Engineering Commons^™

Preparation And Properties Of Novel Dental Adhesives Based Upon Pentaerythritol, Yuan-Yuan Su

Theses

Urethane methacrylates were synthesized from Pentaerythritol, TDI, HEMA and four phenolic blocking agents or from hydroxypropyl methacrylatel TDI and two phenolic blocking agents. All the products were characterized by melting pointy infrared spectroscopy, NMR spectra, and elemental analysis. The bonding of these materials to dentin slices was also investigated. Such materials are supposed to not only react with the organic constituent of dentin but also polymerized with restorative resin. It was found that bond strength was enhanced by the use of the urethane methacrylates, resulting in best mean bonding strengths of 2400 psi.

Preparation And Testing Of Blocked Isocyanate Dental Adhesives, George W. Sweitzer

Theses

Three monomers were used in this study. Two were prepared from 2,4-toluene diisocyanate (TDI),2 hydroxyethyl methacrylate (HEMA), and either o-methoxyphenol, or o-chlorophenol. The third monomer was prepared from pentaerythritol, TDI, HEMA, and p-cresol.

These monomers were bonded to dentin slices, and then combined with an adhesive copolymer consisting of methyl methacrylate and poly(methyl methacrylate). This mixture was polymerized at room temperature by addition of N,N-dimethyl-p-toluidine, and benzoyl peroxide. This adhesive copolymer was applied to monomer coated slices of dentin, and to aluminum coupons already fixed in a jig. The monomer-coated dentin slices (treated with the adhesive copolymer) were then placed …

Digitally Implemented Klapper-Kratt Fm Detector Using The Intel-292o Digital Signal Processor, Chang-Hwan Park

Theses

This thesis describes and analyses a digitally implemented FM detector, which is a new member of the family of FM detectors introduced by Drs. Klapper and Kratt.

The properties of the new detector are low delay, excellent sensitivity, extreme linearity, and compatibility of components with integrated circuit technology.

A working model is implemented by adapting FIR digital s signal processing methods, and is realized using the Single-Chip Digital Signal Processor Intel-2920 which is comprised of micro-processor, scratch-pad data RAMs, program store EPROMs, A/D and D/A conversion circuitry, and I/O circuitry.

The performance of the working model shows very good linearity …

Determining Process Latitude With Electrically Measurable Test Structures, Jonathan Littlehale

Theses

Collection of linewidth data is an important part of photoresist characterization. Linewidth data are usually collected by optical measurements or scanning electron microscopy. Both of these techniques are tedious and time-consuming. In this work, electrically measurable test structures are used to collect linewidth data. These structures use a measured sheet resistance, a known length of conducting material, and the measured resistance of the structure to determine the linewidth. The benefits of using these structures include completely automated data collection and the ability to collect statistically significant amounts of data. This allows the use of existing statistical analysis software to analyze …

Conversion And Kinetics In The Reaction Of Chloroform With Water Vapor At High Temperatures, Chii-Guang Hwang

Theses

This is an experimental study on thermolytic reactions of chloroform with excess water vapor where kinetic parameters are determined and complete product analysis made at atmospheric pressure over a temperature range from 550to 1050°C. In this study, water vapor was introduced as a reactant to convert chlorine in chlorocarbons to stable HCl which is an easily neutralized end-product and thereby completely destroy chloroform. Substantial amounts of thermodynamically stable species: HCl, CO, CO₂, C(s) etc. were observed as products.

The reaction was studied in a 46cm tubular flow reactor mounted in a furnace that had three independently temperature-controlled heating …

Reactions Of Hydrogen With Chloroform And Trichloroethylene At High Temperatures, Burhan Mahmood

Theses

The reactions of chloroform and trichloroethylene with hydrogen in the temperature range 550 to 1000°C were studied using tubular flow reactors of varying diameters. The residence time range was from 0.05 to 3.0 seconds.Two different concentrations of the chlorinated species were used, each with hydrogen in large excess. Flat temperature profiles (+/- 5°C) were achieved over 80 to 85 per cent of the 45 cm long reaction zone, with inlet gases preheated to about 400°C.

