Engineering Commons^™

Interplay Of Composition, Structure, And Electron Density Of States In W-Os Cathode Materials And Relationship With Thermionic Emission, Qunfei Zhou, Thomas John Balk, Matthew J. Beck

Chemical and Materials Engineering Faculty Publications

The presence and composition of W-Os alloys have been found to significantly affect the thermionic emission properties of Os-coated tungsten dispenser cathodes. However, the comprehensive understanding of structure–property relationships needed to design improved tungsten cathodes with larger thermionic emission is still lacking. In this study, composition–structure–property relationships governing thermionic emission from W-Os alloys were investigated using quantum mechanical calculations. Low-energy W-Os atomic configurations at various compositions were determined from first-principles calculations based on density functional theory in combination with cluster expansion calculations. Electronic properties were investigated in terms of the electron density of states. The relative position of the Fermi …

Inhibition Of Mammalian Glycoprotein Ykl-40 Identification Of The Physiological Ligand, Abhishek A. Kognole, Christina M. Payne

Chemical and Materials Engineering Faculty Publications

YKL-40 is a mammalian glycoprotein associated with progression, severity, and prognosis of chronic inflammatory diseases and a multitude of cancers. Despite this well documented association, identification of the lectin′s physiological ligand and, accordingly, biological function has proven experimentally difficult. YKL-40 has been shown to bind chito-oligosaccharides; however, the production of chitin by the human body has not yet been documented. Possible alternative ligands include proteoglycans, polysaccharides, and fibers like collagen, all of which makeup the extracellular matrix. It is likely that YKL-40 is interacting with these alternative polysaccharides or proteins within the body, extending its function to cell biological roles …

Apparatus And Method For Harvesting Carbon Nanotube Arrays, Matthew C. Weisenberger, John D. Craddock

Center for Applied Energy Research Faculty Patents

An apparatus is provided for harvesting a carbon nanotube array from a substrate. The apparatus includes a peeler that peels the carbon nanotube array from the substrate and a support that receives the carbon nanotube array peeled from the substrate. In addition the apparatus includes a drawing device that simultaneously draws the carbon nanotube array from the substrate onto the support as the carbon nanotube array is peeled from the substrate. The peeler and drawing device are synchronized in operation so that as a given length of carbon nanotube array is peeled from the substrate, that same given length of …

Efficient Planar Heterojunction Perovskite Solar Cells With Li-Doped Compact Tio2 Layer, Detao Liu, Shibin Li, Peng Zhang, Yafei Wang, Rui Zhang, Hojjatollah Sarvari, Feng Wang, Jiang Wu, Zhiming Wang, Zhi Chen

Electrical and Computer Engineering Faculty Publications

Perovskite solar cells (PSCs) have been developed rapidly in recent time, and efficient planar PSCs are regarded as the most promising alternative to the Si solar cells. In this study, we demonstrated that Li-doping of compact TiO₂ can reduce the density of electron traps and increase the conductivity of the electron transport layer (ETL) of PSCs. Due to the improved electronic property of ETL, the Li-doped compact TiO₂ based planar heterojunction PSCs exhibit negligible hysteretic J-V behavior. Comparing with the undoped compact TiO₂ based PSCs, the power conversion efficiency (PCE) of the Li-doped compact TiO₂ film …

Time-Frequency Masking Performance For Improved Intelligibility With Microphone Arrays, Joshua P. Morgan

Theses and Dissertations--Electrical and Computer Engineering

Time-Frequency (TF) masking is an audio processing technique useful for isolating an audio source from interfering sources. TF masking has been applied and studied in monaural and binaural applications, but has only recently been applied to distributed microphone arrays. This work focuses on evaluating the TF masking technique's ability to isolate human speech and improve speech intelligibility in an immersive "cocktail party" environment. In particular, an upper-bound on TF masking performance is established and compared to the traditional delay-sum and general sidelobe canceler (GSC) beamformers. Additionally, the novel technique of combining the GSC with TF masking is investigated and its …

Assessment Of Potential Impacts To Surface And Subsurface Water Bodies Due To Longwall Mining, Christopher R. Newman, Zacharias Agioutantis, Gabriel Boede Jimenez Leon

