Engineering Commons^™

Influence Of Marine Organisms Upon Corrosion Of Steel Piling Systems, Jiunn-Shyong Luo, Cliff Rau, Kuei-Ching Chen

Journal of Electrochemistry

To study the influence of marine organisms upon corrosion of ASTM A36 steel piling sysems, specimens were immersed in both natural and synthetic seawater. Electrochemical techniques such as linear polarization resistance and electrochemical impedance scan(EIS) were applied to evaluate corrosion of the steel. The results indicated that attachment of marine organisms to form fouling layers on the steel surface reduced general corrosion, but localized corrosion occurred underneath marine organisms. An equivalent circuit model was established to simulate attachment of marine organisms upon carbon carbon steel surfaces.

Severe Corrosivity And Its Eletrochemical Mechanism Of Seawater In Xiamen Sea Area To Al-Mg Alloys, Le-Yun Lin, Yue-Hong Zhao

Journal of Electrochemistry

The surface layer seawater of different sea areas in China exhibit different corrosivity to Al-Mg alloys according to the experiment results of 16 years exposure in seawater. The seawater in Xiamen sea area possesses severe corrosivity while seawater in Qingdao possesses the mildest corrosivity to Al-Mg alloys with better regularity of corrosion behavior. The present paper illustrates by experiment data that the strongest corrosivity of Xiamen seawater to Al-Mg alloys is owing to the low salinity of the seawater and the “electrolyte effect” come from it. The 16 year corrosion data and corrosion morphology of the typical Al-Mg alloys from …

Discussion On Factors Of Unstable 304 Stainless Steel Stress Corrosion Cracking, Xin-Sheng Zhang, Chun-Chun Xu, Gang Hu

Journal of Electrochemistry

The 304 stainless steels were stretched at low temperatures to get different martensite phase transformation. Ferrmagnetometer was used to measure the martensite phase content. It was found that the dislocation density of 304 stainless sted was increased unavoidably with increase of deformation. Transmission electron microscope (TEM) was used to study the distribution of the dislocation. The influence of microstructure change on SCC of 304 stainless steel was discussed by slow strain rate testing (SSRT) in 42% MgCl₂ boiling solution,metallurgical microscope and scanning electron microscope (SEM).The results showed that martensite phase and dislocation flaw act together on the SCC susceptibility …

The Electroless Plating Ni-Fe-P Alloy And Its Voltammetric Behavior, Sen-Lin Wang, Hui-Huang Wu

Journal of Electrochemistry

Electroless Ni-Fe-P alloy deposition from an alkaline bath, containing sodium hypophosphite as reducer, boric acid as buffer agent and sodium citrate as complexing agent, was investigated. To increase the plating rate and to inprove the bath stability, the deposition parameters were optimized. The effects of process parameters (pH, temperature and mole ratio of [Fe²⁺]/([Ni²⁺]+[Fe²⁺]) on the plating rate and deposit composition were examined and it was found that the presence of ferrous sulfate in the bath has an inhibitory effect on the alloy deposition. As a consequence, the percentage of iron in the electroless …

The Mechanism Of Electrocatalytic Reduction Of Oxygen On Manganese Dioxide, Yu-Liang Cao, Han-Xi Yang, Xin-Ping Ai, Li-Fen Xiao

Journal of Electrochemistry

The oxygen electroreduction on the MnO₂ electrode was investigated by analysis of the polarzation properties of oxygen reduciton and its dependence on MnO₂ discharge state, in combination with the characterization of discharge intermediate and the kinetic parameters of the oxygen reduction. Based on the experimental observation and mechanistic analysis, it was suggested that the reduction of oxygen was closely related to the discharge behaviors of MnO₂. When MnO₂ was electrochimically reduced to MnOOH, it was immediately oxidized by oxygen molecules. Thus the oxygen reduction proceeds through continuous oxidation of the discharge product of MnO_{2 …}

The Technique Of Rare-Earth Conversion Coatings On Aluminum Alloy, Jun-Tao Wang, Jian-Hua Wu, Guang-Zhang Chen

Journal of Electrochemistry

The orthogonal design was used to screen the film_forming technique on LY12 aluminum alloy using quadrivalent cerium salt, and the corrosion-resistance performance of the coating was studied. The results revealed that: after LY12 aluminum alloy was treated by cerium salt, its pitting potential shifts to positive direction while the corrosion potential slightly decreases, showing that the alloy becomes less sensitive to pitting corrosion was greatly improved, comparable to that after chromate treatment; in addition, by combining the results of electrochemical measurements with surface analysis, the mechanism of corrosion-resistance on the race-earth conversion coating of the aluminum alloy was also discussed.

