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Full-Text Articles in Engineering

Synthesis And Dielectric Properties Of Nanocrystalline Barium Titanate And Silver/Barium Titanate Particles, Hiroki Maie May 2008

Synthesis And Dielectric Properties Of Nanocrystalline Barium Titanate And Silver/Barium Titanate Particles, Hiroki Maie

All Theses

The increasing needs for further functionality, higher performance, and miniaturization of electronic devices have highly demanded down-size and volume-efficiency of electronic components such as multilayer ceramic capacitors (MLCCs). To meet this demand, the use of high dielectric constant material with nanometer size and spherical shape is considered as requirements. Embedded capacitors are an important emerging technology for meeting the performance and functionality requirements of next-generation electronic devices. One major obstacle for implementing this technology is the scarcity of dielectric materials with appropriate dielectric and mechanical properties was mainly discussed

Considering these backgrounds, this research is devoted to synthesis of high …


Factors Affecting The Performance Of Brick Veneer Construction, Jocelyn Dickie May 2008

Factors Affecting The Performance Of Brick Veneer Construction, Jocelyn Dickie

All Theses

The first topic focused on in this report is the height restriction imposed by the masonry standard for brick veneer on wood frame backing. The current US standard (ACI 530-05/ASCE 5-05/TMS 402-05 Building Code Requirements for Masonry Structures) does not allow brick veneer to extend more than thirty feet above the foundation when supported by wood framing. These prescriptive requirements are compared with those of the Canadian (CSA 304.1-04) and Australian (AS 3700-2001) masonry standards. The logic found for this height restriction is based on the vertical differential movement caused by moisture and thermal expansion of the brick veneer and …


Immobilization Of Biomolecules On Polymer Scaffolds: A Novel Approach, Joshua Barringer May 2008

Immobilization Of Biomolecules On Polymer Scaffolds: A Novel Approach, Joshua Barringer

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In this thesis, I describe the successful development of a procedure for the step-by-step formation of a multi-layer polymer scaffold on a silicon wafer and the characterization of these materials. Also discussed is the development of a procedure for the non-site specific attachment of a biomolecule to the modified silicon wafer, including scaffolds modified via drop-on-demand, DOD, inkjet printing. Ellipsometry, x-ray photoelectron spectroscopy (XPS), FTIR, fluorometry, and static water contact angle measurements are used to study the nanoscale structure and properties of the interfacial, thin film-modified surfaces. Polymers based on 2-vinyl-4,4-dimethylazlactone (VDMA) are used as the platform onto which biomolecules …


Analysis And Experiments For Tendril-Type Robots, Lara Cowan May 2008

Analysis And Experiments For Tendril-Type Robots, Lara Cowan

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New models for the Tendril continuous backbone robot, and other similarly constructed robots, are introduced and expanded upon in this thesis. The ability of the application of geometric models to result in more precise control of the Tendril manipulator is evaluated on a Tendril prototype. We examine key issues underlying the design and operation of 'soft' robots featuring continuous body ('continuum') elements. Inspiration from nature is used to develop new methods of operation for continuum robots. These new methods of operation are tested in experiments to evaluate their effectiveness and potential.


Improved Closed-Form Bounds On The Performance Of Convolutional Codes With Correlated Rayleigh Fading, Dwight Hutchenson May 2008

Improved Closed-Form Bounds On The Performance Of Convolutional Codes With Correlated Rayleigh Fading, Dwight Hutchenson

All Theses

New bounds on the probability of bit error are presented for a coded communication system with binary antipodal modulation and soft-decision maximum-likelihood decoding over a correlated Rayleigh-fading channel. The bounds are closed-form expressions in terms of the code's transfer function; they are illustrated by considering a system using convolutional encoding. A long-standing conjecture regarding the worst-case error event in correlated Rician fading is proven for the special case of correlated Rayleigh fading, and it is used in the development of some of the new bounds. The bounds are shown to be tighter than previously developed closed-form bounds for communications using …


Analysis Of The Impact Of Fuel Price And Bidding Volume On The Engineer's Estimate, Greaton Sellers May 2008

Analysis Of The Impact Of Fuel Price And Bidding Volume On The Engineer's Estimate, Greaton Sellers

All Theses

The research project 'Analysis of the Impact of Fuel Price and Bidding Volume on the Engineer's Estimate' was initiated by the South Carolina Department of Transportation and conducted by Clemson University. This research was executed as a two part study, 'Best Practices for Developing the Engineer's Estimate', which addressed two distinct but related objectives. The first research objective was to fully explore the advantages and disadvantage of alternative methodologies utilized to compile the engineer's cost estimate. This research objective is addressed in Report Volume I. The second research objective, which is addressed in this Report Volume II, was to develop …


