Engineering Commons^™

The Fate Of Hazardous Polluting Substances In An Aqueous Environment, Robert Paul Casani

Theses

The fate of Hazardous Polluting. Substances (HPS) in an aqueous environment has been investigated using ultraviolet light. Chlorobenzene, o-cresol and nitrobenzene were used as model HPS for this study. The kinetics were followed and good first order plots were obtained for all compounds. The temperature of the reaction was shown to effect the rate. Solid insoluble and soluble non-volatile products were formed in the photolytic reaction of the three model systems.

The Preparation Of Cis- And Trans-1,2-Dimethoxyethylene. The Study Of The Cis-Trans-Rearrangement And Evaluation Of Equilibrium Constants, James T. Waldron

Dissertations

Equilibrium constants for the mercuric acetate-catalyzed reaction, cis-CH₃ OCH=CHOCH₃ D trans-CH₃ OCH=CHOCH₃, have been determined in the liquid and vapor phase over the temperature range 30° - 175°C by gas chromatography analysis. A novel synthesis of the cis- and trans-isomers of 1,2-dimethoxyethylene is discussed. From a screening of 29 catalysts, mercuric acetate, mercuric benzoate, and mercuric salicylate were found to be favorable isomerization catalysts. For the liquid phase reaction,

ln K = -779.8/T + 0.6748

with ΔH° = +1.549 ± 0.019 Kcal/mole
and ΔS° = +1.34 ± 0.05 e.u./mole

Similarly, for the vapor phase reaction, …

The Aging Of Sbr Vulcanizates, Arthur Robert Leckart

Theses

A literature survey was conducted on SBR aging, Being vulnerable to attack by the forces of nature (such as ozone, oxygen, heat and light), SBR vulcanizates requires the addition of chemicals to retard aging. Phenylamines were found to be the best type of antiaging additives, The effectiveness of other antiaging additives were examined. Although the mechanisms of aging are not perfectly understood; sane theories and aging reactions are discussed.

A Study Of The Prevalent Categories Of Conflict As Perceived By The Architect And The School Client On School Construction Projects In Indiana, Tracy Dust

All-Inclusive List of Electronic Theses and Dissertations

In view of the complexities which are now involved in school facility construction, it is paramount that the relationship between the architect and his school client develop fully and that it be based upon a clear and mutual understanding of role expectation. The school board, as the hiring agency, is characteristically composed of laymen both in the field of education and in the field of heavy construction. They must rely upon the judgment of the architect regarding the design features of the proposed facility and must depend upon their superintendent and his staff for determining educational program requirements.

Peak Temperature Distribution In Steel Plates During Arc-Welding, Bhanuprakash M. Patel

Theses and Dissertations

The welding of steel plays an important role as a major fabricating process in industry. In the field of welding metallurgy, much attention is given to the effects which a welding arc or flame will have on the structure and properties of the metals being joined. The engineer is interested in the intensify and extent of physical changes brought about by the unavoidable heat treatment which accompanies the execution of a weld. In order to gain some quantitative appreciation of the way in which the metallurgical effects of welding depend on welding variables, geometry, and physical properties, considerable attention has …

An Experimental Investigation Of The Relation Between The Cooling Rate And Welding Variables In Fusion Welding, Sujit Biswas

Theses and Dissertations

In the field of welding metallurgy, much attention is given to the effects which the welding arc or flame will have on the structure and properties of the metals being joined. The engineer is interested in the intensity and extent of physical changes brought about by the unavoidable "heat treatment" which accompanies the execution of a weld.

Application Of The Finite Element Method Using The Method Of Weighted Residuals To Two Dimensional Newtonian Steady Flow With Constant Fluid Properties, Mien Ray Chi

Theses and Dissertations

In this thesis we will be concerned with the two-dimensional steady laminar Newtonian fluid flow with constant fluid properties in Cartesian coordinate system. More precisely, we will consider a flow for which the interesting dependent variables, for example, velocity, vorticity, stream function, etc., are expressible as functions of two independent Cartesian coordinates.

Design Of Near-Time-Optimal Feedback Controllers., Chon Ho Hyon

Electrical and Computer Engineering ETDs

This dissertation presents a method for designing near-time-optimal feedback controllers of time-invariant linear normal systems in which the system matrix is negative definite and the control input is a bounded scalar function.

The basic design approach is to systematically construct a sequence of multiplane (piecewise linear) suboptimal switching surfaces which converges to the optimal switching surface and to test the quality of the suboptimal switching surface constructed in each iteration until one which satisfies the relative (optimal/suboptimal) performance criterion given a priori is obtained.

