Engineering Commons^™

Hydrothermal Synthesis And Structural Investigation Of A Crystalline Uranyl Borosilicate, Kristen A. Pace, Vladislav V. Klepov, Mark D. Smith, Travis Williams, Gregory Morrison, Jochen A. Lauterbach, Scott T. Misture, Hans Conrad Zur Loye

Faculty Publications

The relevance of multidimensional and porous crystalline materials to nuclear waste reme-diation and storage applications has motivated exploratory research focused on materials discovery of compounds, such as actinide mixed-oxoanion phases, which exhibit rich structural chemistry. The novel phase K1.8 Na1.2 [(UO2)BSi4 O12 ] has been synthesized using hydrothermal methods, rep-resenting the first example of a uranyl borosilicate. The three-dimensional structure crystallizes in the orthorhombic space group Cmce with lattice parameters a = 15.5471(19) Å, b = 14.3403(17) Å, c = 11.7315(15) Å, and V = 2615.5(6) Å3, and is composed of UO6 octahedra linked by [BSi4 O12 ]5− chains to …

Ion Gnss Software-Defined Radio Metadata Standard, Sanjeev Gunawardena, Thomas Pany, James Curran

Faculty Publications

The past several years have seen a proliferation of software‐defined radio (SDR) data collection systems and processing platforms designed for or applicable to satellite navigation (satnav) applications. These systems necessarily produce datasets in a wide range of different formats. To correctly interpret this SDR data, essential information such as the packed sample format and sampling rate is needed. Communicating this metadata between creators and users has historically been an ad‐hoc, cumbersome, and error‐prone process. To address this issue, the satnav SDR community developed a metadata standard and normative software library to automate this process, thus simplifying the exchange of datasets …

Twisted Spatiotemporal Optical Vortex Random Fields, Milo W. Hyde Iv

Faculty Publications

We present twisted spatiotemporal optical vortex (STOV) beams, which are partially coherent light sources that possess a coherent optical vortex and a random twist coupling their space and time dimensions. These beams have controllable partial coherence and transverse orbital angular momentum (OAM), which distinguishes them from the more common spatial vortex and twisted beams (known to carry longitudinal OAM) in the literature and should ultimately make them useful in applications such as optical communications and optical tweezing. We present the mathematical analysis of twisted STOV beams, deriving the mutual coherence function and linear and angular momentum densities. We simulate the …

Development Of Small-Scale Plutonium Electrorefining In Molten Cacl2, Devin Rappleye, James Mcneese, Richard Torres, Kiel Holliday, Jason R. Jeffries

Faculty Publications

Molten salt extraction and electrorefining of plutonium were successfully conducted with only a 200-g initial charge. Due to this small scale, the electrorefining cell components were redesigned relative to conventional, multi-kg standards. The efficiency and yield of this small-scale process are comparable to those of larger-scale exemplars. Chemical analysis of the plutonium product and the anode heel is presented. The product was 99.8% pure. The anode heel was able to be depleted beyond the expected freezing point without significant impurity carryover.

“When They Say Weed Causes Depression, But It’S Your Fav Antidepressant”: Knowledge-Aware Attention Framework For Relationship Extraction, Shweta Yadav, Usha Lokala, Raminta Daniulaityte, Krishnaprasad Thirunarayan, Francois Lamy, Amit P. Sheth

Faculty Publications

With the increasing legalization of medical and recreational use of cannabis, more research is needed to understand the association between depression and consumer behavior related to cannabis consumption. Big social media data has potential to provide deeper insights about these associations to public health analysts. In this interdisciplinary study, we demonstrate the value of incorporating domain-specific knowledge in the learning process to identify the relationships between cannabis use and depression. We develop an end-to-end knowledge infused deep learning framework (Gated-K-BERT) that leverages the pre-trained BERT language representation model and domain-specific declarative knowledge source (Drug Abuse Ontology) to jointly extract entities …

Nonlinear Trajectory Tracking Control For Winged Evtol Uavs, Jacob Willis, Randal W. Beard

Faculty Publications

Current control methods for winged eVTOL UAVs consider the vehicle primarily as a fixed-wing aircraft with the addition of vertical thrust used only during takeoff and landing. These methods provide good long-range flight handling but fail to consider the full dynamics of the vehicle for tracking complex trajectories. We present a trajectory tracking controller for the full dynamics of a winged eVTOL UAV in hover, fixed-wing, and partially transitioned flight scenarios. We show that in low- to moderate-speed flight, trajectory tracking can be achieved using a variety of pitch angles. In these conditions, the pitch of the vehicle is a …

