Engineering Commons^™

Consuming Digital Debris In The Plasticene, Stephen R. Parks

Theses and Dissertations

Claims of customization and control by socio-technical industries are altering the role of consumer and producer. These narratives are often misleading attempts to engage consumers with new forms of technology. By addressing capitalist intent, material, and the reproduction limits of 3-D printed objects’, I observe the aspirational promise of becoming a producer of my own belongings through new networks of production. I am interested in gaining a better understanding of the data consumed that perpetuates hyper-consumptive tendencies for new technological apparatuses. My role as a designer focuses on the resolution of not only the surface of the object through 3-D …

Nuclear Rupture In Progeria Expressing Cells, Kranthidhar Bathula

Theses and Dissertations

Cells regularly take on various types of force in the body. They have structures that are able to mediate, transfer and respond to the forces. A mutation in force regulating proteins such as lamin in the nucleus or the KASH domain which connects the nucleus to the cytoskeleton of the cell can cause catastrophic events to occur. The aims of this study were to better understand the response of the nucleus when structural proteins are mutated or are not present while under force. Progeria, a rare disease where an additional farnesyl group is attached to lamin was used in this …

Graphene As A Solid-State Ligand For Palladium Catalyzed Cross-Coupling Reactions, Yuan Yang

Theses and Dissertations

Palladium-catalyzed carbon-carbon cross-coupling reactions have emerged a broadly useful, selective and widely applicable method to synthesize pharmaceutical active ingredients. As currently practiced in the pharmaceutical industry, homogeneous Pd catalysts are typically used in cross-coupling reactions. The rational development of heterogeneous catalysts for cross-coupling reactions is critical for overcoming the major drawbacks of homogeneous catalysis including difficulties in the separation, purification, and quality control process in drug production. In order to apply heterogeneous catalysis to flow reactors that may overcome this limitation, the catalyst must be strongly bound to a support, highly stable with respect to leaching, and highly active. While …

Engineering Surface Properties To Modulate Inflammation And Stem Cell Recruitment Through Macrophage Activation, Kelly M. Hotchkiss

Theses and Dissertations

Biomaterials are becoming the most commonly used therapeutic method for treatment of lost or damaged tissue in the body. Metallic materials are chosen for high strength orthopaedic and dental applications. Titanium (Ti) implants are highly successful in young, healthy patients with the ability to fully integrate to surrounding tissue. However the main population requiring these corrective treatments will not be healthy or young, therefore further research into material modifications have been started to improve outcomes in compromised patients. The body’s immune system will generate a response to any implanted material, and control the final outcome. Among the first and most …

Molecular Dynamics Simulation Of Gas Transport And Adsorption In Ultra-Tight Formations, Yannick Tambe Agbor

Theses and Dissertations

Kerogen, which plays a very important part in reservoir characterization for ultra-tight formations, is also involved in the storage and production of hydrocarbons in shale. In this work, we study the kerogen structure and its interaction with insitu hydrocarbons to fully understand the fluid flow and adsorption mechanisms in the shale. Also the advancement in pore network modelling has greatly helped the understanding of mesoscale fluid flow. In this work, transport of methane in a type II marine environment kerogen model is studied using molecular dynamics simulations. Non Equilibrium Molecular Dynamics Simulations (NEMDS) using GROMACS code and Grand Canonical Monte …

Study Of 4h-Sic And Alxga1-Xn Based Heterojunction Devices For Ultraviolet Detection Applications, Venkata Surya Naga Raju Chava

Theses and Dissertations

Ultraviolet (UV) detectors are important for their applications in flame detection, furnace gas control systems, plume monitoring etc. Due to their wide band-gap, 4H-SiC (Eg=3.26eV) and III-V semiconductors such as GaN (Eg=3.4eV), AlxGa1-xN (Eg=3.4eV to 6.2eV) etc., are excellent candidates for visible(��cut-0ff=400nm) and solar blind(��cut-0ff=290nm) UV detectors. Conventional SiC UV detectors suffer from poor UV responsivities due to reflection/absorption/transmission losses caused by the metal electrodes used in those detectors.