Continuous Crystallization Of High Explosives, Larry E. Hatler

Chemical and Biological Engineering ETDs

Nitroguanidine (NQ) is a high explosive which is commercially available in low bulk density form (0.20 to 0.30 gms/cm³). This low bulk density limits its usefulness as an explosive. High bulk density NQ can be produced from a NQ-N, N-dime-thylformamide-Versamid 125 system when crystallized in a mixed suspension mixed product removal crystallizer. Bulk densities ranged from 0.92 to 1.05 gms/cm³ for the operating conditions used. The effect of agitator speed, growth rate, and solids concentration on nucleation rates was determined using a multiple linear regression technique. The resulting equation is: B₀ = 0.19 (RPM) ^1.54 (G) …

Entropy Reduction Of English Text Using Variable Length Grouping, Vincent Norman Ast Jr.

Dissertations and Theses

It is known that the entropy of English text can be reduced by arranging the text into groups of two or more letters each. The higher the order of the grouping the greater is the entropy reduction. Using this principle in a computer text compressing system brings about difficulties, however, because the number of entries required in the translation table increases exponentially with group size. This experiment examined the possibility of using a translation table containing only selected entries of all group sizes with the expectation of obtaining a substantial entropy reduction with a relatively small table.

An expression was …

A New Optimization Procedure For Digital Simulation, Donald Howard Schroeder

Electrical and Computer Engineering ETDs

The theory needed to define and obtain an optimized digital simulation of a given continuous system is presented in this dissertation. The frequency domain approach to simulation is used and a nonlinear function minimization algorithm, implemented on a digital computer, is incorporated to obtain the optimum simulation.

The discrete transfer function obtained from z-transform theory is used to represent the digital system. The frequency domain response of this discrete transfer function can then be expressed simply as a function of frequency, for frequencies up to one-half the sampling frequency. A frequency domain error measure, in the complex plane, is defined …

Dispersion In Laminiar Flow Of Non-Newtonian Fluids, Subhash N. Shah

Chemical and Biological Engineering ETDs

In the present investigation, Taylor's analysis of the dispersion of solutes in laminar flow of a Newtonian fluid through a circular tube was extended to the case of a non-Newtonian Eyring model fluid. A new approach was taken to solve the convective diffusion equation for the Eyring model fluid. This approach incorporates the use of the dimensionless longitudinal pressure gradient and the mean velocity to obtain the dimensionless concentration. Using an approach similar to that of Taylor, a solution of the diffusion equation was obtained for quantities such as the dimensionless concentration, mean concentration, and effective dispersion coefficient as a …

Moment-Curvature-Thrust Relationships In Hybrid Members, Douglas Wrenn Fiala

Dissertations and Theses

In order to overcome the difficulties encountered in closed form solutions, moment-curvature-thrust relationships are developed for hybrid and nonhybrid cross sections utilizing an open form method. The use of horizontal sectors permits the inclusion of residual stresses and/or nonbilinear stress-strain relationships, if desired. Theoretical and experimental data are compared. Applications to circular tubes and other cross sections are discussed. Results indicate that open form solutions are feasible for calculating moment-curvature-thrust data. Hybrid cross sections are easily treated by open form solutions.

A Numerical Technique For Solving Rigid Body Impact On An Incompressible, Viscous Medium, Cecil Thomas Chapman

Civil & Environmental Engineering Theses & Dissertations

A technique for solving rigid-body impact on a viscous, incompressible medium is presented. The numerical scheme is adapted from the Marker and Cell (MAC) method developed to solve problems involving time-dependent motion of a viscous, incompressible fluid in two-dimensional space. As the pressure end velocity fields are computed throughout the flow field, the solution gives the force and displacement time history of the rigid-body during the impact phase. In conjunction with this, through a system of marker particles, the changes in configuration of the viscous medium on impact can be studied. With a "movie frame" (incremental time) approach, computational experimentation …

Structure And Magnetic Properties Of Rare Earth Garnets, Milan R. Kokta

Dissertations

This study deals with preparation and magnetic properties of garnet compounds containing rare earth ions and scandium ions on two crystallographic sites: the dodecahedral and the octahedral. A number of compounds of the types {R_3-yr_y}[r_x Ga_2-x](Ga₃) O_12' {R₃}[Sc₂](Fe_z Ga_3-x) O_12' {R_3-y Sc_y}[Sc₂] (Fe₃) O_12' and {R_3-y r_y)[r₂ (Fe_z Ga_3-z) O_12' where R stands for large rare earth ions such as Nd³⁺ and Pr³⁺, …

Electromagnetic Wave Propagation In Nonuniform Waveguides With Perfect Conducting Walls, Irwin Share

Dissertations

The analysis of nonuniform waveguides is formulated in terms of non-orthogonal generalized coordinates by utilizing the Hertz vector potentials and the Riemann metric tensor.

