Engineering Commons^™

Modeling Battery Performance Due To Volume Change In Porous Electrodes Due To Intercalation, Taylor R. Garrick

Theses and Dissertations

The demand for energy continues to increase as the economies of developing countries become more modern and show an increased need for a reliable energy infrastructure in order to meet the increased demand associated with a large and more mobile population. An increased demand puts a strain on all sectors, however it is specifically noticeable in the transportation sector where a significant portion of the fuel utilized for transportation comes from petroleum and other fossil fuels. Recently, using alternative forms of energy for transportation has become reality, and in turn, using electricity as a transportation fuel has gained significant momentum, …

High Quality Low Offcut 4h-Sic Epitaxy And Integrated Growth Of Epitaxial Graphene For Hybrid Graphene/Sic Devices, Anusha Balachandran

Theses and Dissertations

Power electronic semiconductor devices are critical components in next-generation power systems such as hybrid electric vehicles and smart grid power controls enabling reduction in system size, weight, and cost. Wide bandgap materials such as SiC, GaN, and diamond have been investigated to replace silicon, due to their superior material properties. Of these, 4H-SiC is considered the most viable candidate beyond 3kV due to its technological maturity, its wide band gap (3.23 eV), high breakdown field (4×106 V/cm), high thermal conductivity (5 W/cm/K) and, more importantly, its indirect bandgap.

The main contribution of my research relates to the development and investigating …

Theoretical Investigation Of The Catalytic Hydrodeoxygenation Of Levulinic Acid Over Ru (0001) Catalyst Surface, Osman Mamun

Theses and Dissertations

Due to the rapidly declining fossil fuel reserves and the onset of global climate change, the development of active, selective, and stable catalytic materials for the efficient production of biomass derived platform chemicals, i.e., levulinic acid (LA), succinic acid (SA), γ-valerolactone (GVL) etc., is receiving considerable attention in order to produce second generation biofuels and commodity chemicals. Though solid lignocellulosic biomass is significantly cheaper than petroleum; however, the available technology is the significant barrier for large scale utilization of biomass for the production of biofuels. The development of biomass conversion technology requires, 1) identification of potential biomass chemicals that can …

Development Of High Efficiency Dry Powder Inhalers For Use With Spray Dried Formulations, Dale Farkas

Theses and Dissertations

Dry powder inhalers (DPIs) are advantageous for delivering medication to the lungs for the treatment of respiratory diseases because of the stability of the powders, relative low cost, synchronization of inhalation and dose delivery, and many design options that can be used for optimization. However, currently marketed DPIs are very inefficient in delivering medications to the lungs. This study has developed multiple new high efficiency DPIs for use with spray dried excipient enhanced growth (EEG) powder formulations based on the following platforms: capsule-based for oral inhalation, high-dose for oral inhalation, inline with 3D rod array dispersion, and inline with capillary …

Development Of An Electrospun And 3d Printed Cellular Delivery Device For Dermal Wound Healing, Ryan M. Clohessy

Theses and Dissertations

The goal of this research was to develop a system of individualized medicine that could be applied to dermal wounds serving as a wound dressing and synthetic extracellular matrix while delivering stem cells to the wound bed. First, fabrication parameters for electrospinning polymer fibers were determined. This involved evaluating fiber morphology with respect to polymer selection and solution concentration. Next, construct fabrication was examined to produce an integrated void space, or cargo area, suitable to maintain stem cells. In vitro studies to ensure stem cell viability and phenotype were conducted, and results supported the notion that cells could be administered …

Advancing Automated Methods For Microrna Profiling, Kia N. Zellars

Theses and Dissertations

The widespread influence of miRNAs in many biological processes and characteristic changes in expression profiles make them potential biomarkers for a range of diseases. With recent discoveries highlighting the enrichment of particular circulating miRNAs in plasma under pathological conditions, there has been a push for technological advances in miRNA profiling studies as a diagnostic tool. A standardized, automated, high-throughput method for miRNA isolation from human plasma samples was developed in this study. Samples were subject to full miRNome profiling utilizing RT-qPCR. These unique findings demonstrate that developing a distinct miRNA biomarker profile for heart failure patients is feasible and holds …

