulation, And Bioaugmentation Ofpetroleum-Hydrocarbon Contaminated Soil, Mohammad-Saeed Safdari, Hamid-Reza Kariminia, Mahmood Rahmati, Farhad Fazlollahi, Alexandra Polasko, Shaily Mahendra, W Vincent Wilding, Thomas H. Fletcher

Faculty Publications

Bioremediation of soil and groundwater sites contaminated by petroleum hydrocarbons is known as a technically viable, cost-effective, and environmentally sustainable technology. The purpose of this study is to investigate laboratory-scale bioremediation of petroleum-hydrocarbon contaminated soil through development of eight bioreactors, two bioreactors for each bioremediation mode. The modes were: (1)natural attenuation (NA); (2) biostimulation (BS) with oxygen and nutrients; (3) bioaugmentation (BA)with hydrocarbon degrading isolates; (4) a combination of biostimulation and bioaugmentation (BS-BA). Total petroleum hydrocarbons (TPH) mass balance over the bioreactors showed about 2% of initial20,000 mg kg-soil−1TPH was removed by advection due to synthetic groundwater which was flow-ing …

Design Of Dna Strand Displacement Based Circuits, Aby Konampurath George

Wayne State University Dissertations

DNA is the basic building block of any living organism. DNA is considered a popular candidate for future biological devices and circuits for solving genetic disorders and several other medical problems. With this objective in mind, this research aims at developing novel approaches for the design of DNA based circuits. There are many recent developments in the medical field such as the development of biological nanorobots, SMART drugs, and CRISPR-Cas9 technologies. There is a strong need for circuits that can work with these technologies and devices. DNA is considered a suitable candidate for designing such circuits because of the programmability …

Influential Factors In Consumer's Adoption Of Innovative Products, Mahdokht Kalantari

Wayne State University Dissertations

This dissertation addresses the challenges involved with the process of diffusion of innovations in the contexts of innovative educational materials and technological innovations.

Chapters 2 and 3 discuss building and using Online Brand Communities (OBCs) to disseminate innovative math educational materials. OBCs are known to be important platforms where consumers can communicate with the brand as well as other consumers. Through the effective use of these platforms, brands could accelerate the process of diffusion of their innovations. However, OBCs will not survive if consumers do not get engaged and participate in these communities. The purpose of this section of the …

The Impact Of Machine Learning Algorithms On Benchmarking Process In Healthcare Service Delivery, Egbe-Etu Emmanuel Etu

Wayne State University Theses

Currently, organizations have adopted and implemented a variety of innovative quality management philosophies, approaches, and techniques to stay competitive in an ever-changing global economy. Benchmarking is one of such techniques deployed by organizations to stay competitive. The motivation for this research stems from a real-world problem being faced by hospitals in the healthcare industry who have amassed a ton of data and want to embark on benchmarking project to assess the performance of the emergency departments due to challenges faced with poor management of operations which has led to high patient boarding rates, high patient wait-times, poor quality service, low …

Uncertainty In Combustion Reaction Rates And Its Effects On Combustion Simulations, Joshua Piehl

Wayne State University Theses

This work investigates the uncertainties in reaction rates of an n-dodecane model on turbulent spray combustion simulations. Six major reactions were found to significantly impact the ignition delay of the mechanism in a 0-D batch reactor model. These reactions’ rates were independently modified and placed into individual mechanisms. These newly developed mechanisms were simulated in a 3-D turbulent spray simulation and a 0-D batch reactor at a pressure of 60 bar and temperatures from 900 to 1100 K. The combustion characteristics (e.g. ignition delays, flame lift-off length, liquid and vapor penetration) of the modified mechanisms were compared to those produced …