Engineering Commons^™

Session 1a: Nutrients And Sediment, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Nutrient Concentrations, Loads, and Yields at Ambient Water Quality Monitoring Stations
• Advancement in Watershed and Sediment Transport Modeling Using Dynamic Lateral, Longitudinal, and Vertical Sediment (Dis)connectivity Prediction
• Canine Nutrient Contributions to the Urban Environment
• Continuous Nutrient and Turbidity Sensors Reveal the Response of Watershed Sources Connected During Storm Events

Session 1b: Ecological Restoration, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• The Restoration of Cane Run Creek through Lexington’s Coldstream Park and UK’s Coldstream Research Campus
• Using Multiple Methods for Better Stream Restoration: Including 2-Dimensional Modeling
• An Ongoing Success Story: What Data, Persistence, and Patience has Enabled in the Hanging Fork Watershed
• Reclaiming Mill Creek: A Case Study in Urban Stream Restoration

Poster Session 1, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• 1.1 Evaluating Soil Characteristics in Rural and Urban Areas
• 1.2 Use of eDNA in Detection of Multiple Salamander Species in Eastern Kentucky Streams
• 1.3 Evaluation of biomass and filtration method on eDNA detection of fantail darters (Etheostoma flabellare)
• 1.4 The Impact of Agricultural Development on Nutrient Contamination Hotspots Within a Small, Intermittent Watershed at EKU’s Meadowbrook Farm, Madison County, Kentucky
• 1.5 How Does Drought Length Impact the Runoff and Nutrient Storm Response in an Agricultural, Intermittent Catchment in Central Kentucky?
• 1.6 Analyzing Sanitary Sewer Overflow Sensitivity to Storm Characteristics
• 1.7 Evaluating Soil Properties in No-Till and Conventional Tillage Systems
• 1.8 …

Plenary Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

No abstract provided.

Proceedings Of 2019 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was planned and conducted as a part of the state water resources research institute annual program that is supported by Grant/Cooperative Agreement Number G16AP00055 from the United States Geological Survey. The contents of this proceedings document and the views and conclusions presented at the symposium are solely the responsibility of the individual authors and presenters and do not necessarily represent the official views of the USGS or of the symposium organizers and sponsors. This publication is produced with the understanding that the United States Government is authorized to reproduce and distribute reprints for government purposes. Mention of trade …

Photocatalytic Degradation Of Profenofos And Triazophos Residues In The Chinese Cabbage, Brassica Chinensis, Using Ce-Doped Tio2, Xiangying Liu, You Zhan, Zhongqin Zhang, Lang Pan, Lifeng Hui, Kailin Liu, Xuguo Zhou, Lianyang Bai

Entomology Faculty Publications

Pesticides have revolutionized the modern day of agriculture and substantially reduced crop losses. Synthetic pesticides pose a potential risk to the ecosystem and to the non-target organisms due to their persistency and bioaccumulation in the environment. In recent years, a light-mediated advanced oxidation processes (AOPs) has been adopted to resolve pesticide residue issues in the field. Among the current available semiconductors, titanium dioxide (TiO₂) is one of the most promising photocatalysts. In this study, we investigated the photocatalytic degradation of profenofos and triazophos residues in Chinese cabbage, Brassica chinensis, using a Cerium-doped nano semiconductor TiO₂ (TiO …

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O₂(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O₂(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …

Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C₁–C₇₀₊) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO₂) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. …

Quantifying The Impact Of Weather Events On Travel Time And Reliability, Xu Zhang, Mei Chen

Kentucky Transportation Center Faculty and Researcher Publications

It is of practical significance to understand the specific impact of weather events on the operating condition of the surface transportation system so that proactive and reactive strategies can be quickly implemented by transportation agencies to minimize the negativity resulted from adverse weather events. Many studies have been conducted on quantifying such effects yet suffer from limitations such as subjectively defining a time window under uncongested conditions and not being able to account for the severe impact from weather events which result in travel time unreliability. To overcome those shortcomings in existing literature, an integrated data mining framework based on …

