Engineering Commons^™

Surface Modification Of Nanoplatelets In Polymer Nanocomposites, Shailesh K. Shori

Theses and Dissertations

In polymer nanocomposites (PNCs), it is very important that the nanofiller (typically an inorganic) is well-dispersed in an organic polymer matrix. Optimal compatibility results in end-use products such as packaging materials with enhanced properties. In practice, however, this is challenging to achieve because “ideal” dispersions require the complete uniform separation, termed exfoliation, of the nanofiller within the matrix. As a result, different nanofillers including calcium niobate (CN) and montmorillonite (MMT) are first studied for their ability to exfoliate in aqueous suspensions by measuring the organic cation uptake. The cation exchange capacity, or CEC, determined that CN needs further work before …

Synthesis Of Au And Ag Catalysts With Controlled Sizes Of Metal Particles, Eleni A. Kyriakidou

Theses and Dissertations

The performance of supported metal catalysts largely depends on the structure and composition of the metal particles and the nature of the support. In order to achieve better control over these parameters, synthetic route based on the use of templating agents has been proposed. Among the different templating agents, poly(amidoamine) (PAMAM) dendrimers have attracted a lot of recent attention as nanoparticle stabilizers. In this thesis, Au/G4OH nanocomposites were synthesized in aqueous solutions and used as precursors for the preparation of SiO2-supported Au nanoparticles. Elemental analysis, UV-Vis, and STEM measurements were used to estimate the extent of the Au-dendrimer interactions and …

Application Of Various Adsorbents To Remove Micro-Pollutants In Aquatic System, Chanil Jung

Theses and Dissertations

Untreated or insufficiently treated pharmaceuticals and endocrine disrupting compounds (EDCs) as well as heavy metals have influenced the ecosystem and their exposures in the water system have threatened human health; causing cancers and adverse health effect to immune system. While various water treatment techniques have been applied to solve this problem, adsorption has been considered as one of the most efficient and manageable water purification techniques. Advanced analysis methods for aqueous contaminants have improved comprehension, allowing proficiency about the fate of trace leveled emerging contaminants, thus allowed to reveal the adsorption mechanisms of each pollutant. This dissertation focuses on the …

Ultrasound-Mediated Optical Imaging And Focusing In Scattering Media, Yuta Suzuki

McKelvey School of Engineering Theses & Dissertations

Because of its non-ionizing and molecular sensing nature, light has been an attractive tool in biomedicine. Scanning an optical focus allows not only high-resolution imaging but also manipulation and therapy. However, due to multiple photon scattering events, conventional optical focusing using an ordinary lens is limited to shallow depths of one transport mean free path (lt'), which corresponds to approximately 1 mm in human tissue.

To overcome this limitation, ultrasonic modulation (or encoding) of diffuse light inside scattering media has enabled us to develop both deep-tissue optical imaging and focusing techniques, namely, ultrasound-modulated optical tomography (UOT) and time-reversed ultrasonically encoded …

Contextualized Robot Navigation, David Vincent Lu

McKelvey School of Engineering Theses & Dissertations

In order to improve the interaction between humans and robots, robots need to be able to move about in a way that is appropriate to the complex environments around them. One way to investigate how the robots should move is through the lens of theatre, which provides us with ways to analyze the robot's movements and the motivations for moving in particular ways. In particular, this has proven useful for improving robot navigation. By altering the costmaps used for path planning, robots can navigate around their environment in ways that incorporate additional contexts. Experimental results with user studies have shown …

Metabolic Engineering Of Cyanobacteria For Photosynthetic Production Of Drop-In Liquid Fuels, Bertram Michael Berla

McKelvey School of Engineering Theses & Dissertations

Cyanobacteria are oxygenic phototrophs with great potential as hosts for renewable fuel and chemical production. They grow very quickly (compared with plants) and can use sunlight for energy and CO2 as a carbon source (unlike yeast or E. coli). While cyanobacteria have been engineered to make many chemicals that are native and non-native parts of their metabolism, this work is concerned with the production of heptadecane in Synechocystis sp. PCC 6803. Heptadecane is in a class of natural products produced by all cyanobacteria, but in quantities insufficient for industrialization. Towards this future goal, we have built enabling systems for the …

