Engineering Commons^™

Direct And Inverse Heat Conduction In Rock Materials Using The Finite Element Method, Vernon Dale Allen

Doctoral Dissertations

"A finite element method is presented for solution of direct and inverse heat conduction problems in rock materials. Finite element programs for direct and inverse heat conduction problems were developed and demonstrated. Flow charts are given for the finite element programs.

The direct finite element heat conduction program changes material properties with temperature to approximate the temperature dependent properties of rock materials. An example problem was solved by the finite element method and also using Kirchoff's transformation. The finite element solution compared quite well with the Kirchoff transformation solution.

The inverse method utilizes the direct finite element heat conduction program …

Evaluation Of Methods For The Recovery, Chemical And Toxicological Characterization Of Trace Organics, James Robert Matthews

Doctoral Dissertations

"Organic contaminants are generated in substantial quantities by the activities of man and through natural processes, and are present in natural runoff, industrial wastes, and agricultural discharges; synthetic organic chemicals, many of which are refractory and reach surface and subsurface water, are of particular significance. Earlier studies have generally emphasized the organoleptic and esthetic problems caused by trace organics, although their acute and long-term toxic potential has also been recognized.

The overall objective of this investigation was the analytical and toxicological characterization of trace organics recovered concomitantly from Missouri waters of varied character by large-scale solvent extraction (SEM) and carbon …

Hydrodynamic Mixing Model Applied To A Continuous Stirred-Tank Reactor With And Without Second-Order Reaction, Leon L. Otte

Doctoral Dissertations

Paper 1: "A hydrodynamic mixing (HDM) model, used to calculate the steady-state spatial distribution of conversion for a second-order reaction in a continuous stirred-tank reactor (CSTR) for non-premixed reactants was developed and contrasted with other methods. The HDM model is based on a segmental description of the reactor and includes turbulent mixing effects in each segment. As a test of the model, the experimental results obtained from a tubular reactor were found to be very well represented for a range of reactant ratios. Spatial distributions of concentration and segregation intensity (degree of mixing) within the CSTR were determined for a …

Kalman Filter Equalization For Qpsk Communications, Tze-Shen Lee

Doctoral Dissertations

"The discrete complex Kalman filter is considered as an equalizer for quadrature phase shift keyed (QPSK) systems in the presence of additive noise and intersymbol interference (ISI). For a known linear time-invariant channel with finite duration impulse response, the finite n-dimension complex Kalman filter equalizer is able to reduce the degradation caused by ISI. When the channel is unknown, an adaptive Kalman equalizer is used in which the channel complex tap gains are estimated by decision feedback. A two component multipath channel QPSK system is used as an example. Using the Chernoff upper bound to calculate the error probabilities, the …

Surface Elastic Waves In Piezoelectric Semiconductors And Layered Media, Yu-Pin Han

Doctoral Dissertations

"The primary interest of this investigation is to understand the surface elastic wave properties in piezoelectric semiconductors and layered media. Generalized piezoelectric wave equations in piezoelectric semiconductors and layered media are derived. Systems considered are the piezoelectric semiconductor, the two layer piezoelectric insulator-semiconductor, the three layer piezoelectric insulator- gap-semiconductor and the four layer piezoelectric insulator-gap-semiconductor-dielectric substrate. The eigenwave expansion and the iteration methods in the complex domain are used to solve the problems. Mathematically, it represents a solution of the eigenvalue boundary value problem which involves iteration of functions in the complex domain. Solutions obtained are eigenvalues and eigenvectors which …

An Analytical And Experimental Study Of The Dynamic Response Of A Press, Woosoon Bai

Doctoral Dissertations

"This dissertation presents a simplified mathematical model and computer simulation of the vertical motion of a press. The model is verified by comparing simulation results with actual field measurements.