Surface Functionalized Colloidal Particles And Polymer Synthesis For Led Based Applications, Zachary Hunt May 2008

Surface Functionalized Colloidal Particles And Polymer Synthesis For Led Based Applications, Zachary Hunt

All Theses

Over the last decade atom transfer radical polymerization, ATRP, has become a commonplace route by which tailored polymers can be synthesized. The advent of this polymerization mechanism has enabled the controlled synthesis of block and multi-block polymer systems that maintain a terminal bromine functionality that adds further versatility to the synthesized polymers.
Additionally, in the last few years 'click' chemistry has come to light as an efficient method of selectively linking molecules under mild conditions (e.g. room temperature and aqueous systems). In particular, the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction has become more and more popular, and provides another route by …


The Awe Wall: A Novel Robotic Surface, Martha Kwoka May 2008

The Awe Wall: A Novel Robotic Surface, Martha Kwoka

All Theses

In this thesis, we present fundamental contributions towards AWE, a novel 'Animated Work Environment', which seeks to introduce robotics at the architectural scale to modify environments in real time to the changing needs and moods of their occupants. Part of AWE is a robotic surface, or wall, featuring a multiple folding panel structure. The panels of the AWE wall feature embedded IT and adapt to the current movements and tasks of the user. We describe the overall AWE concept and discuss the construction of the robot surface, its motion planning and its control, and all experiments run to this point.


On New Applications And Sensitivity Enhancement Of Cantilever-Based Sensing Systems, Calvin Bradley May 2008

On New Applications And Sensitivity Enhancement Of Cantilever-Based Sensing Systems, Calvin Bradley

All Theses

Cantilever-based Sensing Systems (CSS) have become a focal area for research with the rise of micro- and nanotechnology. History has led us to use cantilever beams as one of the foremost sensing devices for small scale applications, beginning with the atomic force microscopy, and then being expanded into numerous sensor devices. The CSS include such applications as accelerometers, thermal and chemical sensors which are expanding into the applications of mass sensing and material characterization. Soon, this technology may be used in 'lab on chip' biosensing applications.
This study covers the experimentation into new CSS applications and sensitivity enhancement. In order …


The Formation Of Halonitromethanes In Wastewater Treatment Plant Effluents, Jesse Addison May 2008

The Formation Of Halonitromethanes In Wastewater Treatment Plant Effluents, Jesse Addison

All Theses

Disinfection by-products (DBPs) have been a water treatment concern since their discovery in the 1970's. Today, only eleven drinking water DBPs are regulated by the Environmental Protection Agency (EPA). However, over 500 DBPs have been identified in drinking waters with advances in analytical methods within the last two decades. Halonitromethanes (HNMs) were among the fifty-plus unregulated high-priority DBPs that were monitored for and detected in drinking waters in a recent nationwide occurrence study funded by EPA. The toxicology studies conducted in recent years showed that HNMs are one of the most cytotoxic and genotoxic classes among the emerging DBPs, and …


Ductile-Regime Machining Of Glass Using The Micromilling Process, Kevin Foy May 2008

Ductile-Regime Machining Of Glass Using The Micromilling Process, Kevin Foy

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Glass is a homogeneous material with amorphous crystal structure that is produced through the rapid cooling of its molten state below the glass transition temperature. Glass exhibits many excellent mechanical and physical properties, and it is widely used in automotive, communications, optics, electronics, architectural, and biomedical industries. For certain applications such as DNA microarrays, glass components with microfeatures are typically produced using a combination of photolithography and etching processes, which is generally time consuming and can involve hazardous chemicals. It would be ideal to fabricate some glass devices through mechanical micromachining for some rapid prototyping applications of glass-based devices, but …


A Systems Approach To The Design Of A Two Dimensional Cell Printer, Albert Hill May 2008

A Systems Approach To The Design Of A Two Dimensional Cell Printer, Albert Hill

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Tissue engineering research has the potential to improve the current opportunities for replacement organs and tissues. Precise placement of cells has proven difficult in the early stages of this research. Bioprinting is an important research area that has the potential to accurately position cells and biological materials for tissue engineering. This paper describes the attempt to obtain micrometer accuracy in the placement of cells using a systems approach and technology derived from the Hewlett Packard 500 series of printers and their cartridges the HP26 series. The paper discusses the research and design of a custom printing system that allows control …