No chlorinated hydrocarbons, products or reactants were observed at /above 850°C. The major products at these temperatures were C₂H₂, C_{2 …}

Failure Rates And Leakage Current Increase In Tantalum Capacitors Of Different Manufacturers, Joseph G. Grant

Theses

This study has determined the effect of high humidity and temperature on solid tantalum capacitors, from five different sources.

The reasons for using capacitors from five different prestigious sources is to first determine how the parameters change with the different manufacturing techniques used by the different sources. Secondly to rank the different sources according to reliability. The parameters that were measured before and after the "1000 hour" high temperature and humidity test were, capacitance, leakage current, and equivalent series resistance. All the capacitors showed significant increase in leakage current after the test, but there were wide variations in catastrophic failure …

A Comparison Of Training Available To Entry Level Naval And Merchant Marine Engineroom Personnel, Paul J. Bugelski

Theses

Similarities between occupations or industrial environments are often overshadowed by differences between goals, services, or products. From the time that shipboard steam propulsion became a practicality the Naval and merchant marine services have experienced this phenomena. For various reasons, the two sectors have ignored similarities between their respective occupational sub-groups, e.g. engineroom crews, and the training which facilitates each group's performance.

Manning and training problems, related to the evolution of automated shipboard propulsion plants, have been shared by the U.S. Navy and commercial ship operators. Recent events such as the British Falkland Islands crisis and the implementation of the U.S. …

A Cogeneration Industrial Park In An Urban Environment In The Year 2000, Raymond T. Scott

Theses

An investigation into the feasibilty of placing an industrial park in an urban environment in the year 2000 was made. A selected cogeneration facility located within the park would supply electricity and process steam to the industries with minimal transmission costs and environmental effects. A projection was made on the industries that would exhibit growth to the end of this century, and yet be environmentally benign in nature. These industries would be placed within the industrial park. The selection of the cogeneration facility was based upon projections of fuel availability, environmental factors and available technologies. Socio-economic factors and the effects …

A Maintenance Program Guide For The Non-Technical Building Manager, Luis M. Tavares

Theses

For the most part, the title of Building Manager is conferred upon an individual who is given the responsibility of services support for a facility. However, this title many times is carried by men/women who are responsible not only for the upkeep of the general building, janitorial, and food services but also for the safekeeping of the building equipment, such as mechanical and electrical machinery. At times, these individuals may be involved with general service responsibilities and tend to lose sight of maintenance needs.

In order for the Building Manager to implement maintenance successfully, he/she must understand the close cooperative …

Comparative Study Of Computational Methods For Kinematics Of Mechanism Analysis, Ren-Jea Wang

Theses

This thesis introduces three numerical methods of solving nonlinear algebraic equations, i.e. Newton's method, Brown's method, and Brent's method, and applies these methods to kinematics of mechanism problems for comparative study.

Firstly, each method is reviewed in some detail. Then experimental computer programs, NABKAP(Nonlinear Algebraic equations Based Kinematic Analysis Programs), are developed based on the above methods and used to solve kinematic of mechanism problems. Example problems include various kinds of four-bar mechanisms and two degree of freedom mechanism. Lastly, each technique is compared with the others based on the above computational experiences.

The FORTRAN programs used for this study …

A Global Resource Allocation Model For An Electrical Utility, Pantelis G. Tinios

Theses

The management of the electric utility company, as the management of any other company, has to make important decisions which will have a direct impact on the company's future operations.

In this study, a global model was devised which enables the management to make more intelligent decisions related to the company's planning process.

The company's goals and subgoals are formulated, in a systematic way, into the mathematical model along with operational and financial constraints. Productivity growth, steady labor force, fuel availability, cash flow requirements, share rating, and coverage were some of the goals to be achieved. The goal programming technique …

Simulation Of The Manufacturing System : A General Discussion, Di-Cheing Chien

Theses

This thesis treats the problem of multi-variable sensitivity analysis in a production system which may be used in investigating a variety of characteristics of a flow production system which involve idle time, cost, production rate, ect. are the subjects of the analysis.

