Engineering Commons^™

Salts In Tri-State Mill Waters: Their Ill-Effect On The Flotation Of Zinc And Their Removal, Warren Lincoln Howes

Masters Theses

"The application of the flotation process has become one of the greatest innovations in modern ore dressing. In a comparatively short span of years it has grown to be one of the most powerful tools of the ore dressing engineer. Flotation is particularly adapted for the recovery of finely ground mineral and has thus enabled the miner to open up enormous deposits of low grade, disseminated ores for profitable treatment. In conjunction with other methods, the process has raised the recovery in practically every ore dressing plant by the treatment of slimes which otherwise would go to waste, carrying valuable …

A Power Study Of A Laboratory Ball Mill, Frederick Clearman

Masters Theses

"Ball milling practice in the ore dressing industry is largely empirical. Although many investigators have worked on various of its phases, the present operating methods are mostly a matter of cut-and-try, with the result that the industry is not guided by its underlying principles. Consequently, practice varies extensively with regard to nearly all conditions of operations. Even in neighboring concentrators such factors as speed, ball charge, and ore load differ in similar ball mills. Since fine grinding is continually becoming of more importance, and often accounts for thirty per cent of the milling cost, it is very necessary that a …

A Study Of The Iodine Content Of Missouri Vegetables And Soils, Charles Jackson Potter

Masters Theses

"Investigations have shown that the iodine content of vegetables, water, and soils has a direct relationship to the goiter incidence of a given region. A few countries, notably New Zealand and Switzerland have made a rather complete survey. In the United States, South Carolina has made the most progress in this direction.

At the present time there are no available records of vegetable and soil analysis for iodine in Missouri. Hunze determined the amount of iodine in waters in Missouri. The connection of his results with the author's results will be seen later.

The present investigation was carried out at …

Beneficiation Of Manganese Ores, Michael V. Healey

Masters Theses

"The purpose of this investigation is to study the means of beneficiating domestic manganese ores in order that a marketable product may be made. Within the limits of the paper the term "Manganese ores" is applied to those ores mined primarily for their manganese content, to the exclusion of manganiferous iron and silver ores"--Object, page 1.

The Change In The Order Of Catalytic Action Of Lithium Chloride, Sodium Chloride, Magnesium Chloride, And Calcium Chloride In The Ketonic Splitting Of Ethyl Acetoacetate, Richard Dwight Duff

Masters Theses

"The catalytic action of neutral salts on many reactions has been investigated under various conditions, and a large number of explanations have been put forward. In this work the catalytic action of normal solutions of lithium chloride, sodium chloride, magnesium chloride, and calcium chloride in the presence of .1 N. hydrochloric acid on the ketonic splitting of ethyl acetoacetate has been investigated at several temperatures between 80⁰C. and 95⁰C. An attempt has been made to explain the results obtained"--Introduction, page 1.

A Study Of The Determination Of Fluorine And Other Constituents In Fluorspar, Robert Knowlton Grantham

Masters Theses

"A method for the determination of certain constituents in fluorspar has been studied. Fluorspar can be complete decomposed by fuming with perchloric acid. Agitation and boiling is essential to a rapid and quantitative decomposition. Lead, ferric oxide, titanium oxide, aluminum oxide and total calcium have been quantitatively determined in the solution obtained by the perchloric acid method of decomposition. Silica cannot be determined quantitatively by the use of perchloric acid alone. Preferential solution of calcium carbonate by means of very dilute perchloric acid cannot be used as a method for determining calcium in carbonates in the presence of calcium fluoride"--Summary, …

A Study Of Petroleum Emulsions, Howard Halcomb Gross

Masters Theses

"The producer of crude oil experiences a continuous source of trouble and loss in the emulsion problem. These emulsions cannot be entirely discarded for several reasons: First because it is a waste of natural resource and second because there are such large quantities that no feasible outlet could be found on account of fire hazard and stream polution [sic]. Further to keep these emulsions in storage for slow settling puts a storage burden on the producers. To handle the emulsions most economically many producers are treating them and a large number of methods for treating have been devised. The object …