Mining Engineering Faculty Publications

Ground movements due to longwall mining operations have the potential to damage the hydrological balance within as well as outside the mine permit area in the form of increased surface ponding and changes to hydrogeological properties. Recently, the Office of Surface Mining, Reclamation and Enforcement (OSMRE) in the USA, has completed a public comment period on a newly proposed rule for the protection of streams and groundwater from adverse impacts of surface and underground mining operations (80 FR 44435). With increased community and regulatory focus on mining operations and their potential to adversely affect streams and groundwater, now there is …

Fate And Impacts Of Priority Pollutant Metals In Coal Fly Ash–Soil–Switchgrass Plant Mesocosms, Olushola M. Awoyemi, E. Kudjo Dzantor

Coal Combustion and Gasification Products Journal Archive

Coal fly ash (CFA) is a coal combustion by-product containing heavy metals (HMs) that can enter and accumulate in environmental matrices. The current study assessed the fate and effects of HMs contained in CFA on Armour silt loam (ASL) soil, switchgrass plant, and leachate. Soil impact indices compared levels of HMs in the CFA-soil admixtures to control soil (without CFA). These indices include contamination factor (*C*~f~), modified degree of contamination (m*C*~d~), and pollution load index (PLI). The ratio of the levels of HMs in switchgrass root and shoot tissues to their levels in the CFA-soil admixtures were used to determine …

Sediment Transport Modelling Using Dynamic (Dis)Connectivity Prediction For A Bedrock Controlled Catchment, David Tyler Mahoney

Theses and Dissertations--Civil Engineering

The (dis)connectivity of sediment, defined as the detachment and transport of sediment from source to sink between geomorphic zones, is a major control on sediment transport rates but has seldom taken precedence in sediment transport models that focus on assessment of sediment impacts on water supply. A watershed-scale sediment transport model was formulated that incorporates sediment (dis)connectivity knowledge and subroutines and predicts sediment flux through coupling with an excessive shear stress erosion equation. The intersecting probabilities of sediment supply, detachment, transport, and (dis)connectivity produce the probability of sediment connectivity for a watershed or region of a watershed. The integration of …

Transportation Network Companies: Influencers Of Transit Ridership Trends, Richard A. Mucci

Theses and Dissertations--Civil Engineering

The major transit systems operating in San Francisco are San Francisco Municipal (MUNI), Bay Area Rapid Transit (BART), and Caltrain. The system of interest for this paper is MUNI, in particular the bus and light rail systems. During the past decade transit ridership in the area has experienced diverging growth, with bus ridership declining while rail ridership is growing significantly (Erhardt et al. 2017). Our data show that between 2009 and 2016, MUNI rail ridership increases from 146,000 to 171,400, while MUNI bus ridership decreases from 520,000 to 450,000. Direct ridership models (DRMs) are used to determine what factors are …

Prediction Of Protected-Permissive Left-Turn Phasing Crashes Based On Conflict Analysis, Shraddha Sagar

Theses and Dissertations--Civil Engineering

Left-turning maneuvers are considered to be the highest risk movements at intersections and two-thirds of the crashes associated with left-turns are reported at signalized intersections. Left-turning vehicles typically encounter conflicts from opposing through traffic. To separate conflicting movements, transportation agencies use a protected-only phase at signalized intersections where each movement is allowed to move alone. However, this could create delays and thus the concept of a protected-permissive phase has been introduced to balance safety and delays. However, the permissive part of this phasing scheme retains the safety concerns and could increase the possibility of conflicts resulting in crashes. This research …

Self-Sensing Cementitious Materials, Alexander Nicholas Houk

Theses and Dissertations--Civil Engineering

The study of self-sensing cementitious materials is a constantly expanding topic of study in the materials and civil engineering fields and refers to the creation and utilization of cement-based materials (including cement paste, cement mortar, and concrete) that are capable of sensing (i.e. measuring) stress and strain states without the use of embedded or attached sensors. With the inclusion of electrically conductive fillers, cementitious materials can become truly self-sensing. Previous researchers have provided only qualitative studies of self-sensing material stress-electrical response. The overall goal of this research was to modify and apply previously developed predictive models on cylinder compression test …

Laboratory Performance Comparison Of Vortecone Inertial Dust Scrubber To Flooded-Bed Dust Scrubber, Adam J. Levy

Theses and Dissertations--Mining Engineering

Increasing incidence of Black Lung disease in miners since the early 1990s has concerned law makers and the mining industry. New regulations promulgated by MSHA in 2014 lowered the permissible limit of dust exposure of underground workers. The hazards of respirable coal dust have been common knowledge throughout the mining industry since the enactment of the 1969 Federal Coal Mine Health and Safety Act, and many administrative controls have been put in place since its enactment.