Advanced Digital Signal Processing Based Redefined Power Quality Indices, And Their Applications To Wind Power, Md Moinul Islam

Theses and Dissertations

This dissertation proposes a time-frequency distribution (TFD) based new method to redefine the power quality (PQ) indices for the assessment of PQ disturbances typically present in electric power systems. The redefined PQ indices are applied to various types of synthetic and real-world PQ disturbances in order to verify the efficacy and applicability of the proposed method. The case studies show that the proposed method provides actual results with respect to the existing TFD-based transient PQ indices, and provides much more accurate results than the traditional fast Fourier transform (FFT) based PQ indices under stationary and nonstationary PQ disturbances. In addition, …

Quantifying Individual Losses In A Direct Methanol Fuel Cell, Jennifer Rae Ruffing

Theses and Dissertations

The performance of a direct methanol fuel cell (DMFC) is complicated due to the complex interactions of kinetic and transport processes. As a result, changes in one aspect of the cell have consequences in other aspects, which are difficult to elucidate from the full-cell polarization (i.e. voltage vs. current) behavior that fuel cell researchers often use to characterize the performance of their systems. The objective of this work was to develop a strategy to use current and voltage relationships from anode half cells, cathode half-cells, and a hydrogen pump, coupled with methanol crossover data and a mathematical model, to quantify …

On The Development Of High Strain Rate Experiments For The Characterization Of Engineering Materials, Silas P. Mallon

Theses and Dissertations

In order to predict the damage accumulation and failure processes associated with highly dynamic events such as blast loading, shock wave loading, and ballistic impact loading, a commensurate understanding of the fundamental constitutive and fracture behavior of materials subjected to such high rate loading conditions is necessary. In this effort, high strain rate experimental facilities consisting of a shock tube apparatus and a torsional split Hopkinson bar apparatus have been designed, constructed, and subsequently used to investigate the mechanical properties of an array of engineering materials subjected to a variety of dynamic loading conditions. Designs for the experimental equipment utilized …

High-Performance Meta-Genomic Gene Identification, Ibrahim Savran

Theses and Dissertations

Computational Genomics, or Computational Genetics, refers to the use of computational and statistical analysis for understanding the structure and the function of genetic material in organisms. The primary focus of research in computational genomics in the past three decades has been the understanding of genomes and their functional elements by analyzing biological sequence data. The high demand for low-cost sequencing has driven the development of highthroughput sequencing technologies, next-generation sequencing (NGS), that parallelize the sequencing process, producing thousands or millions of sequences concurrently. Moore’s Law is the observation that the number of transistors on integrated circuits doubles approximately every two …

Low Reynolds Number Turbulence: Mechanisms And Applications, Wei Zhao

Theses and Dissertations

Turbulence, as one of "the most important unsolved classical problem in physics" (R. Feynman, 1932), has been investigated for more than 130 years. Conventionally, turbulence is believed to be a phenomenon of high Reynolds numbers (Re). However, we find that turbulence can also be achieved at low Re by proper external forcing, either in macroflows or in microflows. In macroflows, the characteristics of high Re turbulence can be achieved in confined flows, when the bulk flow Re is around 400, by external forcing at its optimal frequency (Wang 2003; Wang 2006). Interestingly, the optimal narrow band of frequency is fixed …

Quantitative Comparison Of Time-Frequency Decomposed Gait Emg Signals, L. Patrick Mitchell

Theses and Dissertations

Falls in the senior population represent an immediate threat to both current and future generations’ quality of life. The results of falls can be disastrous, create a long road to recovery, and in many cases result in death. Hypertension represents a difficult-to-quantify condition which is known to contribute to gait and balance dysfunction. Accurate assessment of conditions such as these represents an area of primary investigative need. In order to meet this need, a new experimental setup is developed which combines time-frequency analysis with surface electromyography (sEMG) signals obtained during ambulation. 3-bit pressure data is acquired using a pressure-sensitive mat, …

An Engineering Approach For The Design Of Archaeological Reburial Systems, Angel Ari Perez Mejia