A Systematic Study On The Effects Of Dimensional And Materials Tolerances On Permanent Magnet Synchronous Machines Based On The Ieee Std 1812, Narges Taran, Vandana Rallabandi, Dan M. Ionel, Ping Zhou, Mark Theile, Greg Heins

Power and Energy Institute of Kentucky Faculty Publications

In the process of designing and manufacturing an electrical machine, a systematic study of dimensional and material tolerances is of the utmost importance. This paper proposes a systematic method by which the effect of design specification variations on permanent magnet (PM) synchronous machine performance may be identified and quantified. The method combines design of experiments techniques, open-circuit and short-circuit physical measurements, and virtual test simulations conducted based on the recently approved IEEE Std 1812 testing guide. Three case studies, two provided by a spoke-type PM radial field machine configuration, in two designs with different electromagnetic loading, and an axial flux …

Development Of A Laboratory Test For Evaluation Of Geogrid Materials, Charlie Sun, R. Clark Graves

Kentucky Transportation Center Research Report

Two test methods have been developed in this project. The first test method is a compression test of a cylinder constructed out of geogrid material and filled with crushed stone. This test is simple and can be easily performed. Only a compression loading machine is needed for this test. The sample preparation is straightforward. However, multiple tests must be run to analyze geogrids with different ultimate tensile strength or different grid aperture size on machine direction and cross machine direction. The second test method is Geogrid Bearing Ratio (GBR) test. This test was developed to measure the effect of geogrids …

A Pilot Study Identifying Brain-Targeting Adaptive Immunity In Pediatric Extracorporeal Membrane Oxygenation Patients With Acquired Brain Injury, Sterling B. Ortega, Poornima Pandiyan, Jana Windsor, Vanessa O. Torres, Uma M. Selvaraj, Amy Lee, Michael Morriss, Fenghua Tian, Lakshmi Raman, Ann M. Stowe

Neurology Faculty Publications

OBJECTIVES: Extracorporeal membrane oxygenation provides short-term cardiopulmonary life support, but is associated with peripheral innate inflammation, disruptions in cerebral autoregulation, and acquired brain injury. We tested the hypothesis that extracorporeal membrane oxygenation also induces CNS-directed adaptive immune responses which may exacerbate extracorporeal membrane oxygenation-associated brain injury.

DESIGN: A single center prospective observational study.

SETTING: Pediatric and cardiac ICUs at a single tertiary care, academic center.

PATIENTS: Twenty pediatric extracorporeal membrane oxygenation patients (0-14 yr; 13 females, 7 males) and five nonextracorporeal membrane oxygenation Pediatric Logistic Organ Dysfunction score matched patients.

INTERVENTIONS: None.

MEASUREMENTS AND MAIN RESULTS: Venous blood samples were …

Process Analysis For Disposal Of Surplus Property, Bryan Gibson, Christopher Van Dyke, Candice Y. Wallace, Jeff Jasper, Steven Douglas Kreis

Kentucky Transportation Center Research Report

The Kentucky Transportation Cabinet (KYTC) frequently acquires property to secure the right of way for transportation projects. Some property may eventually be declared excess and deemed surplus, enabling the Cabinet to dispose of it. Excess property can be declared surplus by an official order of the Secretary or Commissioner of the Department of Highways. Current law and policy require that KYTC undertake a 21-step process to dispose of surplus property, including reviews by the Governor, Finance and Administration Cabinet, and several KYTC personnel. The Cabinet lacks the personnel required to undertake the lengthy disposal process. This report provides background on …

Effect Of Stoniness On The Hydraulic Properties Of A Soil From An Evaporation Experiment Using The Wind And Inverse Estimation Methods, Nerea Arias, Iñigo Virto, Alberto Enrique, Paloma Bescansa, Riley Walton, Ole O. Wendroth