The purpose of this thesis is to analyze the performance of a Vortecone scrubber, used in the automotive industry to remove paint overspray from …

Field-Observed Angles Of Repose For Stored Grain In The United States, Rumela Bhadra, Mark E. Casada, Sidney A. Thompson, Josephine M. Boac, Ronaldo G. Maghirang, Michael D. Montross, Aaron P. Turner, Samuel G. Mcneill

Biosystems and Agricultural Engineering Faculty Publications

Bulk grain angle of repose (AoR) is a key parameter for inventorying grain, predicting flow characteristics, and designing bins and grain handling systems. The AoR is defined for two cases, piling (dynamic) or emptying (static), and usually varies with grain type. The objective of this study was to measure piling angles of repose for corn, sorghum, barley, soybeans, oats, and hard red winter (HRW) wheat in steel and concrete bins in the United States. Angles were measured in 182 bins and 7 outdoor piles. The piling AoR for corn ranged from 15.7° to 30.2° (median of 20.4° and standard deviation …

Automated Calibration Of Electrochemical Oxygen Sensors For Use In Compost Bedded Pack Barns, John T. Evans, Michael P. Sama, Joseph L. Taraba, George B. Day

Biosystems and Agricultural Engineering Faculty Publications

The objective of this study was to develop an automated calibration process for a galvanic cell type oxygen sensor. The manufacturer recommended a two-point calibration at room temperature; however, testing revealed that the response was not linear when both the temperature and oxygen concentrations varied. Thus, additional points were needed to generate a representative calibration equation and to reduce the sensor prediction interval. The calibration process needed to be capable of automatically recording sensor response (voltage) at an array of temperatures and oxygen concentrations. Calibration gases were used to precisely control the oxygen concentration inside a small manifold, and an …

Application Of Hyperspectral Imaging And Acoustic Emission Techniques For Apple Quality Prediction, Nader Ekramirad, Ahmed Rady, Akinbode A. Adedeji, Reza Alimardani

Biosystems and Agricultural Engineering Faculty Publications

There is a growing demand for developing effective non-destructive quality assessment methods with quick response, high accuracy, and low cost for fresh fruits. In this study, hyperspectral reflectance imaging (400 to 1000 nm) and acoustic emission (AE) tests were applied to ‘GoldRush‘ apples (total number, n = 180) to predict fruit firmness, total soluble solids (TSS), and surface color parameters (L*, a*, b*) during an eight-week storage period. Partial least squares (PLS) regression, least squares support vector machine (LS-SVM), and multivariate linear regression (MLR) methods were used to establish models to predict the quality attributes of the apples. The results …

Ammonia And Carbon Dioxide Emissions Of Three Laying-Hen Housing Systems As Affected By Manure Accumulation Time, Timothy A. Shepherd, Hongwei Xin, John P. Stinn, Morgan D. Hayes, Yang Zhao, Hong Li

Biosystems and Agricultural Engineering Faculty Publications

Laying-hen housing design and management are the most significant factors affecting the generation and release of gaseous ammonia to the atmosphere. Transitioning the hen housing type from traditional high-rise (where manure is stored within the house for about one year) to modern manure-belt style (where manure is removed every 1 to 4 d and placed into long-term storage) has significantly improved in-barn air quality and reduced farm-level ammonia emissions. As a direct result of the advantages, 100% of new construction for U.S. egg production incorporates manure-belt systems that regularly remove manure from the houses. However, manure-belt system designs (e.g., active …

Development And Evaluation Of A Low-Cost Probe-Type Instrument To Measure The Equilibrium Moisture Content Of Grain, Paul R. Armstrong, Samuel G. Mcneill, Naomi Manu, Augustine Bosomtwe, James K. Danso, Enoch Osekre, George Opit

Biosystems and Agricultural Engineering Faculty Publications

Storage of grain in bags is common in Africa, Asia, and many other less developed countries making a bag probing method well-suited for moisture content (MC) measurement. A low-cost meter was developed under a USAID project to reduce post-harvest loss (PHL). The meter, referred to as the PHL meter, measures the MC of maize and other grains based on relative humidity (RH) and temperature (T) measurements obtained by a small digital sensor located in the tip of a tubular probe that can be inserted into bags of grain or other grain bulks. Measurements are used by equilibrium moisture content (EMC) …

