Engineering Commons^™

Schottky Diodes On Copper Phthalocyanine Nanowire Arrays Embedded In Porous Alumina Templates, Goutam Chintakula

University of Kentucky Master's Theses

Vertically aligned nanowire arrays of copper phthalocyanine (CuPc) and CuPc-Al Schottky diodes, of controllable diameter and length were fabricated by cathodic electrodeposition of CuPc into anodized alumina (AAO) templates, followed by annealing at 300 ºC in Argon. AAO over Aluminum tape and that over ITO-glass were both used as starting templates for the device fabrication. Depending on the dimensions of the starting AAO template, diameters of CuPc nanowires ranged from 30 nm to 40 nm and the lengths ranged from 500 nm to 1 μm. The temperature dependence of the phase and the absorption spectrum of the nanowires are reported. …

A Precision Instrument For Research Into Nanolithographic Techniques Using Field-Emitted Electron Beams, King-Fu Hii

University of Kentucky Doctoral Dissertations

Nanomanufacturing is an active research area in academia and industry due to the ever-growing demands for precision surface modifications of thin films or substrates with nanoscale features. Conventional lithographic techniques face many challenges as they approach their fundamental limits. Consequently, new nanomanufacturing tools, fabrication techniques, and precision instruments are being explored and developed to meet these challenges. It has been hypothesized that direct-write nanolithography might be achieved by using a field-emitted electron beam for nanomachining. This dissertation moves this research one step closer by developing a precision instrument that can enable the integration of direct-write nanolithography by a field-emitted electron …

Fabrication And Characterization Of Molecular Spintronics Devices, Pawan Tyagi

University of Kentucky Doctoral Dissertations

Fabrication of molecular spin devices with ferromagnetic electrodes coupled with a high spin molecule is an important challenge. This doctoral study concentrated on realizing a novel molecular spin device by the bridging of magnetic molecules between two ferromagnetic metal layers of a ferromagnetic-insulator-ferromagnetic tunnel junction on its exposed pattern edges. At the exposed sides, distance between the two metal electrodes is equal to the insulator film thickness; insulator film thickness can be precisely controlled to match the length of a target molecule. Photolithography and thin-film deposition were utilized to produce a series of tunnel junctions based on molecular electrodes of …

Matrix Decomposition For Data Disclosure Control And Data Mining Applications, Jie Wang

University of Kentucky Doctoral Dissertations

Access to huge amounts of various data with private information brings out a dual demand for preservation of data privacy and correctness of knowledge discovery, which are two apparently contradictory tasks. Low-rank approximations generated by matrix decompositions are a fundamental element in this dissertation for the privacy preserving data mining (PPDM) applications. Two categories of PPDM are studied: data value hiding (DVH) and data pattern hiding (DPH). A matrix-decomposition-based framework is designed to incorporate matrix decomposition techniques into data preprocessing to distort original data sets. With respect to the challenge in the DVH, how to protect sensitive/confidential attribute values without …

Investigating The Effect Of Stress, Wetting, And Compaction On Settlement Potential Of Mine Spoils, Lauren M. Little

University of Kentucky Master's Theses

Strip mining in Kentucky has left large areas of land that could potentially be used for business and housing developments. However, the mine spoils underlying these areas are prone to severe differential settlement due to a variety of factors. Mine spoil from the Gateway Business Park in Jenkins, Kentucky was used for a series of laboratory tests to develop relationships between shear wave velocity, confining stress, compaction energy, and dry unit weight to develop a method to assess settlement potential. It was found that a stress-corrected shear wave velocity of greater than 275 ft/s/psi^0.25 typically indicated dry mine spoil, …

Production Of Low-Energy, 100% By-Product Cement Utilizing Coal Combustion Products, David E. Rust

University of Kentucky Master's Theses

The ever-increasing quantity of by-products generated from burning coal in the production of electricity has brought about the need for new areas of utilization. This study examined the use of FGD gypsum and fluidized bed combustion ash along with Class F fly ash in the production of low-energy, 100% by-product cement blends. The cement blends used the advantageous properties of the by-product materials to create cementing properties rather than energy intensive clinker used in ordinary portland cement. The FGD gypsum was converted to hemihydrate which rapidly hydrated to provide the cement with early strength gains, whilst the fluidized bed combustion …

An Integrated Framework For Applying Lean Manufacturing And Other Strategies In Mass Customization Environments, Gregory Brandon Stump