Modeling Ash Deposit Growth Rates For A Wide Range Of Solid Fuels In A 100 Kw Combustor, Seyedhassan Fakourian, Zachary Mcallister, Andrew R. Fry, Yueming Wang, Xiaolong Li, Jost O.L. Wendt, Jinze Dai

Faculty Publications

This work details a model for evaluating the relative ash deposition propensity of various solid fuels without the complicated spatial considerations included in CFD modeling. Four deposition mechanisms are included, namely: inertial impaction, thermophoresis, condensation, and eddy impaction. This model has been validated and shown to effectively predict ash deposit rates for a wide range of solid fuels including coal, biomass, and their blends, burned in a 100 kW rated downflow combustor. Specifically, this work presents and compares two separate models for the sticking efficiency of impacting ash particles on a coupon surface: the melt fraction stickiness …

Impact Damage Ascertainment In Composite Plates Using In-Situ Acoustic Emission Signal Signature Identification, Robin James, Roshan Prakash Joseph, Victor Giurgiutiu

Faculty Publications

Barely visible impact damage (BVID) due to low velocity impact events in composite aircraft structures are becoming prevalent. BVID can have an adverse effect on the strength and safety of the structure. During aircraft inspections it can be extremely difficult to visually detect BVID. Moreover, it is also a challenge to ascertain if the BVID has in-fact caused internal damage to the structure or not. This paper describes a method to ascertain whether or not internal damage happened during the impact event by analyzing the high-frequency information contained in the recorded acoustic emission signal signature. Multiple 2 mm quasi-isotropic carbon …

The Influence Of Policy Implementation In The Midwest: How A Sstem Program Broadens Participation And Enhances Engineering Identity For Community College Students, Sarah L. Rodriguez, Maria L. Espino, Brian D. Le, Kelly J. Cunniham

Faculty Publications

This qualitative research study describes how a Midwest community college’s implementation of an Scholarships in Science, Technology, Engineering, and Mathematics (SSTEM) program influences engineering identity development for its students with financial need. Using a phenomenological approach, the study finds that the program enables community college students to have greater financial freedom and an ability to focus on engineering identity. In addition, the SSTEM program enhances student connections with STEM faculty, program staff, and peers. The study highlights the need for creating spaces for engineering identity development, developing connections between faculty, staff, and students, and enhancing transfer connections through different experiences. …

Weather-Related Construction Delays In A Changing Climate: A Systematic State-Of-The-Art Review, Steven J. Schuldt, Matthew R. Nicholson, Yaquarri A. Adams Ii, Justin D. Delorit

Faculty Publications

Adverse weather delays forty-five percent of construction projects worldwide, costing project owners and contractors billions of dollars in additional expenses and lost revenue each year. Additionally, changes in climate are expected to increase the frequency and intensity of weather conditions that cause these construction delays. Researchers have investigated the effect of weather on several aspects of construction. Still, no previous study comprehensively (1) identifies and quantifies the risks weather imposes on construction projects, (2) categorizes modeling and simulation approaches developed, and (3) summarizes mitigation strategies and adaptation techniques to provide best management practices for the construction industry. This paper accomplishes …

Accelerated Controller Tuning For Wind Turbines Under Multiple Hazards, Aly Mousaad Aly, Milad Rezaee

Faculty Publications

During their lifecycle, wind turbines can be subjected to multiple hazard loads, such as high-intensity wind, earthquake, wave, and mechanical unbalance. Excessive vibrations, due to these loads, can have detrimental effects on energy production, structural lifecycle, and the initial cost of wind turbines. Vibration control by various means, such as passive, active, and semi-active control systems provide crucial solutions to these issues. We developed a novel control theory that enables semi-active controller tuning under the complex structural behavior and inherent system nonlinearity. The proposed theory enables the evaluation of semi-active controllers’ performance of multi-degrees-of-freedom systems, without the need for time-consuming …

Thermal Ignition Of A Combustible Over An Inclined Hot Plate, Salaika Parvin, Nepal Chandra Roy, Rama S. R. Gorla

Faculty Publications

In this study, the ignition characteristics and the flow properties of the mixed convection flow are presented. Detailed formulations of the forced, natural and mixed convection problems have been discussed. In order to avoid inconvenient switch between the forced and natural convection we introduce a continuous transformation in the mixed convection. We make a comparison between these situations which reveal a good agreement. For mixed convection flow, the ignition distance is explicitly expressed as a function of the Prandtl number, reaction parameter and wall temperature. It has been observed that owing to the increase of the aforesaid parameters, the thermal …

