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2015

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Articles 91 - 120 of 7510

Full-Text Articles in Engineering

Momentum Of Particles From Time-Of-Flight Measurements, Joseph Best Dec 2015

Momentum Of Particles From Time-Of-Flight Measurements, Joseph Best

Senior Theses

In order to find the momentum of particles from time of flight measurements, I used a program called Geant4 to simulate experiments. I made a simple two detector setup, and I recreated a real world experiment. I spent a lot of time learning to code in C++ so I could use Geant4 correctly. I simulated these experiments shooting electrons, muons, and pions through the geometry and measured the time at two points in their flight. Subtracting the second time from the first gave me the time of flight distribution for each particle. I used ROOT to draw histograms of the …

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Optimization Of Looped Airfoil Wind Turbine (Lawt) And Looped Airfoil Hydro-Turbine (Laht) Design Parameters For Maximum Power Generation, Binhe Song Dec 2015

Optimization Of Looped Airfoil Wind Turbine (Lawt) And Looped Airfoil Hydro-Turbine (Laht) Design Parameters For Maximum Power Generation, Binhe Song

McKelvey School of Engineering Graduate Student Theses & Dissertations

This focus of this research is on the study of the aerodynamic performance of a Looped Airfoil Wind Turbine (LAWT™) using the Computational Fluid Dynamics (CFD) software. The looped airfoil wind turbine (LAWT™) is a patented new technology by EverLift Wind Technology, Inc. for generating power from wind. It takes advantage of the superior lift force of a linearly traveling wing compared to the rotating blades in conventional wind turbine configurations. Compared to horizontal and vertical axis wind turbines, the LAWT™ can be manufactured with minimal cost because it does not require complex gear systems and its blades have a …

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Data Structures And Algorithms For Scalable Ndn Forwarding, Haowei Yuan Dec 2015

Data Structures And Algorithms For Scalable Ndn Forwarding, Haowei Yuan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Named Data Networking (NDN) is a recently proposed general-purpose network architecture that aims to address the limitations of the Internet Protocol (IP), while maintaining its strengths. NDN takes an information-centric approach, focusing on named data rather than computer addresses. In NDN, the content is identified by its name, and each NDN packet has a name that specifies the content it is fetching or delivering. Since there are no source and destination addresses in an NDN packet, it is forwarded based on a lookup of its name in the forwarding plane, which consists of the Forwarding Information Base (FIB), Pending Interest …

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Automating Intensity Modulated Radiation Therapy Treatment Planning By Using Hierarchical Optimization, Paras Babu Tiwari Dec 2015

Automating Intensity Modulated Radiation Therapy Treatment Planning By Using Hierarchical Optimization, Paras Babu Tiwari

McKelvey School of Engineering Graduate Student Theses & Dissertations

The intensity modulated radiation therapy (IMRT) optimizes the beam’s intensity to deliver the prescribed dose to the target while minimizing the radiation exposure to normal structures. The IMRT optimization is a complex optimization problem because of the multiple conflicting objectives in it. Due to the complexity of the optimization, the IMRT treatment planning is still a trial and error process. Hierarchical optimization was proposed to automate the treatment planning process, but its potential has not been demonstrated in a clinical setting. Moreover, hierarchical optimization is slower than the traditional optimization. The dissertation studied a sampling algorithm to reduce the hierarchical …

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Applying Bayesian Machine Learning Methods To Theoretical Surface Science, Shane Carr Dec 2015

Applying Bayesian Machine Learning Methods To Theoretical Surface Science, Shane Carr

McKelvey School of Engineering Graduate Student Theses & Dissertations

Machine learning is a rapidly evolving field in computer science with increasingly many applications to other domains. In this thesis, I present a Bayesian machine learning approach to solving a problem in theoretical surface science: calculating the preferred active site on a catalyst surface for a given adsorbate molecule. I formulate the problem as a low-dimensional objective function. I show how the objective function can be approximated into a certain confidence interval using just one iteration of the self-consistent field (SCF) loop in density functional theory (DFT). I then use Bayesian optimization to perform a global search for the solution. …

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Intercode Advanced Fuels And Cladding Comparison Using Bison, Frapcon, And Femaxi Fuel Performance Codes, Aaren Rice Dec 2015