Using this model, the computer simulation is then extended to study the dynamic response of a bolted press, one with loosened anchor bolts, and one which is isolated. Press performance, in terms of acceleration of the press, velocity of its foundation, and forces transmitted to the foundation, is analyzed in relation to the foundation mass and the stiffness of the isolators, where applicable. Comparative performances of the presses secured by the …

Solid Transformations And Premelting Phenomena In Fluorite Structures And The System Srcl₂Bacl₂, Damri Sukhotanang

Doctoral Dissertations

"Thermal expansion and phase transformations in CaF₂, BaF₂, SrCl₂, and BaCl₂ were studied by high temperature x-ray diffractometry, differential thermal analysis, and thermodilatometric analysis. Thermal expansion characteristics of CaF₂, BaF₂ and SrCl₂ are very similar. The structures expand normally at lower temperatures and depart substantially from linearity at higher temperatures, because of formation of defects and disordering of anions. At high temperatures CaF₂ and BaF₂ react with water vapor, even at low humidities, forming oxides and emitting HF, leading to difficulty in observation of phase transformations. SrCl …

Phase Equilibria And Transformations In Potassium Sulfate, Chromate, Molybdate, And Tungstate, Roy Richard Ramey

Doctoral Dissertations

"Thermal expansion and transformations of K₂SO₄, K₂CrO₄, K₂MoO₄, and K₂WO₄ were studied by high temperature diffractometry, differential thermal analysis, and dilatometry. K₂SO₄ and K₂CrO₄ transform from an orthorhombic to a hexagonal structure at 580°C and 670°C respectively, with initiation of the transformation probably related to increased amplitude of S-O tetrahedral vibrations. K₂MoO₄ and K₂WO₄ transform from a monoclinic to an orthorhombic structure at 300° and 370°C respectively. A minor K₂MoO_{4 …}

Removal Of Nutrients By Sorption On Activated Alumina, Checkman Michael Yue

Doctoral Dissertations

"The nutrient enrichment of surface, primarily impounded, water and the associated problems of accelerated eutrophication and prolific algal growth have become a nationwide concern. Phosphorus and nitrogen are considered to be the key elements in abating eutrophication and are contributed from many sources, natural and manmade; prominent among these is the discharge of domestic and industrial wastes.

The purpose of this study was to evaluate the removal of nutrients, primarily phosphorus and nitrogen, with activated alumina using a continuous-flow pilot plant system. Specific objectives were the: development and construction of appropriate bench and field-scale pilot plant units utilizing the rapid …

State-Space Analysis And Synthesis Of Active Rlc Networks, Wen-Pao Lee

Doctoral Dissertations

"This dissertation provides theoretical foundations for the state-space analysis and synthesis of linear active RLC networks containing all four types of controlled sources. The analysis portion is concerned with an explicit representation of the state model and the order of complexity of a general linear active RLC network. The problem considered in the synthesis portion is the realization of a given A-matrix with an active nondegenerate RLC-ladder network or an active RLC network without any particular structure.

The general active RLC network state model representations are explicitly expressed in terms of the fundamental circuit submatrices, the network element submatrices, and …

Transition Boiling Of Normal Pentane From A Horizontal Flat Gold Surface, Ronald M. Canon

Doctoral Dissertations

"The characteristic boiling curve for Normal Pentane was determined at 1 atmosphere pressure with particular attention devoted to the transition boiling region. The heat transfer surface was a horizontal, gold-plated, copper disc.

Stability analysis was employed to demonstrate why previous investigators have had only limited success in collecting data in the transition region and to provide a valid basis for equipment designed to operate in this region.

A method of predicting the transition region boiling curve from the nucleate curve and the Liedenfrost point is presented. The method was found to predict the transition boiling of Normal Pentane, Freon 12, …

Dropwise Condensation As Affected By Vapor Diffusion And Molecular Sticking, Salil K. Banerjee

Doctoral Dissertations

"Experimental values of heat flux in dropwise condensation on a gold plated vertical copper surface were determined in presence and absence of (or minute traces of) noncondensable gas. The noncondensable gas concentration varied from 0.0045% to 7.5% over a range of subcooling from 2.155 to 17.13°F and system pressure of 4.124 to 16.67 psia. The calculated heat transfer coefficient ranged from 1,545 to 11,135 Btu/hr-ft²-°F. In the part of the experiment where precautions were taken to avoid the presence of noncondensable gas in the water vapor, much higher values of heat flux were observed. Values of heat transfer coefficient ranging …