University of Kentucky Master's Theses

Manufacturing organizations are facing fragmented markets and increased demand of variety from consumers. As a result, many of these firms have adopted mass customization manufacturing strategies in an effort to offer their customers the freedom of choice while maintaining operational efficiency. Lean manufacturing strategies have also seen heavy use in manufacturing environments. This study investigates the possibilities of integrating lean manufacturing principles and practices into mass customization environments in order to improve system performance. The feasibility of other manufacturing strategies such as agility, Quick Response Manufacturing and the Theory of Constraints assisting in the application of lean manufacturing for mass …

Thermal Degradation And Aging Of High Temperature Piezoelectric Ceramics, Sunil W. Gotmare

University of Kentucky Master's Theses

Piezoelectric materials have numerous applications like high temperature accelerometers, pressure, flow and NDT transducers, acoustic emission, ultrasonic cleaning, welding, high voltage generators, medical therapy etc. The commonly used piezoelectric material, PZT continues to dominate the commercial market for piezoelectric actuators applications. The primary limitations of PZT are the lower Curie temperature T_C <390^oC and rapid thermal degradation avobe 200^oC.

Continuing efforts are focused on the development of piezoelectric materials suitable for high temperature applications >200^oC. These materials will be very useful for making sensors for space exploration, oil and geothermal well drilling tools, oil …

Performance Optimization Of A Structured Cfd Code - Ghost On Commodity Cluster Architectures, Pavan K. Kristipati

University of Kentucky Master's Theses

This thesis focuses on optimizing the performance of an in-house, structured, 2D CFD code – GHOST, on commodity cluster architectures. The basic philosophy of the work is to optimize the cache usage of the code by implementing efficient coding techniques without changing the underlying numerical algorithm. Various optimization techniques that were implemented and the resulting changes in performance have been presented. Two techniques, external and internal blocking that were implemented earlier to tune the performance of this code have been reviewed. What follows is further tuning effort in order to circumvent the problems associated with using the blocking techniques. Later, …

Elastic-Plastic Indentation Deformation In Homogeneous And Layered Materials: Finite Element Analysis, Siva Naga Venkata Ravi Kiran Kurapati

University of Kentucky Master's Theses

The complex phenomenon of indentation deformation is studied using finite element analysis for both homogeneous and layered materials. For the homogeneous materials, the elastic-plastic deformation at large indentation depth is studied. The variation of the load-displacement curves as well as the variation of the energy ratio with the applied indentation depth for different strain hardening indices is presented. The power law relation between the indentation load and depth for shallow indentation becomes invalid for deep indentation. The ratio of plastic energy to total mechanical work is a linear function of the ratio of residual indentation depth and maximum indentation depth. …

Process For Formation Of Cationic Poly (Lactic-Co-Glycolic Acid) Nanoparticles Using Static Mixers, Yamuna Reddy Charabudla

University of Kentucky Master's Theses

Nanoparticles have received special attention over past few years as potential drug carriers for proteins/peptides and genes. Biodegradable polymeric poly (lactic-co-glycolic acid) (PLGA) nanoparticles are being employed as non-viral gene delivery systems for DNA. This work demonstrates a scalable technology for synthesis of nanoparticles capable of gene delivery. Cationic PLGA nanoparticles are produced by emulsiondiffusion- evaporation technique employing polyvinyl alcohol (PVA) as stabilizer and chitosan chloride for surface modification. A sonicator is used for the emulsion step and a static mixer is used for dilution in the diffusion step of the synthesis. A static mixer is considered ideal for the …

Phonon-Energy-Coupling-Enhancement Effect And Its Applications, Pang-Leen Ong

University of Kentucky Doctoral Dissertations

Silicon Oxide/Oxynitride (SiO₂/SiON) has been the mainstream material used for gate dielectric for MOS transistors for the past 30 years. The aggressive scaling of the feature size of MOS transistor has limited the ability of SiO₂/SiON to work effectively as the gate dielectric to modulate the conduction of current of MOS transistors due to excess leakage current dominated by direct quantum tunneling. Due to this constraint, alternative gate dielectric/high-k is being employed to reduce the leakage current in order to maintain the rate of scaling of MOS transistors. However, the cost involved in the implementation of …

Dual Bypass Gas Metal Arc Welding Process And Control, Xiaopei Liu

University of Kentucky Doctoral Dissertations

GMAW (Gas Metal Arc Welding) is one of the most important arc welding processes being adopted in modern manufacturing industry due to its advantages in productivity, energy efficiency and automation. By monitoring and improving some of the important properties of GMAW such as production rate, metal transfer and base metal heat input, researchers could bring the process efficiency and stability to a new level. In recent years, some innovative modifications of GMAW such as Twins, Tandem and laser-MIG hybrid welding have been adopted into many industrial applications for better productivity.