Storm Water Export Of Nitrogen, Phosphorous, And Carbon From Developing Catchments In The Upper Piedmont Physiographic Province, Laura Reid May 2008

Storm Water Export Of Nitrogen, Phosphorous, And Carbon From Developing Catchments In The Upper Piedmont Physiographic Province, Laura Reid

All Theses

Impacts on water quality caused by land use change from forests and pastures to housing subdivisions were evaluated in catchments undergoing active development in the upper Piedmont physiographic province of South Carolina. Specific attention was focused on the export of nitrogen, phosphorus and carbon from these catchments during storm events. Three catchments with varying stages of development were compared to categorize the effects of land disturbance. Storm events occurring within a four year period of 2004 through 2007 were studied for changes in water quality within catchment streams. Due to the potential large input of surface runoff to streams following …


Investigating The Role Of Prototyping In Mechanical Design Using Case Study Validation, David Stowe May 2008

Investigating The Role Of Prototyping In Mechanical Design Using Case Study Validation, David Stowe

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The purpose of this research is to explore the application of prototyping in the design process through a case study analysis using structured interviews, an ethnographic study, and documents analysis, to determine what factors and practices result in successful prototyping. In doing so, research questions are established, a prototyping process is developed to assist the investigation, and classification systems are created to organize data collected in the study. As part of the case study, an interview is formulated to answer the proposed research questions and a literature survey of prototyping in design is used to create a larger analytical foundation. …


Computational Method For Solving Spoke Dynamics On High Speed Rolling Tweel, Kranti Kiran Manga May 2008

Computational Method For Solving Spoke Dynamics On High Speed Rolling Tweel, Kranti Kiran Manga

All Theses

Extensive studies have been conducted in the past to show that the characteristics of a non-pneumatic structure, the TweelTM are the same as the pneumatic tires. These characteristics include low contact pressure, low stiffness, low energy loss from obstacle impacts, low mass, and high load-carrying capacity. The TweelTM consists of a ring shaped shear beam comprised of two inextensible membranes separated by a relatively low modulus elastic material. This shear beam is connected to the hub by thin elastic spokes.
When used for high speed rolling applications, the TweelTM produces unacceptably high levels of acoustic noise. It has been suggested …


Random Road Analysis And Improved Gear Ratio Selection Of A Front Wheel Drive Drag Racing Car, Thomas New May 2008

Random Road Analysis And Improved Gear Ratio Selection Of A Front Wheel Drive Drag Racing Car, Thomas New

All Theses

Drag racing has been around since the 1950's and has become a very popular and very competitive sport. The difference between winning and losing can be hundredths and even thousandths of a second. Drag racing teams need every advantage they can get in order to excel in their field. On-track testing is very expensive and can consume large amounts of time and resources that a race team may not be able to afford.
One way to address this potential problem of high cost is by using computer simulation to show how your drag race car may perform at different tracks …


Odometry Correction Of A Mobile Robot Using A Range-Finding Laser, Thomas Epton Dec 2007

Odometry Correction Of A Mobile Robot Using A Range-Finding Laser, Thomas Epton

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Two methods for improving odometry using a pan-tilt range-finding laser is considered. The first method is a one-dimensional model that uses the laser with a sliding platform. The laser is used to determine how far the platform has moved along a rail. The second method is a two-dimensional model that mounts the laser to a mobile robot. In this model, the laser is used to improve the odometry of the robot. Our results show that the one-dimensional model proves our basic geometry is correct, while the two-dimensional model improves the odometry, but does not completely correct it.


Acceleration Of The Maturation Of Tissue Engineered Grafts By Dynamic Force Stimulation Or Gene Therapy, Shila Taylor Dec 2007

Acceleration Of The Maturation Of Tissue Engineered Grafts By Dynamic Force Stimulation Or Gene Therapy, Shila Taylor

All Theses

Over 16 million people suffer from osteoarthritis (OA). As the body ages OA and other cartilage diseases create an imbalance of anabolic and catabolic cell activities in cartilage and or over time the cartilage is damaged and wears away which creates lesion that resulting in pain. Most clinical surgeries are either temporary or have not gone through trials to test their success. For a long term solution researchers have been looking at replacing cartilage with a tissue engineered graft. One of the major problems to date has been is the strength of the scaffold.
Natural cartilage needs loading for its …


