Engineering Commons^™

Transformation Of Uranium In A Geological Environment, Derrell Hood

All Theses

Incorporation of uranium into iron oxide minerals is a promising mechanism for the environmental immobilization of U(VI). In this study, synthesized hematite was doped with uranium and analyzed with SEM-EDS, TEM, XRD, and ICP-MS. The results of this analysis strongly indicate uranium incorporation into the mineral, as well as the possible presence of a co-precipitated uranium mineral clarkeite. Preliminary results also shows an increase in the amount of uranium associated with the hematite particles as a function of mineral aging. Cyclic Voltammetry (CV) was used to induce and characterize electrochemical changes of uranium in the doped hematite system; these changes …

Optimizing Light Collection From Extractive Scintillating Resin In Flow-Cell Detectors, Amy Meldrum

All Theses

The objectives of this study were to investigate the changes in light collection efficiency for flow cell detector as various parameters are altered to find the optimum flow cell configuration. Columns with inner diameters of 0.16 cm, 0.48 cm, 0.79 cm, and 1.11 cm were packed with synthesized nonporous, un-functionalized beads to measure their detection efficiencies for solutions containing 210Po, 14C, or 90Sr/90Y. The average diameter of the beads used in the experiments was 147 µm ± 33 µm. The highest detection efficiency for 210Po was 15.3 ± 3.9% with the 1.11 cm diameter column. The 1.11 cm diameter column …

Thermo-Physical Property Models And Effect On Heat Pipe Modelling, Devakar Dhingra

All Theses

Heat transfer devices find applications in various aspects of life. Be it residential, commercial or industrial application, efficient heat transfer is a challenge to all. Other than geometric design considerations and wick selection, the optimization of heat transfer in the heat pipe also depends on fluid selection. Heat pipe technology has proven to work efficiently with properly selected thermal fluid, from cryogenic temperatures to very high temperatures. Higher heat transfer ability through small temperature differences makes the heat pipe an efficient technology. Hence, it can be stated that selecting a proper working fluid enhances the heat transfer performance of a …

Using Gis To Prioritize Green Infrastructure Installation Strategies In An Urban Watershed, Lauren Owen

All Theses

This study seeks to quantify runoff volume generation and peak flow rates from the urban Sand River Headwaters to determine the most effective placement of additional green infrastructure in Aiken, SC. ArcMap 10.1, HEC-GeoHMS, and HEC-HMS were used to delineate a total outlet watershed along with subwatershed(s) for urban stormwater infrastructure system by 'burning' the stormwater system at an artificial elevation below the existing topologically-based Digital Elevation Model (DEM). The result was a higher resolution DEM that allowed for storm routing and subsequent volume and flow predictions compared to that based on the original DEM created by using Light Detecting …

Stochastic Wavenumber Estimation: Damage Detection Through Simulated Guide Lamb Waves, Garrison Stevens

All Theses

Structural Health Monitoring (SHM) is a field of research that seeks to identify the onset of damage in infrastructure systems such that catastrophic failures can be averted. Acoustic Wavenumber Spectroscopy (AWS) is an emerging SHM technique that can identify and locate change of thickness resulting from damage in thin plates through the estimation of the characteristic wavenumber. AWS measures the ultrasonically induced vibrations of thin plates by laser scanners and monitors the propagation of Rayleigh-Lamb waves through the structure. This method is particularly suitable for thin-walled structures such as those contained in pipes, airplanes, and wind turbine blades. While AWS …

Fabrication And Characterization Of Magnetic Nanoparticle Composite Membranes, Akeem Cruickshank

All Theses

To effectively and accurately deliver drugs within the human body, both new designs and components for implantable micropumps are being studied. Designs must ensure high biocompatibility, drug compatibility, accuracy and small power consumption. The focus of this thesis was to fabricate a prototype magnetic nanoparticle membrane for eventual incorporation into a biomedical pump and then determine the relationship between this membrane deflection and applied pneumatic or magnetic force. The magnetic nanoparticle polymer composite (MNPC) membranes in this study were composed of crosslinked polydimethylsiloxane (PDMS) and iron oxide nanoparticles (IONPs). An optimal iron oxide fabrication route was identified and particle size …