In this dissertation, a novel GMAW called DB-GMAW (Dual Bypass …

Modeling And Analysis Of Split And Merge Production Systems, Yang Liu

University of Kentucky Master's Theses

Many production systems have split and merge operations to increase production capac- ity and variety, improve product quality, and implement product control and scheduling policies. This thesis presents analytical methods to model and analyze split and merge production systems with Bernoulli and exponential reliability machines under circulate, priority and percentage policies. The recursive procedures for performance analysis are de- rived, and the convergence of the procedures and uniqueness of the solutions, along with the structural properties, are proved analytically, and the accuracy of the estimation is justi¯ed numerically with high precision. In addition, comparisons among the e®ects of di®erent policies …

Stranded Core Transformer Loss Analysis, Xingxing Zhang

University of Kentucky Master's Theses

We will present the approaches used to investigating the power loss for the stranded core transformers. One advantage of using stranded core is to reduce power loss or enhance transformer efficiency. One difficulty in the modeling of this type of transformer is that the core is not solid (there are small gaps between core wires due to circular cross section). A two dimensional finite element method with nodal basis function for magnetostatic field was developed to study the effects of the small gaps between core wires. The magnetic flux densities are compared for the uniform (solid) cores and the stranded …

Hdl Implementation And Analysis Of A Residual Register For A Floating-Point Arithmetic Unit, Akil Kaveti

University of Kentucky Master's Theses

Processors used in lower-end scientific applications like graphic cards and video game consoles have IEEE single precision floating-point hardware [23]. Double precision offers higher precision at higher implementation cost and lower performance. The need for high precision computations in these applications is not enough to justify the use double precision hardware and the extra hardware complexity needed [23]. Native-pair arithmetic offers an interesting and feasible solution to this problem. This technique invented by T. J. Dekker uses single-length floating-point numbers to represent higher precision floating-point numbers [3]. Native-pair arithmetic has been proposed by Dr. William R. Dieter and Dr. Henry …

Super Resolution 3d Scanning Using Spatial Light Modulator And Band Correction, Akshay Pethe

University of Kentucky Master's Theses

Multi Frequency Phase Measuring Profilometry is the most popular lateral contact 3-D Scanning technique. The Phase Measuring Profilometry is limited in resolution by the projector and cameras used. Conventional signal projectors have a maximum of 2000 to 4000 scan lines limiting the projector resolution. To obtain greater detail with higher resolution the PMP technique is applied to a Spatial Light Modulator (SLM) having 12000 lines, very large as compared to conventional projectors. This technology can achieve super resolution scans having varied applications. Scans achieved from PMP suffer from a certain type of artifact called “banding” which are periodic bands across …

Aging And Sleep Stage Effects On Entropy Of Electroencephalogram Signals, Swetha Vennelaganti

University of Kentucky Master's Theses

The aging brain is characterized by alteration in synaptic contacts, which leads to decline of motor and cognitive functions. These changes are reflected in the age related shifts in power spectrum of electroencephalogram (EEG) signals in both wakefulness and sleep. Various non-linear measures have been used to obtain more insights from EEG analysis compared to the conventional spectral analysis. In our study we used Sample Entropy to quantify regularity of the EEG signal. Because elderly subjects arouse from sleep more often than younger subjects, we hypothesized that Entropy of EEG signals from elderly subjects would be higher than that from …

Role Of Dipoles In The Bulk Phosphor Layer In The Electroluminance Mechanisms Of A.C. Thin Film Electroluminescent Display Devices, Praveen Kumar Sivakumar

University of Kentucky Doctoral Dissertations

The purpose of this dissertation is to advance the understanding of SrS-based a. c. thin film electroluminescent (ACTFEL) devices. The role of traps in the bulk phosphor layer in the light emission mechanism from ACTFEL devices is studied, characterized and modeled.

Experiments were performed to observe the response of the ACTFEL devices to tailored voltage excitations. A physical model was developed to describe the optoelectronic processes taking place in the phosphor; analytical equations were written and numerically simulated to plot the flux and luminance responses of the device to similarly tailored voltage excitations.

The voltage excitation parameters such as amplitude, …

Thevenin Equivalent Circuit Estimation And Application For Power System Monitoring And Protection, Mohammad M. Iftakhar

University of Kentucky Master's Theses

The Estimation of Thevenin Equivalent Parameters is useful for System Monitoring and Protection. We studied a method for estimating the Thevenin equivalent circuits. We then studied two applications including voltage stability and fault location. A study of the concepts of Voltage Stability is done in the initial part of this thesis. A Six Bus Power System Model was simulated using MATLAB SIMULINK®. Subsequently, the Thevenin Parameters were calculated. The results were then used for two purposes, to calculate the Maximum Power that can be delivered and for Fault Location.