Coarse-Grained Simulation Of Pegylated And Tethered Protein Devices At All Experimentally Accessible Surface Residues On Β-Lactamase For Stability Analysis And Comparison, Addison K. Smith, Mehran Sultani, Joshua Wilkerson, Brandon Timmerman, Emily Long Zhao, Bradley C. Bundy, Thomas A. Knotts

Faculty Publications

PEGylated and surface-tethered proteins are used in a variety of biotechnological applications, but traditional methods offer little control over the placement of the functionalization sites on the protein. Fortunately, recent experimental methods functionalize the protein at any location on the amino acid sequence, so the question becomes one of selecting the site that will result in the best protein function. This work shows how molecular simulation can be used to screen potential attachment sites for surface tethering or PEGylation. Previous simulation work has shown promise in this regard for a model protein, but these studies are limited to screening only …

State Consistence Of Data-Driven Reduced Order Models For Parametric Aeroelastic Analysis, William C. Krolick, Jung I. Shu, Yi Wang, Kapil Pant

Faculty Publications

This paper investigates the state consistence of parametric data-driven reduced order models (ROMs) in a state-space form obtained by various system identification methods, including autoregressive exogenous (ARX) and subspace identification (N4SID), for aeroelastic analysis in varying flight conditions. The target flight envelop is first partitioned into discrete grid points, on each of which an aerodynamic ROM is constructed using system identification to capture the dependence of the generalized aerodynamic force on the generalized displacement of structural modes. High-fidelity aeroelastic modal perturbation simulations are used to generate the ROM training and verification data. Aerodynamic ROMs not on the grid point are …

Editors’ Choice-Power-Generating Electrochemical Co2 Scrubbing From Air Enabling Practical Aemfc Application, Yiwei Zheng, Garrett Huang, Mrinmay Mandal, John R. Varcoe, Paul A. Kohl, William E. Mustain

Faculty Publications

Anion exchange membrane fuel cells (AEMFCs) have been widely touted as a low-cost alternative to existing proton exchange membrane fuel cells. However, AEMFCs operating on air suffer from a severe performance penalty caused by carbonation from exposure to CO2. Many approaches to removing CO2 from the cathode inlet would consume valuable energy and complicate the systems-level balance-of-plant. Therefore, this work focuses on an electrochemical solution where CO2 removal would still generate power, but not expose an entire AEMFC stack to carbonation conditions. Such a system consists of two AEMFCs in series. The first AEMFC, which acts as an anion exchange …

International Journal Of Electrical And Computer Engineering, Fred Lacy

Faculty Publications

A superconductor has the ability to conduct electricity perfectly and exclude magnetic fields from its interior. In order to understand electromagnetic characteristics of superconductors, their material properties need to be examined. To facilitate this understanding, a theoretical model based on concepts of electromagnetics is presented to explain the electrical and magnetic properties of superconductors. The permittivity response is the key aspect of the model and it describes the electrical resistance response and why it vanishes at the material’s critical temperature. The model also explains the behavior of magnetic fields and why they cannot exist inside superconducting materials. The theoretical concepts …

A Life Cycle Comparison Of Remote, Deployed Expeditionary Waste Management Scenarios, David J. Chester, Chandrani Mukherjee, Jeremy M. Slagley, Eric Mbonimpa, Thomas Hornstein

Faculty Publications

The current barrier to acquisition and utilization of viable waste-to-energy (WTE) technologies at remote or deployed expeditionary sites requires high capital and operation & maintenance costs. The impacts to environment and human health of differing expeditionary waste management strategies were compared using the Life Cycle Assessment software SimaPro 8.0. Emissions of individual waste management scenarios were compiled from peer-reviewed literature, converted to values compatible with SimaPro’s waste scenario inputs, and the calculated impacts compared using SimaPro’s pre-loaded methodologies. These calculated impacts and the economic impacts confirm that open-air burning of waste is not only dangerous to humans and the environment, …

Photoinduced Trapping Of Charge At Sulfur Vacancies And Copper Ions In Photorefractive Sn2P2S6 Crystals, Timothy D. Gustafson, Eric M. Golden, Elizabeth M. Scherrer, Nancy C. Giles, A. A. Grabar, Sergey A. Basun, Jonathan E. Slagle [*], Larry E. Halliburton

