Engineering Commons^™

Performance Projection Of A High-Temperature Co2 Transport Membrane Reactor For Combined Co2 Capture And Methane-To-Ethylene Conversion, Xin Li, Kevin Huang, Noah Van Dam, Xinfang Jin

Faculty Publications

Direct conversion of methane into ethylene through the oxidative coupling of methane (OCM) is a technically important reaction. However, conventional co-fed fixed-bed OCM reactors still face serious challenges in conversion and selectivity. In this paper, we apply a finite element model to simulate OCM reaction in a plug-flow CO₂ /O₂ transport membrane (CTM) reactor with a directly captured CO₂ and O₂ mixture as a soft oxidizer. The CTM is made of three phases: molten carbonate, 20% Sm-doped CeO₂ , and LiNiO₂ . The membrane parameters are first validated by CO₂ /O₂ flux …

Chiral Liquid Crystal Microdroplets For Sensing Phospholipid Amphiphiles, Sepideh Norouzi, Jose A. Martinez Gonzalez, Monirosadat (Sanaz) Sadati

Faculty Publications

Designing simple, sensitive, fast, and inexpensive readout devices to detect biological molecules and biomarkers is crucial for early diagnosis and treatments. Here, we have studied the interaction of the chiral liquid crystal (CLC) and biomolecules at the liquid crystal (LC)-droplet interface. CLC droplets with high and low chirality were prepared using a microfluidic device. We explored the reconfiguration of the CLC molecules confined in droplets in the presence of 1,2-diauroyl-sn-glycero3-phosphatidylcholine (DLPC) phospholipid. Cross-polarized optical microscopy and spectrometry techniques were employed to monitor the effect of droplet size and DLPC concentration on the structural reorganization of the CLC molecules. Our results …

A Dual-Band Filtering Structure For Highly Selective Reconfigurable Bandpass Filter And Filtering Balun, Jinqun Ge, Guoan Wang

Faculty Publications

This article proposes a filtering structure consisting of two half-wavelength resonators and two open-stub loaded resonators, which generates two third-order passbands. Multiple transmission zeros are introduced by the newly developed coupling scheme, resulting in extremely sharp roll-off desirable for highly selective filters. The proposed structure is applied to design a PIN-diodes switch-controlled reconfigurable dual-band bandpass filter (BPF) with four-state filtering responses: both passbands ON, both passbands OFF, high-frequency passband ON, and low-frequency passband ON. Stepped-impedance open stubs and one-end-grounded coupled lines are studied and employed in the design to suppress unwanted responses. In addition, two filtering structures are placed symmetrically …

Large Eddy Simulation Of The Wakes Of Three Urban Air Mobility Vehicles, Denis-Gabriel Caprace, Andrew Ning

Faculty Publications

Recent advances in urban air mobility have driven the development of many new VTOL concepts. These vehicles often feature original designs and futuristic shapes. Due to their novelty, the wake characteristics of such aircraft are unknown. However, large wake-induced velocities, should they exist, may be dangerous for any other vehicle evolving in their close proximity. Therefore, improved knowledge about the wakes of VTOL vehicles is needed to guarantee the safety of urban air mobility operations. In this work, we study the wake of three VTOL aircraft in cruise by means of large eddy simulation. We present a two-stage numerical procedure …

Acoustofluidics For Simultaneous Nanoparticle-Based Drug Loading And Exosome Encapsulation, Zeyu Wang, Joseph Rich, Nanjing Hao, Yuyang Gu, Chuyi Chen, Shujie Yang, Peiran Zhang, Tony Jun Huang

Faculty Publications

Nanocarrier and exosome encapsulation has been found to significantly increase the efficacy of targeted drug delivery while also minimizing unwanted side effects. However, the development of exosome-encapsulated drug nanocarriers is limited by low drug loading efficiencies and/or complex, time-consuming drug loading processes. Herein, we have developed an acoustofluidic device that simultaneously performs both drug loading and exosome encapsulation. By synergistically leveraging the acoustic radiation force, acoustic microstreaming, and shear stresses in a rotating droplet, the concentration, and fusion of exosomes, drugs, and porous silica nanoparticles is achieved. The final product consists of drug-loaded silica nanocarriers that are encased within an …

Audio-Based Wildfire Detection On Embedded Systems, Hung-Tien Huang, Austin Downey, Jason D. Bakos