When the Hertz potential is expressible as a function of the propagation coordinate times a function of the transverse coordinates, then the nonuniform waveguide may be represented by transverse equations and a set of uncoupled nonuniform transmission lines. This decomposition facilitates studying propagation along the propagation coordinate. Sufficient conditions to achieve this decomposition are investigated. It is demonstrated that these constraints may provide guidelines for selecting a useful coordinate system to describe the nonuniform waveguide. In …

An Investigation Of The Neuromuscular Command In The Control Of Respiration, Nirmal Kumar Mishra

Dissertations

The purpose of the investigation is to study the signals involved in the respiratory system and to obtain a model for the dynamics including the activity of the phrenic nerve as the input and the transpulmonary pressure, air flow and the volume as the response.

Experiments were done on anasthetized dogs under natural breathing, with steady state response to various levels of CO2 in the inspired air, and under electrophrenic stimulation. Bipolar electrodes were used at the phrenic nerve, in the cervical region, either for recording the phrenic neurogram or for supramaximal unilateral (or bilateral) stimulation using pulse frequency modulated …

Methods For Acoustic Holography And Acoustic Measurements, Wolfgang Fischer

Dissertations

In this dissertation, a novel "four-step acoustical holographic imaging system" is described and several means for its implementation are analyzed both theoretically and experimentally. This system is compared with other methods of acoustical holography, (ie. permitting to obtain a visible, 3-D image of an object insonified with supersonic waves) and some of its advantages are indicated.

The use of optical holographic techniques to convert an arbitrary acoustic image to a visible image is investigated and a new method - the "holographic sound image converter" - is introduced and analyzed. This converter consists of the "holographic interferometer" and an appropriate "coupler". …

A Solid State Kinetic Study Of Potassium Permanganate In Alkali Halide Disks, Joseph Paul Cusumano

Theses

The stoichiometry and the kinetics of the reactions of KMnO₄ in KCl and KIO₄ in KCl were studied. The kinetics of the reactions were studied at three different temperatures to obtain the thermodynamic parameters. In addition, these reactions were studied in KBr and RbI matrices. The data was obtained using infrared spectrophotometer measurements.

The reactions all appeared to be first order with respect to the permanganate ion. The stoichiometric studies indicate that the Mn₄^- is converted to Mn⁺⁺ and the Mn⁺⁺ ion apparently catalyzes the reduction of KI₄. The results indicate the …

Computerized Computation Of Counter-Current Extraction Problems For Ternary Liquid Systems, Albert Warren Patterson

Theses

A Fortran computer program has been developed that will calculate the number of theoretical equilibrium stages required for a countercurrent liquid-liquid extraction design problem. It also furnishes a complete stagewise material balance. Further utility can be found by using it for optimization studies. The program can be utilized for three-component systems that form one pair of partially miscible liquids, the most frequently occuring situation. The program was written for the General Electric Mark I Time-Sharing System.

The program has a practical advantage in that isothermal liquid equilibria data are used directly for calculation purposes. No use is made of theoretically …

Manpower And Productivity In The Construction Industry, John A. Purciello

Theses

The relationship between manpower and productivity is an important factor in the area of increasing construction costs. Manpower supply is affected by worker mobility, influx of minority workers, work accidents, and training and apprenticeship programs.

A survey was conducted in the state of New Jersey to determine if a manpower shortage existed. The survey was conducted by submitting questionnaires to contractors, unions, owners, and architect-engineers.

The results of the survey indicated that a manpower shortage does exist, and that the shortage has influ enced construction costs, Furthermore, as a result of the increasing costs, indications of a decline in new …

Analysis Of Decomposition Gases And Leach Water From Controlled Sanitary Landfill, Robert Gargano

Theses

A sanitary landfill was simulated by placing "refuse" between two layers of soil in 6" by 24" cylinders. Canine nutriment was used to simulate the refuse. Once the refuse began to decompose, the decomposition gases were collected in a gas cell and analyzed in an Infrared Spectrophotometer. When gas samples were not taken, the decomposition gases were vented through a water trap (to prevent air from backing up into the system) into the atmosphere. Distilled water was added and withdrawn at two week intervals to leach out the pollutants.