Intercode Advanced Fuels And Cladding Comparison Using Bison, Frapcon, And Femaxi Fuel Performance Codes, Aaren Rice

Theses and Dissertations

The high density uranium-based fuels are regaining popularity as the current fleet of LWR’s are showing interest in uprating plants to increase accident tolerance and performance. Fuels such as U3Si2, UN, and UC all contain a higher uranium loading and thermal conductivity than that of UO2 making them attractive in combination with an advanced cladding type such as the ceramic SiC cladding. In addition to adding more mass uranium to the core without surpassing current enrichment limits, these advanced fuels and claddings are designed with increased accident tolerance performance in a LOCA type scenario in mind. One of the possible …

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Development Of Ultra-Low Loading Of Compressive Pt Lattice Cathode Catalyst On Highly Stable Support For Pemfc Automotive Applications, Tianyuan Xie Dec 2015

Development Of Ultra-Low Loading Of Compressive Pt Lattice Cathode Catalyst On Highly Stable Support For Pemfc Automotive Applications, Tianyuan Xie

Theses and Dissertations

The major barriers in the commercialization of the fuel cell technology for automotive applications are the cost and durability of the Pt catalyst and the support stability at high potentials. The U.S. Department of Energy (DOE) targets direct hydrogen fuel cell systems for transportation to meet 65% peak-efficiency, 5,000 hour durability with a mass production cost of $40/kW by 2020. Currently in 2015, the system can be operated at peak energy efficiency of 60% for 3,900 hours with cost of $55/kW. To meet these targets, precious metal loadings must be greatly reduced without altering the catalyst stability. The primary objective …

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Wavelet Analysis Of Periodic Error In Heterodyne Interferometry, Chao Lu Dec 2015

Wavelet Analysis Of Periodic Error In Heterodyne Interferometry, Chao Lu

Theses and Dissertations

Heterodyne displacement measuring interferometry provides important metrology for applications requiring high resolution and accuracy. Heterodyne Michelson interferometers use a two-frequency laser source and separate the two optical frequencies into one fixed length and one variable length path via polarization. Ideally these two beams are linearly polarized and orthogonal so that only one frequency is directed toward each path. An interference signal is obtained by recombining the light from the two paths; this results in a measurement signal at the heterodyne (split) frequency of the laser source. This measurement signal is compared to the optical reference signal. Motion in the measurement …

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Assessment Of Classifiers For Potential Voice-Enabled Transportation Apps, Md Majbah Uddin Dec 2015

Assessment Of Classifiers For Potential Voice-Enabled Transportation Apps, Md Majbah Uddin

Theses and Dissertations

Transportation apps are playing a positive role for today’s technology-driven users. They provide users with a convenient and flexible tool to access transportation data and services, as well as collect and manage data. In many of these apps, such as Google Maps, their operations rely on the effectiveness of the voice recognition system. For the existing and new apps to be truly effective, the built-in voice recognition system needs to be robust (i.e., being able to recognize words spoken in different pitch and tone). The goal of this study is to assess three post-processing classifiers (i.e., bag-of-sentences, support vector machine, …

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Numerical And Experimental Investigations Of Dam And Levee Failure, Ezzat Youssef Elhassan Mohamed Elalfy Dec 2015

Numerical And Experimental Investigations Of Dam And Levee Failure, Ezzat Youssef Elhassan Mohamed Elalfy

Theses and Dissertations

Both numerical and experimental investigations are conducted to study the failure of earthen dams and levees. Boussinesq equations describing one-dimensional unsteady flow including non-hydrostatic pressure distribution are solved numerically along with Exner equation for the sediment mass conservation to include the effects of the streamline curvature on the failure of non-cohesive earthen embankments. In addition, the effects of the steep bottom slope on the flow variables during the failure are studied by solving the Saint- Venant equations modified for steep bed slope along with the Exner equation to simulate non-cohesive earthen embankment failure due to overtopping. The Boussinesq equations are …

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Identity, Critical Agency, And Engineering Majors: An Affective Model For Predicting Engineering As A Career Choice., Allison Godwin, Geoff Potvin, Zahra Hazari, Robynne Lock Dec 2015