A Device To Record Naturally Daily Wrist Motion, Surya Sharma

All Theses

We introduce a new device to record and store wrist motion activity data. The motivation to create this device was the fact that this data can be used to detect periods of eating or the number of bites consumed. There is no similar device available in the market. This device uses new components that have been recently introduced to the market, and newer techniques that can be used for low quantity production. The production cost for this device was $52, similar to other fitness trackers on the market. The device was capable of recording wrist motion activity for 24 hours …

Geotechnical Analysis Of The Foundation Of Fort Sumter National Monument Using Numerical Modeling, Daniel Kyser

All Theses

The foundational condition of the historical coastal fortification of Fort Sumter in Charleston, SC was analyzed though the use of numerical modeling. In this study, two-dimensional Finite Element (FE) analyses were conducted to assess the stability of the foundation-casemates-wall system in a coupled manner subjected to potential loadings such as ocean waves, storm surge and earthquake. The finite element model was verified by modeling the historical events (construction between 1820 and 1860, demolition due to artillery bombardment, reconstruction, earthquake, building of the Battery Huger, and the removal of fill from the parade ground) since the construction of the fort in …

Characterizing Navigational Tools In A Virtual Search Task, Austin Riggs

All Theses

The goal of this thesis is to characterize and empirically compare navigational tools in the context of a virtual inspection task. The framework considers both directional-cue navigational tools (e.g., GPS navigation arrows) and trail navigational tools (e.g.,footprints) in comparison to a control condition. Characterizing the tools allows for documented relationships between specific navigational tool-performance combinations. It is intended that by characterizing and comparing the tools a more advantageous use of navigational tools will emerge to increase the benefit provided to both the users and implementers of virtual environments. The focus of the metrics in the paper were distance traveled, speed …

Combined Numberical And Experimental Assessment Of Steel Roof Decks Subjected To Windborne Debris, Robert Roper

All Theses

In the summer of 2013, a steel roof deck manufacturer (Company A) approached Clemson University about testing their steel roof decking product to evaluate the performance of the steel roof deck to resist impact from tornado windborne debris using FEMA P-361 Design and Construction Guidance for Community Safe Rooms. To assist Company A in better serving their customers in areas prone to severe wind events and to facilitate use of their products in community safe rooms, debris impact tests were conducted on two cold-formed corrugated steel roof decking products. Community safe rooms are buildings that are constructed in accordance with …

A Model Of The Diurnal Variation In Lake Surface Temperature, Jonathan L. Hodges

All Theses

Satellite measurements of water surface temperature can benefit several environmental ap-plications such as predictions of lake evaporation, meteorological forecasts, and predictions of lake overturning events, among others. However, limitations on the temporal resolution of satellite mea-surements restrict these improvements. A model of the diurnal variation in lake surface temperature could potentially increase the effective temporal resolution of satellite measurements of surface tem-perature, thereby enhancing the utility of these measurements in the above applications. Herein, a one-dimensional transient thermal model of a lake is used in combination with surface tempera-ture measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument aboard the …

Design Of A Sign-Out Process To Improve Surgical Safety, Sumonthip Chompoodang Gmitro

All Theses

According to the World Health Organization (WHO), the surgical safety checklist consists of three parts; sign-in, time-out and sign-out. It has been observed that the sign-out process is the least frequently completed. In this study, because of a concern for the risk of adverse events occurring in the OR, the sign-out process used in a local hospital was redesigned as a web-based application embedded on a desktop computer and on a mobile device. Both web-based platforms were tested along with the current sign-out process on a computer. Eighteen circulating nurses in the operating rooms of Greenville Memorial Hospital used each …

An Examination Of Radionuclide Transport In The Vadose Zone Using Field Lysimeters, Michael Witmer