In the first part, a novel bipolar transistor with epitaxial graphene(EG)/p-SiC (30μm)/n+-SiC substrate was fabricated and characterized. The 2-3 ML thick, transparent and conducting, EG used in this work was grown …

The Rational Synthesis Of Bimetallic Catalysts On Oxide Supports, Andrew Phillip Wong

Theses and Dissertations

Catalysts play an important role in many chemical reactions. However, simple impregnated monometallic catalysts are often limited in their function. One way to overcome this limitation is through the incorporation of a secondary metal to the catalysts. These bimetallic catalysts often have synergistic benefits not observed in the monometallic analogues. Here, we focused on the synthesis of bimetallic catalysts using rational methods in order to improve catalyst function; specifically by tuning the particle size, morphology, and composition. The two methods of interests were Strong Electrostatic Adsorption (SEA) and Electroless Deposition (ED). An adaptation of SEA to bimetallic catalysts (coSEA) was …

Monitoring The Progress Of Damage In A Sicf-Sicm Composite Nuclear Fuel Cladding Under Internal Pressure Using Acoustic Emission, Luis H. Alva

Theses and Dissertations

The relation between the progress of damage and the acoustic emission (AE) activity of a nuclear grade Sif-SiCm composite tubing under internal pressure was studied. The nuclear grade Sif-SiCm composite tubing is manufactured by the company General Atomics (GA) and made of nuclear grade HI Nicalon type S fiber preforms following a chemical vapor infiltration (CVI) technique. Sif-SiCm composites are good candidates to replace current nuclear fuel cladding materials because of the good chemical stability and strength at high temperatures. In this work, a Sif-SiCm composite tubing was tested under internal pressure at room temperature (RT) to study the damage …

Multifunction Radio Frequency Composite Structures, David L. Zeppettella

Theses and Dissertations

There has been recent interest in the development of multifunction structures for weight-critical applications. A multifunction structure is a load-bearing structure that also allows one or more additional functions such as RF communication, energy storage, sensing etc. The focus of this dissertation is to analyze, design, develop, and test new high performance (broadband, high gain, circularly polarized) internal antennas that are structural and integral to the aircraft. It is demonstrated that antennas with more bandwidth and higher efficiency could be developed if the space and materials available in an aircraft structure could be judiciously exploited for multifunctional usage. This is …

Combinatorial Study Of Oxidation Catalysts: Uncovering Synthesis-Structure-Activity Relationships, Kathleen B. Mingle

Theses and Dissertations

High throughput experimentation (HTE) in catalysis has proven useful in expediting materials discovery via parallelized synthesis, characterization, and testing of candidate materials. However, even in a high-throughput manner, the combinatorial explosion of relevant parameters far exceeds our ability to study. To further complicate the problem, a large time investment and great deal of characterization is often required to build an in-depth understanding of catalytic materials. It follows that the field of heterogeneous catalysis is rich with examples of catalytic systems that have been developed using trial and error efforts for which a lot is known but context is lacking. Techniques …

Role Of Bed Design Characteristics On The Effective Thermal Conductivity Of A Structured Adsorbent, Pravin Bosco Charles Antony Amalraj

Theses and Dissertations

This work evaluates the role of different design variables on the effective thermal conduction of a structured adsorbent bed for its possible application in a temperature swing adsorption (TSA) process. The structured adsorbent bed is represented by eight parallel layers of intercalated smooth and corrugated foils of a metal support coated with 13X zeolite resulting in the formation of parallel triangular channels. The variables investigated include the thickness of the adsorbent coating, thickness of the metal, nature of contacts between smooth and corrugated foils, type of metal, presence and magnitude of an air gap between the foils, difference in alignment …

High Temperature Compression Creep Of U3si2, Emil Angelo Cahanap Mercado

Theses and Dissertations

As a result of the Fukushima Daiichi Nuclear Disaster in 2011, a push for increasing the safety of nuclear power plants was made through research grants funded through the United States Department of Energy via the Accident Tolerant Fuels (ATF) campaign. One of the focuses of the campaign is improving the accident tolerance of nuclear fuel during a loss of coolant accident.