Theses and Dissertations

Archaeological sites are a non-renewable resource which is often our only link to the past. However, sites are under constant threat of destruction due to construction activities. Civil engineers and archaeologists must the work together to ensure both the continued survival of archaeological sites while allowing for development to continue. Reburial systems, when properly designed and constructed, allow for the protection of archaeological sites while allowing the continued use of the land. However, because reburial as an intentional conservation technique is relatively modern, practice is fragmented and there are no universally accepted guidelines. Current reburial system design relies on prescriptive …

Cost Avoidance Analysis Of Military Aircraft Components Utilizing Condition-Based Maintenance Practices, Erin Ballentine

Theses and Dissertations

This research involves two major case studies. Both look at the current maintenance practices done by the United States Army and propose a solution for improvement utilizing condition-based maintenance (CBM) practices. Each study details a cost avoidance that can be earned by implementing the solutions and the resulting benefits that can be experienced. Case Study I is a return on investment (ROI) that analyzes the benefits of the implementation of elastomeric wedges as vibration control on the Apache (AH-64D) aircraft. Analysis of the material and operational costs shows that the use of self-adhering elastomeric trailing edge wedges on the Apache …

Slow Wave Structures Integrated With Ferro-Magnetic And Ferro-Electric Thin Films For Smart Rf Applications, B M Farid Rahman

Theses and Dissertations

Modern communications systems are following a common trend to increase the operational frequency, level of integration and number of frequency bands. Although 90-95% components in a cell phone are passives which take 80% of the total board area. High performance RF passive components play limited role and are desired towards this technological advancement. Slow wave structure is one of the most promising candidates to design compact RF and mm-Wave passive components. Slow wave structures are the specially designed transmission line realized by placing the alternate narrow and wide signal conductors in order to reduce the physical size of the components. …

Functionalized Graphitic Nanoreinforcement For Cement Composites, Nima Zohhadi

Theses and Dissertations

Physical and mechanical properties of graphitic nanomaterials, in particular multiwalled carbon nanotubes (MWCNTs) and graphene nano-platelets (GNPs) make them promising candidates for nanoreinforcement of cement composites. The two key challenges associated with the incorporation of MWCNTs and GNPs are to attain uniform dispersion and interfacial bonding within the composite matrix. The effects of three main-stream dispersion techniques (namely, ultrasonication, acid-etching, and surfactant-coating) on the mechanical properties and microstructure of MWCNT- and GNP-cement composites were experimentally studied. Compressive strength tests and different characterization techniques including dynamic light scattering, Raman spectroscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission …

Finite Element Analysis Simulations Of Micro And Nano-Electromechanical Sensors For Design Optimization, Nicholas Frank Deroller

Theses and Dissertations

Micro and Nano-electromechanical sensors (MEMS and NEMS) provide a means of actively sensing minute changes in the surrounding environment. Small changes in temperature, momentum, and strain may be sensed in passive modes while greater sensing possibilities exist in active modes. Theoretical femto-gram resolution mass detection and heated element sensing methods may be used while volatile organic compound (VOC) sensing may be achieved when combined with a functionalization layer or device heating. These devices offer a great reduction in cost and offer increased mobility by allowing a "lab-on-chip" solution for the prospective user while also greatly reducing the amount of energy …

Influence Of Defects In Epitaxial Graphene Towards Material Growth And Device Performances, Shamaita Shithi Shetu

Theses and Dissertations

Since its invention in 2004, Graphene, a two dimensional array of SP2 bonded carbon atoms has received significant interest by the scientific community due to its unique electrical, optical and mechanical properties. A promising route to the synthesis of large-area graphene, is epitaxial graphene formed by sublimation of silicon atoms from Silicon carbide at elevated temperatures (>1200oC). Although the electronic and mechanical properties of graphene with perfect atomic lattice are outstanding, the structural defects, which may appear during graphene growth, can influence the growth mechanism and material properties. However, deviations from perfection, i.e. introducing dopants in semiconductors often considered …

High Level Control Implementation For A Residential Smart Grid Power System, Hang Xu

