Engineering Commons^™

Raman Computational And Experimental Studies On Label-Free Biological Investigations, John Ciubuc

Open Access Theses & Dissertations

Raman spectroscopy is an optical technique that allows for label-free biological investigations to take place. This approach presents both new perspectives and a means for visualizing investigations. This thesis confronts two biological cases: dopamine (DA) detection at physiological levels and assessment of renal osteodystrophy (ROD). We employed surface-enhanced Raman spectroscopy on silver nanoparticles recording DA concentrations as low as 10−11 molar. Quantum chemical density functional calculations were carried out using Gaussian-09 analytical suite software. Good agreement between the simulated and experimentally determined results indicates the existence of distinct DA molecular forms, such as uncharged DA±, anionic DA−, and dopaminequinone. Disappearance …

Direct Write 3d Printing Of Functional Ceramics, Jorge Angel Diaz

Open Access Theses & Dissertations

Humidity sensors are used in many industries and are important for ensuring quality and safety. Ceramic sensors are preferred because of their quick response time, ability to withstand high temperatures and excellent Chemical and mechanical stability. The manufacturing world has been moving toward additive manufacturing which is a form of synthesizing 3D tangible layer by layer in witch minimal waste is produced. Additive manufacturing also is known as 3D printing has opened new possibilities to design engineers by giving them design freedom and access to the layers of a part to allow embedded sensors. There is a category of ceramics …

Strategies To Improve The Electrochemical Of Performance Transition Metal Compounds As Anode Materials For Li-Ion Batteries, Noemi Dominguez

Open Access Theses & Dissertations

Nowadays, our society depends on fossil fuels as the main energy source. However, depletion, price fluctuations, and other concerns, such as global warming, have led to an exhaustive research for renewable energy resources. Here is where electrochemical energy systems play a critical role since they can provide power when renewable energy is not available. Among these electrochemical energy storage systems Li-ion batteries (LIBs) have shown higher volumetric, gravimetric, and power density capacities over other battery systems.

However, commercial LIBs are still relying on graphite base materials for the anode. However, graphite possesses a low specific capacity. Recently, transition metal compounds …

Incorporating Cybersecurity Engineering Within The Discipline Of Systems Engineering, Chuck Easttom

Open Access Theses & Dissertations

The current study is an examination of integrating cybersecurity and systems engineering. The goal is to provide a framework that accomplishes three objectives. The first is to integrate the existing systems engineering methods into cybersecurity. The second is to provide a template for cybersecurity engineering curriculum. The third is to provide a modeling language specific to cybersecurity.

Characterization And Quality Assessment Of Smart Polymer Systems Fabricated By Using 3d Printing Technique, Carlos Alejandro Garcia Rosales

Open Access Theses & Dissertations

Shape memory polymers (SMPs) are classified as smart materials due to their inherent stimulus-induced response. SMP is capable of recovering its original shape from a high degree of deformation by applying an external stimulus such as thermal energy. Other stimuli are electricity, light, chemical, and magnetic field. Shape memory polymers (SMPs) and its fabrication process has recently attracted much attention as a result of their potential application as soft active materials. Demonstration of SMP systems fabricated via 3D printing technologies has been one of the most popular attempts. This Dissertation presents an integration of two commercial SMP materials (DiAPLEX and …

The Design And Testing Of A 500 Lbf Liquid Oxygen/Liquid Methane Engine, Manuel Jesus Herrera

Open Access Theses & Dissertations

The development of liquid oxygen/liquid methane (LOX/LCH4) propulsion systems has recently become a topic of interest ever since this particular propellant combination was determined to be a suitable candidate for use in space exploration, more specifically missions to Mars. This propellant combination is unique because the propellants can be synthesized from local resources on Mars, a process called In-situ Resource Utilization (ISRU). ISRU would allow for spacecrafts to be lighter and/or increase its payload capacity to Mars-bound missions because the vehicle would not have to store the propellants required for the voyage back to earth.

