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2005

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Articles 151 - 180 of 3074

Full-Text Articles in Engineering

Architecture And Execution Model For A Survivable Workflow Transaction Infrastructure, Haraldur D. Thorvaldsson, Kenneth J. Goldman Dec 2005

Architecture And Execution Model For A Survivable Workflow Transaction Infrastructure, Haraldur D. Thorvaldsson, Kenneth J. Goldman

All Computer Science and Engineering Research

We present a novel architecture and execution model for an infrastructure supporting fault-tolerant, long-running distributed applications spanning multiple administrative domains. Components for both transaction processing and persistent state are replicated across multiple servers, en-suring that applications continue to function correctly de-spite arbitrary (Byzantine) failure of a bounded number of servers. We give a formal model of application execution, based on atomic execution steps, linearizability and a sep-aration between data objects and transactions that act on them. The architecture is designed for robust interoperability across domains, in an open and shared Internet computing infrastructure. A notable feature supporting cross-domain applications is …


A Performance Evaluation Of A Homogeneous Wireless Network Using Opnet It Guru, Roy Lee Gentry Jr. Nov 2005

A Performance Evaluation Of A Homogeneous Wireless Network Using Opnet It Guru, Roy Lee Gentry Jr.

Morehead State Theses and Dissertations

A thesis presented to the faculty of the College of Science and Technology at Morehead State University in partial fulfillment of the requirements for the Degree of Master of Science by Roy Lee Gentry Jr. on November 30, 2005.


Inertial Navigation System, Michael Calabrese Jr., David Engblom, Aaron Fleckenstein Nov 2005

Inertial Navigation System, Michael Calabrese Jr., David Engblom, Aaron Fleckenstein

Honors Theses

Accelerometer-based inertial navigation systems present an inexpensive alternative to gyroscope and global positioning navigation systems. An array of accelerometers comprises the basic design of the inertial navigation system. The position of the device can be continuously updated based on the previous device location and measurements of the device acceleration. There are fewer moving parts in an accelerometer-based system than in a gyroscopic device, and it is free of the earth bound constraints of a global positioning system. The prototype wirelessly interfaces with a data-collection system, which processes the data and provides a graphical display of the trajectory traveled.

Two accelerometer …


A New Method For The Rapid Calculation Of Finely-Gridded Reservoir Simulation Pressures, Benjamin Arik Hardy Nov 2005

A New Method For The Rapid Calculation Of Finely-Gridded Reservoir Simulation Pressures, Benjamin Arik Hardy

Theses and Dissertations

A new method for the determination of finely-gridded reservoir simulation pressures has been developed. It is estimated to be as much as hundreds to thousands of times faster than other methods for very large reservoir simulation grids. The method extends the work of Weber et al. Weber demonstrated accuracies for the pressure solution normally requiring millions of cells using traditional finite-difference equations with only hundreds of cells. This was accomplished through the use of finite-difference equations that incorporate the physics of the flow. Although these coarse-grid solutions achieve accuracies normally requiring orders of magnitude more resolution, their coarse resolution does …


Reactivity Study Of Platinum Nanoparticles And Nanowires Inside The Channels Of Mesoporous Silica, Marcus R. Smith Nov 2005

Reactivity Study Of Platinum Nanoparticles And Nanowires Inside The Channels Of Mesoporous Silica, Marcus R. Smith

Chemical and Biological Engineering ETDs

Pt metal nanowires and nanoparticles were prepared using mesoporous silica as the template. Mesoporous silica with straight 1-dimensional, tortuous 1-dimensional and 3-dimensional channels was used. The experimental techniques included CO oxidation, Chemisorption, XRD, and STEM. CO oxidation and chemisorption provided the data to calculate the intrinsic reactivity, known as turn over frequency (TOF). Powder XRD was used to measure line broadening. The FWHM of the XRD line broadening was used with the Scherrer formula to determine Pt metal crystallite size. STEM images permitted for the measurement of the particle diameters, and the determination of morphology.