From the Infrared analysis, the decomposition gases were determined to be …

Separations Via Semicontinuous Parametric Pumping, Edward H. Reiss

Theses

A semicontinuous parametric pump with batch operation during one half-cycle and continuous operation in the other half-cycle was experimentally investigated in the model system, toluene-n-heptane on silica gel adsorbent. Comparison was made with analytical results obtained by the equilibrium theory. It was shown that when the penetration distance for the cold cycle was less than or equal to that of the hot cycle and the height of the column, the rate of production of pure solvent in the semicontinuous pump may become quite large relative to that in the continuous pump.

Predictions Of Catalyst Utilization With Continuous Replacement In Multistage Continuous Reactors From Batch Reactor Data, Norman M. Feinberg

Theses

This thesis presents a new equation for predicting catalyst utilization with continuous replacement in multistage continuous reactors from batch reactor data.

An equation is derived from experimental data for a. no-replacement system which predicts catalyst activity as a function of time. The assumption of constant inventory, constant replacement rate and perfect mixing permit the calculation of catalyst age distribution. By combining age distribution with a measure of catalyst productivity, as determined from activity as a function of time, an equation for catalyst utilization was derived. The case used to prepare this equation was where the activity decline curve appears as …

Computer Simulation Of A Linde "Double Column", John A. Bazan

Theses

The purpose of this thesis is to develop a Fortran Computer Program to simulate the operation of a Linde "Double Column" for the separation of air into oxygen and nitrogen. The model outputs the number of contact stages required, the reflux ratio, the heat loads (condenser and reboiler, and the five profiles of temperature, pressure, vapor flow rate, liquid flow rate, and light component composition. From this data, the proposed design can be evaluated, and the effect of varying operating conditions explored.

Complex Systems And The Price-Resource Directive Coordination Procedure, Chamberlain Lambros Foes

Dissertations and Theses

In this thesis, the problem considered is that of linear static optimization of a large system which is composed of a finite number of subsystems, each characterized by its own constraint matrix and objective function.

The total system is itself constrained by resource availabilities and other factors, and its objective function is the mathematical linear sum of the objective function of the subsystems. The total system constraints couple together all the subsystems. The total system is first reformulated as a two-level problem by decoupling the total system constraints utilizing an arbitrary partition of the total system resources and other factors …

Rotary Engine Designs Based On A Particular Off-Set Cavity/Rotor System, M. Dean Black

Theses and Dissertations

The subject of this thesis is a family of rotary engines, each consisting of a two-tipped rotor turning about an off-center axis within a nearly round cavity.

Vibration And Buckling Of Elastic Plates With Shear And Rotatory Inertia, Bomi Batiwalla

Dissertations

The effects of shear, rotatory inertia and inplane forces on the transverse vibration of thin plates are studied. In addition, the effect of shear on the buckling of thin plates is examined. A general differential equation of motion is derived for an isotropic thin plate subjected to normal and inplane forces with the consideration of shear and rotatory inertia. The method of internal constraints and Hamilton's principle are utilized.

The resulting fourth order differential equation is solved for simply supported plates of various shapes by employing a finite difference technique. The shapes examined are a square, a circle, a circular …

The Reaction Of P-Nitrophenyl Acetate With Lysine Hydrochloride And Poly-1-Lysine Hydrobromide, Emmanuel Plange Matteer

Theses

The reactions of p-nitrophenylacetate with L-lysine hydrochloride and poly-L-lysine hydrobromide as a function of pH were investigated.

The results indicate that both compounds react with the substrate in the pH range 7.0-10.0 with an apparent optimum pH in the region near 9.65.

Poly-L-lysine reacts more rapidly over the entire pH range investigated than does L-lysine.

Effectiveness Of Training Programs For Graduate Engineers, V.C. Rajashekar

Theses

This thesis represents an investigation of effectiveness as a result of engineering training. The basic elements of effectiveness and its learning process are explained and said that the effectiveness could be learnt and improved.

The term training, is basically the process of education and training. But training cannot be performed as an individual, but is performed as a group. Therefore training a group with having so many individuals needs careful consideration in designing a training program.

In order to get the broadest possible picture of current thinking and current activity in the area of company training programs for graduate engineers, …