Engineering Commons^™

Strategies To Improve The Electrochemical Performance Of Lithium-Ion Batteries By Stabilizing The Interface Of Electrode/Electrolyte, Ye Jin

Doctoral Dissertations

”Lithium-ion batteries (LIBs) provide great potential for electric vehicles, and smart grids as future energy-storage devices. However, there are many challenges in the development of the LIB industry, including low energy and power density of electrode materials, poor rate performance, short cycle life of electrode materials, and safety issues caused by the flammability of the conventional organic liquid electrolytes.

In this research, we were committed to using general approach to efficiently and economically synthesize or modify LIB materials by stabilizing the interface between electrode and electrolyte. Atomic layer deposition (ALD) method was used to coat metal oxide thin films on …

Development Of Lightweight Materials By Meso- And Microstructure Control, Myranda Shea Spratt

Doctoral Dissertations

”In this work, two lightweight structures – lattice structures and metal matrix syntactic foams (MMSF) – were studied. Honeycomb lattices were manufactured by powder bed selective laser melting (SLM) from 304L stainless steel. The wall thicknesses of these structures ranged from 0.2 to 0.5 mm. Surface roughness was the primary cause of dimensional mismatch between the expected and as-built structures with an average wall thickness increase of 0.12 mm. The strength of the honeycombs increased with increasing wall thickness. A feature of the SLM microstructure, the melt pool boundary, was also studied as a part of this work. 3D models …

Improved Attenuation And Crosstalk Modeling Techniques For High-Speed Channels, Shaohui Yong

Doctoral Dissertations

”As digital systems are moving in the direction of faster data transmission rate and higher density of circuits, the problem of the far-end crosstalk (FEXT) and frequency-dependent attenuation are becoming the major factors that limit signal integrity performance. This research is focusing on providing several more comprehensive and accurate modeling approaches for striplines on fabricated printed circuit board (PCB). By characterizing the dielectric permittivity of prepreg and core, dielectric loss tangent, and copper foil surface roughness using measurement data, a better agreement between the stripline model and measurement is achieved. First, a method is proposed to extract dielectric loss tangent …

Fabrication Of Micro-/Nanofluidic Models And Their Applications For Enhanced Oil Recovery Mechanism Study, Yandong Zhang

Doctoral Dissertations

”Micro-/nanofluidic model, as a potential powerful tool, has been used for decades for investigating fluid flow at pore-scale in energy field. It is still increasingly imperative nowadays to use different micromodels to direct observe pore-level fluid flow and analyze mechanisms of different enhanced oil recovery methods. In this work, three main tasks including three dimensional micromodels (1D,2D,3D) are proposed to fabricate and use for investigating different mechanisms of different enhanced oil recovery methods. For 1D capillary tube micromodel, we fabricate and use it to investigate the dynamics of a trapped oil droplet under seismic vibration. Seismic stimulation is a promising …

Development Of Horizontal Axis Hydrokinetic Turbine Using Experimental And Numerical Approaches, Abdulaziz Abutunis

Doctoral Dissertations

“Hydrokinetic energy conversion systems (HECSs) are emerging as viable solutions for harnessing the kinetic energy in river streams and tidal currents due to their low operating head and flexible mobility. This study is focused on the experimental and numerical aspects of developing an axial HECS for applications with low head ranges and limited operational space. In Part I, blade element momentum (BEM) and neural network (NN) models were developed and coupled to overcome the BEM’s inherent convergence issues which hinder the blade design process. The NNs were also used as a multivariate interpolation tool to estimate the blade hydrodynamic characteristics …

Seismic Behavior Of Composite Bridge Columns, Mohanad M. Abdulazeez

Doctoral Dissertations

“This study investigates experimentally and numerically the seismic behavior of large-scale hollow-core fiber-reinforced polymer-concrete-steel (HC-FCS) innovative bridge columns as a sustainable approach to endure and rapidly recover from natural disasters such as earthquakes. The HC-FCS column consisted of a concrete shell sandwiched between an outer fiber-reinforced polymer (GFRP) tube and an inner steel tube to provided continuous confinement for the concrete shell along with the height of the column. The columns have a slender inner steel tube with diameter-to-thickness (D_s/t_s) ratios ranged between 85 to 254. Each steel tube was embedded into the footing, while the …