For this reason, The University …

Understanding Of Deformation And Fracture Behavior In Next Generation High Strength-High Ductility Steels, Venkata Sai Yashwanth Injeti

Open Access Theses & Dissertations

The industrial demand for low density high strength steels without compromising on ductility in is endless. In this regards, grain refinement and austenitic stability considered to the practical approach in order to meet the needs. The concept of phase reversion involving sever cold deformation of metastable austenite to generate strain-induced martensite, followed by time-temperature annealing sequence, was used to obtain varying grain size from nanograined/ultrafine-grained (NG/UFG) to coarse-grained (CG) regime. This concept was used to obtain "high strength-high ductility" combination in nano/ultrafine-grained (NG/UFG) austenite stainless steel. Using this concept, the objective of the study here is to elucidate the dependence …

Computational Studies On Perovskite-Metallofullerene Interface And Magnetic Properties Of Mn-Based Mixed Olivines, Bethuel Omutiti Khamala

Open Access Theses & Dissertations

Methyl ammonium lead halide (MAPbX3) perovskite based solar cells have recently emerged as promising class of materials for photovoltaic applications with efficiencies reaching over 22%. Designing interfaces with strong binding is vital to developing efficient, high-performing solar cells. Fullerene-based materials are widely employed as efficient electron acceptors and can serve as electron transporting layer in perovskite based solar cells. We have studied interfaces of methyl ammonium lead iodide MAPbI3 with Sc3N@C80 fullerene and Sc3N@C80PCBM fullerene derivate within the density functional formalism. Different surface terminations and orientations of the methyl ammonium are examined for binding of the fullerene layer. Our calculated …

Pressureless Sintering Of Zirconium Diboride Obtained By Combustion Synthesis, Gabriel Llausas

Open Access Theses & Dissertations

Magnetohydrodynamic (MHD) direct power generation has the potential to significantly increase the thermal efficiency of coal fired power plants. Materials for MHD electrodes should have high melting points, high electrical and thermal conductivities, and excellent thermal shock and corrosion resistance. Zirconium diboride (ZrB2), which belongs to the class of ultra-high temperature ceramics (UHTC), is a promising material for this application. Mechanically activated self-propagating high-temperature synThesis (MASHS) is an attractive method for its fabrication. Previous studies have shown that zirconium diboride can be fabricated from inexpensive oxides of zirconium and boron (ZrO2 and B2O3) using magnesium as a reducing agent and …

Materials Characterization In The Development Of Combustion-Based Methods For Synthesis Of Niobium Silicides, Edgar Maguregui

Open Access Theses & Dissertations

The use of characterization techniques is essential for a better understanding of novel manufacturing processes and for investigating how the process parameters affect the products. Mechanically activated self-propagating high-temperature synthesis (MASHS) is an attractive method for the production of high-temperature structural materials. In the present work, it was used to fabricate Nb5Si3 compound and Nb5Si3/Nb composites. It has been shown that for mechanical activation of Nb/Si mixtures, a planetary ball mill is more effective than a shaker ball mill used in prior research on MASHS of Nb5Si3. The influence of mixture composition and experimental parameters, such as milling time and …

Applications Of A New Genetic Algorithm To Solve The Centralized Carrier Collaboration And Multihub Location Problem Considering Environmental Impacts, Eduardo Jose Castillo Fatule

Open Access Theses & Dissertations

The Centralized Carrier Collaboration and Multi-hub Location Problem (CCCMLP) represents a strategy that small-to-medium sized less-than-truckload (LTL) carrier companies can use in order to improve their profit margins. It is a strategy that is being explored in order to make these companies more sustainable as they are forced to reinvent their processes and supply chains. In this work, I will present a metaheuristic approach to optimizing their hub establishment and routing policies in order to better their expected profit margins and reduce their environmental impacts. The study considers the costs of transportation, loading and unloading, maintenance, operations, and inventory holding …

Comparative Study Of Analytical Models Of The Gruneisen Parameter Of Metals As Function Of Pressure, Celia Garcia Amparan

Open Access Theses & Dissertations

Commonly used Gruneisen parameter (γ) models only hold accurate in limited regimes making them inapplicable for use over wide temperature-pressure conditions. The accuracy of these analytical models of γ and of the thermal expansion of solids are of particular interest as these are considered proxies for quantifying anharmonicity, which may be a significant contribution to the thermal pressure at high temperatures. This work reviews various definitions of γ and their relations to the equations of state and apply them to two simple metals: Tantalum (Ta) and Copper (Cu), for which a high body of experimental data exists. Classical Molecular Dynamics …

Development Of Actuators Using Material Extrusion Additive Manufacturing With Embedded Shape Memory Alloy Wire, Alfonso Fernandez

Open Access Theses & Dissertations

Over the past several decades, the advancements in Additive Manufacturing (AM) technologies have opened a wide variety of applications where AM can be used. Some examples of these advancements are the introduction of automatic wire embedding capabilities, the introduction of multi-material processing and the printing of thermoplastic elastomers. With the availability of these advancements, it is now possible to create spark-free, dust-free actuation mechanisms for applications where it is crucial that no spark is generated (i.e. space shuttle fuel valve).