Comparison Of Thermal Cyclic Oxidation Of The Pvd Ni-Al And Hvof-Mcraly Coatings, J-T Chang, C-H Yeh, J-L He, K-C Chen

Journal of Electrochemistry

A PVD process-cathodic arc plasma ion plating was used to deposit Ni-Al films on Inconel 600 superalloy. The oxidation behaviors of PVD Ni-Al coating and the thermal sprayed CoCrAlY coatings were revealed and compared by performing cyclic thermal oxidation test at 1100 ℃ to evaluate its feasibility. Experimental results showed that the films with different compositions of Ni₆₂Al₃₈, Ni₆₃Al₃₇ and Ni₆₉Al₃₁ could be obtained when using Ni₅₂Al₄₈, Ni₆₀Al₄₀ and Ni₇₀Al₃₀ as targets, respectively. During the cyclic thermal oxidation test, the …

Fabrication Of Scanning Micro Cl- Probe And In Situ Imaging Of Cl- At The Interface Of 2024 Al Aloy/Solution, Yu-Hua Lin, Min-Hua Shao, Rong-Gang Hu, Yan Li, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

Micro combination Ag/AgCl electrode with a tip measuring tens micron in diameter was fabricated. The probe satisfied in situ imaging of Cl^- distribution at metal surface in chloride solution because of its excellent linearity between potential and Cl- concentration, rapid response, good stability and selectivity. With the aid of the home made Micro Electrode Scanning system and scanning Cl^- probe, the effect of the [Cl^-] at 2024-Al/solution interface on localized corrosion process was investigated. It was demonstated directly that Cl^- ion in solution immigrated toward, then adsorbed preferentially and accumulated at the junction between the …

An Electrochemical Prediction Method For Caustic Scc Of Fe-Cr-Ni Alloy, Chun-Bo Huang, Zhan-Peng Lv, Wu Yang

Journal of Electrochemistry

Stress corrosion cracking (SCC) of Fe-Cr-Ni alloy (alloy 800 M) in hot concentrated caustic solution was investigated by means of tests of C-rings under controlled potentials. The steady dissolution current densities (i_st) of the plate specimens and C-rings polarized potentiostatically were measured. The simplifed steady potentiostatical curves were drawn on the basis of i_st. The ratio R_PD measured from i_st and steady passive current density i p at low potentials (R_PD = i_st/i_p) was designed as a polarization dissolution susceptibility parameter. The parameter R_PD values of both plate …

Electrochemistry And Electrocatalysis Of A Novel Μ-Oxamido Copper(Ⅱ) Binuclear Complex, Gui-Lian Gao, Guo-Bao Li, Qiu-Xia Yang, Xue-Lin Wang

Journal of Electrochemistry

In this paper, the cyclic voltammetric and spectroelectrochemical behaviors of μ-oxamido Copper(Ⅱ) Binuclear Complex (deCu) in PBS were studied. Cyclic voltammograms of this complex in PBS (pH=9) exhibited two reductive peaks (E_pc1 =-0.25 V, E_pc2 = -0.50 V) at hanging mercury drop electrode(HMDE), peaks at -0.50 V and -0.25 V corresponded to the reduction of ligand and copper(Ⅱ) complex, respectively. The spectroelectrochimical experiments showed that there was a new absorption band at 440 nm, and the absorption peaks at 270 nm, 280 nm red shifted to 300 nm, 310 nm under potential of -0.75 V. It was meant …

Semiconductor Wafer Processing System With Vertically-Stacked Process Chambers And Single-Axis Dual-Wafer Transfer System, Richard N. Savage, Frank S. Menagh, Helder R. Carvalheira, Philip A. Troiani, Dan L. Cossentine, Eric R. Vaughan, Bruce E. Mayer