Property Measurements And Evaluation Of Heat Leak, Nathan Race Dec 2007

Property Measurements And Evaluation Of Heat Leak, Nathan Race

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Heat transport in capillary wick structures is an important parameter in loop heat pipe (LHP) design. The purpose of this study was to investigate the conductive heat leak in operating capillary wick structures. The heat leak is the portion of applied heat load conducted through the wick in spite of the convection of working fluid. Four sintered 316 stainless steel wicks were tested for porosity, effective thermal conductivity, pore size, and heat leak. Pore sizes were found to correlate well with the nominal pore size and pores were very narrowly distributed within a size range of approximately 1-10μm. Effective thermal …


Metalloporphyrin Catalyzed Degradation Of Pce: Effects Of Reductants, Buffers And Cosolvent Concentration, Sowmya Suryanarayanan Dec 2007

Metalloporphyrin Catalyzed Degradation Of Pce: Effects Of Reductants, Buffers And Cosolvent Concentration, Sowmya Suryanarayanan

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Reductive dechlorination of chlorinated organic contaminants using metalloporphyrins as catalysts may be an effective approach to treat widespread contamination. However, most previous studies have examined water-soluble rather than insoluble metalloporphyrins despite the fact that the latter category makes up the largest fraction found in nature. Recent studies have shown that addition of different cosolvents to water can activate otherwise non-reactive metalloporphyrin catalysts and facilitate the reduction of tetrachloroethylene (PCE), presumably by the mere process of making the otherwise insoluble metalloporphyrins dissolve in solution. Therefore, solubility has been advanced as a key factor in the ability of metalloporphyrins to catalyze organic …


Development Of The Impedance-Based Arc-Flash Determination Device (Iadd), Timothy Smith Dec 2007

Development Of The Impedance-Based Arc-Flash Determination Device (Iadd), Timothy Smith

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This thesis entitled, 'Development of the Impedance based Arc-Fault Determination Device (IADD)' details the development of a testing device that, when attached to an electrical node on the power system and through observations on voltage, current and phase shift with a step load change, determines the effective Thevenin or Norton impedance at the point of test. This thesis includes discussion of the theory and design process that enables the determination of an equivalent circuit, software development using National Instruments' LabView software development package and suggestions for future development.
The purpose of this thesis is to produce a device that can …


Evaluation Of A Computer Vision Traffic Surveillance System, Robert Graham Dec 2007

Evaluation Of A Computer Vision Traffic Surveillance System, Robert Graham

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This thesis presents an evaluation of the accuracy of a novel computer vision traffic sensor - developed by the Clemson University Electrical and Civil Engineering Departments - capable of collecting a variety of traffic parameters. More specific, the thesis examines how the camera height and distance from the travel way affects the accuracy. The details of the quantitative and qualitative evaluations used to validate the system are provided. The parameters chosen to evaluate were volume, vehicle classification, and speed. Experimental results of cameras mounted at heights of 20 and 30 feet and a lateral distance of 10 and 20 feet …


Bacterial Auto-Aggregation And Co-Aggregation In Activated Sludge, Fei Chen Dec 2007

Bacterial Auto-Aggregation And Co-Aggregation In Activated Sludge, Fei Chen

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Microbial auto-aggregation and co-aggregation, leading to biofilm or floc formation, widely occur in natural systems. This study was conducted to investigate the extent of bacterial auto-aggregation and co-aggregation in activated sludge and their contributions in activated sludge floc formation. In this study, an activated sludge sample was separated into a supernatant part (planktonic community) and a sediment part (floc community) by centrifugation at 650_g for 2 minutes. 197 strains were isolated from both communities. These isolates belong to 18 phylotypes based on molecular identifications. Similar phylogenetic distributions of these isolates were observed in planktonic and floc communities, suggesting a similar …


Thermal Diffusion Coefficient Modeling For High Pressure Combustion Simulations, Soundararaghavan Vasudevan Dec 2007

Thermal Diffusion Coefficient Modeling For High Pressure Combustion Simulations, Soundararaghavan Vasudevan

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The effects of Soret and Dufour diffusion on the behavior of high pressure laminar diffusion flames relevant to modern combustion devices are investigated. A novel model for thermal diffusion coefficients is developed based on experimental data found in the literature and the principle of corresponding states. The new model is first compared with existing models and experimental data and is shown to be more accurate and to exhibit correct behavior in the limit of high temperature relevant to combustion. The model furthermore does not exhibit sensitivity to the equation of state, its mixing rules, or unphysical sign changes observed in …


The Role Of Computer Aided Engineering In Developing A Combined Trash And Recycling Truck : A Case Study, Peter Johnston Dec 2007

The Role Of Computer Aided Engineering In Developing A Combined Trash And Recycling Truck : A Case Study, Peter Johnston