Instability In Nonequilibrium And Nonthermal Plasma Discharges, Rajib Mahamud

Theses and Dissertations

Microplasma, or plasma in micron scale interelectrode separation, is an effective way to attain nonthermal plasma operation at atmospheric and higher pressure. However, the small size causes the effect of other operating parameters to be crucial in stable operation and make the microplasma discharge system to be susceptible to instabilities. The two major instabilities that are commonly observed are the instability in the negative differential resistance (NDR) region and the Striations or the ionization waves. The physics and reaction kinetics of NDR instability for high pressure system is not well understood. This study pursues both experimental characterization and development of …

Fiber Optic Guided Wave Sensors For Structural Health Monitoring, Erik Frankforter

Theses and Dissertations

Risks and costs associated with aging infrastructure have been mounting, presenting a clear need for innovative damage monitoring solutions. One of the more powerful damage monitoring approaches involves using ultrasonic guided waves which propagate through a structure and carry damage-related information to permanently bonded sensors. Ultrasonic fiber-optic sensors are one of the most promising technologies for this application: they are immune to electromagnetic interference, present no ignition hazard, and transmit their data over tens of kilometers. However, before they can be widely employed, several limitations need to be overcome: poor sensitivity, unidirectional sensing, and loss of ultrasonic functionality due to …

Ultra High-Speed Signaling And Return On Technology Investment (Roti) For The Electrical Interconnects Sector, Azniza Abd Aziz

Theses and Dissertations

Demand for smaller platform sizes with increasing bandwidth has driven crosstalk problems that prevent bus performance to scale with Moore’s Law. Several approaches to reduce crosstalk such as the use of shields, differential links, and equalizers have been rejected due to higher cost and power required to overcome the signal integrity impediments at Gigahertz data rates. Eigen-mode signaling based on modal decomposition techniques is the most recent method to mitigate crosstalk that can potentially satisfy the demand for higher data rates from modern technology industry.

The goal of this research is to allow maximum dense routing between packages on PCBs …

A Lebesgue Sampling Based Diagnosis And Prognosis Methodology With Application To Lithium-Ion Batteries, Wuzhao Yan

Theses and Dissertations

Fault diagnosis and prognosis (FDP) plays an important role in the modern complex industrial systems to maintain their reliability, safety, and availability. Diagnosis aims to monitor the fault state of the component or the system in real-time. Prognosis refers to the generation of long-term predictions that describe the evolution of a fault and the estimation of the remaining useful life (RUL) of a failing component or subsystem.

Traditional Riemann sampling-based FDP (RS-FDP) takes samples and executes algorithms in periodic time intervals and, in most cases, requires significant computational resources. This makes it difficult or even impossible to implement RS-FDP algorithms …

Numerical Analysis Of Phase Change, Heat Transfer And Fluid Flow Within Miniature Heat Pipes, Mehdi Famouri

Theses and Dissertations

Heat pipes with broad applications in thermal systems have the ability to provide effective heat transport with minimal losses in over reasonable distances due to their passive nature. Their exceptional flexibility, simple fabrication, and easy control, not to mention, all without any external pumping power make them especially attractive in electronics cooling. Heat pipe development is motivated to overcome the need to presumably manage thermal dissipation in progressively compressed and higher-density microelectronic components, while preserving the components temperatures to specification.

Computation of flow and heat transfer in a heat pipe is complicated by the strong coupling among the velocity, pressure …

Behavioral Responses Of Sub-Adult Atlantic Sturgeon (Acipenser Oxyrinchus Oxyrinchus) To Electromagnetic And Magnetic Fields Under Laboratory Conditions, Andrew Mcintyre Iii

Theses and Dissertations

Electromagnetic fields (EMF) produced by high voltage (HV), submarine transmission cables leading from offshore wind energy generation facilities could affect foraging or migratory behaviors of electro-receptive fishes, including endangered Atlantic Sturgeon. However, no published studies have quantitatively evaluated the possible behavioral effects of EMF exposure on sturgeon during residence in coastal waters. This study evaluated behavioral responses by sub-adult Atlantic Sturgeon to electromagnetic and magnetic fields under controlled laboratory conditions. Fabricated EMF generators were used to emulate a range of field EMF conditions that migratory fishes could encounter in proximity to submarine HV sources. Sensor arrays and digital video recorders …