Two commercially available reference samples …


The High Temperature Corrosion Of 2205 Duplex Stainless Steel With Nacl Deposit, Fu-Fu Peng, Chaur-Jeng Wang, Yu-Chang Lin Nov 2005

The High Temperature Corrosion Of 2205 Duplex Stainless Steel With Nacl Deposit, Fu-Fu Peng, Chaur-Jeng Wang, Yu-Chang Lin

Journal of Electrochemistry

The objective of this study was to figure out the hot corrosion behavior of 2205 duplex stainless steel (2205 DSS) within the temperature ranges from 550 to 850℃ in the static air condition with 2 mg/cmNaCl deposit, and in the air atmosphere condition with a constant flow rate of 500 vppm NaCl(g), respectively. Experimental results show that the hot corrosion kinetics met the parabolic rate law and the corrosion rate increased constantly with increasing temperature. The scales formed included Fe2O3/Fe3O4/Cr2O3 and FeCr2O4 …


An Investigation On Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether) Coatings Modified By Rutile Nano-Tio2 Pastes, Xiang Bin, Sheng-Tao Zhang, Yan Li, Bao-Rong Hou Nov 2005

An Investigation On Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether) Coatings Modified By Rutile Nano-Tio2 Pastes, Xiang Bin, Sheng-Tao Zhang, Yan Li, Bao-Rong Hou

Journal of Electrochemistry

The anti-corrosion coating of Poly(Vinyl Chloride-Co-Isobutyl Vinyl Ether) (PVCCIVE) was modified by rutile nano-TiO2. The influence of nano-TiO2 pastes on the coating's corrosion resistance was investigated through electrochemistry impedance spectroscopy (EIS). The results show that the addition of nano-TiO2 pastes does not have obvious effect on the coating's performance of adhesion, flexility, impact resistance, but improves the coating's UV resistance and the gloss.Meanwhile,with the proper addition of rutile nano-TiO2 pastes, the anti-corrosion behavior of the coating was advanced.


A Study Of Overcharge Characteristic Of Lithium-Ion Cells, Jing Pang, Shi-Gang Lu, Sha Liu Nov 2005

A Study Of Overcharge Characteristic Of Lithium-Ion Cells, Jing Pang, Shi-Gang Lu, Sha Liu

Journal of Electrochemistry

The overcharge characteristics and effect factors of lithium-ion cells containing LiMn2Ocathodes were studied in detail. Overcharge testing of Lithium-ion cells with a systematic variation in the cell balance demonstrated that the overcharge characteristics of Lithium-ion cells was affected by the amount of cathode in the cells, which is independent of the amount of anode material. The rate of charge was found to be an important parameter, as electrolyte complete decomposition at low charge rates caused the end of overcharge testing, while high charge rates accelerated the rate of heat generation in the cells and the cell …


An Electrochemical Study Of Electroless Copper Plating Using Glyoxylic Acid As Reducing Agent, Li-Qiong Wu, Fang-Zu Yang, Ling Hang, Shi-Gang Sun, Shao-Min Zhou Nov 2005

An Electrochemical Study Of Electroless Copper Plating Using Glyoxylic Acid As Reducing Agent, Li-Qiong Wu, Fang-Zu Yang, Ling Hang, Shi-Gang Sun, Shao-Min Zhou

Journal of Electrochemistry

The electroless copper plating using glyoxylic acid as a reducing agent,Na2EDTA as a chelating agent and K4FeCN6 and 2,2'-dipyridyl as additives was studied. The effect of chelating agent and addtives on the polangation behaviovs of copper reduction and glyoxylie acid oxidation were analyzed by linear sweep voltammetry. The results mainly demonstrated that the chelating agent hindered both the oxidation of glyoxylic acid and the reduction of copper complexing ions. It has revealed that K4FeCN6 and 2,2'-dipyridyl (with the content over than 20 mg/L) both played negative actions on the oxidation of glyoxylic …


The Deactivation Mechanism Of Metal Oxide Anodes Under Alternative Current Electrolysis Condition, Jun-Tao Wang, Yan Han, Guang-Zhang Chen, Wen-Fa Liu Nov 2005

The Deactivation Mechanism Of Metal Oxide Anodes Under Alternative Current Electrolysis Condition, Jun-Tao Wang, Yan Han, Guang-Zhang Chen, Wen-Fa Liu

Journal of Electrochemistry

The metal oxide anodes coated on titanium used in seawater electrolysis were prepared by thermal decomposition. Their morphologies, compositions and phase structures were determined by scanning electron microscope(SEM), energy dispersive X-ray detector(EDX) and X-ray diffraction(XRD). The electrochemical properties of the anodes were characterized by accelerated life test, cyclic voltammetry and electrochemical impedance spectroscopy. SEM, EDX and XRD showed that solid solution structures of (Ru, Ir, Ti)O2 and (Ir, Ti)O2 were formed after pyrolysis, the solid solution structures and active components were disappeared after the deactivation of the anodes. Electrochemical results indicated that the active area decreased and the …