Faculty Publications

Electron paramagnetic resonance (EPR) is used to monitor photoinduced changes in the charge states of sulfur vacancies and Cu ions in tin hypothiodiphosphate. A Sn₂P₂S₆ crystal containing Cu+ (3d10) ions at Sn²⁺ sites was grown by the chemical vapor transport method. Doubly ionized sulfur vacancies (V²⁺S) are also present in the as-grown crystal (where they serve as charge compensators for the Cu+ ions). For temperatures below 70 K, exposure to 532 or 633 nm laser light produces stable Cu²⁺ (3d⁹) ions, as electrons move from Cu⁺ ions to …

An Assessment Of The Spatial Variation Of Isotopic Ratios In A Candu Reactor For Nuclear Treaty Monitoring, Aaron W. Burkhardt, James E. Bevins, Stephen H. Baxter

Faculty Publications

A 3-D Quarter-Core CANDU-6 is modeled using Serpent 2 for nuclear treaty monitoring. The spatial variation of flux spectra and isotopic concentrations is analyzed to determine the potential isotopic distribution of key radionuclides from standard reactor operations relevant to non-proliferation. The initial results of the model show a 46% difference in overall flux magnitude throughout the core as well as a 2-30% difference in discrete energy flux. The coupled production rate (magnitude) and spectral differences can contribute to significant spatial variations in isotope ratios throughout the core. Initial results indicate 239 Pu/ 240 Pu ratios vary by as much as …

Zynq System-On-Chip Dma Messaging For Processor Monitoring, Daniel F. Koranek, Douglas D. Hodson, Scott R. Graham

Faculty Publications

Xilinx Zynq-7000 System-on-Chip architectures combine an ARM Cortex-A9 core with an FPGA fabric. One benefit of this hybrid architecture is that it allows fast prototyping of designs where the security of either the processing system (PS) is monitored by the programmable logic (PL) or vice versa. The choice of implementing a design in the PS or PL is driven by cost-to-benefit analysis across many factors. This effort examines the design process required to construct security monitoring designs that use both the PS and PL. For background, this effort reviews similar security monitoring projects. For the effort, a PL peripheral was …

Sparc: Statistical Performance Analysis With Relevance Conclusions, Justin C. Tullos, Scott R. Graham, Jeremy D. Jordan, Pranav R. Patel

Faculty Publications

The performance of one computer relative to another is traditionally characterized through benchmarking, a practice occasionally deficient in statistical rigor. The performance is often trivialized through simplified measures, such as the approach of central tendency, but doing so risks a loss of perspective of the variability and non-determinism of modern computer systems. Authentic performance evaluations are derived from statistical methods that accurately interpret and assess data. Methods that currently exist within performance comparison frameworks are limited in efficacy, statistical inference is either overtly simplified or altogether avoided. A prevalent criticism from computer performance literature suggests that the results from difference …

Effect Of Membrane Properties On The Carbonation Of Anion Exchange Membrane Fuel Cells, Yiwei Zheng, Lyzmarie Nicole Irizarry, Noor Ui Hassan, Eric R. Williams, Morgan Stefik, Jacob M. Lamanna, Daniel S. Hussey, Mustain E William

Faculty Publications

Anion exchange membrane fuel cells (AEMFC) are potentially very low-cost replacements for proton exchange membrane fuel cells. However, AEMFCs suffer from one very serious drawback: significant performance loss when CO2 is present in the reacting oxidant gas (e.g., air) due to carbonation. Although the chemical mechanisms for how carbonation leads to voltage loss in operating AEMFCs are known, the way those mechanisms are affected by the properties of the anion exchange membrane (AEM) has not been elucidated. Therefore, this work studies AEMFC carbonation using numerous high-functioning AEMs from the literature and it was found that the ionic conductivity of the …

Development Of A Modular Mixed-Radiation Directional Rotating Scatter Mask Detection System, Bryan V. Egner, Darren E. Holland, Larry W. Burggraf, James E. Bevins

Faculty Publications

The ability to simultaneously identify the direction of both fast neutrons, above 1 MeV, and gamma rays using a light-weight system consisting of a single 1” EJ-309 organic liquid scintillator and a plastic Spartan rotating scatter mask (RSM) is demonstrated computationally through Monte Carlo simulations and validated with experimental measurements. Two sets of directional measurements were performed with an americium–beryllium source, emitting both neutrons and gamma rays. The RSM identified the direction of the source within one 10° rotational increment in the azimuthal and polar directions based on both the neutron and gamma-ray induced signals discriminated by charge integration pulse-shape …

