Engineering Commons^™

Application Of Computer Techniques In Groundwater Contamination Studies, Komratchi Raman

Theses

A study has been undertaken to provide insight into two related aspects of groundwater contamination studies - contaminant transport behavior and its analysis by modeling techniques. The study reviews recent research that explains some of the uncertainties in the transport and fate of chemical contaminants in groundwater. Approaches to modeling techniques and data reduction are developed to illustrate their usefulness in analysing existing groundwater data, and to make predictions on the future water chemical characteristics. Three types of study areas have been chosen for this purpose, each representing a different type of groundwater contamination problem. The first study area has …

Separation And Characterization Of Biologically Significant Chemical Classes In Airborne Particulate Organic Matter : Measurement Of Selected Chemical Classes In Freshly Collected Air Samples, Xueying Sun

Theses

Since hazardous materials present in airborne pollutants can affect human health and environmental quality and most of the specific compounds remain uncharacterized, a study was conducted to characterize airborne particulate extractable organic matter (EOM) with respect to chemical composition. Specifically, a number of chemical classes including N-heterocycles, phenols, quinones, carboxylic acids, and especially N-nitrosamines were tested using an integrated chemical class screening system.

The inhalable particulate matter was collected, using a high volume 10 um inlet sampler, on the roof of Tiernan Hall, New Jersey Institute of Technology, which is located off Warren Street in Newark. Sequential solvent extractions yielded …

Robotization For Assembling Small Parts, Frank J. Valese

Theses

The thrust of this paper is directed toward establishing a roboticized small parts assembly line where none currently exist. Technical and pragmatic requisites were established and reviewed prior to installing the proposed robotic workcell. Although the specific model chosen for discussion is the locksmithing industry, the procedures followed, the design tools utilized, and the methods of job-costing employed apply equally to other small parts industries.

Basic industrywide considerations reviewed for each robotization effort included:

1. Choosing the proper application for robotization
2. Obtaining management support and labor input to insure the success of the project
3. Deciding on the economic and production goals …

Testing Of Ultrasonic Bonding In Microcircuits, Ioannis Andrea Phiniotis

Theses

A model for the ultrasonic bond as used in making microcircuit interconnections was studied. This model was based on Bowden & Tabor's dry friction theory and Mindlin's analysis of Hertz's model for elastic deformation under compressive and shear stresses. To develop a well-controlled bonding system, the critical bonding machine parameters were determined, and a high-frequency capacitor microphone was fitted to the bonding machine to monitor the tool tip oscillation. Application of these techniques made it possible to control the parameters of the machine to ±5%. Flip-chip bond studies were made using this machine. The data obtained were consistent with the …

Approaches To The Synthesis Of Dentin Bonding Agents Containing Vinyl And Carbamate Functional Groups, Steven W. Amato

Theses

The synthesis of four new monomers containing vinyl and carbamate functional groups was attempted. The desired products were N-m-methacryloxyphenyl-O-phenyl carbamate, N-p-methacryloxy-O-phenyl carbamate, m-N-phenylcarbamato-2-methacryloxyethoxy benzoate, and p-N-phenylcarbamato-2-methacryloxyethoxy benzoate. The carbamate functional group was derived by the Lewis Acid catalyzed reaction of meta-aminophenol, para-aminophenol, meta-aminobenzoic acid, and para-aminobenzoic acid with diphenyl carbonate. The vinyl function was derived, in the case of the aminophenols, by reaction with methacrylyl chloride, and in the case of the aminobenzoic acids, with 2-hydroxyethyl methacrylate.