Copper Electrodeposition Under The Perturbation Of Hard Particles, Zeng-Wei Zhu, Di Zhu Nov 2005

Copper Electrodeposition Under The Perturbation Of Hard Particles, Zeng-Wei Zhu, Di Zhu

Journal of Electrochemistry

Copper electrodepositon was carried out on the rotating cathode,with hard particles(such as ceramic beads) filling between the electrodes. The rotation of cathode led hard particles to polish and impact the surface of deposit during electrodeposition.Copper deposits with a mass of cuspidal nodules were produced in acid sulfate solutions while brittle deposits without nodules were produced in alkaline sulfate solutions. It was also found that brightening and smoothing deposit could be obtained from the alkaline solution, and the deposit was approximatively disordered orientation with granular morphology of about 100~300 nm. The results show that the polishing and impact of hard particles …


Silicides And Composites Materials As Anodes For Lithium Ion Batteries, Jun-Mei Yan, Hui-Zhen Huang, Jing Zhang, Yong Yang Nov 2005

Silicides And Composites Materials As Anodes For Lithium Ion Batteries, Jun-Mei Yan, Hui-Zhen Huang, Jing Zhang, Yong Yang

Journal of Electrochemistry

The anode materials of Mg2Si and MnSi were synthesized by mechanically activated annealing(MAA) techniques in this work and the in electrochemical performances were also studied.A series of composite materials of Mg2Si and CNTs or CMS were prepared by ball-milling method respectively. The reversible capacities of the composites were higher than that of the pure Mg2Si and pure carbon materials.The cyclic performances have been improved greatly by ball-milling of the Mg2Si and carbon materials. Results show that ball-milling method is one kind of method to make alloy materials into practical use.


Electrochemical Disinfection Method To Treat Wastewater From Hospitals, Zhi-Fu Li, Ya-Dong Tan, Ning Xu, Shao-Hong Ren, Yu Zhao Nov 2005

Electrochemical Disinfection Method To Treat Wastewater From Hospitals, Zhi-Fu Li, Ya-Dong Tan, Ning Xu, Shao-Hong Ren, Yu Zhao

Journal of Electrochemistry

Electrochemical disinfection method was used to treat wastewater from hospitals. The mechanism of electrochemical disinfection was researched by using the different anode materials. The results showed that when the titanium coated with noble metal (Ru, Pt, Ir)oxide was used as an anode and stainless steel as a cathode, the current density was 6 mA/cm2, hydraulic retention time was 15 min,air flow rate was 40 L/h, the rate of anode effective area to the inner water volume was 1.0, the amount of total colibacillus was below 500 CFU/L after electrochemical disinfection,All these meet the first order of Effluent Discharge …


A Continuous Operation For Electroreduction Of Oxalic Acid To Glyoxylic Acid, Xiao-Hui Hu, Xiang-Fei Yan, Yu-Zhong Su, Jun Li, Qing-Biao Li Nov 2005

A Continuous Operation For Electroreduction Of Oxalic Acid To Glyoxylic Acid, Xiao-Hui Hu, Xiang-Fei Yan, Yu-Zhong Su, Jun Li, Qing-Biao Li

Journal of Electrochemistry

A simulative-continuous-operation approach was proposed to study the continuous operation for electroreduction of oxalic acid to gloxylic acid using a packed bed reactor and a parallel reactor with cooled cathode in order to solve the low productivity problem in current state by using traditional reactor. The effects of the concentration of oxalic acid and temperature on this process were also studied. Results showed that,after 30min of the reaction(residence time), the mass fraction of the produced glyoxylic acid in the catholic solution could reach 3.76% and 3.66% with respect to a saturated oxalic acid method and a step-temperature decreasing method. From …


The Mechanism Of Ethylenediamine On Electroless Ni-B Alloy Deposition, Sen-Lin Wang Nov 2005

The Mechanism Of Ethylenediamine On Electroless Ni-B Alloy Deposition, Sen-Lin Wang

Journal of Electrochemistry

The effects of ethylenediamine stabilizer on the deposition rate and on the stability of the plating bath for electroless deposition of Ni-B alloy were investigated. It was found that the addition of ethylenediamine greatly enhances the stability of the electroless plating bath. The electrochemical polarization including cathodic and anodic polarizations measurements were carried out to examine the effect of ethylenediamine on the deposition process. The results show that ethylenediamine affects both the cathodic and the anodic polarization processes. The oxidation current of the reducer and the reduction current of Ni-B alloy decrease greatly when ethylenediamine was added into the plating …