Mathematical Simulation Of Gas And Water Coning In Petroleum Reservoirs By The Dynamic Material Balance Technique, Visheshwar Nath Simlote

Doctoral Dissertations

"The prediction of coning behavior at a producing oil well is one of the most difficult numerical simulation problems. Because of the convergent flow patterns and small sizes of the inner grid blocks, the radial coordinate models used to study the problem have a tendency to become unstable. Since several hundred pore volumes may flow through the inner grid blocks during a rather small time interval, instabilities are likely to occur in the saturation calculations for these grid blocks. The dynamic approach to saturation calculations is a method which first computes the correct material balance and then calculates the saturation …

Nucleate Boiling Of N-Pentane, N-Hexane And Several Mixtures Of The Two From Various Tube Arrays, Kenneth Wayne Wall

Doctoral Dissertations

"An investigation of nucleate boiling heat transfer in saturated pools of Normal Pentane, Normal Hexane and several mixtures of the two was conducted. The fluids were boiled from gold-plated, copper, cylindrical heat transfer surfaces, 4.96 inches long, and 1.048 inch in diameter. The heat transfer elements were boiled in varying vertical tube arrays at a pressure of 14.70 psia.

It was found that the mixtures boiled with a lower heat transfer coefficient than that for either pure component when boiled alone. When boiling in any of the tube bundle arrangements, the heat transfer coefficients for the upper tubes in the …

A Study Of Exothermic Chemical Reaction In A Porous Catalyst Wedge, Joseph Michael Schardl Jr.

Doctoral Dissertations

"Temperature and composition were measured at various locations in a system where ethylene is hydrogenated to ethane on a 1/4 inch porous catalyst wedge made of nickel supported on alumina. 'When the wedge of catalyst was bathed in hydrogen, experimental results indicated a high temperature rise from the feed temperature to the catalyst which is implied by the diffusion controlled regime for solid catalyzed, highly exothermic reactions. This high activity was reversibly reduced by bathing the catalyst wedge in nitrogen for extended time periods (greater than 24 hours). This nitrogen soaking changed the experimental conditions from those of diffusion controlled …

Solid-Fluid Drag Reduction, Ian Radin

Doctoral Dissertations

"Pressure drop measurements were made on a variety of solid-liquid suspension systems in order to study the effects of particle shape and size, concentration, fluid viscosity and tube diameter on drag reduction. Measurements were made over a wide range of Reynolds numbers in two tubes: 1/4 inch and 1 inch in diameter.

Drag reduction could always be obtained with fibrous additives of length-to-diameter ratio greater than 25-35 if the concentration was sufficiently high. The drag reduction behavior of these suspensions is different from that of high polymer and soap solutions. Laminar flow behavior is stabilized giving lower than normal friction …

Numerical Modeling Of The Early Stage Of Cloud Formation In A Simulation Chamber, Adel Nassif Saad

Doctoral Dissertations

"A numerical model has been developed to simulate the growth of cloud droplets by condensation upon a spectrum of hygroscopic nuclei. The model is applicable to cloud simulation chamber conditions as well as to the study of the role of these nuclei on cloud base microstructure.

Equations are given for the growth by condensation of water vapor on a population of hygroscopic nuclei in a volume being cooled by expansion. The equations are integrated simultaneously, using Hamming's modified predictor-corrector method for given initial conditions, to obtain the droplet size distribution, temperature, pressure, supersaturation, and liquid water content. Temperature fluctuations, sedimentation …

Separation Of Gas Mixtures Via Batch Parametric Pumping : A Theoretical Study, Jose G. Lopez

Theses

An equilibrium plug?flow model, for the batch isothermal separation of a binary gas mixture in a pressure changing parametric pump, was investigated for the system propane?argon on carbon, with the aid of a G. E. Pack 4020 computer. Separation factors comparable to a temperature changing parametric pump are predicted by the model. A change in pressure of the gas mixture may be carried out very rapidly, compared with a temperature change of similar magnitude. The effects of temperature, pressure, concentration, and penetration are discussed.