Partial products only were prepared, these being the two carbamate functional phenols, the two carbamate functional benzoic acids, the two methacryloxy functional derivatives …

Reactions Of Atomic Hydrogen With Dichloromethane In A Flow System, Shun-Hsien Huang

Theses

The reaction kinetics of atomic hydrogen with dichloromethane were studied in a tubular flow reactor with 2.6 cm I.D. Pyrex tube at pressure of 2.1 to 2.7 torr absolute and room temperature . Hydrogen atoms were generated by a microwave discharge plasma. Atomic hydrogen concentration were measured by chemiluminescence titration with nitrogen dioxide. The concentrations of hydrogen atom ranged from 2.0 * 10¹⁴ to 5.0 * 10¹⁵ atoms per cm³. Chlorocarbon reagent and products were monitored by online gas chromatography (FID).

Major products observed were hydrogen chloride and methane. The conversion of dichloromethane increases first to …

Reaction Of Hydrogen With Methylene Chloride And Carbon Tetrachloride At High Temperature, Hun Tsao

Theses

The reactions of methylene chloride and carbon tetrachloride in hydrogen in the temperature range 500 - 1000° C were studied using tubular flow reactors of three diameters. (ID: 0.40, 1.05, 1.60 cm). Residence time range was from 0.3 to 3.5 seconds. Temperature profiles of the reactors was kept within +/- 5° C of central 85% for the 18 inch long reactor, at a total pressure of 1 atmosphere. No chlorinated hydrocarbon products were observed at or above 950° C. The major products in this temperature range were CH4, C2H₂, C2H₄, C2H₆ and HCl.

The pseudo …

Degradation Of Aniline And Nitrobenzene In A Photoreactor, Michael Joseph Sowa

Theses

Degradation of aniline and nitrobenzene in aqueuous solutions was studied. Five reaction processes were utilized, including ultraviolet light, ozone, O₂/UV, O₃/O₂/UV, and H₂O₂/UV. A 30 liter semi-batch gas sparged reactor was used for the development of reaction rate and mass transfer parameters in these systems. The results were used to model a continuous stirred tank reactor (CSTR) for the O₃/O₂/UV case. Reasonable agreement was obtained for steady state exit concentrations between the experimental data and those predicted from the model.

Development Of An Off-Line Robot Programming System For Computer Control Of Ge P50 Robot, Subhas Vitthal Shetty

Theses

The General Electric P50 Robot has Teach Pendent Programming facilities. It is provided with a Computer Linkage - a communication control unit, but is not eguipped with any software which uses this linkage to communicate data between the computer and the P50.

A study was made of many Robot Programming systems existing today. The facilities a programming language should have was noted, and a Robot-Level Programming System was developed, which remote controls the P50 robot.

The program is written in TurboPascal and is developed on IBM PC/AT for communication between the P50 and an IBM PC Compatible Personal Computer. The …

Evaluation Of Word Processing Cost Effectiveness, Nicholas E. Tedesco

Theses

The objective of this thesis is to examine the use of word processing technology to determine if its implementation is a cost effective investment. This will be accomplished by comparing the cost of a typewritten page before and after the implementation or upgrade of word processing equipment. The degree of utilization and the impact of utilization on standard costs will also be examined.

Significant difficulty was encountered attempting to locate and compile statistical information on word processing. Therefore, a questionnaire was developed and distributed to the 100 largest public and 100 largest private companies headquartered in New Jersey, requesting information …

Application Of Robots In Developing Countries, Badi Uddin

Theses

The increasing versatility of robots has led to their use in a widening range of applications. The robot population is growing at a remarkable pace. The increase in the use of robots in industry has changed the standards of productivity and quality. During past years, as labor costs has risen, safety and environmental regulations have been changed to provide more benefits to workers and capabilities of robots became more sophisticated. Therefore, robots became a valuable piece of production equipment.