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …

Continuous-Flow Synthesis Of Fine Chemicals And Pharmaceutical Compounds Over Intelligent Organocatalysts With Bifunctional Reactivity, Abdo-Alslam Alwakwak

Doctoral Dissertations

“Many biological systems that utilize organic active sites to catalyze reactions under mild conditions invoke cooperative catalytic pathways, whereby two or more active sites work together to activate the reactant(s). The use of cooperative (bifunctional) catalysts and continuous flow chemistry (a reaction within the narrow channels of a micro‐ or microfluidic reactor) are commonplace in sustainable chemical transformation and attract a great deal of interest with respect to economic and environmentally-sustainable production of fine chemicals, pharmaceuticals, and agrochemicals, water treatment, as well as upgrading of biomass feedstocks. Although, some methods have been developed for immobilization of bifunctional catalysts for cooperative …

Balancing Labor Requirements In A Manufacturing Environment, Patrick Bernard Dwyer

Doctoral Dissertations

“This research examines construction environments within manufacturing facilities, specifically semiconductor manufacturing facilities, and develops a new optimization method that is scalable for large construction projects with multiple execution modes and resource constraints. The model is developed to represent real-world conditions in which project activities do not have a fixed, prespecified duration but rather a total amount of work that is directly impacted by the level of resources assigned. To expand on the concept of resource driven project durations, this research aims to mimic manufacturing construction environments by allowing a non-continuous resource allocation to project tasks. This concept allows for resources …

Development Of Novel Materials And Processes For Direct Conversion Of Co₂ Flue Gas To Chemicals And Fuels, Ahmed Al-Mamoori

Doctoral Dissertations

“This research focused on addressing the pressing issues of greenhouse gas emissions that greatly contribute to climate change. Specifically, the focus was given to the reduction of anthropogenic CO₂ emission and its subsequent conversion to commodity chemicals and fuels. In the first part of the research, a series of novel high temperature CO₂ adsorbents including double salts (K-Ca and Na-Ca) and metal-doped calcium oxide (Fe_x@CaO and Ga_x@CaO) was developed and evaluated. Both sets of materials exhibited high CO₂ capacity, fast kinetics, and long-term stability. In particular, at 650 °C, the doped adsorbents comprising …

Hydrokinetic Turbine Composite Blades And Sandwich Structures: Damage Evaluation And Numerical Simulation, Mokhtar Fal

Doctoral Dissertations

“Composite materials are gaining interest due to their high strength to weight ratio. This study deals with both experimental and numerical approaches to cover the aspects of the failure of composite materials in hydrokinetic turbine applications. In Part I, the location and magnitude of failure in the horizontal axis water turbine carbon fiber-reinforced polymer (CFRP) composite blades with different laminate stacking sequences were investigated. Two lay-up orientations were adopted for this work ([0⁰]₄ and [0⁰/90⁰]_2s). A finite element analysis model was generated to examine the stresses along the blade. Five angles were introduced to study the effect …

Comprehensive Study Of Bio-Diesel Continuous Flow Synthesis, Aso A. Hassan

Doctoral Dissertations

“Energy has become an indispensable factor in preserving economic growth since the commencement of the industrial revolution. In recent years, biodiesel has gained acceptance as a notable alternative to the widely used petroleum-derived diesel fuel because it is biodegradable, non-toxic, and generates fewer exhaust pollutants. Recently, biodiesel studies have focused on the development of process intensification technologies to resolve some technical challenges facing biodiesel production, such as long residence times and catalyst sensitivity. These intensification technologies enhance process mass/heat transfer to achieve a continuous, scalable process that can be easily transported to utilize locally available feed stocks. Five phases have …

