Engineering Commons^™

Enhancement Of Heat Transfer Coefficient Using Nanofluids For Multi-Stage Flash Desalination (Msf) Plant, Nasser Zouli

Doctoral Dissertations

“The enhancement of thermal conductivity and local heat transfer coefficient, under laminar and turbulent flow regimes, of water-based spherical Al₂O₃, CuO, and Fe₂O₃ nanofluids have been experimentally investigated for the improvement of the thermal desalination processes using a newly developed sophisticated noninvasive heat transfer coefficient probe that is flush mounted on the inner wall surface of the test section. The nanoparticles have been selected because of their superior thermal conductivity and low cost, as well as the magnetic characteristic of Fe₂O₃ nanoparticle since a magnet can collect it and reuse. …

Effects Of Milling Methods, Cooling Strategies And End-Mill Coatings On Machinability In High Speed End-Milling Of Inconel- 718 Using Carbide End-Mills, Paras Mohan Jasra

Doctoral Dissertations

“Inconel-718 superalloy is used extensively in aerospace and nuclear industries due to its excellent properties such as: high strength-to-weight ratio, ability to retain its properties at high temperature, high corrosion and creep resistance. However, Inconel-718 is characterized as a “difficult-to-cut metal”, because it poses severe problems during machining such as: high temperature at the cutting zone due to low thermal conductivity, hardening tendency at elevated temperature, high cutting forces, rapid tool wear and high chemical affinity with many cutting tools. Appropriate cooling strategies, milling methods, tool coatings and cutting speeds play important roles in addressing these problems. This research presents …

Delineation Of A Coal Combustion Residue Landfill And Underlying Karst Subsurface In Southwest Missouri Using Ert And Masw Surveys, Ruobai Zhao

Doctoral Dissertations

"The safe containment of coal combustion residual (CCR) in landfills was addressed by the U.S. Environment Protection Agency (EPA) CCR rule published in 2015. The new rule affects new and existing U.S. based CCR landfills in terms of implementing safeguard systems for safe disposal and contamination control. Electrical resistivity tomography (ERT) and multichannel analysis of surface waves (MASW) data were acquired across and in proximity to a CCR landfill in southwest Missouri, USA, with the intent to identify potential karst features and seepage pathways.

Electrical resistivity tomography data were acquired using an automated 8-channel resistivity meter and multichannel analysis of …

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr

Doctoral Dissertations

"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH₄ and NaAlH₄ indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …

Critical Buckling And Post-Buckling Behavior Of Thin-Walled Liners Encased By Underground Pipelines In Saturated Soils, Zhaochao Li

Doctoral Dissertations

"This study aims to investigate the structural stability of thin-walled liners encased in functionally-obsolete underground pipelines in saturated soil under external hydrostatic pressure, a concentrated load, temperature change or their combination, and develop a simplified circular arch model of thin-walled liners when not constrained by the pipelines. The friction and adhesion on the interface between a liner and its constraining surface (pipeline or grouting), and the pressure gradient on deeply-buried pipelines are neglected. The critical buckling load of elastic liners is analytically derived under a plane strain condition using the principle of minimum potential energy. The analytical solution is either …

Engineering Zeolite Catalysts Through Porosity And Surface Acidity Control For Selective Production Of Light Olefins, Xin Li

Doctoral Dissertations

"Zeolites are broadly used as heterogeneous catalysts in various chemical and petrochemical industries to produce value-added chemicals and fuels, mainly due to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity. In this dissertation, various zeolite catalysts were engineered through fine-tuning micro-meso-macro-porosity and surface acidity. The engineered zeolites were used as heterogeneous catalysts for production of light olefins such as ethylene and propylene through alcohol dehydration and hydrocarbon cracking reactions.