Thermal Oxidation Of Gallium Arsenide Phosphide., Leo Edward Coerver

Electrical and Computer Engineering ETDs

This work covers the most important basic facts about the thermal oxidation of gallium arsenide phosphide. The work is confined to lightly dopes GaAs(1-x)^px material with a phosphorus mole fraction of 0.50+-0.02. All oxidations were carried out in open tubes and consequently at atm

ospheric pressure. Initial studies over a wide range of oxidation temper­atures showed that serious surface damage to the semiconductor surface occurred if the oxidation temperature was greater than 700° C. An anneal in an inert atmosphere at a temperature no greater than 700° C for at least 90 minutes was required to obtain good pinhole-free dielectrics. …

Electron Beam Evaporated Aluminum Oxide Gate Silicon Transistors., Chang-Ching Cheng

Electrical and Computer Engineering ETDs

Aluminum oxide films prepared by the electron beam evaporation of Al2O3 tablets have been studied in metal-insulator-semiconductor devices. The structure of Al2O3 films is amorphous with a density os 2.25 gm/cm3. The film conductivity is smaller than 5x10^14 (ohm-cm)^-1 and the breakdown strength is higher than 1.3x10^6 V/cm. The transport mechanisms in the film are believed to be impurity-induced flow at room temperature and Poole-Frenkel emission at higher temperatures.

The average relative dielectric constant is about 7. The interface surface states of the MIS sample are small in the middle of the forbidden band, gradually increasing toward the band edges. …

Analysis Of A High-Heat-Flux Water Heat Pipe Evaporator, Michael Einar Berger

Mechanical Engineering ETDs

An analysis was made to determine a surface which has potential use in a high-heat-flux, low-temperature-drop water heat pipe evaporator. A comprehensive survey of the literature was made to determine those surfaces which had high-heat-flux potential under evaporation. A circumferentially grooved surface was selected as the surface to be analyzed. Two groove geometries were selected for analysis, rectangular and triangular. A mathematical model of the grooves was constructed in order to predict the maximum surface heat flux capability. In addition, a model of the heat transfer within the fluted surface was proposed which postulated that conduction through the wall and …

Dynamics Of Interconnected Systems With Pulse Frequency Modulators, Halil Ozcan Gulcur

Dissertations

The objective of this dissertation is to study the dynamics of systems consisting of interconnections of an arbitrary number of complete-reset pulse frequency modulators (CRPFM's) and linear dynamical subsystems (in general, time-varying, lumped and/or distributed). CRPFM, which represents a generalization of several types of pulse frequency modulators (PFM's), consists of two basic components; a multi-input dynamic element, called the timing-filter (TF) and a threshold device (TD). Whenever the output of the TF reaches a given threshold value the TD generates an impulse and, at the same time, resets all the states of the TF to zero. This dissertation is devoted …

The Effect Of Variation In The Ratio Of Specific Heats With Temperature And Pressure On Horsepower Requirements Of Reciprocating Compressors, Selim Piskin

Theses

The expansion and compression of fluids is discussed in relation to the design of reciprocating compressors. As part of this thesis, the design equations for reciprocating compressors are developed for both ideal and reel gases.

The resulting design equations contain, as one of the parameters, the ratio of the specific heats. Using published componential specific heat data, a correlation was developed relating the dependence of the ratio of specific heat on temperature and pressure for the nore common gases. These correlations were developed so as to be compatible with the compressor design equation and to provide rapid evaluation of the …

Energy States In Random Media., Peter Chen-Chi Chang

Electrical and Computer Engineering ETDs

This dissertation is concerned with energy levels and the density of states in random crystals.