All Theses

Understanding how radionuclides interact in the subsurface is important for the remediation of contaminated sites, assessment of risk due to radioactive waste disposal, and designing new radioactive waste management strategies. The current understanding of the geochemical behavior of radionuclides in the subsurface and more specifically the vadose zone has been developed through reactive transport modeling supplemented by laboratory experiments. Interactions between radionuclides with the mineral particles and organic matter in the vadose zone can be very complex and while laboratory experiments produce valuable data, few controlled, intermediate scale transport studies have been performed. In order to accurately predict vadose zone …

Development Of An In Vitro System For Evaluation Of Prosthetic Vein Valves, Ross Gorman

All Theses

Chronic venous insufficiency is a chronic disorder where venous pressure is not reduced during exercise. In a healthy individual, the vein valves and muscle pumps of the extremities combine to allow for a reduction in venous pressure during exercise. Consistent high pressure in the leg can lead to disability, pain, and ulcer formation. Typical causes of chronic venous insufficiency are venous reflux and acute venous obstruction. Research is under way to develop a prosthetic vein valve that can easily be implanted with a minimally invasive catheter procedure which addresses chronic venous insufficiency. This thesis discusses development of an in vitro …

Dendritic Polymers As Biocompatible Oil Spill Dispersants: Effectiveness And Mechanisims With Crude Oil, Ying Tu

All Theses

Dendritic polymers have recently been shown to entrap polycyclic aromatic hydrocarbons (PAHs) and other hydrophobic materials. Laboratory results have shown that poly(amidoamine) dendrimers and hyperbranched poly(ethyleneimine) polymers form complexes with linear (hexadecane) and polyaromatic (phenanthrene) hydrocarbons, increasing the dispersion of these model crude oil components. It is thus hypothesized that crude oil can be dispersed using these polymers. Compared with commercial dispersants, dendritic polymers have the potential to be more biocompatible and less toxic. The objective of this research was to gain a fundamental understanding of the interactions of dendritic polymers with crude oil. We used Louisians Sweet Crude oil …

Electrokinetic Instabilities In Ferrofluid Microflows, Dhileep Thanjavur Kumar

All Theses

Lab-on-a-chip devices have been increasingly used in the past two decades for chemical and biomedical analysis. These devices employ the concepts of microfluidics and offer the promise of incorporating multiple laboratory processes onto a single portable chip. Electric field has been often employed in microfluidic devices for the ease of fluid and sample control as well as the convenience of chip integration and interfacing. Flow instabilities can take place when two fluids of unequal electrical properties are pumped through a microchannel under the application of an adequately strong electric field. The study of these electrokinetic instabilities in microfluidic devices is …

Pharmacists' And Patients' Perceptions Of Role Of Pharmacist In Discharge Process, Ravi Teja Vempati

All Theses

The objective of this study was to identify the perceptions of both patients and pharmacists about the pharmacist's role in the hospital discharge process. In order to do this, observations were conducted with the patients and interviews were conducted with both patients and pharmacists. During the interviews, both the patients and pharmacists were asked about the pharmacist's role in the hospital discharge process. The interviews were qualitatively analyzed using the in vivo technique. Four high-level themes emerged from this study: Current role of a pharmacist in the hospital, Ideal role of a pharmacist in the discharge process, Pharmacists' perceptions of …

Space-Capable Long And Thin Continuum Robotic Cable, Manas Milind Tonapi

All Theses

Design of continuum robots, i.e. robots with continuous backbones, has been an active area of research in robotics for minimally invasive surgery, search and rescue, object manipulation, etc. Along the same lines, NASA developed "Tendril", the first long and thin continuum robot of its kind, intended for in-space inspection applications.