3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt

Faculty Publications

Droplet generation has been widely used in conventional two-dimensional (2D) microfluidic devices, and has recently begun to be explored for 3D-printed droplet generators. A major challenge for 3D-printed devices is preventing water-in-oil droplets from sticking to the interior surfaces of the droplet generator when the device is not made from hydrophobic materials. In this study, two approaches were investigated and shown to successfully form droplets in 3D-printed microfluidic devices. First, several printing resin candidates were tested to evaluate their suitability for droplet formation and material properties. We determined that a hexanediol diacrylate/lauryl acrylate (HDDA/LA) resin forms a solid polymer that …

3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt

Faculty Publications

Droplet generation has been widely used in conventional two-dimensional (2D) microfluidic devices, and has recently begun to be explored for 3D-printed droplet generators. A major challenge for 3D-printed devices is preventing water-in-oil droplets from sticking to the interior surfaces of the droplet generator when the device is not made from hydrophobic materials. In this study, two approaches were investigated and shown to successfully form droplets in 3D-printed microfluidic devices. First, several printing resin candidates were tested to evaluate their suitability for droplet formation and material properties. We determined that a hexanediol diacrylate/lauryl acrylate (HDDA/LA) resin forms a solid polymer that …

Identify Rna-Associated Subcellular Localizations Based On Multi-Label Learning Using Chou’S 5-Steps Rule, Hao Wang, Yijie Ding, Jijun Tang Ph.D., Quan Zou, Fei Guo

Faculty Publications

Background: Biological functions of biomolecules rely on the cellular compartments where they are located in cells. Importantly, RNAs are assigned in specific locations of a cell, enabling the cell to implement diverse biochemical processes in the way of concurrency. However, lots of existing RNA subcellular localization classifiers only solve the problem of single-label classification. It is of great practical significance to expand RNA subcellular localization into multi-label classification problem.

Results: In this study, we extract multi-label classification datasets about RNA-associated subcellular localizations on various types of RNAs, and then construct subcellular localization datasets on four RNA categories. In order to …

On-Chip Silicon Photonic Controllable 2 × 2 Four-Mode Waveguide Switch, Cao Dung Truong, Duy Nguyen Thi Hang, Hengky Chandrahalim, Minh Tuan Trinh

Faculty Publications

Multimode optical switch is a key component of mode division multiplexing in modern high-speed optical signal processing. In this paper, we introduce for the first time a novel 2 × 2 multimode switch design and demonstrate in the proof-of-concept. The device composes of four Y-multijunctions and 2 × 2 multimode interference coupler using silicon-on-insulator material with four controllable phase shifters. The shifters operate using thermo-optic effects utilizing Ti heaters enabling simultaneous switching of the optical signal between the output ports on four quasi-transverse electric modes with the electric power consumption is in order of 22.5 mW and the switching time …

First-Order Comprehensive Adjoint Sensitivity Analysis Methodology For Critical Points In Coupled Nonlinear Systems. I: Mathematical Framework, Dan Gabriel Cacuci

Faculty Publications

This work presents the novel first-order comprehensive adjoint sensitivity analysis methodology for critical points (1st-CASAM-CP), which enables the exact and efficient computation of the first-order sensitivities of responses defined at critical points (maxima, minima, saddle points) of coupled nonlinear models of physical systems characterized by imprecisely known parameters underlying the models, boundaries, and interfaces between the coupled systems. Responses defined at critical points are important in many applications, including system optimization, safety analyses and licensing. For the design and licensing of nuclear reactors, such essentially important responses include the maximum temperatures of the fuel and cladding in hot channels. The …

First-Order Comprehensive Adjoint Sensitivity Analysis Methodology For Critical Points In Coupled Nonlinear Systems. Ii: Application To A Nuclear Reactor Thermal-Hydraulics Safety Benchmark, Dan Gabriel Cacuci

Faculty Publications

Responses defined at critical points are particularly important for reactor safety analyses and licensing (e.g., the maximum fuel and/or clad temperature). The novel mathematical framework of the first-order comprehensive adjoint sensitivity analysis methodology for critical points (1st-CASAM-CP) is applied in this work to develop a reactor safety thermal-hydraulics benchmark model which admits exact closed-form expressions for the adjoint functions and for the first-order sensitivities of responses defined at critical points (maxima, minima, saddle points) in physical systems characterized by imprecisely known parameters, external and internal boundaries. This benchmark model is designed for verifying the capabilities and accuracies of computational tools …

Workshop Outcomes Report: 1st International Workshop On Seismic Resilience Of Arctic Infrastructure And Social Systems, Majid Ghayoomi, Katharine Duderstadt, Alexander Kholodov, Alexander Shiklomanov, Matthew Turner, Elham Ajorlou

Faculty Publications

No abstract provided.