To control the zeolite porosity and acidity, SAPO-34@ZSM-5 and SAPO-34@Silicalite-1 composites with core-shell structure were synthesized and evaluated in ethanol dehydration reaction. Analysis of catalytic performance revealed …

Direct Printing Of Single-Crystal Silicon By Microscale Nanoparticle Printing And Confined Laser Melting And Crystallization, Wan Shou

Doctoral Dissertations

"The transport and interfacial phenomena in laser melting and crystallization of silicon in micro-/nano-scale confinement lacks sufficient understanding. Uncovering the underlying mechanisms, and hence harness the melting and crystallization processes can help the formation of controllable single-crystal structures or patterns. In this dissertation, a molecular dynamics (MD) simulation was conducted to calculate the interfacial free energy of the silicon system in contact with flat and structured walls. Then the calculated interfacial energies were employed to predict the nucleation mechanisms in a slab of liquid silicon confined by two walls and compared with MD simulation results. Further, in combination with a …

Investigation Of Additively Manufactured Polymer And Transparent Polymer Composites, Gregory Taylor

Doctoral Dissertations

"The objective of this study is an investigation of both the characterization of fused deposition modeling (FDM) of polymer thermoplastics and the manufacture of glass-reinforced transparent composites. The flexural behavior and fracture toughness of FDM parts are critical for the evaluation and optimization of both material and process. This study focuses on the performance of FDM Ultem 1010 specimens intended to be used as composite tooling due the material's high heat resistance. A three-point bend test is performed for flexure properties while a single edge notch bend test is performed for fracture toughness. For each of the tests, the build …

Atomic Layer Deposition Prepared Nanostructured Materials For Various Catalytic Reactions, Xiaofeng Wang

Doctoral Dissertations

"Atomic layer deposition (ALD) has been widely used for thin film coating and metal nanoparticles (NPs) preparation. In this report, the applications of ALD prepared nanostructured materials in catalysis were examined.

Highly dispersed Pt monometallic catalysts with different substrates and multi-walled carbon nanotubes (MWCNTs) supported Pt-Co bimetallic catalysts were synthesized by ALD for selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols (UA). Pt/MWCNTs showed the highest selectivity of UA in selective hydrogenation of citral, as compared to Pt/SiO₂, Pt/ALD-Al₂O₃, and Pt/γ-Al₂O₃. After adding Co, the highest selectivity was achieved …

Long-Term Behavior Of Fiber Reinforced Polymer (Frp) Confined Concrete Cylinders Subjected To Severe Weather And Seawater Solution Conditions, Song Wang

Doctoral Dissertations

"This study presents an experimental investigation on durability of fiber-reinforced polymer (FRP) confined concrete cylinders subjected to various environmental conditions. Two types of cylinders were tested in this experiment: concrete-filled FRP tube (CFFT) and hollow-core FRP-concrete-steel (HC-FCS), with FRP tubes having two different constitutive resin components: polyester and epoxy. The specimens were subjected to three different environmental conditions: combined freeze/thaw, wet/dry and heating/cooling cycles with options of continuous water immersion and sustained axial load in an environmental chamber, UV exposure in an UV chamber, and seawater immersion in water tanks with sustained axial load. Mechanical and material characterization tests were …

Computational Dynamics And Virtual Dragline Simulation For Extended Rope Service Life, Muhammad Wardeh

Doctoral Dissertations

"The dragline machinery is one of the largest equipment for stripping overburden materials in surface mining operations. Its effectiveness requires rigorous kinematic and dynamic analyses. Current dragline research studies are limited in computational dynamic modeling because they eliminate important structural components from the front-end assembly. Thus, the derived kinematic, dynamic and stress intensity models fail to capture the true response of the dragline under full operating cycle conditions. This research study advances a new and robust computational dynamic model of the dragline front-end assembly using Kane's method. The model is a 3-DOF dynamic model that describes the spatial kinematics and …

Electrochemical Behavior Of Dense Electrodes For Impedancemetric Nox Sensors, Nabamita Pal

Doctoral Dissertations

NOx (NO and NO2) exhaust gas sensors for diesel powered vehicles have traditionally consisted of porous platinum (Pt) electrodes along with a dense ZrO2 based electrolyte. Advancement in diesel engine technology results in lower NOx emissions. Although Pt is chemically and mechanically tolerant to the extreme exhaust gas environment, it is also a strong catalyst for oxygen reduction, which can interfere with the detection of NOx at concentrations below 100 ppm. Countering this behavior can add to the complexity and cost of the conventional NO x sensor design. Recent studies have shown that dense electrodes are less prone to heterogeneous …