Theses and Dissertations

With the environment protection and energy usage efficiency promotion issues concerned more and more by governments and industries these days, smart grid technologies have been in rapid development. On this new technology stage, residential site power management system has become a star. This paper introduces the concept, development of two high level control methods for “Smart Green Power Node” (SGPN), solutions of demand side energy management system. One control algorithm is optimal model method which uses the predictive data of a battery model with electrical parameters and pricing methods, to keep scheduling the optimal control input on the receding time …

Fabrication And Characterization Of Novel Electrodes For Solid Oxide Fuel Cell For Efficient Energy Conversion, Yu Chen

Theses and Dissertations

Solid oxide fuel cells (SOFCs) have been considered as one of the most promising technologies for future energy conversion since they can in principle be operated with fuels ranging from H2 to any hydrocarbon fuel. However, the system cost and coking (when using hydrocarbon as fuel) issues for the state-of-art electrode materials/designs often limit their further application. The objective of this Ph.D dissertation is aiming at overcoming these problems and accelerating SOFC commercialization. One approach to cost reduction is lowering the SOFC operating temperature to below 800 or even 600 oC, so that inexpensive materials can be used and quick …

Characterization Of Electrodeposited Copper Foil Surface Roughness For Accurate Conductor Power Loss Modeling, Michael B. Griesi

Theses and Dissertations

As computer data rates have increased, designers observed that the standard models for estimating the impact of copper foil surface roughness on conductor loss are limited to a few GHz. The more recent snowball model (a “snowball” estimation of the Huray Model) has demonstrated improved conductor loss predictions up to 50 GHz by estimating the necessary parameters using reasonable assumptions about the geometric surface features of electrodeposited copper foil. Since then, the Huray Model has been incorporated into commercial electromagnetic field simulators. However, a standard method of characterizing the electrodeposited copper foil used in high-speed circuits to directly implement the …

Piezotransistive Iii-V Nitride Microcantilever Based Mems/Nems Sensor For Photoacoustic Spectroscopy Of Chemicals, Abdul Hafiz Ibne Talukdar

Theses and Dissertations

Microcantilevers are highly attractive as transducers for detecting chemicals, explosives, and biological molecules due to their high sensitivity, micro-scale dimensions, and low power consumption. Though optical transduction of the mechanical movement of the microcantilevers into an electrical signal is widely practiced, there is a continuous thrust to develop alternative transduction methods that are more conducive to the development of compact miniaturized sensors. Piezoelectric and piezoresistive transduction methods are two of the most popular ones that have been utilized to develop miniaturized sensor systems. Piezoelectric cantilevers, which are commonly made of PZT film, have demonstrated very high sensitivity; however, they suffer …

Comprehensive Joint Time-Frequency Analysis Toward Condition Based Maintenance Regimes For Electrical And Mechanical Components, David Lee Coats

Theses and Dissertations

Based upon a framework of time-frequency analysis, we outline condition based maintenance (CBM), or maintenance only upon evidence of need, for both electrical and mechanical systems. We apply novel time-frequency cross-correlation metrics to helicopter drivetrain systems and electrical cables as remaining useful life assessments by non-destructive and non-invasive tests. In both cases, these metrics for health assessment provide a basis for diagnostic and prognostic analysis of underlying systems and components by performing accelerated condition tests on actual mechanical and electrical systems. We present novel time-frequency domain vibration analysis of a gearbox failure in an AH-64 Apache drivetrain testbed and quantify …

Scheduling Of Container Handling Equipment In Marine Container Terminals, Narges Kaveshgar

Theses and Dissertations

To improve the competitiveness of marine container terminals, it is critical to minimize the makespan of a container vessel. The makespan is defined as the latest completion time among all handling tasks of the container vessel. Lower makespan (i.e. lower vessel turn time) can be achieved through better scheduling of the container handling equipment during vessel operations. The scheduling of terminal equipment is an operational problem, and a detailed schedule for each type of equipment operating in the terminal is necessary. Several studies have applied operations research techniques to optimize the processes of equipment in a terminal. This dissertation investigates …