Electrochemical Controllable Preparation Of Hydroxyapatite Coating With Different Morphologies And Preliminary In Vitro Tests, Hai-Yan Shi, Ren Hu, Chang-Jian Lin Nov 2005

Electrochemical Controllable Preparation Of Hydroxyapatite Coating With Different Morphologies And Preliminary In Vitro Tests, Hai-Yan Shi, Ren Hu, Chang-Jian Lin

Journal of Electrochemistry

The Controllable electrochemical deposition has been developed to prepare the hydroxyapatite(HA) coatings on Ti substrate with different morphologies and structures. Three kinds of typical topography of HA coatings, i.e. standing-up, flower and ordered porous structures have been obtained. The XRD and FTIR results demonstrate high crystallinity of the coating and exclusion of other forms of calcium phosphates. In vitro tests reveal that the biological property is largely dependent on the structure and morphology of the HA coating. It has been found that all pure HA coating show good biocompatibilities, while only the HA coating with ordered porous structures exhibits best …


Ferroelectric Switch For Spin Injection, Mikhail Ye. Zhuravlev, Sitaram Jaswal, Evgeny Y. Tsymbal, Renat F. Sabirianov Nov 2005

Ferroelectric Switch For Spin Injection, Mikhail Ye. Zhuravlev, Sitaram Jaswal, Evgeny Y. Tsymbal, Renat F. Sabirianov

Materials Research Science and Engineering Center: Faculty Publications

A method for the switching of the spin polarization of the electric current injected into a semiconductor is proposed, based on injecting spins from a diluted magnetic semiconductor through a ferroelectric tunnel barrier. We show that the reversal of the electric polarization of the ferroelectric results in a sizable change in the spin polarization of the injected current, thereby providing a two-state electrical control of this spintronic device. We also predict a possibility of switching of tunneling magnetoresistance in magnetic tunnel junctions with a ferroelectric barrier and coexistence of tunneling magnetoresistance and giant electroresistance effects in these multiferroic tunnel junctions.


Interior Node Projection Techniques In Sweeping Algorithms, Michael Andrew Scott Nov 2005

Interior Node Projection Techniques In Sweeping Algorithms, Michael Andrew Scott

Theses and Dissertations

The enhancement of node projection techniques in sweeping is the subject of this thesis. Sweeping is a method used to produce all-hexahedral finite element meshes on certain classes of geometry. The placement of nodes in the interior of the geometry during the sweeping process remains a difficult problem. This thesis presents advancements in this area which improve the speed of the algorithm and the resulting element quality. A comparison of existing projection methods was performed. The existing Faceted projection sweeping method was extended to be applicable to more general classes of sweepable geometry. This comparison and extension of node projection …


A Gasless Method Of Spraying Thermoplastic Resin, Dan T. Rogers Nov 2005

A Gasless Method Of Spraying Thermoplastic Resin, Dan T. Rogers

Theses and Dissertations

This spraying method for thermoplastic resins is a new manufacturing process for applying thermoplastics to a mold or surface in an efficient way that has the potential of reducing cycle time. Spraying thermoplastic resins is similar to spraying other polymers, such as paint, with the differences being higher pressure and temperature. This method uses an injection molding machine with a modified nozzle to spray the plastic material. In this study, temperature, pressure, and nozzle size were factors that influenced the success of this spraying method. The method of spraying in this study proved spraying without a gas is possible, a …


The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu Nov 2005

The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu

Journal of Electrochemistry

The optimal sulfonation condition of self-doped sulfonated polyaniline (prepared from leucoemeraldinebase; denoted as LEB-SPANI) with a high electronic conductivity was obtained by experimental strategies, includingthe fractional factorial design (FFD) and central composite design (CCD). From the FFD experiment, the self-doped LEB-SPANI prepared at a lowtemperature (4℃), a short reaction time (1 h), and a small volume of fumingsulfuric acid (10 mL) showed a better conductivity (ca.127 mS/cm). In the CCD study coupled with a confirmationtest, the highest conductivity (ca.141 mS/cm) of the LEB-SPANI film was obtained under a sulfonation temperatureof 4℃, a sulfonation time of 75 minutes, and a volume …