Stretching The Limits Of Dynamic Range, Shielding Effectiveness, And Multiband Frequency Response, Matthew J. Hartmann

Doctoral Dissertations

In this dissertation, an RF MEMS variable capacitor suitable for applications requiring ultrawide capacitive tuning ranges is reported. The device uses an electrostatically tunable liquid dielectric interface to continuously vary the capacitance without the use of any moving parts. As compared to existing MEMS varactors in literature, this device has an extremely simple design that can be implemented using simple fabrication methods that do not necessitate the use of clean room equipment. In addition, this varactor is particularly suited for incorporating a wide range of liquid dielectric materials for specific tuning ratio requirements.

Additionally, the shielding effectiveness performance of graphene-doped …

Full Simulation For The Qweak Experiment At 1.16 And 0.877 Gev And Their Impact On Extracting The Pv Asymmetry In The N→Δ A Transition, Hend Abdullah Nuhait

Doctoral Dissertations

The Qweak project is seeking to find new physics beyond the Standard Model. It is aimed to measure the weak charge of the proton, which has never been measured, at 4% precision at low momentum transfer. The experiment is performed by scattering electrons from protons and exploiting parity violation in the weak interaction at low four-momentum transfer.

In this experiment, two measurements were considered: which are elastic and inelastic. The elastic is to measure the proton's weak charge. In addition, the inelastic asymmetry measurement, which will extract the low energy constant dΔ. That measurement works in the neutral current …

Understanding The Surface Fouling Mechanism Of Ultrananocrystalline Diamond Microelectrodes Using Microfluidics For Neurochemical Detection, An-Yi Chang

Doctoral Dissertations

Electrochemical methods are widely used for chronic neurochemical sensing, but thus far, the organic solution redox reactions fouled the electrodes' surface. It caused the reduction of sensitivity and the electrodes' lifetime.

Here, we present the boron-doped nanocrystalline diamond microelectrodes (BDUNCD) as the next generation electrode material for neurochemical sensor development. To aid in long-term chronic monitoring of neurochemicals, they have a wide window of electrochemical potential, extremely low background current, and excellent chemical inertness. The main research goal is to reduce the rate of electrode fouling due to the reaction by-products, and significantly extend their useful lifetime.

We systematically characterize …

Improvement Of Fluorescence-Based Microfluidic Dna Analyzers, Collin Tranter

Doctoral Dissertations

A tremendous effort continues in the development of micro-total-analysis-systems; in support of this, many chemical passivation methods have been developed to enhance the biocompatibility of such microfluidic systems. However, the suitability of these passivation techniques to many fluorescence-based assays still remains inconsistent. This part of this work is focused on the performance of a third generation intercalating DNA dye when used within microfluidic devices treated with a select variety of passivating coatings. The results of these tests indicate that passivation coatings which are intended to shed DNA based on electrostatic repulsion will in fact imbibe the fluorescent DNA intercalating dye …

Numerical And Experimental Studies On Coastal Marsh Erosion Under Hurricane Induced Wave And Current, Minhaz M. Shahriar

Doctoral Dissertations

Considering the past history and future risks of hurricanes in the USA, well understood storm protection plans are needed to shelter the important areas of the population and economy, especially within southeastern Louisiana. It is extensively assumed that marshes offer protection from hurricane though the degree of this protection is not well measured or understood due to the complex physics involved in this overall system. Moreover, marshes experience significant erosion while serving as a barrier for important areas. Consequently, a particular method to quantify the effects on marshes during a coastal hurricane period is necessary to mitigate major marsh loss. …

Influence Of Moisture Content Distribution In Soil On Pavement And Geothermal Energy, Md Adnan Khan

Doctoral Dissertations

Moisture content in soil has a great implication in engineering design, and it has been heavily investigated by soil engineers and scientists. If moisture content in expansive soil changes drastically, it will create significant volume change in the soil. If expansive soil is present in building foundation or pavement subgrade, it may result in structural failure. On the other hand, if sufficient moisture content is present in soil, it will increase the production of geothermal energy from the ground soil. This dissertation is an effort to understand the effects of moisture content on both expansive soils and geothermal energy that …

Design, Modeling, Fabrication, And Testing Of A Multistage Micro Gas Compressor With Piezoelectric Unimorph Diaphragm And Passive Microvalves For Microcooling Applications, Shawn Thanhson Le

Doctoral Dissertations

This dissertation investigates the development of a multistage micro gas compressor utilizing multiple pump stages cascaded in series to increase the pressure rise with passive microvalves and piezoelectric unimorph diaphragms. This research was conducted through modeling, simulation, design, and fabrication of the microcompressor and its components. A single-stage and a two-stage microcompressor were developed to demonstrate and compare the performance and effectiveness of using a cascaded multistage design.