In this research, a Lulzbot TAZ 6 desktop material extrusion system was utilized to print parts out of Plasticized Copolymer …

Varying Ratios Of Collagen I And Iii For The Study Of Fibrotic Conditions In Tissue Engineering, Brian Roman

Open Access Theses & Dissertations

Maintenance of collagen I (Col I) and III (Col III) in a 3:1 ratio is necessary to promote cardiac health. Increase in the relative amount of Col I within the myocardium, leads to an imbalance of Col I:III during cardiac fibrosis, which has damaging effects on cardiomyocytes (CM). To represent fibrous- and normal-cardiac tissue, gels composed of Col I:III ratios of 9:1 and 3:1 were developed and used to study resultant changes in CM function. Second harmonic generation (SHG) microscopy, used to image Col I fibers, displayed a decrease in image intensity with the addition of the non-second harmonic Col …

Load Rating Mobility As A Framework For Bridge Owners, Bryan Keith Stephens

Open Access Theses & Dissertations

In this time of financial economy, bridge owners are faced with the important decision of where to focus financial assets while attempting to determine which structures are in most need. Bridge Engineers and researchers alike agree that a large portion of the United States bridge population are reaching the end of their design life. Researchers are currently investigating various means and methods of lengthening the amount of usefulness of these key pieces of infrastructure. This paper introduces the novel idea of bridge Load Rating Mobility and how it can be leveraged by stake holders to assist in making those financial …

Investigating Using Titanium Zirconium Molybdenum For Additively Manufacturing Aerospace Components, Justin Hunter Vanhoose

Open Access Theses & Dissertations

Mankind throughout history has possessed an innate characteristic to explore, migrating to new frontiers.The requirement for this travel is most broadly associated with the need to pursue more resources. Rockets have been used as a means of weapons since the Sung Dynasty in the thirteenth empire and have now been integrated for travel/transport. The sophistication of rocketry and propulsion has reached a level to where it is plausible that mankind will be a multi-planetary species. The space industry has grown significantly with the advancement of the sophistication of these rocket technologies. However, a specific challenge to overcome in the space …

Conductivity Modulation In Strained 2d Transition- Metal- Dichalcogenides Via Micro- Electro- Mechanical Actuation, Aldo Ivan Vidaña

Open Access Theses & Dissertations

In this thesis, strain-induced conductivity modulation in bi-layer molybdenum disulfide (MoS2) flakes is experimentally investigated and modeled. Uniaxial tensile strain in the MoS2 flakes is achieved using a micro-electro-mechanical (MEM) actuator. Conductivity ratios up to 400 are demonstrated. Theoretical predictions of conductivity versus applied voltage in the MEMS-MoS2 device match experimental data reasonably well using only the effective width of the TMDC flakes as the sole fitting parameter. The amount of strain induced in the MoS2 flakes was determined to be as high as 2.7% for one flake using the model fitted to the experiment data. The switching energy required …

Thermo-Fluid System Level Modeling For The Crome And Crome-X Ground Propellant System Using Generalized Fluid System Simulation Program, Mariano Mercado

Open Access Theses & Dissertations

A recent resurgence of interest in space exploration has given rise to a number of newcomers in the space industry. A number of private companies like SpaceX, Blue Origin, and United Launch Alliance have joined the likes of NASA with the goal to expand the current capabilities of space travel and exploration. Perhaps the most ambitious of these goals is a manned mission to Mars. In order to achieve this goal, many of these companies have taken a keen interest in liquid oxygen and methane engine technologies. Engines like the Raptor by SpaceX and the Blue Origin BE-4 already run …

Tailoring The Mechanical And Optical Properties Of Silicon-Niobium-Nitride Composite Coatings, Cristian Orozco

