Engineering Commons^™

Thermodynamic Properties Of Pentene-1, Byron Millard Cody

Theses

The thermodynamic properties of Pentene-1 have been calculated over a temperature range of 32°F to 600°F and at pressures up to 4000 lb/sq. in. abs. These properties were determined from vapor pressure, heat capacity, and latent heat of vaporization data through the application of generalized thermodymnic relationships based on the theory of corresponding states.

A Generalized Correlation For The Effect Of Pressure On The Difference In Heat Capacities Of Gases, Leon Bleich

Theses

A generalized correlation is presented for the difference in heat capacities at constant pressure and constant volume, C_p-C_v, as a function of reduced pressure with parameters of reduced temperature. The correlation covers a pressure range of pr a 0.2 to pr = 15.0 and a temperature range of Tr = 1.0 to Tr = 5.5. The correla- tion was based on values of C_p-C_v calculated from the Benedict - Webb - Rubin Equation of State for five hydrocarbons, namely, methane, ethylene, ethane, propane, and n-butane.

The results show that C_p-C_{v …}

Ultraviolet Analysis Of Mixtures Of O-, P- And M-Nitrotoluene, John Thomas Dempsey

Theses

This paper presents a spectrophotometric method of analysis of mixtures of the isomers of pure nitrotoluene, which are free of the dinitro-compounds and other impurities. The analysis is made in the ultraviolet region with a Beckman DU Spectrophotometer. Graphical methods are developed for both binary and tertiary mixtures. The graphs, which form the basis of the method, represent the theoretical absorbancies for various mixtures of the isomers. From these graphs the concentrations in an unknown mixture can be read directly if the absorbancies, at specified wavelengths, are known.

This analytical method is based on the fact that the absorbancies of …

Vapor Liquid Equilibria Studies For System 1: Cyclohexane, Neo-Hexane; System 2: Neo-Hexane, Iso-Octane; System 3: Cyclohexane, Iso-Octane; At Atmospheric Pressure, Robert Halper

Theses

Vapor liquid equilibria studies were conducted on three systems at atmospheric pressure. The systems represented were: -

System #1 - Neo-hexane, cyclohexane.

System #2 Neo-hexane, isooctane.

System #3 - Cyclohexane, isooctane.

The object of these studies was: -

1. To obtain reliable experimental data on the above systems that would enable the plot of a series of characteristic curves.

2. To test the experimental data for thermodynamic consistency.

3. To correlate the data with the best of several theoretical equations as represented by Van Lear, Margules, Scatchard-Hamer or Redlich-Kister.

Heat Transfer Coefficients Of Condensing Vapors, Carl Lennart Palmer, Thomas W. Weber

Theses

The heat transfer coefficients of the condensing vapors of n-butyl, 1-amyl, and tertiary amyl alcohols have been measured for a single horizontal tube. This is the first time that i-amyl and tertiary amyl alcohols have been investigated. The modified Wilson method presented by Chu was used in analysing the data.

Chu pointed out that over a moderate range of temperature, the condensing heat transfer coefficient should vary inversely with the one-third power of the rate of heat transfer. For the alcohols studied in these experiments, the measured powers were between 0.20 and 0.36, which are in good agreement with Chu's …

Pressure Drop In Packed Beds Of Metal Raschig Rings, Donald William Davis

Theses

Absorption towers packed with split metal Raschig rings have a higher void content than towers packed with ceramic Raschig rings of the same nominal size. This increased void volume is due to the thinner wall of the metal ring. This higher void space should also result in lower pressure drops than would be encountered with ceramic rings. The purpose of this research program was to determine the pressure drop-flow characteristics of this packing, and to develop suitable correlations for design of packed absorption towers.

Split metal Raschig rings of one-half and one inch nominal sizes were tested to determine their …

Effect Of Substituents In The Reductive Dehalogenation Of Substituted Iodobenzenes, George Burton Freda

Theses

Reaction rates for the reductive dehalogenation of ortho or Para substituted iodobenzenes with zinc and acetic acid relative to the rate for unsubstituted iodobenzene were measured. The order of ease of replacement of the iodine for the para substituents on the benzene ring was found to be: -COON -SO₃K> CH₃ -H > -C₆H₅> -OC₂H₅. For ortho substituents the order was -COOH> -C₆H₅> -OC₂H₅ > -SO₃K -CH₃> -H.