Faculty Publications

The occurrence of wildfires often results in significant fatalities. As wildfires are notorious for their high speed of spread, the ability to identify wildfire at its early stage is essential in quickly obtaining control of the fire and in reducing property loss and preventing loss of life. This work presents a machine learning wildfire detecting data pipeline that can be deployed on embedded systems in remote locations. The proposed data pipeline consists of three main steps: audio preprocessing, feature engineering, and classification. Experiments show that the proposed data pipeline is capable of detecting wildfire effectively with high precision and is …

Composite Style Pixel And Point Convolution-Based Deep Fusion Neural Network Architecture For The Semantic Segmentation Of Hyperspectral And Lidar Data, Kevin T. Decker, Brett J. Borghetti

Faculty Publications

Multimodal hyperspectral and lidar data sets provide complementary spectral and structural data. Joint processing and exploitation to produce semantically labeled pixel maps through semantic segmentation has proven useful for a variety of decision tasks. In this work, we identify two areas of improvement over previous approaches and present a proof of concept network implementing these improvements. First, rather than using a late fusion style architecture as in prior work, our approach implements a composite style fusion architecture to allow for the simultaneous generation of multimodal features and the learning of fused features during encoding. Second, our approach processes the higher …

Zintl Phase Compounds Mg3Sb2-XBiX (X=0, 1, And 2) Monolayers: Electronic, Phonon And Thermoelectric Properties From Ab Initio Calculations, Zheng Chang, Jing Ma, Kunpeng Yuan, Jiongzhi Zheng, Bin Wei, Mohammed Al-Fahdi, Yufei Gao, Xiaoliang Zhang, Hezhu Shao, Ming Hu, Dawei Tang

Faculty Publications

The Mg₃Sb_2−xBi_x family has emerged as the potential candidates for thermoelectric applications due to their ultra-low lattice thermal conductivity (K_L) at room temperature (RT) and structural complexity. Here, using ab initio calculations of the electron-phonon averaged (EPA) approximation coupled with Boltzmann transport equation (BTE), we have studied electronic, phonon and thermoelectric properties of Mg₃Sb_2−xBi_x (x = 0, 1, and 2) monolayers. In violation of common mass-trend expectations, increasing Bi element content with heavier Zintl phase compounds yields an abnormal change in K_L in two-dimensional Mg₃Sb …

Koh Vs Deionized Water Operation In Anion Exchange Membrane Electrolyzers, Noor Ul Hassan, Yiwei Zheng, Paul A. Kohl, Mustain E. William

Faculty Publications

Anion exchange membrane water electrolyzers (AEMELs) have recently received significant attention due to their potential advantages over proton exchange membrane electrolyzers (PEMELs). However, some AEMELs feed an aqueous salt solution to the cell where PEMELs typically feed deionized (DI) water. DI water is preferred to keep the system and maintenance costs low. Because of this, many AEMEL researchers report performance both in the salt solution (typically KOH) and DI water. However, the methodology for switching between KOH and DI water is often poorly defined, and it is unclear what impact the residual salt has on cell performance after switching from …

A Case Study Of Protecting Bridges Against Overheight Vehicles, Aly Mousaad Aly, Marc Hoffmann

Faculty Publications

Most transportation departments have recognized and developed procedures to address the ever-increasing weights of trucks traveling on bridges in service today. Transportation agencies also recognize the issues with overheight vehicles’ collisions with bridges, but few stakeholders have definitive countermeasures. Bridges are becoming more vulnerable to collisions from overheight vehicles. The exact response under lateral impact force is difficult to predict. In this paper, nonlinear impact analysis shows that the degree of deformation recorded through the modeling of the unprotected vehicle-girder model provides realistic results compared to the observation from the US-61 bridge overheight vehicle impact. The predicted displacements are 0.229 …

Identification Of Return-Oriented Programming Attacks Using Risc-V Instruction Trace Data, Daniel F. Koranek, Scott R. Graham, Brett J. Borghetti, Wayne C. Henry

Faculty Publications

An increasing number of embedded systems include dedicated neural hardware. To benefit from this specialized hardware, deep learning techniques to discover malware on embedded systems are needed. This effort evaluated candidate machine learning detection techniques for distinguishing exploited from non-exploited RISC-V program behavior using execution traces. We first developed a dataset of execution traces containing Return Oriented Programming (ROP) exploitation on the RISC-V Instruction Set Architecture (ISA) and then developed several deep learning bidirectional Long Short-Term Memory (LSTM) models capable of distinguishing exploited traces from non-exploited traces, each using subsets of features from the execution traces. An objective of this …