Open Access Theses & Dissertations

Nitride nanocomposite thin films have generated significant attention as a result of their robust mechanical properties, excellent triobology, and good chemical (corrosion) stability. Due to their excellent hardness and high wear resistance NbN coatings have found use in a wide variety of applications such as the coating of cutting tools and to strengthen the surface mechanical properties of superconducting cavities. The mechanical properties of NbN can be further improved through mixing with Si3N4, leading to the formation of a nanocomposite structure. NbN-Si3N4 nanocomposite coatings have been actively studied due to their high hardness, high elastic modulus, and high resistance to …

Development And Implementation Of The Triac Data Acquisition And Control System, Raymundo Mendivil Rojo

Open Access Theses & Dissertations

The Technology Research and Innovation Acceleration Park (tRIAC) located at Fabens, Texas, was established for the ongoing development and testing of the miro center for Space Exploration and Technology Research’s (cSETR’s) liquid methane and liquid oxygen rocket engines. These engines range from a 5 lbf Reaction Control Engine (RCE) to the 500 lbf and 2000 lbf Centennial Restartable Oxygen Methane Engines, called CROME and CROME-X respectively. Alongside their development, a comprehensive control system was built in the Modular Instrumentation and Control Interface Trailer (MICIT) and is equipped with National Instrument’s LabVIEW software and hardware. The LabVIEW code is based off …

Dedicated Hardware For Machine/Deep Learning: Domain Specific Architectures, Angel Izael Solis

Open Access Theses & Dissertations

Artificial intelligence has come a very long way from being a mere spectacle on the silver screen in the 1920s [Hml18]. As artificial intelligence continues to evolve, and we begin to develop more sophisticated Artificial Neural Networks, the need for specialized and more efficient machines (less computational strain while maintaining the same performance results) becomes increasingly evident. Though these “new” techniques, such as Multilayer Perceptron’s, Convolutional Neural Networks and Recurrent Neural Networks, may seem as if they are on the cutting edge of technology, many of these ideas are over 60 years old! However, many of these earlier models, at …

Data-Driven Predictive Framework For Modeling Complex Multi-Physics Engineering Applications, Arturo Schiaffino Bustamante

Open Access Theses & Dissertations

Computational models are often encountered in multiple engineering application, such as structural design, material science, heat transfer and fluid dynamics. These simulations offer the engineers the capability of understanding complex physical situations before putting them to practice, either through experimentation or prototyping. The current advances in computational sciences, hardware architecture, software development and big data technology, have allowed the construction of sturdy predicting frameworks for analyzing a wide array of natural phenomena across different disciplines, either through the implementation of statistical methods, such as big data, and uncertainty quantification, or through high performance computing of a numerical model. The objective …

Parallelization And Scalability Analysis Of The \\[1pc] 3d Spatially Variant Lattice Algorithm, Henry Roger Moncada Lopez

Open Access Theses & Dissertations

The purpose of this research is to design a faster implementation of an algorithm to generate 3D spatially variant lattices (SVL) and improve its performance when it is running on a parallel computer system. The algorithm is used to synthesize a SVL for a periodic structure. The algorithm has the ability to spatially vary the unit cell, the orientation of the unit cells, lattice spacing, fill fraction, material composition, and lattice symmetry. The algorithm produces a lattice that is smooth, continuous and free of defects. The lattice spacing remains strikingly uniform even when the lattice is spatially varied. This is …

An Integrated Study Towards Curing Neurodegenerative Disorders Using Materials Science And Stem Cell-Based Tissue Engineering Approaches, Nishat Tasnim

Open Access Theses & Dissertations

Neurodegenerative diseases affect around one billion people globally that are characterized by irreversible degeneration of brain tissues. These diseases cause serious effects on patients degrading their brain functions and causing enormous physical and mental health issues. Parkinson's disease (PD) is one of the most common neurodegenerative disorder affecting millions of people worldwide which results from loss of dopaminergic (DA) neurons in the mid-brain. Unfortunately, no medical treatment is effective to date for these significant brain disorders, except some symptomatic therapies only focusing on improving the quality of patient's life.