A promising set of being researched from the ATF is Silicon Carbide (SiC) composite cladding and Uranium Silicide (U3Si2) fuel pellets. Under high temperatures, stresses, and times the creep deformation can play an important factor in pellet to …

The Visual Ecology Of Speyeria Mormonia, Natalie Sanchez Gonzalez

Theses and Dissertations

Variations in environmental factors such as temperature, precipitation, and day length during larval development are known to affect morphological traits in butterflies related to their visual ecology, including eye size and wing color. These vision-related traits are important for the ability of diurnal butterfly species to detect mates, especially at long distances. Thus, changes in environmental conditions may result in phenotypic modifications to butterflies which may alter their visual ecology and subsequently, their reproductive fitness. To study the interaction of phenotypic plasticity and visual ecology in the Mormon Fritillary, Speyeria mormonia, I set up a natural-laboratory experiment at the Rocky …

Screening Of Novel Active Salicylic Acid Analogs And Identification Of A Bacterial Effector Targeting Key Proteins Involved In Salicylic Acid-Mediated Defense, Ian Palmer

Theses and Dissertations

The master regulator of salicylic acid (SA)-mediated plant defense, NPR1 (NONEXPRESSER OF PR GENES 1), and its paralogs NPR3 and NPR4 act as SA receptors. After the perception of a pathogen, plant cells produce SA in the chloroplast. In the presence of SA, NPR1 protein is reduced from oligomers to monomers, and translocated into the nucleus. There, NPR1 binds to TGA and WRKY transcription factors to induce expression of plant defense genes. EDS1 and PBS3 are two key proteins involved in SA biosynthesis. Previous research has shown that several plant pathogens produce SA hydroxylases. These pathogen-produced hydroxylases act to degrade …

Development Of Advanced Mixed Electronic And Carbonate Ion Conducting Membranes And Reactors For Combined Co2 Capture And Conversion, Jie Fang

Theses and Dissertations

Global warming and climate change resulted from CO2 emissions have been increasingly observed to impact our daily life and damage our economy in recent human history. To deal with this grand challenge, carbon capture and storage (CCS) has been established as a key technology to curb CO2 emission from fossil-fueled power plants. The core of the CCS technology is to capture CO2 at emission sources and geologically bury it for permanent storage or enhanced oil recovery (OER). As the first step of CCS, carbon capture technologies are currently being developed for three power-generation related combustion processes that are responsible for …

Nox Formation In Syngas/Air Combustion, Nazli Asgari

Theses and Dissertations

Syngas is a reliable energy source derived from the gasification of coal and other solid fuels. The feedstock type and the production process of syngas can affect the composition of syngas. Gas turbines utilizing high hydrogen content (HHC) fuels like syngas for power generation applications need to meet stringent pollutant emission standards, particularly with respect to nitrogen oxides (NOx). For gas turbine conditions, reliable experimental data, especially at high-pressure, is necessary for both generating accurate NOx prediction models and improving reaction pathways regarding the NOx chemistry. In this study, NOx formation in post-flame gases of syngas combustion at different conditions …

Role Of Mammary Microenvironment In Promoting Left-Right Differences In Tumor Progression, Metastasis, And Therapeutic Response, Huda Issa Atiya

Theses and Dissertations

Metastasis is the main cause of death in breast cancer patients; however, there are currently no treatments available to treat or prevent metastasis. This is in part because regulators of metastasis are not yet fully understood. Over the past century researchers began to study metastasis regulators by different hypotheses, such as the seed and soil hypothesis which focuses on studying the role of cancer cells, the seeds, and the tissue microenvironment, the soil, in regulating metastasis. Although lots of studies have focused on the microenvironment of metastatic sites and their roles in regulating metastasis, limited studies have focused on the …

Effect Of Material Orientation On The Impact Response Of Graded Cellular Materials, Abigail Wohlford

Theses and Dissertations

In this study, the effect of layer stacking on the energy absorption characteristics of density-graded cellular polymers subjected to high velocity impact is investigated experimentally. The focus in the present work is to characterize the constitutive response and deformation mechanisms of these Functionally Graded Foam Materials (FGFM) using full-field measurements. Uniform foam Quasi-static and dynamic testing of uniform foam specimens are completed for each nominal density used in the layered foam samples. The low strain-rate experiments are performed in order to determine the mechanical properties of foam specimens. The high-rate experiments for homogenous foam specimens were completed to further characterize …