Materials Engineering

A semiconductor wafer processing system including a multi-chamber module having vertically-stacked semiconductor wafer process chambers and a loadlock chamber dedicated to each semiconductor wafer process chamber. Each process chamber includes a chuck for holding a wafer during wafer processing. The multi-chamber modules may be oriented in a linear array. The system further includes an apparatus having a dual-wafer single-axis transfer arm including a monolithic arm pivotally mounted within said loadlock chamber about a single pivot axis. The apparatus is adapted to carry two wafers, one unprocessed and one processed, simultaneously between the loadlock chamber and the process chamber. A method …

Gcip Water And Energy Budget Synthesis (Webs), J. Roads, R. Lawford, E. Bainto, E. Berbery, S. Chen, B. Fekete, K. Gallo, A. Grundstein, W. Higgins, M. Kanamitsu, W. Krajewski, V. Lakshmi, D. Leathers, Dennis P. Lettenmaier, L. Luo, Edwin P. Maurer, T. Meyers, D. Miller, K. Mitchell, T. Mote, R. Pinker, T. Reichler, D. Robinson, A. Robock, J. Smith, G. Srinivasan, K. Verdin, K. Vinnikov, T. Vonder Haar, C. Vörösmarty, S. Williams, E. Yarosh

Civil, Environmental and Sustainable Engineering

As part of the World Climate Research Program's (WCRPs) Global Energy and Water-Cycle Experiment (GEWEX) Continental-scale International Project (GCIP), a preliminary water and energy budget synthesis (WEBS) was developed for the period 1996–1999 from the “best available” observations and models. Besides this summary paper, a companion CD-ROM with more extensive discussion, figures, tables, and raw data is available to the interested researcher from the GEWEX project office, the GAPP project office, or the first author. An updated online version of the CD-ROM is also available at http://ecpc.ucsd.edu/gcip/webs.htm/. Observations cannot adequately characterize or “close” budgets since too many fundamental processes …

A Study Of Radiofrequency Cardiac Ablation Using Analytical And Numerical Techniques, Ryan Todd Roper

Theses and Dissertations

Studies on radiofrequency (RF) ablation are often aimed at accurately predicting tissue temperature distributions by numerical solution of the bioheat equation. This thesis describes the development of an analytical solution to serve as a benchmark for subsequent numerical solutions. The solution, which was obtained using integral transforms, has the form of a surface integral nested within another surface integral. An integration routine capable of evaluating such integrals was developed and a C program was written to implement this routine. The surface integration routine was validated using a surface integral with a known analytical solution. The routine was, then, used to …

Day 5. Friday, August 15, 2003: Rocky Mountain National Park, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

1 page.

Contains references.

Atomic Force Acoustic Microscopy Methods To Determine Thin-Film Elastic Properties, D.C. Hurley, K. Shen, N.M. Jennett, Joseph A. Turner

Nebraska Center for Materials and Nanoscience: Faculty Publications

We discuss atomic force acoustic microscopy (AFAM) methods to determine quantitative values for the elastic properties of thin films. The AFAM approach measures the frequencies of an AFM cantilever’s first two flexural resonances while in contact with a material. The indentation modulus M of an unknown or test material can be obtained by comparing the resonant spectrum of the test material to that of a reference material. We examined a niobium film (d=280±30 nm) with AFAM using two separate reference materials and two different cantilever geometries. Data were analyzed by two methods: an analytical model based on conventional …

Development Of A Systems Engineering Model Of The Chemical Separations Process: Quarterly Progress Report 5/16/03- 8/15/03, Yitung Chen, Randy Clarksean, Darrell Pepper

Separations Campaign (TRP)

Two activities are proposed in this Phase I task: the development of a systems engineering model and the refinement of the Argonne code AMUSE (Argonne Model for Universal Solvent Extraction). The detailed systems engineering model is the start of an integrated approach to the analysis of the materials separations associated with the AAA Program. A second portion of the project is to streamline and improve an integral part of the overall systems model, which is the software package AMUSE. AMUSE analyzes the UREX process and other related solvent extraction processes and defines many of the process streams that are integral …

Development Of A Systems Engineering Model Of The Chemical Separations Process, Yitung Chen, Sean Hsieh, Randy Clarksean, Darrell Pepper

Separations Campaign (TRP)

The AFCI program is developing technology for the transmutation of nuclear waste to address many of the long-term disposal issues. An integral part of this program is the proposed chemical separations scheme.