Investigation Of Liquid Partition Chromatography Of Polyhydric Alcohols, Michael Homiak

Theses

Polyhydric alcohols have previously been separated by tedious chemical procedures and in microgram quantities on columns prepared from silica gel and silica gel - Celite combinations. This study was undertaken to determine whether separation of these alcohols was possible by chromatography on columns of Celite alone, and in quantities considerably greater than those formerly handled. In addition, as a preliminary step to the actual separation, the capacities of the columns for the two polyhydric alcohols were determined. The effect of several variables on the capacities of the columns were investigated. A calculation of the number of theoretical plates in a …

Kinetics Of Hydrolysis Of Some Halonitrobenzenesulfonates, Walter C. Kania

Theses

The object of this thesis was to determine the rela¬tive activity towards hydrolysis of several halogen deriv¬atives of nitrobenzenesulfonate. The halide is Para to a nitro group and ortho to the sulfonic acid group.

The compounds studied were:

(I) sodium 2-chloro-5-nitrobenzenesulfonate

(II) sodium 2-bromo-5-nitrobenzenesulfonate

The chlorine was found to be more reactive than the bromine.

A dichloride, (III), sodium 2,5-dichloro-3-nitroben-zenesulfonate was also studied. Here one chlorine is activated by both the nitro and sulfonic acid groups. The other chlorine being meta to the nitro and sulfonic acid groups would be adverse to hydrolysis.

Rates of hydrolysis of (I), (II), and …

Purification Of Technical Grade Latic Acid, Edward Francis Wezowicz

Theses

A method to manufacture purified lactic acid from technical grade lactic acid 04%) was investigated. In this method, technical grade lactic acid was reacted with normal butyl alcohol, the water formed during the esterification was azeotropically removed, The ester formed, was separated from the excess butanol by vacuum distillation. Finally, the ester separated by distillation :as hydrolyzed to a purified grade of lactic acid.

In this study, several features are reported, which to the best of knowledge, appear in a publication for the first time. They are:

1. Conditions for the esterification of technical grade lactic acid with butanol, resulting …

The Design, Construction And Testing Of An Electrical, Transient Heat Flow Analyser, Bruce Wilcox

Electrical and Computer Engineering ETDs

The purpose of this investigation was (a) to design and build an analog which would produce the solution to a simplified yet typical transient aerodynamic heating problem, (b) to obtain the solution using the analog and to check the accuracy of the solution by mathematical computation, and (c) to code a more involved aerodynamic analog.

The Design Of A Solar Powered Air Conditioning System For An Albuquerque Office Building, Kuo S. Lee

Mechanical Engineering ETDs

The purpose of this investigation is to predict the performance of a solar powered jet refrigeration system for summer air conditioning, to measure the performance of the solar heat collector at the Bridgers and Paxton building in Albuquerque, and to design a Freon-12 ejector and generator for collection to that collector.

The Design, Construction And Investigation Of A Water Gravity Wave Analog Of Two-Dimensional Compression Waves In Gases, John H. Tenbrink

Mechanical Engineering ETDs

The purpose of this investigation was to design equipment for investigating and demonstrating supersonic air flow using water; to fabricate, assemble and calibrate this equipment; and to obtain and evaluate data on the validity of the supersonic flow analogy and the range of the equipment for classroom use.

Comparison Of Observed And Calculated Near-Vertical Radar Ground Return Intensities And Fading Spectra, James Arlin Cooper

Electrical and Computer Engineering ETDs

The study of ground-to-air terrain return is necessary in order to understand the functioning of radar altimeters.

Radar return at vertical incidence can be considered to be composed of two components. One, whic his returned by a mirror-like action, is called the specular component. The other, termed scatter, is due to diffuse rerediation from individual scatterers on the ground.

In recent work on return from angles near vertical, more attention has been given to the scatter component than many had previously assumed necessary.