System Efficient Esd Design Concept For Soft Failures, Giorgi Maghlakelidze

Doctoral Dissertations

"This research covers the topic of developing a systematic methodology of studying electrostatic discharge (ESD)-induced soft failures. ESD-induced soft failures (SF) are non-destructive disruptions of the functionality of an electronic system. The soft failure robustness of a USB3 Gen 1 interface is investigated, modeled, and improved. The injection is performed directly using transmission line pulser (TLP) with varying: pulse width, amplitude, polarity. Characterization provides data for failure thresholds and a SPICE circuit model that describes the transient voltage and current at the victim. Using the injected current, the likelihood of a SF is predicted. ESD protection by transient voltage suppressor …

Transition Metal Chalcogenide Hybrid Systems As Catalysts For Energy Conversion And Biosensing, Siddesh Umapathi

Doctoral Dissertations

"Generation of hydrogen and oxygen through catalyst-aided water splitting which has immense applications in metal air batteries, PEM fuel cells and solar to fuel energy production, has been one of the critical topics in recent times. The state of art oxygen evolution reaction (OER), oxygen reduction reaction (ORR), hydrogen evolution reaction (HER) catalysts are mostly comprised of precious metals. The current challenge lies in replacing these precious metal-based catalysts with non-precious earth-abundant materials without compromising catalytic efficiency.

This research explores mixed metal selenides containing Fe-Ni, Fe-Co and RhSe which were hydrothermally synthesized and/or electrodeposited and tested for OER and ORR …

Behavior Of Negative Stiffness Metamaterial Systems In Structural Engineering Applications, Yasser Darwish

Doctoral Dissertations

“Metamaterial systems with negative stiffness behavior became a point of interest in many energy dissipation applications due to their ability to dissipate high levels of energy. Negative stiffness metamaterial elements can dissipate energy through non-linear elastic behavior when transferred from one stable mode of buckling to another. Hence, the ability of such elements to be reusable for multiple loading cycles exists. Such unique properties made the metamaterial systems a perfect candidate for structural applications such as impact protection of bridges against collision. This research provides innovative metamaterial shell structure that can exhibit negative stiffness behavior by deforming from one shape …

Minimizing The Negative Effect Of Pumping On Scc Freeze-Thaw Durability, Daniel Galvez-Moreno

Doctoral Dissertations

“The durability of concrete must be ensured to reduce the carbon footprint of the production of portland cement. If concrete is properly designed to preserve its integrity under adverse exposure conditions, the service life of the material can be extended with minimum maintenance. Nevertheless, bad handling, placing, finishing or curing practices can abate the durability potential and service life of even the best mix design. Pumping concrete is a very efficient placing technique that offers significant cost reduction and versatility at the jobsite, but it also has the potential of altering the air void system parameters, which are key to …

Complexities Observed During The Development Of A Rheological Testing Procedure For Small Cement Paste Samples, Aida Margarita Ley-Hernandez

Doctoral Dissertations

“Rheology has been widely used to describe the flow properties of fresh cement-based suspensions. The use of a rheometer to characterize these properties is not a straightforward task due to the dependency to different preparation conditions, mixing processes, testing procedures and measuring instruments employed. In addition, shear and time dependency of the material which undergoes chemical and physical particle bonding, caused by hydration of cement and flocculation. Nevertheless, the characterization and understanding of the rheological behavior of cement-based materials have become essential with the recent introduction of novel applications like digital construction in the field of civil engineering, among others. …

Structured Catalysts Designed And Manufactured By 3d-Printing Technique For Functional Integration Of Catalytic Systems, Fatima Magzoub

Doctoral Dissertations

"Microporous zeolites are widely used as heterogeneous catalysts in a wide variety of chemical and petrochemical industries to produce value-added chemicals and fuels, owing to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity.