Identity, Critical Agency, And Engineering Majors: An Affective Model For Predicting Engineering As A Career Choice., Allison Godwin, Geoff Potvin, Zahra Hazari, Robynne Lock

School of Engineering Education Faculty Publications

Prior to college, many students do not have experience with engineering, but some ultimately choose an engineering career. Additionally, women choose engineering at lower rates than men, which results in women’s underrepresentation. The framework of critical engineering agency (CEA) is utilized to understand student attitudes and beliefs for choosing engineering. We investigate the relationships among students’ math and physics identities in high school that predict choice of engineering careers; how students’ beliefs about science and technology predict a choice of engineering careers; whether these beliefs are different by gender; and how well CEA explains students’ engineering choice. The data were …

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Effects Of Cell Adhesion Peptides, Ph, And Matrix Shape On Maintenance Of Breast Cancer Stem Cells In An Engineered Hydrogel Matrix, Leily Daneshian Dec 2015

Effects Of Cell Adhesion Peptides, Ph, And Matrix Shape On Maintenance Of Breast Cancer Stem Cells In An Engineered Hydrogel Matrix, Leily Daneshian

Theses and Dissertations

Metastasis, resistance to chemo- and radiotherapy, and eventual relapse has been attributed to a tumor subpopulation known as cancer stem cells (CSCs). CSCs are regulated in their tumor microenvironment by various factors. Synthetic hydrogels can be used to investigate the effects of individual environmental factors on CSCs by providing inert 3D matrices. In this thesis, poly ethylene glycol diacrylate (PEGDA) hydrogel with 5kpa modulus has been used as a culture system to study the effect of; I) integrin and heparin binding peptides, 2) pH, and 3) the shape of the microenvironment on breast CSCs maintenance and tumorsphere formation in PEGDA. …

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Industrial Robot Acceptance: Effects Of Workforce Demographics And Establishing A Culture Of Acceptance Within Manufacturing Industry, Melissa M. Henderson Dec 2015

Industrial Robot Acceptance: Effects Of Workforce Demographics And Establishing A Culture Of Acceptance Within Manufacturing Industry, Melissa M. Henderson

Theses and Dissertations

Industrial applications have not been extensively researched regarding human-robot interaction. This project investigated industrial robot acceptance in the context of one manufacturing site. Acceptance was examined in relation to the workforce and conditions of acceptance were identified using mixed methodology. Quantitative (surveys) and qualitative (interviews) data was used to measure and analyze the existing state of technology acceptance and site culture. Based on this exploratory study, it was found the manufacturing facility has a weak culture but would be generally accepting of industrial robots if the technology were easy to use and useful. The identified boundary conditions to acceptance included …

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Supported Group Ib-Pd Bimetallic Catalysts Prepared By Electroless Deposition And Galvanic Displacement For Selective Hydrogenation Of Acetylene, Yunya Zhang Dec 2015

Supported Group Ib-Pd Bimetallic Catalysts Prepared By Electroless Deposition And Galvanic Displacement For Selective Hydrogenation Of Acetylene, Yunya Zhang

Theses and Dissertations

Ethylene is the building block for many chemical intermediates in the petrochemical industry. The current worldwide ethylene production is over 150 million tons per year and demand increases by 3-5% annually. However, ethylene produced from steam cracking of light naptha contains up to 2% acetylene which acts as a poison for the downstream ethylene polymerization catalysts. Selective hydrogenation of acetylene in the ethylene stream using supported Pd catalysts is the industrially preferred method of lowering acetylene to acceptable ppm levels (< 5 ppm). Due to inferior selectivity at high acetylene conversion and the formation of “green oil”, or ethylene/acetylene oligomers, during reaction, small amounts of Group IB metals have been added to improve the performance of current generation catalysts. However, the bimetallic effects of the above additives have not been experimentally confirmed, possibly because the conventional methods of catalyst preparation result in both monometallic and bimetallic particles with varying compositions. This in turn makes it difficult to determine the position of the two metallic components, and bimetallic interactions typically occur only when the two metals form proximal contact instead of separate particles. In this study, a series of Ag- and Au-Pd/SiO2 bimetallic catalysts were prepared by electroless deposition (ED) with incremental and controlled coverages of Ag and Au on Pd. The selectivity of acetylene to ethylene and turnover frequencies of acetylene conversion were enhanced at high coverages of Ag and Au on Pd surfaces due to the transition of acetylene adsorption modes, which was further confirmed by the kinetics of acetylene hydrogenation. The similar performance trends for Ag- and Au-Pd/SiO2 suggest that the bimetallic effect for these catalysts was likely geometric and not electronic in nature. For comparison, a series of reverse Pd-Ag/SiO2 bimetallic catalysts where variable coverages of Pd were deposited onto Ag surfaces was prepared using galvanic displacement (GD) of Ago by Pd2+ to further explore the nature of bimetallic effects for selective acetylene hydrogenation. Unlike for the earlier case for Ag on Pd surfaces using ED, for samples prepared by GD there was considerably diffusion of Pd into the Ag lattice to give greater electronic interactions between these two metals, which limited selectivity of acetylene hydrogenation to form ethylene.