The analysis procedure follows the rule of INPUT/OUTPUT through a production process. A simple system model using elements such as : raw material, transfer tool, labor, machine and energy/ or electrical power, is used to lead into the construction of dependent-variable system. A utilization is made of industrial robots as well as humans in loading and unloading machines …

On Circular Hvac Duct Design Through Stress Analysis, Chien-Chung Lee

Theses

In this thesis, comprehensive studies through stress analysis of the circular HVAC ducts are made. The ducts are made of thin gaged steel sheet, and reinforced by stiffeners that are made of hot-rolled steel sections of L or C shapes. The ducts are loaded with pressure, its own weight and the possible seismic accelerations. A comprehensive FORTRAN program is developed as an aid Lo achieving the optimum design of circular ducts, i.e. duct thickness, stiffener spacing, stiffener size and seismic span length, Several stress analysis tables and a design parameter plot arc, provided in this thesis Lo facilitate design optimization.

A Diagnostic Study Of Burning Black Powder Via Stroboscopic Laser Schlieren Photography, Donald Bruce Rowland

Theses

The combustion processes and products of a single grain of burning black powder were experimentally investigated via the stroboscopic laser schlieren photographic technique. A high power modulated argon laser system was used in conjunction with a streak camera to provide a dynamic sequence of time resolved, high resolution schlieren photographs of a burning black powder grain. When black powder burns, a multi-phase product is produced consisting of hot gases, solid particles, and a molten liquid spray. The expansion processes of this multi-phase product cloud were recorded and characterized. Molten drops, reactive and nonreactive particles within as well as outside of …

Keeping Up With Technological Change, Karlis V. Kopans

Theses

Advances in technology over the past fifty (50) years have changed virtually everything that touches our lives today to some degree. However, in the last five years or so, these innovations have been combined into products and systems which have visibly begun to change society as we have known it in the past.

Only in recent years, have the affects of technological change or innovation on society begun to be examined. While a fair amount of literature has been published to date on specific areas of technological change, few publications have been produced which provide a general overview of the …

A Comparison Of The Biodegradation Of Phenol And O-Chlorophenol Using A Municipal Mixed Liquor And Three Commercial Microbial Preparations, Nigel P. Mcmullen

Theses

The biodegradation of phenol and O-chlorophenol was studied in six-liter batch reactors, using a municipal mixed liquor (from the Livingston, NJ treatment plant) that had not previously been exposed to either of the substrates. In addition, three commercial microbial preparations: BI-CHEM (Sybron), Hydrobac (Polybac), and LLMO (General Environmental Science), were tested alone and in combination with the municipal mixed liquor.

It was found that the municipal mixed liquor performed significantly better than any of the commercial preparations by themselves. When the commercial preparations were mixed with the municipal mixed liquor in a ratio of 1:10 it was found that the …

Development Of Dynamic Testing Machine For Laboratory Modeling Of The Rock Fracturing Phenomenon, Mohammad Ali Moghaddass Zadeh Kermani

Theses

The purpose of this thesis is to develop a dynamic testing machine for laboratory modeling of the rock fracturing phenomenon. Bearing stratum fracturing is a construction difficulty which occurs when end-bearing piles are driven to weak rock or weathered sound rock. It is a pile group effect and can result in significantly less pile carrying capacity than the final driving resistance would normally indicate.

A linear scaling factor was derived to establish similitude between the laboratory apparatus and field conditions. This scaling factor is approximate and was used for overall sizing of the apparatus and its components. A more exact …

Stress In The Alveolar Bone Surrounding A Dental Implant, Jagmohan Singh Kohli

Theses

The purpose of this study is to find the stresses developed in mandibular bone due to the occlusal loading of oral endosseous blade implants. Previous work done in this area was based on the theory of "Beam on Elastic Foundation". As the width/length ratio employed is approximately 0.65, the theory of "Plate on Elastic Foundation" used in this thesis is more appropriate. The mandibular bone acts as the foundation supporting the endosseous implants.