The thesis starts with describing and discussing the key disadvantages of the current state of the art mechanical design of "Tendril'' producing undesirable effects during operation. It then includes the design specifics of a novel concept for construction of a next generation long and thin, space-cable, multi-section, continuum cable-like robot, …

Fatigue-Induced Failure In Horizontal-Axis Wind-Turbine (Hawt) Blades And Hawt Drivetrain Gears, Varun Chenna

All Theses

Wind energy is one of the most promising and the fastest growing installed alternative-energy production technologies. In fact, it is anticipated that by 2030, at least 20% of the U.S. energy needs will be met by various onshore and offshore wind-farms [a collection of wind-turbines (converters of wind energy into electrical energy) at the same location]. A majority of wind turbines nowadays fall into the class of the so-called Horizontal Axis Wind Turbines (HAWTs). Turbine blades and the gearbox are perhaps the most critical components/subsystems in the present designs of HAWTs. The combination of high failure rates (particularly those associated …

Adsorption Of Halogenated Aliphatic Contaminants By Graphene Nanomaterials: Comparison With Carbon Nanotubes And Granular Activated Carbons, Yang Zhou

All Theses

Graphene nanomaterials are two-dimensional single layer sp2 hybridized carbon atoms densely packed in a hexagonal honeycomb lattice and can be visualized as basic building blocks for fullerenes, carbon nanotubes (CNTs), and graphite. In addition, they are hydrophobic nanomaterials and possess a large specific surface area (SSA), thus they have been evaluated as promising adsorbents to remove synthetic organic compounds (SOCs) from water. As with granular activated carbons (GACs) and CNTs, adsorption behavior of SOCs on graphene depends on the physicochemical properties of the adsorbents (e.g., specific surface area, pore size distribution and surface chemistry), SOCs (e.g., hydrophobicity, molecular size and …

A Load-Based Approach To Forming A Connected Dominating Set For An Ad Hoc Network, Raihan Hazarika

All Theses

Efficient routing in mobile ad hoc networks (MANETs) is highly desired and connected dominating sets (CDS) have been gaining significant popularity in this regard. The CDS based approach reduces the search for a minimum cost path between a pair of source and destination terminals to the set of terminals forming the backbone network. Researchers over the years have developed numerous distributed and localized algorithms for constructing CDSs which minimize the number of terminals forming the backbone or which provide multiple node-disjoint paths between each pair of terminals. However none of this research focuses on minimizing the load at the bottleneck …

Design And Demonstration Of A Two-Dimentional Test Bed For Uav Controller Evaluation, Ran Huang

All Theses

A three degree-of-freedom (DOF) planar test bed for Unmanned Aerial Vehicle (UAV) controller evaluation was built. The test-bed consists of an instrumented tether and an experimental twin-rotor, planar UAV mounted with a one DOF manipulator mounted below the UAV body. The tether was constructed to constrain the UAV under test to motion on the surface of a sphere. Experiments can be conducted through the tether, approximating motion in a vertical plane by a UAV under test. The tether provides the means to measure the position and attitude of the UAV under test. The experimental twin-rotor UAV and one-link on-board manipulator, …

The Use Of Oxidants For Ndma Precursor Deactivation In Wastewater Treatment, Jaclyn Lauer

All Theses

Water treatment plants in the United States (US) have been switching from chlorination to chloramination in the search for a disinfection process to reduce formation of regulated disinfection by-products (DBPs). Unfortunately, the trade-off is the formation of N-nitrosamines. N-nitrosodimethylamine (NDMA) is the most commonly detected N-nitrosamine in US distribution systems. In the Integrated Risk Information Service (IRIS) database of the United States Environmental Protection Agency (USEPA), NDMA has been identified to have an estimated 10-6 lifetime cancer risk level at a concentration of 0.7 ng/L in drinking water. N-nitrosamines are currently not regulated by the USEPA; however, are listed on …

Decentralized Water Systems For Sustainable And Reliable Supply, Suraj Goverdhanam

All Theses

The water industry is under enormous pressure to provide potable water in circumstances of increasing demands due to population growth, lifestyle change of people and depleting freshwater resources. Deteriorating infrastructure makes the task of meeting the human water consumption needs even more challenging. Distributed water supply systems are currently pursued as a sustainable alternative in arid regions of US to exploit the potential of water reclamation at community or district level to reduce the dependence on freshwater resources. An extension of such a distributed water supply alternative is a complete decentralized supply, which requires on-site water reclamation. The intention of …

Development Of Poly(Lactic Acid)-Poly(Ethylene Glycol) Nanoparticles For The Delivery Of Non- Toxic Drug In Combination Therapy For The Treatment Of Glioblastoma And Neuroblastoma, Olivia Grace Decroes