A Study Of Three Corrosion Inhibitors For Reinforcing Steel In Sps Solution By Electrochemical Methods, Bing Zhao, Rong-Gui Du, Chang-Jian Lin Nov 2005

A Study Of Three Corrosion Inhibitors For Reinforcing Steel In Sps Solution By Electrochemical Methods, Bing Zhao, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

Some electrochemical techniques such as linear polarization,electrochemical noise and EIS have been employedto study the inhibition behavior of N-lauroyl sarcosinate, β-sodium glycerophosphate and D-sodium gluconate for the reinforcing steel immersed in simulated concrete pore solution(SPS) with NaCl addition.The results show that D-sodium gluconatehas an obvious inhibitive effect for the reinforcing steelin containing Cl- SPS solution. It has been proposed that the corrosion inhibition of D-sodium gluconate is due to its competitive adsorption and precipitation on steel surface in the simulated concrete environment.


Effect Of Hco3- Concentration On Co2 Corrosion In Gas And Oil Fields, Guo-An Zhang, Min-Xu Lu, Yin-Shun Wu Nov 2005

Effect Of Hco3- Concentration On Co2 Corrosion In Gas And Oil Fields, Guo-An Zhang, Min-Xu Lu, Yin-Shun Wu

Journal of Electrochemistry

The effecs of HCO3concentration on CO2 corrosion in gas and oil fields were investigated by carrying out potentiodynamic scans and weight loss tests.Potentiodynamic polarization curves showed that the cathodic current density decreased with cm increase of HCO3concentration when HCO3- was lower than 0.042(mol/L). The cathodic reations were promoted by increasing HCO3- when it reached 0.126 mol/L, Anodic behavior was an active process at low er [HCO3-] concentration and the anodic current density decreased with the increase of [HCO3-] concentration. An evident active-passive behavior …


Electrochemical Oxidation Of Organic Additives In Tin Plating Electrolytes, Yin-Mei Cheng, Lan-Kun Cai, Qiang Song Nov 2005

Electrochemical Oxidation Of Organic Additives In Tin Plating Electrolytes, Yin-Mei Cheng, Lan-Kun Cai, Qiang Song

Journal of Electrochemistry

Cyclic voltammetry(CV) was used to characterize the voltammetric behaviours of organic additives, e.g. PSA(phenolsulfonic acid) EN(ethoxylatedα-naphthol) and ENSA(ethoxylatedα-naphthol sulfonic acid), on the anode surface. In PSA solutions, an anodic peak was obtained and the peak potential was about 1.2V. In EN and ENSA solutions, two anodic peaks were obtained and the peak potentials were about(0.95V) and 1.3V. The products of galvanostatic electrolysis were separated by HPLC(high performance liquid chromatography) and analyzed by EI/MS(electron ionizing mass spectrometry). The mechnism of the electrochemical oxidation was also disussed.


The Electrocatalystic Investigation Of 3,4-Dihydroxybenzoic Acid On The Modified Multiply Wall Carbon Nanotubes, Ming-Qi Li, Duo-Chang Cai, Xiao-Ying He Nov 2005

The Electrocatalystic Investigation Of 3,4-Dihydroxybenzoic Acid On The Modified Multiply Wall Carbon Nanotubes, Ming-Qi Li, Duo-Chang Cai, Xiao-Ying He

Journal of Electrochemistry

The electrochemical behavior of 3,4-Dihydroxybenzoic acid(DHBA) on modified multiply wall carbon nanotubes electrode was investigated by cyclic voltammetry(CV) and square wave voltammetry(SWV). Results show that in 0.1 mol/L HCl solutions the modified carbon nanotube electrode has an obvious electrocatalytic effect on the oxidation and deoxidization of DHBA. The oxidation current of DHBA is linear to it's concentration in the range of 4.0×10-6~1.0×10-4 mol/L and 2.0×10-4~8.0×10-4 1mol/L with correlation coefficient of 0.9995 and 0.9992. The detection limit is 1.0×10-6 mol/L.


Solid Oxide Fuel Cells-Materials And Prospects, Molenda Janina, Marzec Jacek Nov 2005

Solid Oxide Fuel Cells-Materials And Prospects, Molenda Janina, Marzec Jacek

Journal of Electrochemistry

The paper summarizes and discusses the basic properties of solid oxide fuel cell (SOFC) components (electrode materials and electrolyte) from the point of view of their essential functional parameters suck as chemicalstability, transport, catalytic and thermomechanical properties under operational conditions in a SOFC. An interrela-tion between the defect structure of these materials related to oxygen nonstoichiometry and their electronic propertiesand catalytic activity was shown. Single-chamber fuel cell concept was also presented.