By developing a non-linear differential equation for the phase process in random crystals, it is shown how to calculate the density of states in one-dimensional random arrays. The method used ha􀀕 the virtues of simplic­ity and, where comparison with previous numerical results can be made, accuracy, with minimal computing time. Various analytical results are found with the phase process method and these are equivalent with results found by other workers.

In the three-dimensional case, it is shown how to use the phase process to help …

Rubbery Acrylic Polymer Adhesives, Steven Walter

Theses

This study shows how rubbery acrylic polymer adhesives can be used to adhere rubber substrates to each other. Two substrate rubber compounds were used. A styrene-butadiene copolymer and a styrene-acrylonitrile copolymer. The adhesives were homopolymers based on polybutyl acrylate and poly2-ethyl hexyl acrylate.

Two reference standards were used. The first was commercial rubber based, solvent cements. The second was commercial acrylic solution polymers. All experimental work was compared to these standards. An attempt was made to optimize the adhesive components, as well as the adhesive application procedures and curing conditions.

A primer coating consisting of polymer, monomer, and catalyst was …

Biocatalytic Oxidation Of Nitrilotriacetate, Saul Hammerman

Theses

The specific scope of this work is to study the biological and chemical effects of a single genetic strain of bacteria, Bacillus subtilis #9524, on the specific destruction to innocuous products of sodium nitrilotriacetate (NTA) and sodium tripolyphosphate (STPP). Insofar as the same strain of bacteria was used each time, under limited variability and sterile conditions, the side effects of multiple bacterial strains and their inter-relationships among themselves and the organic substrates are eliminated. This has allowed for excellent replication of results.

This is a generalized technique for the evaluation of the biodegradability of a compound. Whereas tests with activated …

Correlation Of Drain Breakdown With Excess Noise And Other Surface-Related Phenomena In Enhancement Mosfets, Jerry J. Rij

Theses

An investigation of semiconductor surface-related phenomena has been undertaken to correlate 1/F noise with drain breakdown in P-channel enhancement MOSFET's. Increases in the intensity of drain current fluctuations at 10Hz and at 1KHz, particularly at the higher frequency, was observed following accelerated life-testing for threshold voltage drift. It was also concluded that mobile ions near the oxide-semiconductor interface produce a sharp increase in fast trapping centers. It was also found that 1/F noise intensity consistently peaked at the threshold of drain breakdown and that it steadily decreased with further increases in drain current. Of all the transistors tested, those with …

Recent Developments In The Use Of Precast Concrete Units For Buildings In The United States And Iran, Khosrow Ebadi Farshchi

Dissertations and Theses

The object of this study was to investigate the recent developments in the use of precast prestressed concrete members for buildings in the United States and Iran. In the United States, the study was concerned with developments in the usage of members such as slabs, wall panels, beams and columns. The latest technical and engineering reports, along with personal interviews, were used, and a number of case studies were conducted on recently built structures. The author also studied the newest developments in the precast concrete industry in Iran. A questionnaire was formulated in both Persian (native language of Iran) and …

Explosive Electron Emission And The Characteristics Of High-Current Electron Flow, Robert Kelley Parker

Nuclear Engineering ETDs

Within the past several years, an increasing effort has been concen­trated on the application of high-current, relativistic electron beams to the problem of controlled thermonuclear fusion. Initially, this effort had been impeded by limitations in the high-voltage and pulsed-power technology required to develop pulsed, high-power electron accelerators. These technologies have been developed to a level where powers on the order of 10¹³ watts are now available for time durations of approximately 100 nanoseconds. With the initial limitations removed, the emphasis has more recently been centered on controlling and concentrating these beams to achieve the parameters necessary for fusion experimentation. …

A New Sampling Theorem For Causal (Non-Bandlimited) Functions., Alan Baker Campbell

Electrical and Computer Engineering ETDs

It is shown in this work that whereas any causal function (i.e., any function with a definite starting point) is non-bandlimited and thus would be thought to require an infinite sample rate, there is an infinite class of causal functions (identified as "regionally bandlimited functions" (r.b.f.'s)) for which a finite sample rate is adequate.