The Solubility Of Inorganic Salts In Ether, Clarence Bernard Weiss

Masters Theses

"The data on the solubility of inorganic salts in ether is scarce. Eder made a study of this subject and found few salts whose solubility could be called high. He used both hydrated and dehydrated salts. Neumann mentions the great solubility of aluminum chloride in ether, but did no work to find its exact proportions. It was thought that perhaps with this particular salt, a solubility curve might be obtained that would be both instructive and interesting. Therefore the major portion of this work was spent in determining the solubility of aluminum chloride in ether. Other salts whose solubilities were …

Solubility Of Solid Paraffins In Lower Molecular Weight Hydrocarbons, Ruth Veino Goodhue

Masters Theses

"The solubility of solid paraffins in the lower molecular weight liquid hydrocarbons offers a problem of some considerable commercial importance since it is by use of these low boiling hydrocarbons that the undesirable paraffin waxes are removed from lubricating oils in the Sharples process. Little data is to be found in the literature on the solubility of the paraffin waxes, and that which is available is of a very general nature...This work was undertaken for the purpose of finding if possible, what effect this "cracking" or "telescoping" process has on the solubility of the paraffins in the liquid hydrocarbons"--Introduction, page …

A Study Of The Determination Of Silica In The Presence Of Fluorine, William Harlan Ode

Masters Theses

"The determination of silica in the presence of fluorine has always been accomplished either by difficult and complex analytical procedures or by rapid arbitrary control methods of doubtful precision...Hence, this study was undertaken in order to determine whether a more simple method might be found for the determination of silica in the presence of fluorine"--Introduction, page 1-2.

The Solubility Of Inorganic Salts In Carbon Disulfide: The Case Of Aluminum Bromide, Herman Henry Kaveler

Masters Theses

"Since about 1890, the interest in solubility has turned to a large extent to the investigation of the solubility of compounds in organic solvents. This has resulted in a great deal of work being done on the solubility of inorganic salts in non-aqueous solvents. As this mass of data steadily accumulated, the theoretical considerations of solubility and the ideal solution made rapid advances, as Hildebrand has pointed out. We express as much wonder over these theoretical advances as chemists did over the discover "that salts do dissolve in organic compounds". To add some useful data to that already accumulated on …

Effect Of The Use Of Old Retorts As Grog And Of Zinc Oxide Upon The Properties Of Bodies For The Manufacture Of Retorts, Elmer Gammeter

Masters Theses

"In the fall of 1924 the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, in cooperation with the Missouri School of Mines and Metallurgy began an investigation of the properties of raw materials used in the manufacture of retorts for the zinc industry. The investigation proceeded cooperatively until December, 1926, when the Bureau of Mines withdrew from ceramic research. The School then took over and is completing the problem as outlined. The first phase of the investigation had for its object the determination of the properties of the fireclays and body mixtures now in …

A Study Of The Iodine Content Of Representative Missouri Waters, Edmond Carl Hunze

Masters Theses

"Investigations have shown that the iodine content of natural waters bears a direct relationship to the goiter incidence of a given region. A number of the states have analysed [sic] their water for this constituent in the development of this hypothesis. A search of the literature revealed the fact that with the exception of two instances the iodine content of Missouri water had not been determined. Since in certain regions of Missouri there is quite a prevalence of goiter, it was deemed important to determine the iodine content of Missouri waters. It was believed that such information would be a …

The System: Calcium Oxalate - Sulphuric Acid, Joseph Maple Wilson

Masters Theses

"The manufacture of oxalic acid includes as one of the steps in the process, the conversion of calcium oxalate to the desired oxalic acid by treatment with sulphuric acid, and the subsequent crystalization [sic] of the oxalic acid from the solution of it thus made. This investigation has dealt with this conversion step, with regard to the various factors affecting it. The effect of time, acid concentration, temperature, volume of solution, solubility of reaction products, and possible compound formation have all been considered, and from the information thus gained the conclusion has been drawn"--Introduction, page 1.

A Study Of Electrometric Methods For Determining Selenium And Tellurium, Bertie Lee Browning

Masters Theses

"The quantitative oxidation of tellurious acid to telluric acid by potassium dichromate has been shown by Lenher and Wakefield to be applicable to the volumetric determination of tellurium. The purpose of this investigation was to study the applicability of the electrometric method to this titration"--Introduction, page [1].