All Theses

Glioblastoma and neuroblastoma are both solid-form tumors. Glioblastomas primarily reside in the brain, while neuroblastomas are found in the sympathetic nervous system. Both glioblastoma and neuroblastoma re classified as orphan diseases, which affect less than 200,000 individuals a year. Over the course of 5 years, 40% of patients diagnosed with neuroblastomas and only 6% of patients diagnosed will glioblastomas will be living.^73,74. Glioblastoma and neuroblastoma tumors possess a gene known as MGMT. MGMT is used by tumors as a DNA repair mechanism, which increases the likelihood these tumors will become resistant to traditional drug therapies.^28,37 Other pathways, …

Spatial And Temporal Analysis Of Land Cover Change, Sedimentation And Water Quality In The Lake Issaqueena Watershed, South Carolina, Cassie Pilgrim

All Theses

Soil erosion and increased sediment yields within a watershed lead to impaired water quality, decreased availability of wildlife habitat and reduced recreational opportunities. While some sedimentation occurs naturally within a water system, most erosion processes are the result of anthropogenic activities across a landscape, namely changes in land use and land cover (LULC). This study was conducted to determine temporal and spatial sedimentation trends in the Lake Issaquena watershed using sonar logging equipment, geographic information systems (GIS) and limited hydrologic data from the Soil Conservation Service (1941 and 1949). Sediment deposition was analyzed in relation to several key factors that …

Potential Effects Of Geologic Storage Of Co2 On Surface Water And Shallow Groundwater, Shuangshuang Xie

All Theses

ABSTRACT Storage of supercritical phase CO2 in deep saline aquifers is being considered to reduce greenhouse gases in the atmosphere, and this process is expected to increase the pressure in these deep aquifers. One potential consequence of pressurization is an increase in the upward flux of saline water. Saline groundwater occurs naturally at shallow depths in many sedimentary basins, so an upward flux of solutes could degrade the quality of aquifers, and threaten aquatic ecosystems where groundwater discharge is important. The objective of this research is to evaluate the impacts associated with increasing the upward flux of saline water as …

Synthesis Of Silicon Carbide Fibers From Polycarbosilane By Electrospinning Method, Yuan Yue

All Theses

Silicon carbide (SiC) is widely used in many fields due to its unique properties. Bulk SiC normally has a flexural strength of 500 - 550 MPa, a Vickers hardness of ~27 GPa, a Young's modulus of 380 - 430 GPa, and a thermal conductivity of approximately 120 W/mK. SiC fibers are of great interest since they are the good candidates for reinforcing ceramic matrix composites (CMCs) because of the weavability and high temperature strength of about two to three GPa at about 1000 °C. Silicon carbide fibers have been synthesized from polycarbosilane (PCS) with ~25 μm diameter using the melt-spinning …

Adhesion Of Liquids To Porous Materials And Fibers, Artem Trofimov

All Theses

This research is centered on the analysis of adhesion properties of porous materials and fibers of elliptical shapes. Composites are a unique class of materials having properties, which could not be achieved by either of the constituent materials alone. Composites with porous filler are put into service in buildings, roads, bridges, etc. Fiber-reinforced composites are actively involved in flight vehicles, automobiles, boats, and dozens of other products. In the first part of this study we developed a procedure for evaluation of adhesion of liquids to porous solids, where water, hexadecane and asphalt binder and different rocks were studied to illustrate …

The Impact Of Block Scheduling And Release Time On Operating Room Efficiency, Rebecca Weiss

All Theses

Planning for sufficient surgical capacity at a hospital requires that many tactical and operational decisions be made before the day of surgery. Typically, blocks of time in operating rooms (ORs) are assigned and specific surgical cases are placed in rooms. The hospital monitors utilization to determine the schedule's effectiveness in balancing the risk of overtime with idle time. In this thesis, we will examine how adjusting schedule risk ratios and penalty values, and providing shared, open posting time affected the hospital's ability to identify an efficient but high quality and low cost block schedule. The proposed schedules were tested by …