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Development Of Highly Active And Stable Hybrid Cathode Catalyst For Pemfcs, Won Suk Jung Dec 2015

Development Of Highly Active And Stable Hybrid Cathode Catalyst For Pemfcs, Won Suk Jung

Theses and Dissertations

Polymer electrolyte membrane fuel cells (PEMFCs) are attractive power sources of the future for a variety of applications including portable electronics, stationary power, and automobile application. However, sluggish cathode kinetics, high Pt cost, and durability issues inhibit the commercialization of PEMFCs. To overcome these drawbacks, research has been focused on alloying Pt with transition metals since alloy catalysts show significantly improved catalytic properties like high activity, selectivity, and durability. However, Pt-alloy catalysts synthesized using the conventional impregnation method exhibit uneven particle size and poor particle distribution resulting in poor performance and/or durability in PEMFCs. In this dissertation, a novel catalyst …

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Drones In Logistics: A Feasible Future Or A Waste Of Effort, Andrew Lotz Dec 2015

Drones In Logistics: A Feasible Future Or A Waste Of Effort, Andrew Lotz

Honors Projects

On December 1st, 2013 news around the world was filled with headlines about E- Commerce website Amazon.com. CEO of Amazon Jeff Bezos announced to the world that Amazon was designing a drone delivery program called Amazon Air that could deliver packages to customers in just 30 minutes. Consumers were all too excited for the program to launch while many business and air traffic savvy people were highly skeptical. Now two years later research to look back at the feasibility of drone flight and whether investment into the technology is worth it for small deliveries straight to customers is …

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Experimental Study Of Longitudinal Sorting Of Particles Differing In Size And Density, Nabila Mahjabeen Dec 2015

Experimental Study Of Longitudinal Sorting Of Particles Differing In Size And Density, Nabila Mahjabeen

Theses and Dissertations

Transport, deposition and erosion of sediment particles differing in size, shape and density may result in particle segregation, which in geosciences applications is generally referred to as sediment sorting. A thorough understanding of sediment sorting processes is important to describe and model a wide variety of natural processes such as the decrease in particle size and/or density in a fluvial system (downstream fining and/or lightening), the formation of economic placers, concentration of heavy minerals, chemical and metal pollutants etc. Sorting of sediment grains associated with sediment transport in the streamwise direction results in the development of longitudinal sorting patterns. Vertical …

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Confluence Of Density Currents Over An Erodible Bed, Hassan Ismail Dec 2015

Confluence Of Density Currents Over An Erodible Bed, Hassan Ismail

Theses and Dissertations

Results from laboratory experiments on conservative density current confluence are reported. Hydraulic characteristics and morphodynamic consequences of the confluence of two continuous release density currents in a horizontal, 45 degree asymmetrical junction are examined and compared to those of terrestrial river junctions. It was observed that density current confluence is markedly different than those in river junctions primarily due to the ease of the dense fluid to convect into the ambient fluid in the junction zone. Upward convection in the junction resulted in low horizontal velocity and shear stresses on the bed of the junction zone, followed by re-plunging to …

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Tool Material Degradation Due To Friction Stir Welding Of Aluminum Alloys, Corbin T. Collier Dec 2015

Tool Material Degradation Due To Friction Stir Welding Of Aluminum Alloys, Corbin T. Collier