Fabrication Of Flexible, Biofunctional Architectures From Silk Proteins, Ramendra K. Pal

Theses and Dissertations

Advances in the biomedical field require functional materials and processes that can lead to devices that are biocompatible, and biodegradable while maintaining high performance and mechanical conformability. In this context, a current shift in focus is towards natural polymers as not only the structural but also functional components of such devices. This poses material-specific functionalization and fabrication related questions in the design and fabrication of such systems. Silk protein biopolymers from the silkworm show tremendous promise in this regard due to intrinsic properties: mechanical performance, optical transparency, biocompatibility, biodegradability, processability, and the ability to entrap and stabilize biomolecules. The unique …

Renewable Carbon From Lignin Biomass And Its Electrode And Catalyst Applications In Batteries, Supercapacitors, And Fuel Cells, Muslum Demir

Theses and Dissertations

Over the last century, almost all of the carbon materials developed for the energy industry are derived from fossil fuels. The growing global concerns about energy needs, fossil fuels consumption, and the related environmental issues have motived scientists to find new, green and sustainable energy resources such as the wind, solar and biomass energy. Essentially, biomass-derived materials can be utilized in energy storage and conversion devices such as Li-ion batteries, fuel cells, and supercapacitors. Among the biomass resources, lignin is a high volume byproduct from the pulp and paper industry and is currently burned to generate electricity and steam. The …

Photoelectrochemical Cell Constructed From Bby Membrane With Various Substrate Materials, Yang Liu

Theses and Dissertations

Photoelectrochemical cells have been intensively studied in recent years with regard to using thylakoid and photosynthesis system I/II. BBY membrane is another protein complex that has potential to be utilized to build photoelectrochemical cells. Within the BBY membrane lies the highly active photosynthesis system II complex, which upon light activation, generates electrons transported within the electron transport chain during photosynthesis in green plants. This study presents an approach of immobilizing thylakoid or BBY membrane onto gold nanoparticle modified gold plate or multi-walled carbon nanotube (MWCNT) modified indium tin oxide vi (ITO) coated glass substrate. The results show that BBY membrane …

Tuning Optimization Software Parameters For Mixed Integer Programming Problems, Toni P. Sorrell

Theses and Dissertations

The tuning of optimization software is of key interest to researchers solving mixed integer programming (MIP) problems. The efficiency of the optimization software can be greatly impacted by the solver’s parameter settings and the structure of the MIP. A designed experiment approach is used to fit a statistical model that would suggest settings of the parameters that provided the largest reduction in the primal integral metric. Tuning exemplars of six and 59 factors (parameters) of optimization software, experimentation takes place on three classes of MIPs: survivable fixed telecommunication network design, a formulation of the support vector machine with the ramp …

Improving The Performance And Time-Predictability Of Gpus, Yijie Huangfu

Theses and Dissertations

Graphic Processing Units (GPUs) are originally mainly designed to accelerate graphic applications. Now the capability of GPUs to accelerate applications that can be parallelized into a massive number of threads makes GPUs the ideal accelerator for boosting the performance of such kind of general-purpose applications. Meanwhile it is also very promising to apply GPUs to embedded and real-time applications as well, where high throughput and intensive computation are also needed.

However, due to the different architecture and programming model of GPUs, how to fully utilize the advanced architectural features of GPUs to boost the performance and how to analyze the …

Investigation Of Polymeric Composites For Controlled Drug Release, Hsi-Wei Yeh

Theses and Dissertations

The Electrospray (ES) technique is a promising particle generation method for drug delivery due to its capabilities of producing monodisperse PLGA composite particles with unique configurations and high drug encapsulation efficiency. In the dissertation work, the coaxial dual capillary ES was used to generate drug-loaded core-shell PLGA particles to study the effects of particle filling materials, drug loading locations and particle shell thicknesses on the resultant in vitro release behaviors of the hydrophilic and/ or hydrophobic model drugs. Through release profile characterization of drug-loaded PLGA particles (particle size: 400 nm and 1 μm), it was confirmed that the co-encapsulation of …