A Comprehensive Reengineering Of The Hospital Emergency Triage System, Nicholas D. Boltin

Theses and Dissertations

Hospital emergency triage and specifically Mass Casualty Incidents (MCIs) are of major concern with regard to treatment and patient outcomes. Traditional emergency department triage models are oversimplified and often lead to over/under triaging of patients. Furthermore, triage models do not account for the full spectrum of different types of MCIs which often results in misclassification. In this thesis, we begin by looking at traditional triage models currently being used in hospital systems and identify several shortcomings of using these models within the context of a chemical related MCI. I will then move to describe a new approach to creating a …

Acoustic Emission Detection In 304h Stainless Steel Due To Intergranular Stress Corrosion Cracking, Joseph W. Hill

Theses and Dissertations

Storage of spent nuclear fuel has become problematic in past decades due to delayed completion of long-term repositories for various reasons. Temporary storage containers called Dry Cask Storage Systems (DCSS) made of stainless-steel and surrounded by reinforced concrete have been in use but are exceeding their designed usage periods. Defects in canisters can be exacerbated in climates susceptible to high humidity and salinity levels. As inspection and relicensing of DCSS increases, more efficient monitoring techniques could save nuclear facilities valuable time and resources. Crack detection of the canister walls or welds in real time may be possible utilizing acoustic emission …

Characterization Of Evaporation/Condensation During Pool Boiling And Flow Boiling, Mostafa Mobli

Theses and Dissertations

Present dissertation has investigated pool and flow boiling and their characteristics via numerical means. A code was developed to investigate and enhance heat transfer performance during different modes of phase change phenomena. Multiphase heat transfer has proven to be one of the most effective means of heat transfer in different industries, therefore, there have been numerous experimental and numerical studies on the subject of phase change phenomena in a wide range of conditions and setups; yet there are complex bubble dynamics and heat transfer characteristics that remain unresolved. To have a more detailed look at and a better understanding of …

Acousto-Ultrasonic Shm/Nde Methods Toward Field Application, Stephen Harris Howden

Theses and Dissertations

Acousto-ultrasonic nondestructive evaluation (NDE) and structural health monitoring (SHM) methods offers solutions in damage detection, material properties evaluation and more. These ultrasonic waves can propagate through solids and interact with structural features and discontinuities. In this thesis use of several acousto-ultrasonics NDE/SHM methods were explored to evaluate their sensing and detection capabilities toward damage detection field applications in nuclear and aerospace industries.

For nuclear applications, passive sensing using piezoelectric sensors and acoustic emission (AE) techniques were explored on the spent fuel dry storage casks. Dry storage casks are used in the nuclear industry to transport or store spent nuclear fuel …

High Resolution Radiation Detectors Based On 4h-Sic N-Type Epitaxial Layers And Pixilated Cdznte Single Crystal Devices, Cihan Oner

Theses and Dissertations

Silicon Carbide (SiC) is an indirect wide bandgap semiconductor with high thermal conductivity, high breakdown electric field, high carrier saturation drift velocity, and large displacement energy making it a suitable candidate for replacing conventional radiation detectors based on Si, Ge, CdTe, and CdZnTe (CZT). In this dissertation, fabrication and characterization of high-resolution Schottky barrier detectors for alpha particles using 20 µm thick n-type 4H-SiC epitaxial layers are reported. Schottky barriers were obtained by depositing circular nickel contacts of ~10 mm2 area.

Room temperature current-voltage (I-V) measurements revealed Schottky barrier heights of the order of 1.7 eV, ideality factor of ~1.1, …

Three-Way Catalysts In Passive Selective Catalytic Reduction Systems, Calvin Thomas

Theses and Dissertations

Conventional gasoline-powered engines operate with a stoichiometric air-fuel ratio (AFR), but greater fuel economy is achieved in lean burn engines by increasing the AFR. The primary drawback to these engines is the nitrogen oxide (NOX) emissions, which cannot be reduced over a conventional three-way catalyst (TWC). Passive selective catalytic reduction (SCR) is a promising approach for the control of NOX emissions in lean burn systems. By periodically decreasing the AFR to fuel-rich levels, ammonia (NH3) can be produced over a TWC and stored on a downstream SCR catalyst for the reduction of NOX during normal lean operation. While passive SCR …