Sub- And Near-Critical Hydrothermal Carbonization Of Animal Manures, Kyoung S. Ro, Michael A. Jackson, Ariel A. Szogi, David L. Compton, Bryan R. Moser, Nicole D. Berge

Faculty Publications

To produce hydrochar with less volatile matter (VM) and more fixed carbon (FC) to increase its stability, this study compared the hydrothermal carbonization (HTC) of hen (HM) and swine (SM) manures at typical HTC sub-critical temperature of 210 °C and slightly super-critical temperature of 400 °C. Physico-chemical properties such as proximate analysis; ultimate analysis; Brunauer–Emmett–Teller (BET) surface area; higher heating value (HHV); chemical oxygen demand (COD); and inorganic nutrients of hydrochar, gaseous, and liquid products were determined. As expected, both VM and yield decreased with temperature. The heats of HTC reactions were estimated to be exothermic, ranging from −5.7 to …

Antiviral Polymers: A Review, Ali Akbari, Ashkan Bigham, Vahid Rahimkhoei, Sina Sharifi, Esmaiel Jabbari

Faculty Publications

Polymers, due to their high molecular weight, tunable architecture, functionality, and buffering effect for endosomal escape, possess unique properties as a carrier or prophylactic agent in preventing pandemic outbreak of new viruses. Polymers are used as a carrier to reduce the minimum required dose, bioavailability, and therapeutic effectiveness of antiviral agents. Polymers are also used as multifunctional nanomaterials to, directly or indirectly, inhibit viral infections. Multifunctional polymers can interact directly with envelope glycoproteins on the viral surface to block fusion and entry of the virus in the host cell. Polymers can indirectly mobilize the immune system by activating macrophages and …

Editorial For Gels 6th Anniversary Special Issue, Esmaiel Jabbari, Gulden Camci-Unal

Faculty Publications

Note: In lieu of an abstract, this is an excerpt from the first page.

This Special Issue celebrates many outstanding quality papers published in Gels over the past six years since its first issue was published in 2015 [...]

Simplified Thermal Runaway Model For Assisting The Design Of A Novel Safe Li-Ion Battery Pack, Paul T. Coman, Eric C. Darcy, Ralph E. White

Faculty Publications

This paper presents a simplified thermal runaway model (FEM) used to guide the design of a novel battery pack designed to resist thermal runaway propagation passively. The model is based on the heat equation for a 2D geometry with a heat generation term based on the maximum amount of energy measured using a custom-made calorimeter. The model was validated against experimental data using a 48-cell subscale of a full-scale battery pack for three different runs with three trigger cells with Internal Short Circuit Devices (ISCD) implanted in the separators. One trigger cell was placed at the edge, one placed in …

Beyond Profitable Shifts To Green Energies, Towards Energy Sustainability, Farboud Khatami, Erfan Goharian

Faculty Publications

The traditional carbon-based approach towards sustainability has long caused the concepts of green and sustainable energies to be used interchangeably. Recent studies have tried to advance this archaic view by considering more aspects of sustainability. However, almost all major studies have been concerned with only the economic and environmental aspects of electricity generation, whereas the concept of sustainability is beyond these two criteria. In this paper, we seek to provide a methodology for a more comprehensive definition of electricity generation sustainability based on the lessons learned from previous studies and additional metrics suggested by them. The main characteristics of select …

Materialsatlas.Org: A Materials Informatics Web App Platform For Materials Discovery And Survey Of State-Of-The-Art, Jianjun Hu, Stanislav Stefanov, Yuqi Song, Sadman Sadeed Omee, Steph-Yves Louis, Edirisuriya M.D. Siriwardane, Yong Zhao, Lai Wei

Faculty Publications

The availability and easy access of large-scale experimental and computational materials data have enabled the emergence of accelerated development of algorithms and models for materials property prediction, structure prediction, and generative design of materials. However, the lack of user-friendly materials informatics web servers has severely constrained the wide adoption of such tools in the daily practice of materials screening, tinkering, and design space exploration by materials scientists. Herein we first survey current materials informatics web apps and then propose and develop MaterialsAtlas.org, a web-based materials informatics toolbox for materials discovery, which includes a variety of routinely needed tools for exploratory …

Atmospheric Plasma Spraying To Fabricate Metal-Supported Solid Oxide Fuel Cells With Open-Channel Porous Metal Support, Jie Lin, Haixia Li, Wanhua Wang, Peng Qiu, Greg Tao, Kevin Huang, Fanglin Chen