Plant and Soil Sciences Faculty Publications

Stony soils are distributed all over the world. The study of their characteristics has gained importance lately due to their increasing use as agricultural soils. The effect that rock fragments exert on the soil hydraulic properties is difficult to measure in situ, and is usually derived from the fine earth properties. However, the corrections used so far do not seem accurate for all types of stony soils. Our objective was to assess the adequacy of estimating the hydraulic properties of a stony soil from the fine earth ones by correcting the latter by the volume occupied by rock fragments. To …

Method Of Increasing Mass Transfer Rate Of Acid Gas Scrubbing Solvents, Joseph E. Remias, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty Patents

A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Is Dns Ready For Ubiquitous Internet Of Things?, Zhiwei Yan, Hongtao Li, Sherali Zeadally, Yu Zheng, Guanggang Geng

Information Science Faculty Publications

The vision of the Internet of Things (IoT) covers not only the well-regulated processes of specific applications in different areas but also includes ubiquitous connectivity of more generic objects (or things and devices) in the physical world and the related information in the virtual world. For example, a typical IoT application, such as a smart city, includes smarter urban transport networks, upgraded water supply, and waste-disposal facilities, along with more efficient ways to light and heat buildings. For smart city applications and others, we require unique naming of every object and a secure, scalable, and efficient name resolution which can …

Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

Pt represents an effective promoter of supported Ni catalysts in the transformation of tristearin to green diesel via decarbonylation/decarboxylation (deCO_x), conversion increasing from 2% over 20% Ni/Al₂O₃ to 100% over 20% Ni-0.5% Pt/Al₂O₃ at 260 °C. Catalyst characterization reveals that the superior activity of Ni-Pt relative to Ni-only catalysts is not a result of Ni particle size effects or surface area differences, but rather stems from several other phenomena, including the improved reducibility of NiO when Pt is present. Indeed, the addition of a small amount of Pt to the supported Ni …

Barn Considerations For Cash Hay Operations, Morgan D. Hayes

Kentucky Alfalfa and Stored Forage Conference

A well designed and built a barn can be invaluable for cash hay operation. Barn provide opportunity to reduce losses in dry matter and help maintain quality throughout the winter. There are numerous styles of barns that hay producers can purchase or build themselves. Wood frame structures, often with metal roofs and metal sides, are fairly common. You can also build barns with a steel structure with or without metal siding on the walls. Hoop barns are another common hay storage structure - particularly common with round bale storage. All, however, provide valuable storage for hay. There are four areas …

Near-Surface Material Phases And Microstructure Of Scandate Cathodes, Xiaotao Liu, Bernard K. Vancil, Matthew J. Beck, Thomas John Balk

Chemical and Materials Engineering Faculty Publications

Scandate cathodes that were fabricated using the liquid-solid process and that exhibited excellent emission performance were characterized using complementary state-of-the-art electron microscopy techniques. Sub-micron BaAl₂O₄ particles were observed on the surfaces and edges of tungsten particles, as seen in cross-section samples extracted from the scandate cathode surface regions. Although several BaAl₂O₄ particles were observed to surround smaller Sc₂O₃ nanoparticles, no chemical mixing of the two oxides was detected, and in fact the distinct oxide phases were separately verified by chemical analysis and also by 3D elemental tomography. Nanobeam electron diffraction confirmed …

Potential Economic Impacts Of Allocating More Land For Bioenergy Biomass Production In Virginia, Thomas O. Ochuodho, Janaki R. R. Alavalapati, Pankaj Lal, Domena A. Agyeman, Bernabas Wolde, Pralhad Burli

Forestry and Natural Resources Faculty Publications

The growing attention to renewable energy and rural development has created greater demand for production of biomass feedstock for bioenergy. However, forest growth rates and the amount of land in most existing forests may not be sufficient to sustainably supply the forest biomass required to support existing forest products industries and the expanding bioenergy industry. Additionally, concerns about agricultural land use competition have dampened expansion of biomass production on agricultural land base. One of the ways to meet the growing forest biomass feedstock demand for bioenergy production is by allocating currently marginal non-forested land for growing bioenergy feedstocks. In Virginia, …