Theses and Dissertations

The purpose of this study is to investigate the friction stir welding (FSW) tool material degradation factors due variation in tool material properties and the effect of an aluminum diffusion wear mechanism on three different FSW tool material when exposed to various welding temperatures and times. The degradation factors are essential to FSW tool design due to the effect of the tool pin and shoulders on the heat generation and material flow which directly correlated to the weld quality created during the FSW process. For this investigation the three materials used are H13, TSP1, and MP159. To determine degradation factors …

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Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao Dec 2015

Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao

Theses and Dissertations

Pt-Ru bimetallic catalysts are widely used for direct methanol fuel cells, biomass upgrading and hydrocarbon refining and offer unique properties compared to Pt or Ru monometallic catalysts due to ensemble effects, electronic effects, and/or bifunctional effects. To achieve better performance, strong metal-metal interactions and true bimetallic surface are needed. Electroless deposition (ED) methods are used in our laboratory to synthesize such bimetallic catalysts. In this study, two series of Ru@Pt/C (Pt deposited on Ru surfaces) and Pt@Ru/C (Ru deposited on Pt surfaces) catalysts have been synthesized. Characterization data from temperature programmed reduction (TPR), selective chemisorption, X-ray photoelectron spectroscopy (XPS), and …

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Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao Dec 2015

Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao

Theses and Dissertations

This work seeks a better understanding of mechanical reinforcement and energy dissipation in elastomer composites containing the layered silicate magadiite (MGD, Na2Si14O29·nH2O). We characterized the elastomer’s accessibility into MGD interlayer spaces and studied the factors that influence the composite mechanical properties. We also compare the mechanical reinforcement of MGD with montmorillonite (MMT, a layered aluminosilicate clay mineral), which is widely used as filler in other kinds of nanocomposites. The study explores the grafting chemistry, vulcanization, and reinforcement mechanism in MGD/elastomer composites, which may help us to formulate the platelet/elastomer composites with superior mechanical properties and performance in the future. We …

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Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed Dec 2015

Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed

Theses and Dissertations

Primary objective of this work is to introduce the multi-scale computational model for the bio-inspired acousto-ultrasonic band pass sensor that are capable of mechanically sense and/or filter wide range user defined frequencies. Selecting a particular and/or a distinct band of frequencies is essential for many applications in science engineering and technologies. For example design of sensors in chemical, biomedical and biological applications; device application for acoustic modulation by breaking the acoustic reciprocity and the sensors used in precision manufacturing applications requires sensing and/or filtering of wide range of acousto-ultrasonic frequencies. Presently, electronic devices are widely employed in commercial applications for …

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Dielectric Characteristics Of Microstructural Changes And Property Evolution In Engineered Materials, Jallisa Janet Clifford Dec 2015

Dielectric Characteristics Of Microstructural Changes And Property Evolution In Engineered Materials, Jallisa Janet Clifford

Theses and Dissertations

Heterogeneous materials are increasingly used in a wide range of applications such as aerospace, civil infrastructure, fuel cells and many others. The ability to take properties from two or more materials to create a material with properties engineered to specific needs is always very attractive. Hence engineered materials are evolving into more complex formulations or heterogeneities in multiple disciplines. Design of microstructure at multiple scales controls the global functional properties of these materials and their structures. However, local microstructural changes do not directly cause a proportional change to the global properties (such as strength and stiffness). Instead, local changes follow …

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In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang Dec 2015

In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang

Theses and Dissertations

The reduction of automotive exhaust emissions has been one of the hottest topics in catalysis community since 1970s. Thanks to the development of three-way catalysts, main auto-exhaust pollutants, such as carbon monoxide, nitrogen oxides and unburned hydrocarbons, can be removed simultaneously. Nowadays, diesel engines and lean-engines become more and more popular due to their high fuel-efficiency and low CO2 emissions. Unfortunately, conventional three-way catalysts are not effective at reducing the NOx emissions from these engines due to the excess oxygen in the exhaust stream. Platinum catalysts were found to be highly active for selective NO reduction with hydrocarbons in excess …

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A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin Dec 2015