Analysis And Design Of A Highly Compact Ellipse-Shaped Ultra-Wideband Bandpass Filter (Uwb-Bpf) With A Notched Band, Xuetan Liu

Theses and Dissertations

Since the Federal Communications Commission’s endorsement of the frequency band of 3.1 – 10.6 GHz in 2002 to be unlicensed for wireless communication applications, various ultra-wideband bandpass filters (UWB-BPFs) have been proposed and designed. Different UWB-BPF configurations were presented in the past years to meet the very strict UWB-BPF specifications in terms of ultra-band requirement, low return loss, high rejection in notched bands. However, most of the previous works are limited by large dimension size, complex geometry, and high production cost.

The major objective of this work is to design a highly compact, simple geometry, and low-cost UWB-BPF, which passes …

Distributed Optimization Method For Intelligent Control Of Dc Microgrids, Yuanyuan Fan

Theses and Dissertations

Most of the distributed energy resources, loads and energy storage systems in a DC microgrid are equipped with power electronic converters. With the integration of advanced power electronics devices, a microgrid is able to utilize a broader range of technologies in its design and operation. A key feature of power electronic converter based systems is the ability to direct energy flow within a system with their coordinated operation. A system level control is needed for coordination where converters execute reference points dictated by a system-level control in order to achieve system level goals. System goals can be expressed as a …

Nondestructive Evaluation And Health Monitoring Of Adhesively Bonded Composite Structures, William Walker Roth

Theses and Dissertations

As the growth of fiber reinforced composite materials continues in many industries, structural designers will have to look to new methods of joining components. In order to take full advantage of composite materials, such as increased stiffness, decreased weight, tailored material properties and increased fatigue life, mechanical fasteners will need to be replaced by adhesive bonding or welding, when possible. Mechanical fasteners require the drilling of holes, which damages the laminate and becomes the source of further fatigue damage. Also, an increase in laminate thickness or inclusion of other features is required for the material to withstand the bearing stress …

A Comprehensive Evaluation Of Hybrid Wetting Configurations On Dropwise Condensation, Karim Khazal Egab

Theses and Dissertations

The heat transfer during condensation on a surface depends on the pattern design of the surface, which can highly influence hydrophobic/hydrophilic wettability. In this study hybrid pattern designs were studied. The relationship between the droplet dynamic and the hybrid pattern design can alter the drainage rates, droplet departure frequencies, and the condensation heat transfer rates. Therefore, two series of hybrid patterned surfaces have been designed, developed, and tested during condensation of water vapor on horizontal copper tubes, and compared to complete dropwise and complete filmwise condensation samples. This is to investigate the design that provides the maximum improvement in the …

Determination And Validation Of High-Pressure Equilibrium Adsorption Isotherms Via A Volumetric System, Hind Jihad Kadhim Shabbani

Theses and Dissertations

Adsorption equilibrium isotherms for N2, CO2, and CH4 on zeolite 13X were investigated at three different temperatures (25.5, 50.5 and 75.5 ̊ C) and a pressure range of (0-6.89475) MPa for CH4 and N2 and in the range of (0-4.82633) MPa for CO2 using built in volumetric apparatus. The results were validated using with a volumetric system (ASAP) at the same temperatures and a pressure up to (160-110) KPa respectively. The experimental results were correlated using three process Langmuir (TPLM). The correlated isotherms were then used to calculate the isosteric heat of adsorption for the three gases on 13X. The …

Stilbenes: Therapeutic Interventions Targeting Amyloid Β Protein Aggregation In Alzheimer’S Disease, Yiying Wang

Theses and Dissertations

Alzheimer’s disease (AD) is the most common form of dementia and accounts for 60-80 % of all dementia cases. In the United States, AD is ranked as the 6th leading cause of death and it is the only one among the top 10 that cannot be prevented, treated or even slowed. All FDA approved drugs focus on attenuating the symptoms for a limited time by regulating neurotransmitters without any intervention with the underlying disease process. A major player in the initiation and development of this debilitating disorder is the misfolding and subsequent aggregating of amyloid-β (Aβ) peptide. This aggregation process …