Electrothermic Dry Distillation Of Zinc, Ira Nathan Goff

Masters Theses

"Although the work described in this thesis cannot be considered as complete, until certain mechanical changes have been made and the furnace operated continuously over a considerable period of time, this electrothermic dry distillation process for the extraction of zinc from ores offers excellent commercial possibilities. The literature has been reviewed, the process that was used at East St. Louis described, and the results of work at the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, Rolla, Missouri along the line of electrothermic metallurgy of zinc considered"--Summary, page 58.

A Study Of The Reduction Of Zinc Oxide By Hydrogen And Methane, Frederick Adam Weirich

Masters Theses

"The purpose of the investigation was to make a study of the reduction of zinc oxide by hydrogen and methane and to study the conditions for the most efficient condensation of the zinc vapor"--Investigations, page 4.

The Properties Of Refractories In Zinc Metallurgy. Part Iii. Comparison Of Various Clays, Richard Elkanah Sears

Masters Theses

"This thesis...contains a description of a part of a general investigation on the subject of the refractories used in the distillation of zinc. This investigation has been in progress for the past eighteen months at the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, in cooperation with the School of Mines and Metallurgy of the University of Missouri. The first phase of this investigation had for its theme the determination of the properties of the fire clays and body mixtures now used in the manufacture of zinc retorts. The second phase deals with the …

The Properties Of The Fire Clays Used For The Manufacture Of Zinc Retorts, Adolph Harmon Kuechler

Masters Theses

"The ultimate object of this refractories investigation is to develop a body for zinc retorts, or changes in the method of their manufacture, that will result in better retorts than the ones now in use. In doing this, the question of permissible cost must, at all times, be kept in mind. The immediate object of the present phase of this investigation, of which this thesis covers only a part, is to determine the physical and chemical properties of the refractories (fire clays, grogs, bodies, etc.) now used for the manufacture of zinc retorts. This will be a basis for later …

Hydro-Electric Treatment Of Joplin-Miami Zinc Concentrate, David Francis Walsh

Masters Theses

"The Electrolytic Process is a process capable of almost unlimited mechanicalization. For obvious reasons it is more economic to treat high grade concentrates; yet, the extremely high grade concentrates are not essential. The Electrolytic Process can treat economically concentrates as low as 30.% zinc under certain conditions. It is significant that as the grade of concentrates offered for treatment is lowered, the treatment cost per ton of concentrates decreases for the Electrolytic Process; whereas, it will increase, as previously stated, for the Retort Process. It is seen then that the position of the Electrolytic Process is strengthened where lower grade …

Lactose Fermenting Bacteria In The Water Supplies Of The Rolla Quadrangle, Joe Beaty Butler

Masters Theses

"I. Preliminary investigations. This includes the securing of 139 water samples from water sources in the Rolla Quadrangle, and inoculating 1cc samples from these into Dunham's Lactose tubes and thereby getting lactose gas production checks on the field samples. II. Confirmatory tests. This consisted in the isolation of lactose fermenters on Eosin-Methylene Blue Agar and checking of the cultures back through the lactose and then through dulcitel and saccharose so as to complete Jackson's Classification. 106 cultures were classified in this manner. III. Running through a complete set of tests of pure cultures, so as to completely (as possible) identify …

The Solubilities Of Certain Inorganic Salts In Anhydrous Normal Alcohols, William Orval Keeling

Masters Theses

"An examination of the literature shows that extensive studies have been made of the solubilities of inorganic salts in aqueous, normal alcohols, but that little has been done in determining the solubilities in anhydrous alcohols. Northing was found of a systematic study of the solubilities of NaCl, KCl, NaN0₃ and KNO₃ in the lower alcohols over a fairly wide range of temperature. The author has made a study of the solubilities of the above mentioned salts in lower anhydrous normal alcohols at the temperatures 20°C, 25°C, 30°C and 40°C"--Introduction, page 1.