Now, robots are able to perform all kinds of hazardous and heavy duty jobs which are harmful to human life or …

A Theoretical Investigation Of The Possibility Of Coexistence Of Three Microbial Populations Competing Purely And Simply In Configurations Of Three Interconnected Chemostats, Shiuan-Wu Chang

Theses

It is known from the literature that out of any number of microbial populations competing purely and simply in an environment which is homogeneous and has time invariant inputs (e.g. in an ideal chemostat) only one population can survive in a steady state under any conditions. However it has been proven possible for two competitors to coexist in two interconnected chemostats, which indicates that spatial heterogeneities may lead to coexistence of pure and simple competitors. The present study investigates whether the spatial heterogeneities created by three interconnected bioreactors may lead to a mixed culture (i.e. coexistence) of three pure and …

A Dsp Toolkit For The Unix/C Environment Of The Pc 7300 Compute, Suwutchai Jesdanun

Theses

The Digital Signal Processing (DSP) TOOLKIT is a package of programs designed to use the fast Fourier transform (FFT) and display its output responses in graphics form. This tool provides three different window functions and five data modifiers for filter designing and spectrum analysis. Flexible features for modifying the plottings, such as y-axis auto-scaling, xy-axis scaling and center line adjusting of the graphics display, are included.

All programs are written in C programming language for the UNIX System Environment of the UNIX PC 7300 computer. The program structure of DSP TOOLKIT is designed so that modules can be added or …

Implementation Of Inverse Multiprofile Streak Technique, Brian Edward Fuchs

Theses

The inverse multiprofile streak technique is a new measurement technique available to researchers and was implemented to better achieve measurements on detonation phenomena. This technique provides the wave front geometry around the perimeter of an explosive charge through the use of multiple slits placed on the charge and a high speed streak camera. Testing, analysis, and methodology for this technique are presented in order to provide information to interested researchers. A personal computer program and sample tests are included to illustrate the method used.

Post-Cracking And Nonlinear Microcomputer Analysis In Reinforced Concrete Beams, Pedro Ricardo Munoz Arias

Theses

The main objective of this Thesis work is to study a non-linear behavior of reinforced concrete structures using the Finite Element Method and an incremental load strategy.

Bond between steel and concrete is simulated using linkage spring elements. The proposed model has a generalized crack propagation capability and it accounts for nonlinearities due to cracking and material properties.

Load-displacement relationships describing the aggregate interlock along the crack and the dowel action at the level of reinforcement are incorporated into a computer program.

A simply supported reinforced concrete beam is analyzed from zero load until failure. Contributions to the shear capacity …

Computered-Aided Digital Filter Design And Simulatio, Pao-Tsan Chiang

Theses

The simulation is written by C language on AT&T Unix pc 7300 environment, some fundamental mathematics is introduced in the beginning, then digital filter specification method: window, frequency sampling, equiripple are discussed, and Kaiser window method is discussed in details for programming.

There are many problems are met in my simulation, such as F.F.T. aliasing, leakage, Picket fence convolution, correlation, but solutions are proposed.

The result could be output data and graph, GSS_Drivers graph package is utilized, because consideration of operation speed and convenience are emphasized, speed is compromised, but easy to be restructured.

Thermal Decomposition Of Dichlorobenzene In An Atmosphere Of Hydrogen And Helium, Mingta Hung

Theses

Reactions of dilute mixtures of dichlorobenzene in hydrogen and in helium were studied in a tubular reactor at a pressure of 1 atm, residence times of 0.04 to 2.7 seconds, and temperature range of 825 to 1000° C. Product distributions at various reaction conditions are measured with a flame ionization detector gas chromatograph, and qualitative analysis of batch samples was also performed by GC/Mass Spectrometry. The major products were observed as the thermodynamically stable species, HC1, Cis), benzene and chlorobenzene. Thermal reaction in helium at 1 second residence time in 1.05 cm ID reactor yielded less benzene and chlorobenzene when …

A Prognostication Of Just-In-Time Efficacy In American Manufacturing, Mark L. Kahan

Theses

"Just-in-time" is a Japanese philosophy of business management which has as its ideal the complete elimination of waste in the process of adding value to a product. Some experts have contended that its basis is not cultural, but technical, and is thus applicable to American manufacturing concerns. After an initial exploration of economics and productivity concepts, and of U.S. logistics, inventory, and purchasing practices, the matter of Just-in-time will be addressed, both theoretically and in terms of Japanese business and labor relationships and culture. Then, based upon a case study consisting of observations made at a traditional American manufacturer, this …