Evaluating Ventilation Rates Based On New Heat And Moisture Production Data For Swine Production, Yanxi Lu, Morgan D. Hayes, John P. Stinn, Tami M. Brown-Brandl, Hongwei Xin

Biosystems and Agricultural Engineering Faculty Publications

Heat and moisture production (HMP) rates of animals are used for calculation of ventilation rate (VR) in animal housing. New swine HMP data revealed considerable differences from previously reported data. This project determined new design VRs and evaluated differences from previously recommended VRs. The swine production stages evaluated included gestation, farrowing, nursery, growing, and finishing. The ranges of ambient temperature and ambient relative humidity (RH) evaluated for VR were -25°C to 15°C in 10°C increments and 15% to 75% in 15% increments, respectively. Indoor set points for temperature and RH were, respectively, 15°C, 20°C, 25°C and 60%, 70%, 80% for …

Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algae can be used as a feedstock for agricultural fertilizers, livestock and poultry feeds, anaerobic digestion, and biofuel production. For each end product, the requirements for moisture content (or solids content) vary, such that a desirable water removal strategy needs to be adaptable to varying levels of water removal. Flocculation, sedimentation, and filtration were evaluated as possible strategies for thickening and dewatering of algae. The goal of this study was to validate that algae cells treated by such means could be processed by vacuum belt filters and to determine the conditions under which the solids content could be increased to …

Effects Of Biochar Treatment Of Municipal Biosolids And Horse Manure On Quality Of Runoff From Fescue Plots, Rachel Williams, Dwayne R. Edwards

Biosystems and Agricultural Engineering Faculty Publications

Land-applied horse manure and municipal biosolids can increase nutrient and bacteria concentrations in runoff. Biochar has been demonstrated to have beneficial impacts on nutrient retention and runoff quality when used to treat other land-applied organic soil amendments (e.g., poultry manure). The objective of this study was to evaluate the effects of biochar addition to horse manure and municipal biosolids on runoff concentrations of nutrients and fecal coliforms. Biochar was added at 5% to 8% (wet basis) to horse manure and biosolids that were applied to 2.4 m x 6.1 m fescue plots followed by application of simulated rainfall (102 mm …

Geopolymerization Of Coal Ash To Produce Cementless Binders, Hamid Akbari, Robert Mensah-Biney, Jonathan Simms

Coal Combustion and Gasification Products Journal Archive

The main objective of this study was to evaluate geopolymer concrete made from coal combustion by-products, disposed of in landfills, as a potential substitute for the ordinary Portland cement (OPC), which is responsible for 5-8% of the total CO2 emissions in the world. In this study, a coal fly ash sample from the Carolinas was used in a chemical process known as geopolymerization to produce a “geopolymer” binder. The developed geopolymer binder could competently substitute the OPC binder in regular concrete applications. An experimental design program was conducted to optimize parameters of the geopolymerization affecting the strength of the final …

Groundwater Monitoring And Data Analysis Under The Coal Combustion Residuals Rule, Bruce Hensel

Coal Combustion and Gasification Products Journal Archive

No abstract provided.

Ponded And Landfilled Fly Ash As A Source Of Rare Earth Elements From A Kentucky Power Plant, James C. Hower, John G. Groppo, Kevin R. Henke, Uschi M. Graham, Madison M. Hood, Prakash Joshi, Dorin V. Preda

Coal Combustion and Gasification Products Journal Archive

Twenty samples, with one composite sample built out of the 20 individual samples, of ponded ash were collected at a Kentucky power plant. The coal feed throughout the history of the power plant was central eastern Kentucky low- to moderate-S high volatile A bituminous coal. The pond was in the process of being excavated, with the ash moved to a landfill on another company property. In spite of the long history of the pond and the expected variation in coal supply, and perhaps because of the mixing due to the excavation, there is little variation in ash-basis rare earth elements …

Rare Earth Element Distribution In Fly Ash Derived From The Fire Clay Coal, Kentucky, Madison M. Hood, Ross K. Taggart, Ryan C. Smith, Heileen Hsu-Kim, Kevin R. Henke, Uschi Graham, John G. Groppo, Jason M. Unrine, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Fly ash was collected from individual mechanical and electrostatic precipitator (ESP) hoppers at a 130-MW pulverized-coal utility unit burning a southeastern Kentucky moderate- to high-S Pennsylvanian Fire Clay coal. The fly ash particle size is generally similar within each row of the mechanical and ESP hoppers, with the mean particle diameter decreasing from >36 μmin the mechanical hoppers to 6 μm in the last ESP row. Rare earth element (REE)–bearing phases occur within fine minerals and, possibly, as part of the fly ash glass phase. Transmission electron microscopy was used to identify Y-Ce-Nd-La–bearing regions within a glassy matrix. Y- and …