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This work will illustrate how Environmental America Inc., EAI, and the Clemson University design team utilized lean manufacturing principles to revolutionize the curbside waste collection process. Through the application of lean manufacturing principles the number of non-value added steps was significantly reduced and the information gathered from the lean process tree acted as a framework to develop initial constraints and criteria for the vehicle's development. The design team was asked to construct the fifth iteration of the prototype collection vehicle in an effort to minimize vehicle cost, size and weight. An extensive case study will be presented which illustrates how …


Fabrication, Electrical Characterization, And Annealing Of Al/, Cu/, And Au/4h-Sic Schottky Diodes, Nikhil Karkhanis Dec 2007

Fabrication, Electrical Characterization, And Annealing Of Al/, Cu/, And Au/4h-Sic Schottky Diodes, Nikhil Karkhanis

All Theses

Schottky diodes were fabricated on n-type 4H-SiC with Nickel ohmic contacts and Aluminum, Copper, and Gold Schottky contacts. An improved and revised fabrication process was developed in the course of this research project. The Schottky diodes were electrically characterized using I-V and C-V measurements to extract electrical parameters which include Schottky barrier height, ideality factor, the diode series resistance, and substrate doping density. Al/4H-SiC and Au/4H-SiC were annealed at 600¼C and 500¼C respectively to improve the Schottky parameters. Schottky barrier height was raised and the ideality factor was reduced in both cases. Significant improvement was observed in the ideality factor …


Operational Strategies For Continuum Manipulators, Matt Csencsits Dec 2007

Operational Strategies For Continuum Manipulators, Matt Csencsits

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We introduce a novel, intuitive user interface for continuum manipulators through the use of various joystick mappings. This user interface allows for the effective use of continuum manipulators in the lab and in the field. A novel geometric approach is developed to produce a more intuitive understanding of continuum manipulator kinematics. Using this geometric approach we derive the first closed-form solution to the inverse kinematics problem for continuum robots. Using the derived inverse kinematics to convert from workspace coordinates to configuration space coordinates we develop a potential-field path planner for continuum manipulators.


Laboratory Evaluation Of Microbial Aggregation In Activated Sludge, Xiaoling Liu Dec 2007

Laboratory Evaluation Of Microbial Aggregation In Activated Sludge, Xiaoling Liu

All Theses

Microbial aggregation was investigated in this study using the activated sludge process as a model system, the performance of which is highly dependent on effective bioaggregation. This research includes two experiments. First, four laboratory-scale activated sludge sequencing batch reactors (SBRs) were constructed in order to evaluate the effect of solids retention time (SRT) on microbial aggregation. These SBRs were operated at SRT of 4, 8, 16, and 32 days, respectively, fed with a protein-based synthetic wastewater, and monitored over a period of 268 days for performance and sludge settling characteristics including soluble COD in the effluent (sCOD), sludge volume index …


Optical Force Based Cancer Cell Identification, Justin Roman Dec 2007

Optical Force Based Cancer Cell Identification, Justin Roman

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We present the basis of a novel, non-invasive technique for cell diagnostics which utilizes the optical force generated by a weakly focused laser beam to distinguish cells based on their size, structure, composition, and membrane properties. Cell populations of different types, biological states or with different treatments can be studied. This research focuses on two particular instances where other methods of cell sorting, such as those that require fluorescent markers, are not ideal. What's more, this research emphasizes the ability to sort morphologically similar cells that are identical to the naked eye, but phenotypically different on the molecular level. The …


Cosolvent Effects On The Reductive Dechlorination Of Tetrachloroethylene Catalyzed By Iron Tetraphenyl Porphyrin Chloride, Lavanya Ramasubramanian Dec 2007

Cosolvent Effects On The Reductive Dechlorination Of Tetrachloroethylene Catalyzed By Iron Tetraphenyl Porphyrin Chloride, Lavanya Ramasubramanian

All Theses

Abiotic electron transfer mediated reductive dechlorination reactions have been studied extensively in the past decade. Porphyrins and metalloporphyrins are common electron transfer mediators used. Past studies have shown that some metalloporphyrins play a key role in increasing the rate of reaction in the presence of cosolvents. There have also been suggestions that organic cosolvents enhance the rate of reduction by increasing the solubility of metalloporphyrins.
The primary objective of this project was to examine the effect of cosolvents on the metalloporphyrin-catalyzed reductive dechlorination of tetrachloroethylene (PCE). Subsequently, experiments were also conducted to test the hypothesis that metalloporphyrin solubility is linked …