Two current approaches hold great promise in targeting PD as well …

Assessing Corrosivity Of Galvanized Soil Reinforcements From Electrochemical Tests, Diana Alejandra Cabrera

Open Access Theses & Dissertations

The accurate estimation of the service lives of mechanically stabilized earth (MSE) walls requires a proper evaluation of the corrosion potential through electrochemical test methods. Robust field tests are required to assess the corrosivity of galvanized metal used in MSE walls. To simulate an environment similar to an MSE wall, cylindrical soil specimens about 12 in. (300 mm) in diameter and 10 in. (250 mm) in height were constructed. For every specimen, two instruments were used. The first instrument measured the polarization resistance corrosion tests carried out on galvanized strips and meshes, as well as epoxy-coated rebars. The second instrument …

High Recovery Inland Desalination: A Technical And Economic Performance Evaluation Of Zero Discharge Desalination And Other Technologies, Malynda Aragon Cappelle

Open Access Theses & Dissertations

Increasing population and diminishing freshwater resources are leading to increased competition between users of freshwater, both in terms of surface water and groundwater. Desalination can augment the water supply, but conventional approaches like reverse osmosis are usually limited to 70-80% recovery. Inland brine disposal options are often limited, presenting significant technical and economic obstacles to implementing desalination technology. In comparison to conventional desalination technologies, high recovery desalination methods such as Zero Discharge Desalination (ZDD) offer substantially higher potable water yield (i.e., 95-98%) from brackish water. ZDD is a hybrid process that combines reverse osmosis (RO) or nanofiltration (NF) with electrodialysis …

Improving Time-Of-Flight And Other Depth Images: Super-Resolution And Denoising Using Variational Methods, Salvador Canales Andrade

Open Access Theses & Dissertations

Depth information is a new important source of perception for machines, which allow them to have a better representation of the surroundings. The depth information provides a more precise map of the location of every object and surfaces in a space of interest in comparison with conventional cameras. Time of flight (ToF) cameras provide one of the techniques to acquire depth maps, however they produce low spatial resolution and noisy maps. This research proposes a framework to enhance and up-scale depth maps by using two different regularization terms: Total Generalized Variation (TGV) and Total Generalized Variation with a Structure Tensor …

Design And Experimental Study Of A High Pressure And Supercritical Methane-Oxygen Burner, A S M Arifur Rahim Chowdhury

Open Access Theses & Dissertations

Directly heated supercritical oxy-fuel power cycles have potential to offer a higher thermal efficiency and lower pollutant emissions compared to existing power cycles. Recent thermodynamic analysis of the cycle performed by several groups including the UTEP-Air Liquide research team show that combustion in the vicinity of 300 bar pressure and 1000-1400 K temperature allows for relatively high system efficiencies while operating within the limit of practical combustor materials. However, the realization of directly heated supercritical power cycle requires combustion systems be designed to operate in supercritical conditions and at temperature far below the blowout limit of conventional flames (above 1500 …

Interference Analysis And Mitigation Of Telemetry (Tm) And 4g Long-Term Evolution (Lte) Systems In Adjacent Spectrum Bands, Juan Francisco Gonzalez

Open Access Theses & Dissertations

Currently, the telecommunications, radio systems, and many other wireless services in the United States are using the spectrum from the 6 kHz to the 300 GHz frequencies. Although it may seem enough for said systems, as more users and devices are being introduced into the market, the spectrum is limiting the faster introduction of these devices and/or systems. The radio frequency spectrum is home to many transmissions, from amateur radio to cellphone applications, which all share similar frequency bands. By sharing, the number of applications can be increased in a single band, but their performance may be affected. Herein, experiments …

Additive Manufacturing Of Multi-Functional Nanocomposites For Sensor And Energy Storage Devices, Hoejin Kim

Open Access Theses & Dissertations

The goal of this research is to develop novel 3D printing process and design nanocomposites for piezoelectric and dielectric devices using fused deposition modeling (FDM) and stereolithography (SL) 3D printing techniques for use in sensor and energy storage applications. Techniques for electric and corona assisted in-situ poling during 3D printing were developed to improve the piezoelectric property and ease of manufacture. Poly(vinylidene fluoride) (PVDF) and barium titanate (BaTiO3, BT) are well-known for their high piezo- and dielectric constants among polymers and ceramics, while multi-walled carbon nanotubes (CNTs) were introduced to improve efficiency of stress reinforcement and conductivity for charge carriers …