The Relative Impact Framework For Evaluating Coal Combustion Residual Surface Impoundment Closure Options: Applications And Lessons Learned, Ari S. Lewis, Andrew B. Bittner

Coal Combustion and Gasification Products Journal Archive

In response to the U.S. Environmental Protection Agency’s new rule regarding the disposal of coal combustion residuals (CCRs), many utilities need to re-examine their waste disposal practices and make decisions regarding if and how unlined surface impoundments (SIs) should be closed. The two primary options for closing SIs are in-place closure, with capping and engineering controls, and excavation of the CCR for transport to and re-disposal in a lined landfill. To help inform closure option decisions, we supported the Electric Power Research Institute’s development of a practical, science-based decision framework that comprehensively evaluates the potential impacts to human health and …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2016, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The 2016 Annual Technical Report for Kentucky consolidates reporting requirements for the Section 104(b) base grant award into a single document that includes: 1) a synopsis of each student research enhancement project that was conducted during the period, 2) citations for related publications, reports, and presentations, 3) a description of information transfer activities, 4) a summary of student support during the period, and 5) notable awards and achievements.

No funds were requested for general program administration activities. However, travel funds were provided to support the participation of the director and associate director in the annual meeting of the National Institutes …

Estimating The Effects Of Blasting Vibrations On The High-Wall Stability, Abhinav Sharma

Theses and Dissertations--Mining Engineering

The stability of the high-walls is one of the major concerns for open pit mines. Among the various factors affecting the stability of high-walls, blast vibrations can be an important one. In general, worldwide the established respective government regulations and industry standards are used as guidance to determine the maximum recommended levels of the peak particle velocity and frequency from the blast to avoid any effects on the structures around the mining project. However, most of the regulations are meant for buildings or houses and do not concern high-walls.

This thesis investigates the response of high-walls under the effects of …

Kentucky Traffic Collision Facts 2016, Eric R. Green, Paul A. Ross, Christopher L. Blackden, Kentucky State Police

Kentucky Transportation Center Research Report

KENTUCKY’S TRAFFIC COLLISION FACTS report is based on collision reports submitted to the Kentucky State Police Records Branch. As required by Kentucky Revised Statutes 189.635, “every law enforcement agency whose officers investigate a vehicle accident of which a report must be made...shall file a report of the accident...within ten days after investigation of the accident upon forms supplied by the bureau.” The stated purpose of this requirement is to utilize data on traffic collisions for such purposes as will improve the traffic safety program in the Commonwealth. Data contained in this report are based solely on the observations and judgements …

Quantifying The Effects Of Hydrostatic Pressure On Fibroblast Growth Factor-2 Binding By The Human Endothelium, Taylor R. Mckenty

Theses and Dissertations--Biomedical Engineering

Fluid pressures regulate endothelial cell (EC) tubulogenic activity involving fibroblast growth factor 2 (FGF-2) and its receptor, FGF receptor 2 (FGFR2). Our lab has recently shown that sustained 20 mmHg hydrostatic pressure (HP) upregulates EC sprout formation in a FGF2-dependent fashion. This upregulation of sprout formation may be due to enhanced FGF-2 / FGFR2 interactions in the presence of 20 mmHg HP. We hypothesize that exposure of ECs to 20 mmHg sustained HP enhances FGF-2 binding kinetics. We used a custom hydrostatic pressure system, immunofluorescence, and FACS to quantify FGF-2 binding by ECs in the absence or presence of a …

Age-Related Differences In The Lumbopelvic Kinematics During The Trunk Motions In The Anatomical Planes, Milad Vazirian

Theses and Dissertations--Biomedical Engineering

Management and control of the low back pain as an important health problem in the industrial societies necessitates to investigate how the risk of this disease is affected by aging. Since the abnormalities of the lumbopelvic kinematics are related to the existence or risk of low back injuries, the objective of this dissertation was set to find the age-related differences in lumbopelvic kinematics when performing basic trunk motions reaching to range of motion in different anatomical planes.

A cross-sectional study was designed where sixty asymptomatic individuals between 20–70 years old with no confounding health condition, no current or previous highly …