The overall goal of this research was to shape engineer composite zeolites and fine-tune their physiochemical properties to improve the catalytic production of dimethyl ether (DME) and light olefins that are typically used as substitution to diesel fuel and polymer precursors, respectively. Specifically, HZSM-5 and silicalite-1 zeolites were formulated into monolithic contactors using 3D printing technique, followed by subsequent SAPO-34 crystals growth through …

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Additive Manufacturing Of Customized Lithium-Ion Batteries: Process Fundamentals And Applications, Xiaowei Yu

Doctoral Dissertations

“In the pasting decades, considerable efforts have been spent in developing the next-generation lithium-ion batteries (LIBs), from advanced active materials to new manufacturing methods. The development of additive manufacturing (AM) has brought new opportunities to LIBs. In this work, two AM methods are introduced for fabricating electrodes of LIBs. The first method is aerosol printing, which is a solvent-based wet additive method. Whereas the second method is a solvent-free, dry printing method. The commonly used materials for current collectors and active materials (including cathodes and anodes) of LIBs are aerosol printed and the electrochemical functionalities of the printed materials are …

Analysis And Modeling Of Power Supply Induced Jitter For High Speed Driver And Low Dropout Voltage Regulator, Yin Sun

Doctoral Dissertations

”With the scaling of power supply voltage levels and improving trans-conductance of drivers, the sensitivity of drivers to power supply induced delays has increased. The power supply induced jitter (PSIJ) has become one of the major concerns for high-speed system. In this work, the PSIJ analysis and modeling method are proposed for high speed drivers and the system with on-die low dropout (LDO) voltage regulator. In addition, a jitter-aware target impedance concept is proposed for power distribution network (PDN) design to correlate the PSIJ with PDN parasitic.

The proposed PSIJ analysis model is based on the driver power supply rejection …

Investigation Of Urea Decomposition And Deposit Formation In Diesel Exhaust After-Treatment System, Anand Alembath

Doctoral Dissertations

“Urea-selective catalytic reduction (SCR) system has proved to be an effective solution to reduce NO_x emissions in commercial vehicle (CV) diesel engines. A significant challenge in urea injection is to comprehend its decomposition chemistry that leads to formation of undesired deposits in the exhaust system unit. Due to complex interaction of multi-phase fluid flow and transport processes, significant uncertainty is associated with the identification of interacting factors that control the deposit initiation and its growth. To meet the future ultra-low NO_x emissions and to deliver ammonia without deposit formation, there is an imminent need to develop the urea-SCR …

Fabrication And Characterization Of Multifunctional Composites, Aditya R. Thakur

Doctoral Dissertations

“This study details the research to facilitate fabrication and characterization of novel structural composites reinforced with carbon fibers. Across industries, materials with high performance-to-weight ratio are sought after. Using carbon fibers as secondary phases in these proposed composites, specific characteristics can be tailored in these materials to manufacture strong, lightweight, high performance structures. The first part of the research focused on the improvement in the mechanical properties of the composites using carbon fiber reinforcement. As a part of this study, toughened ceramic composites with predictable failure patterns were produced using carbon fiber inclusions. A closed-form analytical model was developed to …

Finite Time Suboptimal Control Design Of Nonlinear Systems With Θ-D Technique And Implementation To Aerospace Applications, Jie Yao

Doctoral Dissertations

“A finite time suboptimal control strategy (named θ - D approximated algorithm) was proposed in this study, which can provide the control engineers with a novel effective and efficient design tool from the finite time optimal perspective. Based on the framework of this proposed method, the original nonlinear dynamics were formulated in pseudo-linear form, and the performance index was denoted by a linear quadratic regulator prototype in this research. After that, the approximated solutions to intractable Hamilton-Jacobi-Bellman (HJB) equation were acquired by putting vanishing perturbation terms into the performance index. By tuning the parameters in perturbation terms, semi-global stability and …

Design And Fabrication Of Field-Effect Iii-V Schottky Junction Solar Cells, Amirhossein Ghods

Doctoral Dissertations

“A new concept of field-effect photovoltaic devices with a focus on design and fabrication of single and multi-junction solar cells using III-V materials has been shown and proved. Schottky solar cells based on metal-(insulator)-semiconductor (M-I-S) structure have been designed and fabricated using various wide bandgap semiconductors, such as GaAs and Al_0.3Ga_0.7As. A secondary bias layer has been introduced to the device structure, in which it creates additional band bending and subsequently depletion region at the flat band regions on the top surface of the device. It should be mentioned that the bias layer is designed to …

Investigation Of Wide Bandgap Semiconductors For Room Temperature Spintronic, And Photovoltaic Applications, Vishal Saravade

Doctoral Dissertations

"Suitability of wide bandgap semiconductors for room temperature (RT) spintronic, and photovoltaic applications is investigated.