Nearly all issues related to risks to future generations arising from long-term disposal of such spent nuclear fuel is attributable to about 2% of its content. Such 2% is made up primarily of plutonium, neptunium, americium, and curium (the transuranic elements) and long-lived isotopes of iodine and technetium created as products from the fission process in power reactors. When transuranics are removed from discharged fuel destined for disposal, …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides: Quarterly Progress Report 5/16/03- 8/15/03, Yitung Chen, Randy Clarksean, Darrell Pepper

Fuels Campaign (TRP)

The analysis of mold filling and solidification continues with progress being made for the consideration of these two features within one model. Analysis of the induction heating process of an Induction Skull Melter (ISM) is under study. Efforts are underway to validate the modeling procedure and specific comparisons are being made to previously published work. Few detailed modeling results have been reported by other researchers, making the validations an important part of the overall modeling process. Skin heating depths, power deposition rates, and other process parameters are being evaluated for use in upcoming furnace design simulations. Efforts are beginning on …

Day 4. Thursday, August 14, 2003: Hayden Power Plant, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

5 pages (includes color illustrations and maps).

Contains references.

Day 4. Thursday, August 14, 2003: Trapper Mine, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

8 pages (includes some color illustrations).

Contains references.

Characteristics Of Phototrophic And Non-Phototrophic Lagoons For Swine Manure, Tongtong Chen, Dennis D. Schulte, Richard K. Koelsch, Anne M. Parkhurst

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Odors are a major result of inadequately sized and mismanaged anaerobic lagoons. However, purple or pink colored lagoons, indicating the presence of phototrophic purple bacteria, are less likely to be an odor nuisance than are non–purple lagoons. Eight swine lagoons were studied to quantify critical parameters thought to allow purple lagoons to be a more reliable odor control alternative. Bacteriochlorophyll a (Bchl a), which indirectly measures the abundance of phototrophic bacteria, was greater in purple lagoons than in non–purple lagoons (P = 0.01). Oxidation–reduction potential (ORP) was less negative for purple lagoons than for non–purple lagoons in both spring …

Extended Hough Methodology In Geo-Spatial Image Exploitation, Rufus H. Cofer, Samuel Peter Kozaitis, Jihun Cha

Electrical Engineering and Computer Science Faculty Publications

Hough transform theory provides a heuristically appealing approach toward finding lineal features in imagery. Unfortunately direct algorithmic implementation of its theory results in many practical problems. We provide two interlocking theoretical extensions to greatly enhances the Hough transform's ability to handle finite lineal features and allow directed search for parallel lines within the scene while balancing memory and computational complexity. Both extensions involve expansion of the Hough space concept to allow easier access to processed data for both dedicated silicon and general-purpose computer implementations.

Linear Feature Detection Of Rural Imagery Using Multiresolution Filters, Samuel Peter Kozaitis, Rufus H. Cofer

Electrical Engineering and Computer Science Faculty Publications

We detected roads in aerial imagery using a method based on lineal feature detection. Our method used the products of wavelet coefficients at several scales were to identify and locate lineal features. Using our approach effectively increased the size of the region we examined when looking for possible road pixels, and decreased the probability of false positive road pixels. Then, we used a shortest path algorithm to link road pixels to form road networks. Our approach restricted possible road network solutions based on the initial detection of road pixels. We found that our approach leads to an effective method for …

Day 3. Wednesday, August 13, 2003: Oil Shale, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

8 pages.

Contains references.

Day 3. Wednesday, August 13, 2003: Travel To Grand Junction, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

5 pages (includes color illustration and map).

Contains references.

Day 3. Wednesday, August 13, 2003: Lighthawk Flyover, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

11 pages (includes some color illustrations and maps).

Contains references.

Day 3. Wednesday, August 13, 2003: Coalbed Methane Development, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

10 pages (includes color illustrations and maps).

Day 2. Tuesday, August 12, 2003: Delta Montrose Energy, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

1 page.

Contains references.

Day 2. Tuesday, August 12, 2003: Valley Oil And Gas Development, University Of Colorado Boulder. Natural Resources Law Center

Energy Field Tour 2003 (August 11-16)

1 page.

Contains references.

Day 2. Tuesday, August 12, 2003: Roan Plateau Proposed Wilderness Area, Roan Plateau

Energy Field Tour 2003 (August 11-16)

4 pages (includes color illustration).

Contains references.