Structural Health Monitoring Using Ultrasonic Guided Waves And Piezoelectric Wafer Active Sensors, Faisal Haider Mohammad

Theses and Dissertations

This dissertation is organized in three major parts covering ardent and challenging research topics in structural health monitoring (SHM). Part I focuses on the theoretical and numerical analysis of acoustic emission (AE) guided waves in both Cartesian coordinates (2D) and cylindrical coordinates (3D) system using energy approach, which, to the best of our knowledge, has not been yet reported elsewhere. AE guided waves appear due to sudden energy release during incremental crack propagation in a plate. The Helmholtz decomposition approach is applied to the inhomogeneous elastodynamic Navier-Lame equation for both the displacement field and body forces. For the displacement field, …

Probabilistic Multilevel Constitutive Model Of The Compressive Strength Of Hardened Cement Paste Reinforced With Mwcnts, Yohanna Mejia Cruz

Theses and Dissertations

Constitutive models available in the literature typically describe the compressive strength of ordinary Portland cement paste (OPC) in a deterministic fashion, in some cases as a function of variables such as W/C, porosity, and the clinker chemical composition. The significant effect of the proportion of W/C on the final strength, porosity and density have been reported in several works in material science. Some studies have shown that the addition of MWCNTs can also modify the microstructure of cement significantly, and improve compressive strength and other mechanical and physical properties. In principle, W/C, MWCNTs addition, porosity, density, and compressive strength are …

Meso-Scale Simulation Of Size-Dependent Shear Behavior In Glass Fiber Reinforced Polymer Reinforced Concrete Beams Without Stirrups, Sina Khodaie

Theses and Dissertations

There is extensive experimental evidence of the decrease in the shear stress at failure at increasing effective depths in concrete beams reinforced with glass fiberreinforced polymer (GFRP) bars without shear reinforcement. An important practical implication is that extrapolating strength values from typical laboratory-scaled experiments to design larger members may be misleading. The complexity of the underlying mechanics is reflected in the difficulty of using commercially available numerical tools to accurately estimate shear strength irrespective of beam size. This dissertation presents research on a Lattice Discrete Particle Model (LDPM) based model to simulate the response of scaled slender GFRP reinforced concrete …

Development Of Models And Solution Methods For Different Drayage Applications, Samaneh Shiri

Theses and Dissertations

In the last decades, intermodal freight transport is becoming more attractive in the global supply chains and freight transport policy makings. Intermodal freight transport provides a cost-effective, reliable, and efficient movement of freight by utilizing the strengths of different transport modes. The initial and final segment of intermodal freight transport, performed by truck, is known as “drayage.” The scheduling of truck movements in drayage operation within the service area of an intermodal terminal is an operational problem which leads to a truck scheduling problem that determines the efficient schedule of trucks while satisfying all transportation demands and constraints. Drayage accounts …

System Optimization And Material Development Of Solid Oxide Cells For Energy Conversion And Storage, Libin Lei

Theses and Dissertations

Solid oxide cells (SOCs) can convert chemical energy to electricity in the fuel cell mode and store electricity to chemicals in the electrolysis mode. However, there are still critical barriers, such as energy efficiency and durability, for the development and commercialization of SOCs. The objective of this dissertation is to apply system optimization and materials design to address the critical barriers for solid oxide cells in energy conversion and energy storage applications. One major focus of the dissertation is related to improve energy efficiency, enhance the cell performance and achieve multifunctionality in solid oxide electrolysis cells (SOECs). In addition, development …

Bytecode-Based Multiple Condition Coverage: An Initial Investigation, Srujana Bollina

Theses and Dissertations

Masking occurs when one condition prevents another condition from influencing the output of a Boolean expression. Logic-based adequacy criteria such as Multiple Condition Coverage (MCC) are designed to overcome masking at the within-expression level, but can offer no guarantees about masking in subsequent expressions. As a result, a Boolean expression written as a single complex statement will yield test cases that are more likely to overcome masking than when the expression is written as series of simple statements. Many approaches to automated analysis and test case generation for Java systems operate not on the source code representation of code, but …