Conductivity And Ionization Of Certain Salts In Absolute Alcohol, Armin Brene Jewell

Masters Theses

"One of the most striking observations one makes in connection with the study of the conductivities of alcoholic solutions is their great similiarity [sic] to those of aqueous solutions with the exception that the values of the concentrations are very much smaller. The differences are rather of degree than of kind. It will be noted that as the temperature is increased the molecular conductivity increases and the fraction of salt decreases which is what would be expected by analogy"--Discussion, page 43.

The Reduction Of Zinc Oxide By Carbon, George August Zeller

Masters Theses

"In spite of the fact that the reduction of zinc oxide by carbon is the fundamental reaction upon which the pyrometallurgy of zinc is based, there is a decided lack of accurate knowledge concerning the mechanism of the reaction, the temperature at which it begins, and the effect of various factors upon the rate at which it takes place"--Introduction, page 1.

On Plain Carbon Steel, Walter Edward Remmers

Masters Theses

"In 1921, an investigation was carried on by Messrs. Howe, Foley and Winlock, under the auspices of the National Research Council, the results of which were published under the title of - "Influence of Temperature, Time and Rate of Cooling on Physical Properties of Carbon Steel," by the American Institute of Mining and Metallurgical Engineers, February, 1923. These results showed that all physical properties of a 0.34 C. percent steel are improved by increasing the rate of cooling from temperatures above the critical range up to a certain rapidity beyond which, there is a gain in strength at the expense …

On The Breakage Of Rock Drill Steel, Muir Luken Frey

Masters Theses

"Prior to 1920 there was little attention paid to the general problem of breakage of rock drill steel. Each locality had its problem and the matter was treated as a purely local one, independent upon conditions in that particular section. But in the above-mentioned year, there arose an interest of wider scope, from what causes it is impossible to determine accurately, and the matter is now the subject of a broad investigation in which the users of rock drill steel, the United States Bureau of Mines, and the United States Bureau of Standards are cooperating...There is, to date, no satisfactory …

Effect Of Time And Temperature On Distillation Of Zinc-Lead-Silver Complex Sulphide Concentrates, Ernest Sterling Wheeler

Masters Theses

"Accurate information is lacking as to the effect of temperature and time of distillation on the relative proportions of zinc, lead and silver volatilized from complex ores, and while it is evident that the possibility of the commercial treatment of these complex ores has engaged the attention of metallurgists for years, it is one that will still bear investigation even on a small scale"--Statement of Problem, page 5.

Design And Construction Of The Experimental Mine, Robert Knox Stroup

Masters Theses

"The mining laboratory and experimental mine at the Missouri School of Mines was opened in 1913. At a suitable location, on the site of an old dolomite quarry, one and one half miles southwest of town a tunnel was started into the hillside and the necessary plant erected. This plant consisted of a fifty horse-power Erie Iron Works boiler of the modified locomotive type, and an Ingersoll Rand type 10 single stage duplex air compressor of a capacity of one hundred cubic feet of free air per minute. This plant was in operation during the fall months of each year …

Determination Of The Solubilities Of Lithium, Sodium, And Potassium Sulphates In Absolute Methyl And Ethyl Alcohols, Jennie Lynn Lenox

Masters Theses

"It was thought by the author that there might be some relation between the solubility of a salt in the alcohols and the position of those alcohols in the series of monohydric alcohols; that is, that there should be a definite increase or decrease in the solubility of any particular salt in going from a higher to a lower alcohol. The object of this paper was to find the solubilities of some simple salts in as pure alcohol as could be prepared, and to find any relationships if possible"--page 2.

Drill Steel Investigation, Richard J. Stroup, Kurt H. De Cousser

Masters Theses

"

Purpose of Investigation

To determine the best composition of a straight carbon drill steel for drilling in granite.

Method of Investigation

1. Obtain several brands of standard grade drill steel. Determine analysis and transformation points of each.
2. Determine that heat treatment which gives the best drilling qualities in granite.
3. Determine the micro-structure of such steel.
4. Obtain steel of a certain specified composition considered best for the conditions and compare the results on this steel with the results obtained on the market products.
5. Design of heating furnace for forging steels.

It will be observed from what follows that this outline was …