Steady fluid flow through static microvalves structure was studied to gain insight on its gas flow dynamics and characteristics. Transient analysis combined with the structure's interaction was investigated with an analytical model …

A Study Of Mathematics Achievement, Placement, And Graduation Of Engineering Students, Sara Hahler Blazek

Doctoral Dissertations

The purpose of this study was to determine how background knowledge impacts freshmen engineering students' success at Louisiana Tech University in terms of grades in two different freshman classes and graduation. To determine what factors impact students, three different studies were implemented. The first study used linear regression to analyze which demographic and academic variables significantly impacted freshman math and engineering courses. Using regression discontinuity, the second study determined if the university's placement requirement for Pre-Calculus was appropriate. The final study analyzed factors that impact graduation for engineering students as well as other disciplines to determine which significant variables were …

Expanding The Applications Of Poly(Dimethylsiloxane) In Biomicrofluidics, Sawyer D. Stone

Doctoral Dissertations

This work aims to create novel applications for poly(dimethylsiloxane) (PDMS) in the field of biomicrofluidics through oxidative stress detection, doping of the polymer for intentional leaching into microdevices, and the development of low-cost implements for fabricating PDMS microfluidic devices. PDMS has become the polymer of choice for research in microfluidics due to its optical clarity, ease of fabrication, flexibility in design, good mechanical properties, and the ability to chemically modify the surface.

Biomicrofluidics enables the rapid throughput and analysis of small biological samples requiring less time investment and reagent use than traditional macroscale laboratory techniques. Polymer devices are inexpensive, easily …

Application Of Nearly Linear Solvers To Electric Power System Computation, Lisa L. Grant

Doctoral Dissertations

"To meet the future needs of the electric power system, improvements need to be made in the areas of power system algorithms, simulation, and modeling, specifically to achieve a time frame that is useful to industry. If power system time-domain simulations could run in real-time, then system operators would have situational awareness to implement and avoid cascading failures, significantly improving power system reliability. Several power system applications rely on the solution of a very large linear system. As the demands on power systems continue to grow, there is a greater computational complexity involved in solving these large linear systems within …

Experimental And Computational Investigation Of Multi-Principal Element Alloys, Mohsen Beyramali Kivy

Doctoral Dissertations

"Multi-principal element (MPE) alloys, unlike traditional alloys, consist of five or more principal elements with near equi-atomic compositions creating a large new compositional space for exploring new alloy possibilities. However, designing MPE alloys with the desired phases, microstructures and properties is challenging task, and there is a demand for basic research for a better understanding of structure-processing-property relations in these alloys.

In this Ph.D. research, different computational models and experiments were integrated to study phase formations, and mechanical properties of different MPE alloys. Density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations were used to determine crystal structures, …

Investigation Of Local Velocities And Phase Holdups, And Flow Regimes And Maldistribution Identification In A Trickle Bed Reactor, Mohd Fitri Bin Abdul Rahman

Doctoral Dissertations

"Trickle bed reactors are packed beds of catalyst on which gas and liquid reactants flow concurrently downward. In this work, the experimental work was carried out in 0.14 m diameter Plexiglas column using air-water system flowing over a packed bed of 3 mm glass bead particles. The local liquid and gas velocities, phase saturation and their time series have been investigated for the first time by developing, validating, and implementing a new two-tip optical fiber probe technique. It was found the radially and axially the liquid and gas velocities and their saturation vary and they also vary with times. In …

Screening Guidelines And Data Analysis For The Application Of In-Situ Polymer Gels For Injection Well Conformance Improvement, Munqith Naeem Rashak Aldhaheri

Doctoral Dissertations

"Excessive water production represents a major industry challenge because of its serious economic and environmental impacts. Polymer gels have been effectively applied to mitigate water production and extend the productive lives of mature oilfields. However, selecting a proper gel technology for a given reservoir is a challenging task for reservoir engineers because of the associated geological and technical complexities and the absence of efficient screening tools.