Spin properties of metal-organic chemical vapor deposition (MOCVD) – grown gadolinium-doped gallium nitride (GaGdN) are studied and underlying mechanism is identified. GaGdN exhibits Anomalous Hall Effect at room temperature if it contains oxygen or carbon atoms but shows Ordinary Hall Effect in their absence. The mechanism for spin and ferromagnetism in GaGdN is a combination of intrinsic, metallic conduction, and carrier-hopping mechanisms, and is activated by oxygen or carbon centers at interstitial or similar sites. A carrier-related mechanism in MOCVD-grown GaGdN at room temperature makes …

Geophysical Assessment Of The Lake Chesterfield Site, Missouri, Diya Ali Ahmad Alfuqara

Doctoral Dissertations

"Since construction of the Lake Chesterfield, Missouri in 1986, significant leaks have occurred causing the lake to lose substantive volumes of water. Mitigation efforts, have not solved the problem. Indeed, in June of 2017, the water level in Lake Chesterfield dropped at an alarmingly rapid rate. Prior to authorizing additional mitigation work, the Lake Chesterfield. Home Owners Association (LCHOA) decided to acquire geophysical data across the drained and dry lake bed. These information would help a geotechnical engineering firm determine the most appropriate mitigation plan.

In the summer of 2018, electrical resistivity tomography, multichannel analysis of surface wave, and spontaneous-potential …

Imaging In Karst Terrain Using The Electrical Resistivity Tomography (Ert) And Multi-Channel Analysis Of Surface Waves (Masw) Methods, Hassan Abdullah Alzahrani

Doctoral Dissertations

"Electrical Resistivity Tomography (ERT) and Multi-channel Analysis of Surface Waves (MASW) methods were used to image the subsurface in karst terrain in the southeast of Missouri. A SuperSting R8 system was used to acquire the ERT profiles; a multi-channel engineering seismograph was used to acquire the MASW data. The latter data were used to constrain and verify the ERT interpreted depth to top-of-rock and soil thickness. The ERT data were used to delineate the soil/rock interface and to identify zones of anomalously high moisture content within the bedrock.

The primary objective of the research was to determine the cause of …

Physical And Biological Factors Affecting Oxygen Transfer In The Activated Sludge Wastewater Treatment Process, Kenneth A. Campbell

Doctoral Dissertations

“The activated sludge (AS) process is widely utilized for wastewater treatment due to its versatility and general resiliency, but is energy intensive, requiring aeration and mixing energy inputs to maintain the biochemical reaction and optimize treatment performance. This study is focused on determining different factors that influence oxygen transfer and consequently its energy demand.

AS morphology, as described by the d₁₀, d₂₀, d₃₂, specific filament length (SFL), 30 min settleability (SV₃₀), etc., does influence the OTE. Filamentous organisms increase the hydrodynamic radius of suspended particles, which dilates mixed liquor apparent viscosity (µ …

Factors Impacting The Transport And Enhanced Oil Recovery Potential Of Polymeric Nanogel In Sandstone, Haifeng Ding

Doctoral Dissertations

"Enhanced oil recovery (EOR) using nanometer-sized particles has drawn great attention in the oil industry because of their various advantages brought by size. However, their applications on a field scale are very limited, especially for deformable nanoparticles. The objective of this research is to explore the transport behavior of deformable polymeric nanoparticles (nanogel), the factors impacting these behavior, and their EOR potentials. First, 240 published nanoparticle core flooding experiment data were collected and analyzed about the extent to what the nanoparticles can improve oil recovery. Results show that on the laboratory scale the incremental oil recovery could be as high …