A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin

Theses and Dissertations

Cost-effective and large scale energy storage is essential for the growth of the future’s ‘‘green energy’’ infrastructure. Among the energy storage technologies currently being used, rechargeable batteries represent a class of advanced electrical energy storage (EES) mechanisms that can be valuable for the future renewable integration and smart grid. Rechargeable batteries have innumerous advantages over the conventional pumped hydro and compressed-air energy storage system. Now days, There are various types of rechargeable batteries available to work as an energy storage device in a smart grid but it still needs many breakthroughs to become commercially viable for stationary energy storage. First …

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Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab Dec 2015

Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab

Theses and Dissertations

The continued miniaturization of electronic device components requires new lightweight polymers with high thermal stability, high thermal conductivity, low electrical conductivity, and low dielectric constant. Composites of nanodiamond (ND) and poly(ether ether ketone) (PEEK) are candidates for these applications due their unique combination of properties. The objectives of this research are to explore new routes for surface functionalization of nanodiamond (ND), develop methods for maximizing dispersion of ND as a nano-scale filler in PEEK, and characterize the effect of dispersed ND on the mechanical, thermal and dielectric properties of ND/PEEK composites. Initial attempts to disperse different kinds of commercially available, …

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Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian Dec 2015

Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian

Theses and Dissertations

Damage detection and health monitoring are critical for ensuring the structural safety in various fields, such as aerospace, civil and nuclear engineering. Structural health monitoring (SHM) performs online nondestructive evaluation (NDE) and can predict the structural remaining life through appropriate diagnosis and prognosis technologies. Among various SHM/NDE technologies, guided ultrasonic waves have shown great potential for fast and large area SHM/NDE, due to their sensitivity to small defects and capability to propagate long distances. Recent advances in guided wave based SHM/NDE technologies have demonstrated the feasibility of detecting damage in simple structures such as metallic plates and pipes. However, there …

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Nd − Pdpa: N Dimensional Probability Density Profile Analysis, Arjang Fahim Dec 2015

Nd − Pdpa: N Dimensional Probability Density Profile Analysis, Arjang Fahim

Theses and Dissertations

Proteins are often referred as working molecule of a cell, performing many structural, functional and regulatory processes. Revealing the function of proteins still remains a challenging problem. Advancement in genomics sequence projects produces large protein sequence repository, but due to technical difficulty and cost related to structure determination, the number of identified protein structure is far behind. Novel structures identification are particularly important for a number of reasons: they generate models of similar proteins for comparison; identify evolutionary relationships; further contribute to our understanding of protein function and mechanism; and allow for the fold of other family members to be …

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Evolution Of Non-Metallic Inclusions In Foundry Steel Casting Processes, Marc Harris, Von Richards, Ronald J. O'Malley, Semen Naumovich Lekakh Dec 2015

Evolution Of Non-Metallic Inclusions In Foundry Steel Casting Processes, Marc Harris, Von Richards, Ronald J. O'Malley, Semen Naumovich Lekakh

Materials Science and Engineering Faculty Research & Creative Works

The evolution of nonmetallic inclusions was examined for 4320 steel at an industrial steel foundry. The steel was followed from electric arc furnace melting through ladle refining to final casting. Timed sampling was performed at all stages of the process. Samples were analyzed using an automated SEM/EDS system. The overall evolution of oxide inclusions in terms of nucleation, growth, and flotation during liquid processing was studied using area fraction and average diameter. Chemical composition evolution was observed using a joint ternary plotting tool developed under this program. It was found that the use of zirconium as an addition for nitrogen/oxygen …

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High Capacity Silicon Electrodes With Nafion As Binders For Lithium-Ion Batteries, Jiagang Xu, Qinglin Zhang, Yang-Tse Cheng Dec 2015

High Capacity Silicon Electrodes With Nafion As Binders For Lithium-Ion Batteries, Jiagang Xu, Qinglin Zhang, Yang-Tse Cheng

Chemical and Materials Engineering Faculty Publications

Silicon is capable of delivering a high theoretical specific capacity of 3579 mAh g−1 which is about 10 times higher than that of the state-of-the-art graphite based negative electrodes for lithium-ion batteries. However, the poor cycle life of silicon electrodes, caused by the large volumetric strain during cycling, limits the commercialization of silicon electrodes. As one of the essential components, the polymeric binder is critical to the performance and durability of lithium-ion batteries as it keeps the integrity of electrodes, maintains conductive path and must be stable in the electrolyte. In this work, we demonstrate that electrodes consisting of …

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