Statistical Mechanics Of Lipid-Liquid Crystal Systems: From Fundamentals To Sensing Applications, Donya Ohadi Kabir Maghsudlu

Theses and Dissertations

Understanding the thermodynamics of small systems has a well-established history. The non-intuitive behavior of the intensive properties of small systems comprised of less than a few hundred particles has important implications in many areas of engineering and materials science. Nevertheless, many open questions about the thermophysical properties of systems not in the thermodynamic limit remain unanswered. In the first part of this work, we explore the consequences of the coupling of two small subsystems that together make up a larger isolated system through the use of statistical mechanics and molecular dynamics simulations of Lennard-Jones particles in two dimensions. The results …

Pollutant Formation In Oxy-Coal Combustion, Nujhat Choudhury

Theses and Dissertations

With the increasing levels of carbon dioxide (CO2) in the atmosphere, researchers are driven to seek cleaner combustion techniques to burn coal for power generation. Oxy-coal combustion is a promising technique to cut down CO2 emissions. This technology requires the introduction of a pure oxygen (O2) stream and a recycled flue gas stream into the boiler instead of air. Flue gas stream generated from the system will be low in volume and highly concentrated in CO2. Thus, the capture and sequestration process will be facilitated. But, one of the concerns of adopting this technology is the altered chemistry of pollutants …

Characterization Of Subgrade Resilient Modulus For Mepdg And The Effects On Pavement Rutting, Md Mostaqur Rahman

Theses and Dissertations

In 2008, the American Association of State Highway and Transportation Officials (AASHTO) released a modified pavement design method (i.e., the Mechanistic Empirical Pavement Design Guide (MEPDG)) based on Long Term Pavement Performance (LTPP) data from all over the United States. The MEPDG default design parameters developed from the LTPP database are expected to be significantly different than those for South Carolina material, traffic and weather conditions, thus the default design parameters may not be accurate for South Carolina. Therefore, the new pavement design method should be calibrated for South Carolina conditions by performing MEPDG local calibration.

Different input variables should …

Multi-Axis Multi-Material Fused Filament Fabrication With Continuous Fiber Reinforcement, Wout De Backer

Theses and Dissertations

Additive Manufacturing (AM) has become a well-recognized method of manufacturing and has steadily become more accessible as it allows designers to prototype ideas, products and structures unconceivable with subtractive manufacturing techniques for both consumer grade and industrial grade applications. Commonly used thermoplastics for 3D printing have properties that may not be sufficient to comply with the application’s certification requirements, or their performance is less than desirable for aerospace and other high performance applications. Additionally, additively manufactured parts have reduced mechanical properties in the build direction of the print, and are generally weaker than their equivalent injection-molded parts. Furthermore, Computer Aided …

Integrating Nano-Patterned Ferromagnetic And Ferroelectric Materials For Smart Tunable Microwave Applications, Tengxing Wang

Theses and Dissertations

The wireless communication market has been ever-growing in the recent decades. Radios with high performance and capabilities to support wireless connections are increasingly demanded. Recent developments in wireless communications targeting ubiquitous connections have resulted in ever more complex system structures for supporting multiple frequency bands and standards. Reconfigurable and tunable RF/microwave technologies have the potential to significantly simplify the systems. The main objective of this dissertation is to develop tunable technologies and design concepts, and propose a new design methodology to implement dually electrically tunable microwave components by integrating both selectively patterned ferromagnetic and ferroelectric materials.

The first part of …

Performance Assessment Of Hsrm Concrete Ties Through Finite Element Model Simulations, Adam I. Zeitouni

Theses and Dissertations

Concrete ties have become a promising alternative to timber ties for freight lines with increased curvature, high annual traffic, and large axle loads. They are also widely adopted in passenger lines. High strength (HS) concrete is the material of choice in the fabrication of prestressed concrete railroad ties. The higher strength of the concrete is directly related to higher values of the Elastic Modulus, thus increasing the rigidity of the material. The combination of increased strength, rigidity, and the material brittleness may lead to the development of high amplitude stresses with high gradients, which appears to be a common underlying …