Nanostructured Thin Films And Tubes Of Titania For Room Temperature Sensing Of Gases, Satish Kumar Kandala

University of Kentucky Master's Theses

The main objective of this work was to study the applicability of Nano porous/Nanocrystalline TiO₂ films for serving the growing demand for fast accurate and low cost air quality analysis techniques. The sensitivity of response to variations in microstructure pointed the way to obtain controlled, reproducible and regular microstructures with critical dimensions proportionate with the Debye- length of the oxide. This work aimed to study the sensor properties of thin films of Nanocrystalline Titania and Titania nanotubes at room temperature. Nano porous/Nanocrystalline TiO₂ films were fabricated through evaporation driven convection/sol-gel method by controlling the process conditions. We also …

Synthesis And Characterization Of Schottky Diodes On N-Type Cdte Nanowires Embedded In Porous Alumina Templates, Srikanth Yanamanagandla

University of Kentucky Master's Theses

This work focuses on the growth of vertically aligned CdTe nanowire arrays of controllable diameter and length using cathodic electro deposition in anodized alumina templates. This step was followed by annealing at 250° C in a reducing environment (95% Ar + 5% H2). AAO template over ITO-glass was used as starting template for the device fabrication. The deposited nanowires showed nanocrystalline cubic phase structures with a strong preference in [111] direction. First gold (Au) was deposited into AAO using cathodic electro deposition. This was followed by CdTe deposition into the pore. Gold was deposited first as it aids the growth …

Modular Fast Direct Analysis Using Non-Radiating Local-Global Solution Modes, Xin Xu

University of Kentucky Doctoral Dissertations

This dissertation proposes a modular fast direct (MFD) analysis method for a class of problems involving a large fixed platform region and a smaller, variable design region. A modular solution algorithm is obtained by first decomposing the problem geometry into platform and design regions. The two regions are effectively detached from one another using basic equivalence concepts. Equivalence principles allow the total system model to be constructed in terms of independent interaction modules associated with the platform and design regions. These modules include interactions with the equivalent surface that bounds the design region. This dissertation discusses how to analyze (fill …

Novel Catalysts For The Production Of Co- And Co2-Free Hydrogen And Carbon Nanotubes By Non-Oxidative Dehydrogenation Of Hydrocarbons, Wenqin Shen

University of Kentucky Doctoral Dissertations

Non-oxidative dehydrogenation of hydrocarbons is an attractive alternative route for the production of CO- and CO₂-free hydrogen. It will satisfy a major requirement for successful utilization of polymer electrolyte membrane (PEM) fuel cells (< 10 ppm CO) and sequestering carbon as a potentially valuable by-product, carbon nanotubes (CNTs). Due to the deposition of carbon on the surface of catalyst particles during the reaction, catalyst performance, life-time, and purification of the generated carbon product, are significant issues to solve in order to make the process practically feasible. The scope of this thesis includes: the development of novel Fe, Ni, and Fe-Ni catalysts supported on a Mg(Al)O support to achieve improved catalytic performance with easily-purified CNTs; evaluation of catalysts for ethane/methane dehydrogenation at moderate reaction temperatures; and study of activation and deactivation mechanisms by a variety of characterization techniques including TEM, HRTEM, XRD, Mössbauer spectroscopy, and x-ray absorption fine structure (XAFS) spectroscopy. The Mg(Al)O support was prepared by calcination of synthetic MgAl-hydrotalcite with a Mg to Al ratio of 5. The catalysts were prepared either by conventional incipient wetness method or by a novel nanoparticle impregnation method, where the monodisperse catalyst nanoparticles were prepared in advance by thermal decomposition of a metal-organic complex in an organic-phase solution and then dispersed onto the Mg(Al)O support. Dehydrogenation of undiluted methane was conducted in a fix-bed plug-flow reactor. Before reaction, the catalysts were activated by reduction in hydrogen. Fe-based catalysts exhibit a higher hydrogen yield at temperature above 600ºC compared with monometallic Ni catalyst. FeNi-9 nm/Mg(Al)O, Fe-10 nm/Mg(Al)O and Fe-5 nm/ Mg(Al)O nanoparticle catalysts show much improved performance and longer life-times compared with the corresponding FeNi IW/Mg(Al)O and Fe IW/Mg(Al)O catalysts prepared by incipient wetness. 10 nm is the optimum particle size for methane dehydrogenation. Addition of Ni to Fe forming a bimetallic FeNi alloy catalyst enhances the catalytic performance at the temperatures below 650ºC. Metallic Fe, Ni, FeNi alloy and Fe-Ni-C alloy, unstable iron carbide are all catalytically active components. Catalysts deactivation is due to the carbon encapsulation. The carbon products are in the form of stack-cone CNTs (SCNTs) and multi-walled CNTs (MWNTs), depending on the reaction temperature and catalyst composition. The growth of CNTs follows a tip growth mechanism and the purity of cleaned CNTs is more than 99.5%.