The Non-Contacting Surface Area Assessment Of Burn Wounds Using Computer Imaging Methods, Sarmishtha Meeta Rath

Theses

The need for a reliable and accurate method for assessing the surface area of burn wounds currently exists in the branch of medicine involved with burn care and treatment. The percentage of the body affected by burns, measured by the percent total burn surface area, is of critical importance in evaluating fluid replacement amounts and nutritional support during the first 24 hours of postburn therapy. A simple technique has been developed which facilitates the measurement of burned areas non-invasively. Directly measuring burn surfaces yields quantitative results which can be used in assessing the extent of burns, monitoring the healing progression …

A Mathematical Model Of Photopolymerization In A Batch Reactor, Jyh-Yao Li

Theses

A mathematical model of a photo initiated additionpolymerization in a batch reactor was developed.

The model considered initiation, propagation and, termination to simulate the addition polymerization process, The model has the advantage that the concentration of any particular n-mer may be calculated without calculating all of its precursors. Other methods do not have this property. An analytical solution to the model for the photopolymerization of styrene was solved. The calculations were run on a VAX 8800 computer and the results were then compared with the experimental results. The calculated results fitted the experimental results to some extent. Effects from the …

Non-Linear Finite Element Of Analysis Of Reinforced Concrete Members, Chellathurai Jeyamohan

Theses

A finite element analysis of reinforced concrete members is used to study the initiation and propagation of cracks and the behavior at the interface of concrete and steel. The increase of concrete strength due to the biaxial compression and the shear capacity of the cracked elements are also considered in the analysis.

The results of the present analysis are compared with some available experimental data in beam tests. It has been found that the present analysis is capable of calculating the stress ( or moment ) and strain ( or deformation ) from zero load upto the ultimate load.

Time Series Analysis Of Respiration Component In Heart Rate Variability, Anuradha Ramaswamy Iyengar

Theses

Time series signal processing techniques (Fourier based) were applied to analyze the relationship between heart rate and respiration. This analysis takes advantage of the different timing charecteristics of the autonomic nervous system inputs to analyze their influence on the heart rate.

Data from three experiments were analyzed. The first set of data was from helicopter pilots of the US Army. They injected atropine into themselves on certain days. The effect of atropine on the heart rate spectrum and the relationship between heart rate and respiration was studied. It was found that atropine abolishes the respiration peak in the heart rate …

Analysis Of Nitrated Polycyclic Hydrocarbons, Pah-Quinones And Related Compounds In Ambient Air, Yalan Wang

Theses

Studies were conducted to characterized airborne particulate extractable organic matter (EOM) with respect to chemical composition and biological activity. It has been well established that the nitrated polycyclic hydrocarbons (nitroPAH) are environmental contaminants. To identify nitro-PAH in ambient air sample, a technique was developed involving introduction of a reducer column into an reversephase high performance liquid chromatography (HPLC) system. Strong fluorescence signals were achieved from nitro-PAH and detected together with u.v. signals for the qualitative and quantitative analysis of nitro-PAH. 2-Nitrotriptycene was synthesized according to published procedures and used as an internal standard. By use of the above technique, 9nitroanthracene, …

An Investigation Of Electrical And Optical Properties Of Sputtered Amorphous Silicon Nitride And Germanium Thin Films, Rajendra S. Khandelwal

Theses

Low temperature preparation of thin amorphous Silicon Nitride and Germanium Films by direct RF sputter deposition was investigated. Influence of various sputtering parameters on film properties was studied. Infrared transmission spectrophotometry was used to evaluate optical properties of the films whereas electrical characteristics of the films were determined from current-voltage measurements of MIS structures. For Silicon Nitride films it was observed that the stoichiometry, as indicated by the IR transmission, dielectric constant and current density versus square root of electric field measurements, was a strong function of the sputtering gas composition and particularly the Ar/N ratio in the sputtering gas. …