Faculty Publications

Metal-supported solid oxide fuel cells (MS-SOFCs) have been fabricated by applying phase-inversion tape-casting and atmospheric plasma spraying (APS). The effect of the binder amount of the phase-inversion slurries on the microstructure development of the 430L stainless steel metal support was investigated. The pore structures, the viscosity of the slurry, porosity and permeability of the as-prepared metal supports are significantly influenced by the amount of the binder. NiO–scandia-stabilized zirconia (ScSZ) anode, ScSZ electrolyte and La_0.6Sr_0.4Co_0.2Fe0.8O_3−δ (LSCF) cathode layers were consecutively deposited on the metal support with an ideal microstructure by APS process. The effect …

Visual Homing For Robot Teams: Do You See What I See?, Damian Lyons, Noah Petzinger

Faculty Publications

Visual homing is a lightweight approach to visual navigation which does not require GPS. It is very attractive for robot platforms with a low computational capacity. However, a limitation is that the stored home location must be initially within the field of view of the robot. Motivated by the increasing ubiquity of camera information we propose to address this line-of-sight limitation by leveraging camera information from other robots and fixed cameras. To home to a location that is not initially within view, a robot must be able to identify a common visual landmark with another robot that can be used …

Visual Homing For Robot Teams: Do You See What I See?, Damian Lyons, Noah Petzinger

Faculty Publications

Visual homing is a lightweight approach to visual navigation which does not require GPS. It is very attractive for robot platforms with a low computational capacity. However, a limitation is that the stored home location must be initially within the field of view of the robot. Motivated by the increasing ubiquity of camera information we propose to address this line-of-sight limitation by leveraging camera information from other robots and fixed cameras. To home to a location that is not initially within view, a robot must be able to identify a common visual landmark with another robot that can be used …

Evaluating Climatic Influences On The Technical Performance Of Built Infrastructure Assets, Sarah L. Brown, Steven J. Schuldt, Michael N. Grussing, Michael A. Johnson, Justin D. Delorit

Faculty Publications

Asset performance evaluations serve as a benchmark that can be used to make asset manufacturer selection decisions, i.e., choosing the brand of manufacturer that provides the highest performance among all brand competitors. Understanding the environmental conditions to which assets are subjected provides facility managers another data point to understand asset performance. This research builds upon a previously published performance-based manufacturer selection metric by investigating the linkage between asset performance and exposure to local climate, using chiller and air handler data from 20 United States Air Force installations. The link between environmental factors such as Heating Degree Days (HDD); Cooling Degree …

Survivability Analysis In The Shadow Of Apollo: Part Ii - Spacecraft Charging Vulnerability Near The Stable Earth-Moon Lagrange Points, Robert A. Bettinger, Nathan R. Boone, Nicholas S. Hamilton, Bryan D. Little

Faculty Publications

Though the reality of routine travel and sustained operations in space likely remains several decades away, the building blocks of space exploration and space system development necessary to realize this reality are currently being laid by peer, near-peer, and emerging space-faring nations. The pursuance of sustained cislunar space operations will necessitate a renewed examination of spacecraft survivability and the capability of spacecraft to avoid and/or withstand the natural and manmade environmental risks posed by this “new” ultimate high ground.

Pseudo-Modal Expansions For Generating Random Electromagnetic Beams, Milo W. Hyde Iv, Olga Korotkova

Faculty Publications

Excerpt: We derive two pseudo-modal expansions that provide insight into the structure of stationary electromagnetic sources and can be used for their physical realization and in computer simulations. Both expansions are derived from the vectorial version of Bochner’s theorem of functional analysis.

Biomechanical And Psychological Predictors Of Failure In The Air Force Physical Fitness Test, Jeffrey Turner, Brent T. Langhals, Torrey J. Wagner

Faculty Publications

Physical fitness is a pillar of U.S. Air Force (USAF) readiness and ensures that Airmen can fulfill their assigned mission and be fit to deploy in any environment. The USAF assesses the fitness of service members on a periodic basis, and discharge can result from failed assessments. In this study, a 21-feature dataset was analyzed related to 223 active-duty Airmen who participated in a comprehensive mental and social health survey, body composition assessment, and physical performance battery. Graphical analysis revealed pass/fail trends related to body composition and obesity. Logistic regression and limited-capacity neural network algorithms were then applied to predict …

Aerial Radiation Detection Identification And Measurement System Detector Material Comparison Study, Benjamin C. Troxell, Kacey D. Mcgee, Christina L. Dugan