Efficient And Scalable Network Security Protocols Based On Lfsr Sequences, Saikat Chakrabarti

University of Kentucky Doctoral Dissertations

The gap between abstract, mathematics-oriented research in cryptography and the engineering approach of designing practical, network security protocols is widening. Network researchers experiment with well-known cryptographic protocols suitable for different network models. On the other hand, researchers inclined toward theory often design cryptographic schemes without considering the practical network constraints. The goal of this dissertation is to address problems in these two challenging areas: building bridges between practical network security protocols and theoretical cryptography. This dissertation presents techniques for building performance sensitive security protocols, using primitives from linear feedback register sequences (LFSR) sequences, for a variety of challenging networking applications. …

An Investigation Of Size Effects On Thin Sheet Formability For Microforming Applications, Nasr Abdelrahman Shuaib

University of Kentucky Doctoral Dissertations

The increasing demand for powerful miniaturized products for all industrial applications has prompted the industry to develop new and innovative manufacturing processes to fabricate miniature parts. One of the major challenges facing the industry is the dynamic market which requires continuous improvements in design and fabrication techniques. This means providing products with complex features while sustaining high functionality. As a result, microfabrication has gained a wide interest as the technology of the future, where tabletop machine systems exist. Microforming processes have the capability of achieving mass production while minimizing material waste. Microforming techniques can produce net-shape products with intricacy in …

Surfactant And Metal Sorption Studies By Functionalized Membranes And Quartz Crystal Microbalance, Abhay R. Ladhe

University of Kentucky Doctoral Dissertations

Functionalized membranes provide an elegant platform for selective separations and sorptions. In this dissertation, application of functionalized membranes for surfactant and metal sorption studies are discussed. Sorption behavior of surfactants is also studied using quartz crystal microbalance (QCM) and other techniques.

Adsorption of the ethoxylated surfactants on polymeric materials (cotton and polyester) and model gold surface was quantified from a non-aqueous siloxane based solvent (D5) and water. The role of ethylene oxide group and the effect of nature of polymeric materials on adsorption behavior was quantified and established. In the case of gold-water interface, the adsorption data was fitted to …

Linking The Structure And Mechanical Behavior Of Nanoporous Gold, Ye Sun

University of Kentucky Doctoral Dissertations

The structure of nanoporous gold (np-Au) provides a very limited volume for deformation to occur, and thus offers an opportunity to study the role of defects such as dislocations in nanoscale metal volumes. A practical goal is to understand mechanical properties of np-Au so that it can be can produced in stable form, for use in applications that require some mechanical integrity. Bulk and thin film np-Au have been fabricated and studied here.

Bulk np-Au was prepared by electrochemically dealloying Au-Ag alloys with 25 and 30 at.% Au. In the lower Au content material, cracks always formed during dealloying. When …

Investigation Of Blast Mitigation Properties Of Carbon And Polyurethane Based Foams, Bradley E. Toon

University of Kentucky Master's Theses

Solid foams have been studied for years for their ability to mitigate damage from sudden impact. Small explosive attacks threaten to damage or destroy key structures in some parts of the world. A newly developed material, carbon foam, may offer the ability to mitigate the effects of such blasts. This project investigates the energy absorbing properties of carbon and polyurethane based foams in dynamic compression to illustrate their viability to protect concrete structures from the damaging effects of pressure waves from a small blast. Cellular solid mechanics fundamentals and a survey of the microscopic cellular structure of each type of …

Proportional Feedback Control Of Duty Cycle For Dc Hybrid Active Power Filter, Govind N. Malleichervu

University of Kentucky Master's Theses

This thesis deals with the design and implementation of a feedback control scheme for a DC Hybrid Active Power Filter used to filter harmonics from a Switched Reluctance Motor (SRM) Drive load. Power electronic systems are non-linear & dynamic [1,3,5]. Power electronic systems employ switching circuits to maximize their efficiency at the penalty that switching circuits generate electrical noise called ripple current and voltage or conducted electromagnetic interference (EMI). The ripple current drawn by the power electronic systems needs to be attenuated to an acceptable level. Filters attenuate this to an acceptable level. Traditionally filters with passive inductors and capacitors …