Design And Analysis Of Long-Stroke Planar Switched Reluctance Motor For Positioning Applications, Su-Dan Huang, Guang-Zhong Cao, Yeping Peng, Chao Wu, Deliang Liang, Jiangbiao He

Electrical and Computer Engineering Faculty Publications

This paper presents the design, control, and experimental performance evaluation of a long-stroke planar switched reluctance motor (PSRM) for positioning applications. Based on comprehensive consideration of the electromagnetic and mechanical characteristics of the PSRM, a motor design is first developed to reduce the force ripple and deformation. A control scheme with LuGre friction compensation is then proposed to improve the positioning accuracy of the PSRM. Furthermore, this control scheme is proven to ensure the stable motion of the PSRM system. Additionally, the response speed and steady-state error of the PSRM system with this control scheme are theoretically analyzed. Finally, the …

Carboxylic Acids Accelerate Acidic Environment-Mediated Nanoceria Dissolution, Robert A. Yokel, Matthew L. Hancock, Eric A. Grulke, Jason M. Unrine, Alan K. Dozier, Uschi M. Graham

Pharmaceutical Sciences Faculty Publications

Ligands that accelerate nanoceria dissolution may greatly affect its fate and effects. This project assessed the carboxylic acid contribution to nanoceria dissolution in aqueous, acidic environments. Nanoceria has commercial and potential therapeutic and energy storage applications. It biotransforms in vivo. Citric acid stabilizes nanoceria during synthesis and in aqueous dispersions. In this study, citrate-stabilized nanoceria dispersions (∼4 nm average primary particle size) were loaded into dialysis cassettes whose membranes passed cerium salts but not nanoceria particles. The cassettes were immersed in iso-osmotic baths containing carboxylic acids at pH 4.5 and 37 °C, or other select agents. Cerium atom material …

Increasing Salt Rejection Of Polybenzimidazole Nanofiltration Membranes Via The Addition Of Immobilized And Aligned Aquaporins, Priyesh Ashokrao Wagh, Xinyi Zhang, Ryan Blood, Peter M. Kekenes-Huskey, Prasangi Rajapaksha, Yinan Wei, Isabel C. Escobar

Chemical and Materials Engineering Faculty Publications

Aquaporins are water channel proteins in cell membrane, highly specific for water molecules while restricting the passage of contaminants and small molecules, such as urea and boric acid. Cysteine functional groups were installed on aquaporin Z for covalent attachment to the polymer membrane matrix so that the proteins could be immobilized to the membranes and aligned in the direction of the flow. Depth profiling using x-ray photoelectron spectrometer (XPS) analysis showed the presence of functional groups corresponding to aquaporin Z modified with cysteine (Aqp-SH). Aqp-SH modified membranes showed a higher salt rejection as compared to unmodified membranes. For 2 M …

Aid Project Summary Report For Intelligent Compaction, David Q. Hunsucker, Kean H. Ashurst Jr., Brad W. Rister

Kentucky Transportation Center Research Report

This study reviews data from five roadway construction projects on which intelligent compaction (IC) techniques were used to achieve the more uniform compaction of road-building materials. Kentucky Transportation Center (KTC) researchers looked at IC data collected from these projects — resulting in the production of eight analyzable data sets — to determine whether they complied with the special construction note included in contract documents. The report also compares the intelligent compaction measurement value (ICMV) collected on each project to traditional laboratory results. Researchers used Veta software to analyze geospatial data collected from IC machines during construction work. Of the data …

Fluorescence Of Cdse/Zns Quantum Dots In Toluene: Effect Of Cyclic Temperature, Ting Chen, Weiling Luan, Shaofu Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Quantum dots (QDs) are the potential material for the application in optical thermometry, and have been successfully applied to solar cells, LEDs, bio-labeling, structural health monitoring, etc. In this paper, we study the fluorescence properties of CdSe/ZnS QDs in toluene under the action of heating-cooling cycles. The experimental results show that, in a heating-cooling cycle, increasing temperature causes red-shift of the emission peak and the decrease of the PL intensity, and decreasing temperature causes blue-shift of the emission peak and the increase of the PL intensity. The surface structures of the QDs likely are dependent on the cycle numbers, which …

Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCO_x) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al₂O₃ in the deCO_x of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …

Coatings On Mammalian Cells: Interfacing Cells With Their Environment, Kara A. Davis, Pei-Jung Wu, Calvin F. Cahall, Cong Li, Anuhya Gottipati, Brad J. Berron

Chemical and Materials Engineering Faculty Publications

The research community is intent on harnessing increasingly complex biological building blocks. At present, cells represent a highly functional component for integration into higher order systems. In this review, we discuss the current application space for cellular coating technologies and emphasize the relationship between the target application and coating design. We also discuss how the cell and the coating interact in common analytical techniques, and where caution must be exercised in the interpretation of results. Finally, we look ahead at emerging application areas that are ideal for innovation in cellular coatings. In all, cellular coatings leverage the machinery unique to …

Achieving Superelasticity In Additively Manufactured Niti In Compression Without Post-Process Heat Treatment, Narges Shayesteh Moghaddam, Soheil Saedi, Amirhesam Amerinatanzi, Alejandro Hinojos, Ali Ramazani, Julia Kundin, Michael J. Mills, Haluk E. Karaca, Mohammad Elahinia

Mechanical Engineering Faculty Publications

Shape memory alloys (SMAs), such as Nitinol (i.e., NiTi), are of great importance in biomedical and engineering applications due to their unique superelasticity and shape memory properties. In recent years, additive manufacturing (AM) processes have been used to produce complex NiTi components, which provide the ability to tailor microstructure and thus the critical properties of the alloys, such as the superelastic behavior and transformation temperatures (TTs), by selection of processing parameters. In biomedical applications, superelasticity in implants play a critical role since it gives the implants bone-like behavior. In this study, a methodology of improving superelasticity in Ni-rich NiTi components …

Effect Of Crystallization Modes In Tips-Pentacene/Insulating Polymer Blends On The Gas Sensing Properties Of Organic Field-Effect Transistors, Jung Hun Lee, Yena Seo, Yeong Don Park, John E. Anthony, Do Hun Kwak, Jung Ah Lim, Sunglim Ko, Ho Won Jang, Kilwon Cho, Wi Hyoung Lee

Center for Applied Energy Research Faculty and Staff Publications

Blending organic semiconductors with insulating polymers has been known to be an effective way to overcome the disadvantages of single-component organic semiconductors for high-performance organic field-effect transistors (OFETs). We show that when a solution processable organic semiconductor (6,13-bis(triisopropylsilylethynyl)pentacene, TIPS-pentacene) is blended with an insulating polymer (PS), morphological and structural characteristics of the blend films could be significantly influenced by the processing conditions like the spin coating time. Although vertical phase-separated structures (TIPS-pentacene-top/PS-bottom) were formed on the substrate regardless of the spin coating time, the spin time governed the growth mode of the TIPS-pentacene molecules that phase-separated and crystallized on the …

Computationally Efficient, Multi-Domain Hybrid Modeling Of Surface Integrity In Machining And Related Thermomechanical Finishing Processes, Julius M. Schoop, David Adeniji, Ian S. Brown

Mechanical Engineering Faculty Publications

In order to enable more widespread implementation of sophisticated process modeling, a novel, rapidly deployable multi-physics hybrid model of surface integrity in finishing operations is proposed. Rather than modeling detailed chip formation mechanics, as is common in numerical models, the proposed models integrates existing analytical and semi-empirical models of the plastic, elastic, thermal and thermodynamic domains. Using this approach, highly complex surface integrity phenomena such as residual stresses, grain size, phase composition, microhardness profile, etc. can be accurately predicted in a manner of seconds. It is envisioned that this highly efficient modeling scheme will drive new innovations in surface engineering.