Procedure for Gathering Data:

Two pulse radar units were used, one having a frequency of 3.8 KMC, …

Analysis Of Cushioned Impact By Wave Propagation Techniques, Lowell P. Martin

Mechanical Engineering ETDs

A typical problem of wave propagation which has received substantial attention concerns the longitudinal vibrations of a long, slender, uniform elastic rod after it has been dropped on one end.

The purpose of this investigation was to extend the problem to include the effect of cushioning material attached to the impacting end of a rod similar to that described above; and to conduct experiments designed to verify the analysis. This study is essentially the first step toward the analysis, by wave propagation methods, of many practical impact problems encountered in military airborne operations, experimental rocket programs, and the packaging industry.

Design Of An Experiment To Separate Specular And Scattered Radar Returns, Robert B. Glascock

Electrical and Computer Engineering ETDs

This paper describes the design of a radar experiment that will be conducted by the U.S. Naval Research Laboratory at Washington, D.C. The proposed experiment and the background of the problem are discussed, as well as the theoretical background, experimental background, and other design considerations are discussed in later sections.

A Study Of The Reset Cycle Of A Half-Wave Self-Saturable Magnetic Amplifier, William W. Lee

Electrical and Computer Engineering ETDs

It was the purpose of this study (1) to investigate the reset cycle of a half-wave self-saturable magnetic amplifier by graphical analysis of the irregular voltage functions appearing across the gate winding during reset; and (2) to determine if possible from this analysis a more satisfactory design method than those now available. Conditions of constant current reset were employed and the core material used had a nearly rectangular hysteresis loop. Resistive loads only are considered.

Utilization Of The Relationship Between The Complex Immittance And The Indicial Immittance Functions For The Synthesis Of Two Terminal Networks, Julian T. Lefler

Electrical and Computer Engineering ETDs

It was the purpose of this study (1) to develop a new method of network synthesis from a specified complex immittance function; and (2) to demonstrate the application of the method by means of its use in the solution of representative synthesis problems. This work deals only with the synthesis of two terminal networks containing linear, passive, lumped-constant elements, from given rational immittance functions of the complex frequency variable.

Not considered part of this work are (1) the development of the immittance function from frequency-response specifications (the approximation problem); or (2) the treatment of active, non-linear, or time varying network …

A Study Of A Complementary Symmetrical Power Switching Circuit, Glenn S. Mills

Electrical and Computer Engineering ETDs

This paper contains an analysis of a symmetrical, complementary, power switching circuit employing complementary power transistors. A DC analysis is made for the bistable states. Also described is a voltage regulation and bias circuit which improves stability and contributes to the protection of the transistors. The problem of switching transients is investigated and empirical results presented to support theoretical considerations. A new triggered method is proposed to utilize the bilateral characteristics of a transistor. Applications of the circuit are suggested for controlled-frequency and self-triggering modes of operation. A method and analysis for self-triggering is presented. The advantages of this power …

The Use Of Electrical Resistance Strain Elements In Three-Dimensional Stress Analysis, Robert I. Brasier

Electrical and Computer Engineering ETDs

The purpose of this thesis is to present a new method of experimental stress analysis and to give the solution to a problem which has been handled by this method.

Metallurgical Applications Of Polarized Light, Kenneth R. Evans

Bachelors Theses and Reports, 1928 - 1970

Very little has been written concerning the theory of the metallurgical polarization microscope. Records of metallurgical studies utilizing this instrument are widely scattered among the literature, and are mostly material of an uncoordinated and irrelevant nature. It is the feeling of the author that a coordinated investigation of the metallurgical applications of polarized light will yield results providing the metallurgist with another means for the study of metals and their properties.

Ferro And Ferricyanides In Industrial Waste Water, Frederick Joseph Neff

Theses

The role of the Ferro and ferricyanides in present day waste treatment practice is reviewed. Possible conventional methods for the disposal of the compounds appear inadequate. It is shown experimentally that the cyanide content of Ferrocyanide may be oxidized by hypochlorite in alkaline solution when exposed to ultra-violet light and that no oxidation of the cyanide occurs when reacted with hypochlorite in diffuse laboratory light.