The analysis is complicated by the fact that the implants are irregular plates of varying thickness, the foundation modulus is a variable and the occlusal loading is …

An Experimental Investigation Of The Kinetics And Thermal Properties Of Poly(Ethylene) Terephthalate And Its Related Di-Acid Modified Copolymers, Satish Baliga

Theses

Poly(ethylene) Terephthalate , PET, is synthesized from purified Bis-hydroxyethyl Terephthalate,(BHET), in the presence of antimony oxide catalyst. Rate constant for the polycondensation reaction, based on a second order kinetic model is found to be 152.4/mol/hr.

A new modified polyester Polyethylene Adipic Terephthalate (PEAT) is synthesized from BHET and adipic acid. The effect of adipic acid content in the copolymer,on the rate of polycondensation is studied. Adipic acid is shown to improve the activity of the polymer chain ends thereby increasing the apparent reaction rate constants.

The modified polyesters are observed to melt at a lower temperature than PET. Moreover, the …

The Biodegradation Of Phenol And O-Chlorophenol Using Activated Sludge Bacteria, Jeffery Colish

Theses

The biological degradation of phenol up to 500 ppm and 0-chlorophenol up to 40 ppm was studied in an aerated 4.0 liter hatch reactor using activated sludge bacteria from the Livingston, N.J. wastewater treatment plant. From the concentration versus time data, kinetic rate constants were determined for phenol (@ 100 ppm) and o-chlorophenol (@ 20 ppm and 40 ppm). Air stripping was determined to be an insignificant removal mechanism for the compounds studied.

It was noted that the acclimation times decreased with repeated exposure to a particular concentration of phenol or o-chlorophenol, and that the activated sludge bacteria first had …

Synthesis Of Trimethylpropane-Tolylene-2,4-Diisocyanate Adduct And Its Blocked Monomers, Farhad Forohar

Theses

A trimethylolpropane adduct of tolylene-2,4-diisocyanate (TMP-TDI) was prepared by reaction in a heterogeneous solvent system. The isocyanate functional groups of the TMP-TDI adduct were blocked with the following blocking agents: p-cresol, eugenol, o-chlorophenol, and one to one mole ratio of mixtures of 2-hydroxyethyl methacrylate (HEMA) and each of the three preceding blocking agents. A sample of TMP-TDI adduct blocked with only HEMA was also prepared. The products were characterized by melting point, infrared spectroscopy, and elemental analysis. Monomers of TMP-TDI blocked with 50% HEMA and 50% blocking agents may be very useful as dental restorative materials.

Microbial Characteristics Of An Activated Sludge And Three Commercial Preparations After Exposure To Phenolics, Laurie Gneiding

Theses

The biological characteristics of four microbial mixtures were examined after successive exposure to phenol and 2-chlorophenol at room temperature. One of the microbial mixtures was an activated sludge from the Livingston, NJ municipal wastewater treatment plant. The other three mixtures were commercial preparations sold by Polybac Corp.(Hydrobac), Sybron Corp. (BI-CHEM DC 1006/1007), and General Environmental Sciences(LLMO).

The characteristics examined were relative counts and species of gram negative/gram positive bacteria, yeast and fungi, protozoa, and higher organisms. For the gram negative bacteria and yeasts, culturing techniques and diagnostic tubes were used to determine the predominant species. Biochemical tests were done on …

Homogenous Reaction Kinetics Of Reduction Of Sulfur Dioxide, Satyanarayana Manthani

Theses

Homogeneous reduction of sulfur dioxide by carbon monoxide was investigated in the temperature range between 700 and 1000°C, initial sulfur dioxide concentration of about 3000 ppm, typical of a flue gas from coal fired power plants, and excess carbon monoxide concentration, in a 12 mm O.D. quartz tubular reactor. Over ninty percent reduction of sulfur dioxide was obtained at temperatures above 900°C and space times of the order of about 3.5 seconds. Substantial carbonyl sulfide was also produced.