Novel Biofabrication Technologies To Recapitulate In Vivo Geometries In Collagen Hydrogels, Veronica Rodriguez-Rivera

Theses and Dissertations

Tissue engineering and regenerative medicine aims to restore form and function to tissues that have been lost or damaged due to disease, congenital defect, or trauma. Biomaterials suitable to restore these complex tissues need to provide a balance between chemical and mechanical properties, providing accurate cell-matrix interaction and induce in vivo behaviors such as proliferation, differentiation and migration. It also requires that physical and chemical cues be presented to the body in the proper temporal and spatial pattern. The extracellular matrix exerts forces that are transmitted through focal adhesion causing changes in the cell behavior. The hypothesis for this dissertation …

Applications Of Advanced Imaging Methods: Macro-Scale Studies Of Woven Composites And Micro-Scale Measurements On Heated Ic Packages, Siming Guo

Theses and Dissertations

As a representative advanced imaging technique, the digital image correlation (DIC) method has been well established and widely used for deformation measurements in experimental mechanics. This methodology, both 2D and 3D, provides qualitative and quantitative information regarding the specimen’s non-uniform deformation response. Its full-field capabilities and non-contacting approach are especially advantageous when applied to heterogeneous material systems such as fiber-reinforced composites and integrated chip (IC) packages. To increase understanding of damage evolution in advanced composite material systems, a series of large deflection bending-compression experiments and model predictions have been performed for a woven glass-epoxy composite material system. Stereo digital image …

Practical Concurrency Support For Web Service Transactions, Emad Alsuwat

Theses and Dissertations

Traditional database concurrency control methods use locking, timestampordering, and optimistic-ordering to achieve DB consistency. However, these approaches are not suitable for long-running Web Service Compositions (WSCs) due to associated performance degradation. Our hypothesis asserts that, using transactional semantic and ordering information, the execution time of a WSC can be reduced, thus allowing the use of traditional database concurrency control methods while avoiding unacceptable performance degradation. Our solution is based on the following approaches: § We model a WSC as WS-BPEL specification, i.e., a partial order of WS transactions. § We allow some of the WS transactions in the WSC to …

A Three-Dimensional-Engineered Matrix To Study The Microenvironment Of Cancer Stem Cells, Samaneh Kamali Sarvestani

Theses and Dissertations

Maintenance of cancer stem cells (CSCs) is regulated by their microenvironment. As cancer cells are affected by many factors in their microenvironment, a major challenge is to isolate the effect of a specific factor on CSCs while keeping other factors unchanged. We developed a synthetic inert 3D Poly Ethylene Glycol Di-Acrylate (PEGDA) gel culture system as a unique tool to study the effect of microenvironmental factors on CSCs response. Synthetic hydrogels provide the flexibility to design three-dimensional (3D) matrices to isolate and study individual factors in the tumor microenvironment. The first objective of this work was to investigate the effect …

Automatic Loop Tuning And Memory Management For Stencil Computations, Fan Zhang

Theses and Dissertations

The Texas Instruments C66x Digital Signal Processor (DSP) is an embedded processor technology that is targeted at real time signal processing. It is also developed with a high potential to become the new generation of coprocessor technology for high performance embedded computing. Of particular interest is its performance for stencil computations, such as those found in signal processing and computer vision tasks. A stencil is a loop in which the output value is updated at each position of an array by taking a weighted function of its neighbors. Efficiently mapping stencil-based kernels to the C66x device presents two challenges. The …

Experimental And Theoretical Studies Of Native And Engineered Vascular Tissue Mechanics, Boran Zhou

Theses and Dissertations

Background: Implantation of vascular grafts provides a means to restore blood flow in compromised regions of the circulatory system, and thus is used to treat a wide range of cardiovascular diseases. Despite significant advancements in autologous grafting strategies as well as the engineering of synthetic alternatives, mechanical, structural, and compositional incongruities between the graft and the host artery remain as contributing factors to graft failure. The typical failure modality manifests as proximal anastomotic intimal hyperplasia, which places restrictions on the host vessel size currently treated with grafting strategies (> 5 mm internal diameter). In order to improve long-term clinical outcomes, …