Genetic Engineering Of Plants Through Manipulation Of Lignin Biosynthesis, Vincent Lee C. Chiang, Chung-Jui Tsai, Wen-Jing Hu Nov 2005

Genetic Engineering Of Plants Through Manipulation Of Lignin Biosynthesis, Vincent Lee C. Chiang, Chung-Jui Tsai, Wen-Jing Hu

Michigan Tech Patents

The invention pertains to the genetically down regulating a lignin pathway p-coumarate Co-enzyme A ligase (CCL) in trees.


Object Oriented Cae Software For The Exploration And Design Of Microstructures, Stephen D. Sintay Nov 2005

Object Oriented Cae Software For The Exploration And Design Of Microstructures, Stephen D. Sintay

Theses and Dissertations

Through the use of generalized spherical harmonic basis functions a spectral representation is used to model the microstructure of cubic materials. This model is then used to predict the macroscopic elastic and plastic properties of materials with cubic crystal symmetry and various sample symmetry including triclinic and axial—symmetric. Building on the work of citeN{Barnett-FractureMechanics} the influence that anisotropy has on the fatigue response of the material is also modeled. This is accomplished through using the effective elastic stiffness tensor in the computation of crack extension force G. The resulting material model and macroscopic property calculations are the foundation for …


Roadmap Query For Sensor Network Assisted Navigation In Dynamic Environments, Sangeeta Bhattacharya, Nuzhet Atay, Gazihan Alankus, Chenyang Lu, O. Burchan Bayazit, Gruia-Catalin Roman Nov 2005

Roadmap Query For Sensor Network Assisted Navigation In Dynamic Environments, Sangeeta Bhattacharya, Nuzhet Atay, Gazihan Alankus, Chenyang Lu, O. Burchan Bayazit, Gruia-Catalin Roman

All Computer Science and Engineering Research

Autonomous mobile entity navigation through dynamic and unknown environments is an essential part of many mission critical applications like search and rescue and fire fighting. The dynamism of the environment necessitates the mobile entity to constantly maintain a high degree of awareness of the changing environment. This criteria makes it difficult to achieve good navigation performance by using just on-board sensors and existing navigation methods and motivates the use of wireless sensor networks (WSNs) to aid navigation. In this paper, we present a novel approach that integrates a roadmap based navigation algorithm with a novel network query protocol called Roadmap …


Group Scheduling In Selinux To Mitigate Cpu-Focused Denial Of Service Attacks, Armando Migliaccio, Terry Tidwell, Christopher Gill, Tejasvi Aswathanarayana, Douglas Niehaus Nov 2005

Group Scheduling In Selinux To Mitigate Cpu-Focused Denial Of Service Attacks, Armando Migliaccio, Terry Tidwell, Christopher Gill, Tejasvi Aswathanarayana, Douglas Niehaus

All Computer Science and Engineering Research

Popular security techniques such as public-private key encryption, firewalls, and role-based access control offer significant protec-tion of system data, but offer only limited protection of the computations using that data from significant interference due to accident or adversarial attack. However, in an increasing number of modern systems, ensuring the reliable execution of system activities is every bit as important as ensuring data security. This paper makes three contributions to the state of the art in protection of the execution of system activities from accidental or adversarial interference. First, we consider the motivating problem of CPU-focused denial of service attacks, and …


Mpsa Effects On Copper Electrodeposition: Understanding Molecular Behavior At The Electrochemical Interface, Clint Gordon Guymon Nov 2005

Mpsa Effects On Copper Electrodeposition: Understanding Molecular Behavior At The Electrochemical Interface, Clint Gordon Guymon

Theses and Dissertations

In this work the structure of the electrochemical metal-liquid interface is determined through use of quantum mechanics, molecular simulation, and experiment. Herein are profiled the molecular dynamics details and results of solid-liquid interfaces at flat non-specific solid surfaces and copper metal electrodes. Ab initio quantum-mechanical calculations are reported and define the interatomic potentials in the simulations. Some of the quantum-mechanical calculations involve small copper clusters interacting with 3-mercaptopropanesulfonic acid (MPSA), sodium, chloride, bisulfate and cuprous ions. In connection with these I develop the electrode charge dynamics (ECD) routine to treat the charge mobility in a metal. ECD bridges the gap …