A comprehensive review for the worldwide gel field projects was conducted to develop an integrated systematic methodology that determines the applicability of three injection well gel technologies including bulk gels, colloidal dispersion gels, and …

Mass Transfer Studies In Heavy Oil Recovery Using Solvents, Vijitha Mohan

Doctoral Dissertations

"Heavy oil, sometimes called bitumen, is known for its high viscosity (above 100 cp) and low API gravity (below 22⁰). In most cases, viscosity reduction is needed for the final product. There is a considerable amount of heavy oil in Alberta, Canada and the world's largest heavy oil deposit is in Venezuela. Yet less than 1% of it can be recovered because of its high viscosity. For shallow reservoirs, it is possible to resort to open cast mining. For deeper reservoirs, steam is used at ~ 350 ⁰C which gets the oil viscosity reduced to 1cp, which can now be …

Remote Sensing And Localization Of Smart Rocks With Orientation-Controlled Magnets For Real-Time Monitoring Of Bridge Scour And Riprap Effectiveness, Yan Tang

Doctoral Dissertations

"This study aims to develop and implement a novel smart rock technology for real-time monitoring of the maximum scour depth and the effectiveness of riprap mitigation measures. A smart rock is one or more stacked magnets encased in concrete that can automatically roll to the deepest point of a scour hole around a bridge pier and provide its location through remote measurement over time. Once integrated into a riprap measure, the smart rock moves together with natural rocks and is thus a potential indicator of the effectiveness of the riprap measure. Therefore, the localization and movement of smart rocks were …

Durability Behavior Of Fiber Reinforced Polymer And Steel Reinforced Polymer For Infrastructure Applications, Wei Wang

Doctoral Dissertations

"Crack development in reinforced concrete (RC) structures is common in elements such as bridge decks. However, these cracks can impose significant problems over time, because they allow chlorides from deicing chemicals to infiltrate concrete which will then corrode steel bars as RC structures are exposed to harsh weather. In the last decade, composite reinforcement systems are internally or externally applied to concrete structures instead of traditional steel reinforcing bars, or to strengthen concrete elements in flexure and shear. However, studies regarding the long-term durability performance of composite reinforcement systems is limited. Therefore, in order to popularize the application of these …

Atomic/Molecular Layer Deposition Prepared Size-Selective Catalysts And Supported Nickel Catalysts, Zeyu Shang

Doctoral Dissertations

"Heterogeneous catalysts are widely used because of their many advantages. In this dissertation, the application of atomic/molecular layer deposition (ALD/MLD) in heterogeneous catalyst synthesis and modification was examined.

A novel nanostructured size-selective catalyst was synthesized by depositing ultra-thin porous shells on the surface of catalysts. The ultra-thin porous shells were formed by oxidation of aluminum alkoxide films deposited by MLD. The catalytic activity of the size-selective catalyst was improved by introducing gaps between the porous shell and catalytic metal nanoparticles. The introduction of gaps greatly reduced the catalyst activity loss, which resulted from the contact areas between the active sites …

Development Of A Nonlinear Model For The Prediction Of Response Times Of Glucose Affinity Sensors Using Concanavalin A And Dextran And The Development Of A Differential Osmotic Glucose Affinity Sensor, Louis G. Reis

Doctoral Dissertations

With the increasing prevalence of diabetes in the United States and worldwide, blood glucose monitoring must be accurate and reliable. Current enzymatic sensors have numerous disadvantages that make them unreliable and unfavorable among patients. Recent research in glucose affinity sensors correct some of the problems that enzymatic sensors experience. Dextran and concanavalin A are two of the more common components used in glucose affinity sensors. When these sensors were first explored, a model was derived to predict the response time of a glucose affinity sensor using concanavalin A and dextran. However, the model assumed the system was linear and fell …