A Comparison Of The Biodegradation Of Nitrobenzene, 1-Butanol, And 2,4-Dichlorphenoxyacetic Acid Using A Municipal Mixed Liquor And Three Commercial Bacterial Preparations, Salvatore P. Salerno

Theses

The biological degradation of nitrobenzene, 1-butanol, and 2,4-dichlorophenoxyacetic acid (2,4-D) was studied in aerated 6 liter batch reactors using activated sludge from the Livingston, NJ wastewater treatment plant-- by itself and in a 10:1 by volume mixture with each of three commercial bacterial preparations: Hydrobac, BI-CHEM DC-1006/7, and Liquid Live Microorganisms (LLMO). Air stripping and adsorption were determined to be insignificant removal mechanisms for the three compounds studied. None of the bacterial mixtures were able to degrade 10 ppm nitrobenzene to any significant extent. A small but noticeable improvement in degradation rates occurred when the Livingston sludge was mixed with …

X-Ray Fluorescence Spectroscopic Analysis Of Coal Ash, George Patrick Watson

Theses

Several coal ashes and prepared mixtures were analyzed by x-ray fluorescence spectroscopy. Various techniques were studied to determine the most reliable procedure for quantitatively estimating, from fluorescent peak intensities, the concentrations of seven major oxides typically present in the ash. These ashes were analyzed with only minimal sample preparation. In order to determine the self-consistency of the procedure, several mixtures of known composition were prepared containing the major elements present in an ash.

Because of inter-element absorption and enhancement effects, several computational techniques were used to calculate composition from spectrum peak intensities. The method that yielded the most accurate estimates …

Management Concept For Consumer Services Via Microprocessor Systems, Thomas William Bradshaw

Theses

With the proliferation of home computers and the subsequent ability to communicate with retail establishments, an opportunity exists for alternative delivery of goods and products to residential consumers. This paper explores the establishment, management, and problems associated with these burgeoning enterprizes.

Presently, there are several technologies and market strategies under devlopment which stress the convenience of making purchases. In addition to home computers there are other communication networks using different protocols such as videotext which consists of several arrangements of text and graphical protocols. In addition there are several mediums like cable and videotext by which product information can be …

Correlation Of Dissolved Oxygen With Flowrate And Water Temperature In The Passaic River Basin, Shan-Pei Fanchiang

Theses

Passaic River water is utilized by a number of major water purveyors in New Jersey. They are the North Jersey Water Supply District Commission, the city of Jersey City, the city of Newark, the Commonwealth Water Company, and the Passaic Valley Water Commission (i.e. PVWC).

Since all are interrelated in that the demands and releases of each affect the other, there is an interest in insuring sufficient water to maintain adequate water quality for the last user on the line (i.e. PVWC) who draws water close to Little Falls.

Having daily data of flowrate, water temperature and dissolved oxygen in …

Prefeasibility Study Of Flexible Manufacturing System, Patrice Gerault

Theses

Most major companies over the world are or intend to go into Flexible Manufacturing System. But, FMS is not as easy to implement as most cf the other equipments. It affects the whole company and careful studies must be done before parchasing it.

After a description of this new system, this paper reviews the effects introduced by FMS and the alements of savings or surcosts in comparison to conventional systems ; but no numerical evaluations are stated.

This paper gives a frame to any company which wants to undertake a prefeasibility study.

Modeling And Analysis Of Switching Dc-To-Dc Converters, Suresh Hariharan

Theses

Modeling and analysis of switching dc-to-dc converters has been achieved through several techniques. The state space averaging technique is valid only for disturbances which are less than one-tenth the switching frequency. The discrete technique does not yield accurate results. In this thesis a new approach to the stability analysis of switching regulators has been discussed and the model is far more accurate than the state space averaging technique or the discrete technique. It can be easily programmed into any computer and the results compare well with the experimental results. It also gives a good insight into the design of the …