Properties Of Sputtered A-Ge And A-Ge : H Thin Films, Hanjin Cho

Theses

The effect of the amorphous and glassy structure of amorphous germanium films on their electrical characteristics was investigated experimentally. The films were deposited onto silicon substrates using a modified MRC 8800 triode sputtering system. The Poole-Frenkel and Schottky mechanisms are discussed in detail and the shortcomings of the accepted picture of the former in amorphous materials are dealt with. It was concluded on the basis available evidence that the current flow in amorphous germanium favors the Poole-Frenkel mechanism at high fields.

Amorphous hydrogenated germanium films which were deposited by bias sputtering were characterized by measuring the infrared absorption. The films …

Process Hazard Review For Drug Development, Rudolph R. Schwarz

Theses

The development of drugs has become increasingly complex, requiring the use of a wide variety of pharmaceutical actives and isolated intermediates, a majority of which are not always completely characterized with respect to their hazard potential. This can present a source of potential exposure to those who handle these substances during initial drug development, manufacturing of the drug active and ultimately the finished pharamaceutical product. It is, therefore, essential that safety and health information be documented and communicated during the entire drug development process.

The need for application of process hazard review techniques to the development of new drug materials …

Construction Labor And Productivity : Productivity Improvements, Stavros C. Nicolaou

Theses

Construction productivity has been on the decline in the last decade. Although an important factor in the nation's economy, productivity of construction labor has been given little attention over the years. A review of the literature dealing with construction was performed that revealed the importance of the declining productivity as well as the confusion among construction managers and labor leaders as to what productivity is all about and how it can be improved. It has been found also, that construction labor motivation, which is the most important factor in improving productivity, is almost nonexist. Very few construction companies employ any …

Studies Directed Toward Beta-Cyclodextrin And Capped Beta-Cyclodextrin Mimics Of Alpha-Chymotrypsin, Preston Marlon Canzius

Theses

Molecular mechanics calculations were used to investigate beta-cyclodextrin and capped beta-cyclodextrin as models for the active site of alpha-chymotrypsin. The Amber molecular mechanics force field was used to investigate the effect that addition of the caps has on the conformation of the beta-cyclodextrin macrocycle.

The RMS module of Amber was used to calculate differences in position between the atoms of the minimized mimics and those of the X-ray crystal structure. The deviation in position of the atoms of the minimized capped beta-cyclodextrin macrocycle was found to be larger than that of the minimized beta-cyclodextrin, indicating that the caps do affect …

Hydrodechlorination Reactions On Silica-Supported Rhodium Catalysts, Yung-Ming Chen

Theses

The objectives of this study were to investigate the pathways of the hydrodechlorination reactions over silica-supported Rh catalysts as well as identify selectivities and deactivation properties.

Reaction of 1,2-dichloroethane with hydrogen over Rh/SiO₂ catalyst was studied in the temperature range 200 to 300°C. Formation of two intermediates was proposed while 1,2-dichloroethane was adsorbed on the catalyst, the reactive intermediates then produce ethane, ethylene, chloroethane and methane. From the methane formation, it was inferred that the ethane hydrogenolysis occured over the Rh/SiO₂ catalysts. Higher conversion to C₁ and C₂ hydrocarbons was observed at higher reaction temperature. The …

Separation Of Chromium From Waste Sludges By An Electric Membrane Process, Freeman Nai-Tchun Ho

Theses

The process is characterized by using metallic membrane as a filter which is charged by a separate DC-power supply and it may become experimentally very effective in increasing the separation potency and migration flux. The technique of integrating migration with electromembrane was evaluated for the removal of chromium. The transport was found to be adequately described by an equation in which the rate is proportional to the chromium concentration. The rate of dichromate ions transported across the membranes and the gel water content of membrane increased when the ratio of electromembrane potential and cell system potential was increased. The back …