Faculty Publications

The 20th Chemical Biological Radiological Nuclear and Explosives Command (CBRNE) currently utilizes an airborne sodium iodide gamma and beta detection system to map radiation fields over large areas of interest. The 20th CBRNE explored emergent detector technologies utilizing two detection materials; thallium-activated cesium iodide and high purity germanium (HPGe). These detectors were simulated at various altitudes and compared to background measurements. The sodium iodide detector failed to provide isotopic discrimination at distance. The thallium-activated cesium iodide CsI(Tl) detector provided sufficient absolute efficiency and energy resolution to identify isotopics at distance. The HPGe detector provided the best energy resolution. However, current …

Application Of Machine Learning To Predict The Performance Of An Emipg Reactor Using Data From Numerical Simulations, Owen Sedej, Eric G. Mbonimpa, Trevor Sleight, Jeremy Slagley

Faculty Publications

Microwave-driven plasma gasification technology has the potential to produce clean energy from municipal and industrial solid wastes. It can generate temperatures above 2000 K (as high as 30,000 K) in a reactor, leading to complete combustion and reduction of toxic byproducts. Characterizing complex processes inside such a system is however challenging. In previous studies, simulations using computational fluid dynamics (CFD) produced reproducible results, but the simulations are tedious and involve assumptions. In this study, we propose machine-learning models that can be used in tandem with CFD, to accelerate high-fidelity fluid simulation, improve turbulence modeling, and enhance reduced-order models. A two-dimensional …

Developing An Optimized Policy Tree-Based Reservoir Operation Model For High Aswan Dam Reservoir, Nile River, Erfan Goharian, Mohamed Shaltout, Mahdi Erfani, Ahmed Eladawy

Faculty Publications

The impacts of climate change on the Nile River and Grand Ethiopian Renaissance Dam (GERD) along with the increased water demand downstream suggest an urgent need for more efficient management of the reservoir system that is well-informed by accurate modeling and optimization of the reservoir operation. This study provides an updated water balance model for Aswan High Dam Reservoir, which was validated using combined heterogeneous sources of information, including in situ gauge data, bias-corrected reanalyzed data, and remote sensing information. To investigate the future challenges, the spatial distribution of the annual/seasonal Aswan High Dam Reservoir surface air temperature trends over …

Developing An Optimized Policy Tree-Based Reservoir Operation Model For High Aswan Dam Reservoir, Nile River, Erfan Goharian, Mohamed Shaltout, Mahdi Erfani, Ahmed Eladawy

Faculty Publications

The impacts of climate change on the Nile River and Grand Ethiopian Renaissance Dam (GERD) along with the increased water demand downstream suggest an urgent need for more efficient management of the reservoir system that is well-informed by accurate modeling and optimization of the reservoir operation. This study provides an updated water balance model for Aswan High Dam Reservoir, which was validated using combined heterogeneous sources of information, including in situ gauge data, bias-corrected reanalyzed data, and remote sensing information. To investigate the future challenges, the spatial distribution of the annual/seasonal Aswan High Dam Reservoir surface air temperature trends over …

Photo-Induced Drug Release From Polymeric Micelles And Liposomes: Phototriggering Mechanisms In Drug Delivery Systems, Najla M. Salkho, Nahid S. Awad, William G. Pitt, Ghaleb A. Husseini

Faculty Publications

Chemotherapeutic drugs are highly effective in treating cancer. However, the side effects associated with this treatment lower the quality of life of cancer patients. Smart nanocarriers are able to encapsulate these drugs to deliver them to tumors while reducing their contact with the healthy cells and the subsequent side effects. Upon reaching their target, the release of the encapsulated drugs should be carefully controlled to achieve therapeutic levels at the required time. Light is one of the promising triggering mechanisms used as external stimuli to trigger drug release from the light-responsive nanocarriers. Photo-induced drug release can be achieved at a …

A Comparison Of Square-Wave Voltammetry Models To Determine The Number Of Electrons Exchanged In Metal Deposition, Ranon Fuller, Tyler Williams, Mark H. Schvaneveldt, Devin Rappleye

Faculty Publications

A comparison of square-wave voltammetry models for calculating the number of electrons exchanged in a metal deposition reaction. Experiments were conducted for silver deposition on platinum in an aqueous HNO₃ solution and for nickel and lanthanum deposition on platinum in molten LiCl. Diffusion coefficients for Ni²⁺ and La³⁺ in LiCl at 700^oC are calculated. Accuracy of soluble-soluble models versus a soluble-insoluble model is discussed. A simple method for determining the number of electrons exchanged under the constraint of well-compensated ohmic drop is proposed and evaluated.