Ion Exchange Technology In The Sodium And Ferric Ion-Dowex 50 Systems, Alfred George Hoerrner

Theses

This investigation was directed toward the extension of data on the kinetics of monovalent - trivalent cation exchange and to establish data on the relationship between temperature and total capacity of an ion exchange resin. In order to compare the present study to a previous investigation by Klosowski (2), the capacity of the resin used for ferric and chromic ions was also measured.

In the kinetic study, the ferric ion-hydrogen ion exchange using Dowex 50 X-8 resin was studied in an agitated vessel. A two-bladed marine type propellor was used and the agitator speed was varied from 400 to 800 …

A Study Of A Production Control System In A Job Order Die Casting Plant, Robert Gordon Woodnorth

Theses

This thesis examines the production planning and control system in a job-order die casting plant. After comparing to the criteria for an ideal system the following changes were recommended.

1. Central work storage and dispatching. This would reduce work in process and workload fluctuations through closer planning. It would also provide a perpetual inventory system and a central control point which would be constantly informed of production progress.

2. Operator trucking. By having operators do their own trucking material handling costs and production delays would be reduced.

3. Simplified job cost accounting. The use of standard costs for finishing and …

Evaluation Of Two Generalized Compressibility Correlations, Elbert Dale Hooper

Theses

Lydersen's critica1 compressibility correlation and Pitzer's acentric factor correlation are compared by the accuracy with which they reproduce P-V-T data. Each introduces a new parameter to be employed in conjunction with reduced temperature and reduced pressure to account for the behavior of substances of various types.

It is established here that the correlation proposed by Pitzer and co-workers is the more reliable for compressibility and saturation pressure predictions for most substances over a wider temperature and pressure range. The critica1 compressibility, however, improves compressibility predictions near the critica1 point for polar compounds.

Included are graphs and tables showing the deviations …

Back-Reflection Camera, Charles T. Burtch

Bachelors Theses and Reports, 1928 - 1970

The following paper is a record of the procedure used to construct a back-reflection camera. It will also discuss the difficulties encountered and some of the methods used to eliminate or reduce them.

The Application Of Amalgam Metallurgy To Copper, Barry J. Hansen

Bachelors Theses and Reports, 1928 - 1970

The object of this investigation is the application of "Amalgam Metallurgy" to the extraction of copper from its ores. "Amalgam Metallurgy" as defined by Hohn is the use of liquid mercury in the extraction of metals. The ore under study was from the Kelly Mine in Butte, Montana and contains about 1.0% copper of which about 0.1% is acid soluble.

Production Of Standard-Grade Ferromanganese In An Electric Arc Furnace, John P. Hager

Bachelors Theses and Reports, 1928 - 1970

The original purpose of this thesis was to determine the feasibility of producing standard-grade ferromanganese from the Cuban concentrates using an electric arc furnace. This purpose was later changed since it became necessary to study the adequacy of a laboratory electric arc furnace for comparability with commercial operations.

Since the original purpose of the investigation had been changed while the area of investigation had not, the research work was then continued with the purpose of collecting information on ferromanganese production as a background for anticipated future work in pyrochemical research at the Montana School of Mines.

Ferromagnetism In Some Alloys Of The Copper-Manganese-Tin System, Leonard W. Boyd Jr.

Bachelors Theses and Reports, 1928 - 1970

The specific purpose of this investigation is to study the effects of heat treating at various temperatures for different lengths of time, with special attention paid to changes in magnetization. Identical heat-treating conditions were used on several different alloys, the compositions of which are such that some specimens are in the single-phase beta prime and beta regions, whereas others are in two-phase regions. For this investigation, only magnetic measurements will be attempted.

Determination Of Q Factors And Operating Characteristics For Microwave Cavities And Oscillations, W.P. Stearns

Electrical and Computer Engineering ETDs

This paper has as its objective the presentation of the theory involved and method used with respect to the resonant cavity parameters; loaded Q, unloaded Q, external Q, pulling figure, and circuit efficiency for the resonant cavity investigated. Experimental data on a particular cavity are discussed and the previously mentioned cavity parameters determined with the use of such data and the particular method presented. A Rieke diagram for the particular cavity investigated is also presented and discussed.