Engineering Commons^™

Minimizing Wash Water Usage After Acid Hydrolysis Pretreatment Of Biomass, Noaa Frederick

Biological and Agricultural Engineering Undergraduate Honors Theses

Abstract Dilute acid pretreatment, needed to prepare biomass for saccharification, results in the production of a number of byproducts, which inhibit subsequent enzymatic hydrolysis and fermentation steps. In order to improve saccharification yields in the enzyme hydrolysis step, the pretreated biomass is often rinsed with room temperature water to remove these byproducts. High-density poplar was pretreated with 1% dilute sulfuric acid at 140 ºC for 40 minutes. After pretreatment the biomass was washed with water volumes equal to 0, 1 ½, or 3 times the biomass volume. The rinsed biomass was then enzymatically hydrolyzed and the concentrations of byproducts and …

New Effects Of Aging And Lattice Intercalation On Surface Properties Of Titanate Nanobelts, Roger Williams

Graduate Theses and Dissertations

Titanate nanobelts (NBs) have structural characteristics beyond that of clays. Due to a negatively charged lattice matrix of edge-shared TiO6-octahedra, the location of intercalated cations within the interlayer space may dictate the charge-conductions. This environment may in turn govern the lattice-framework's stability and surface properties, based upon our preliminary

data.

On that basis, these nanomaterials have been found in our lab to possess superb biological compatibility that is closely related to the types of the intercalated cations. In addition, a prolonged agitation was proven to enable us to manipulate the titanate NBs' length. In a parallel study, a ripening was …

Surveillance Planning Against Smart Insurgents In Complex Terrain, Nabil Lehlou

Graduate Theses and Dissertations

This study is concerned with finding a way to solve a surveillance system allocation problem based on the need to consider intelligent insurgency that takes place in a complex geographical environment. Although this effort can be generalized to other situations, it is particularly geared towards protecting military outposts in foreign lands. The technological assets that are assumed available include stare-devices, such as tower-cameras and aerostats, as well as manned and unmanned aerial systems. Since acquiring these assets depends on the ability to control and monitor them on the target terrain, their operations on the geo-location of interest ought to be …

Cad Tools For Synthesis Of Sleep Convention Logic, Parviz Palangpour

Graduate Theses and Dissertations

This dissertation proposes an automated flow for the Sleep Convention Logic (SCL) asynchronous design style. The proposed flow synthesizes synchronous RTL into an SCL netlist. The flow utilizes commercial design tools, while supplementing missing functionality using custom tools. A method for determining the performance bottleneck in an SCL design is proposed. A constraint-driven method to increase the performance of linear SCL pipelines is proposed. Several enhancements to SCL are proposed, including techniques to reduce the number of registers and total sleep capacitance in an SCL design.

Load Mixing To Improve Container Utilization, Crystal Wilson

Graduate Theses and Dissertations

The under utilization in trucking leads to nearly 5 billion gallons of wasted fuel annually. One way to recapture part of this waste is to use collaborative logistics. This research focuses on one specific aspect of collaborative logistics: load mixing. Load mixing is the idea of mixing two or more items of different weights in the same container to reduce the number of trucks needed.

Load mixing is similar to other packing problems such as the knapsack and container loading problems. However, traditional packing problems typically only assume a single type of capacity (e.g., weight), whereas load mixing must simultaneously …

Design And Implementation Of Wireless Point-Of-Care Health Monitoring Systems: Diagnosis For Sleep Disorders And Cardiovascular Diseases, Se Chang Oh

Graduate Theses and Dissertations

Chronic sleep disorders are present in 40 million people in the United States. More than 25 million people remain undiagnosed and untreated, which accounts for over $22 billion in unnecessary healthcare costs. In addition, another major chronic disease is the heart diseases which cause 23.8% of the deaths in the United States. Thus, there is a need for a low cost, reliable, and ubiquitous patient monitoring system. A remote point-of-care system can satisfy this need by providing real time monitoring of the patient's health condition at remote places. However, the currently available POC systems have some drawbacks; the fixed number …

Synthesis And Characterization Of Iron Pyrite Nanocrystals For Photovoltaic Devices, Scott Curtis Mangham

Graduate Theses and Dissertations

Iron pyrite nanocrystals have been synthesized using a hot-injection method with a variety of amines and characterized with properties necessary for photovoltaic devices. The iron pyrite nanocrystals were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, optical absorption, micro-Raman, and micro-Photoluminescence. The optical absorbance spectra showed the large absorption in the visible and near infrared spectral range for the nanocrystals as well as to show the band gap. The face-centered cubic crystal structure of the iron pyrite nanocrystals was shown by matching the measured X-ray diffraction pattern to a face-centered cubic iron pyrite reference pattern. Using Bragg's law …

Bio-Separation Process Improvement Via Genomic Manipulation: Development Of Novel Strains For Use In Immobilized Metal Affinity Chromatography (Imac), Ryan Curtis Haley

Graduate Theses and Dissertations

The dissertation is comprised of three parts. Part I describes proteomic analysis of native bacterial proteins from Escherichia coli (E.coli) that bind during Immobilized Metal Affinity Chromatography (IMAC). Part II describes the value in exploiting proteome based data as a tool toward the design an E. coli expression strain that is particularly useful when Immobilized Metal Affinity Chromatography is employed as the initial capture step of a homologous protein purification process. Part III describes a methodology of chromosomal mapping of all contaminant gene products.

The objective of Part I was to identify all E. coli proteins that bind to Co(II), …

Improvements In Microdialysis Sampling Extraction Efficiency Using Recycled Flow, Justin Cole Deaton

Graduate Theses and Dissertations

Incomplete recovery during microdialysis sampling is hindering important research in neurology, proteomics, and immunology. Although the current generalized solution, decreasing volumetric flow rates (Q), has been and will remain to be a useful strategy it has reached it's a physical limitation due to evaporation at the collection site. Consequently, many important signaling molecules, such as signaling proteins, remain difficult to study. It is more fundamental to consider relative recovery as a function of the interaction time between the perfusate and the environment surrounding the probe.

In this work an increase in relative recovery was predicted by a mathematical model. Using …

Expression, Production, And Purification Of Novel Therapeutic Proteins, Mckinzie Shea Fruchtl

Graduate Theses and Dissertations

Interest in the production of recombinant proteins consisting of collagen binding domain (CBD) fused to a bioactive material has increased due to the targeting/attachment capabilities of CBD. For example, CBD fusions can be applied to the reversing of bone density loss and the repair of the eardrum, specifically, by choosing an appropriate fusion partner (parathyroid hormone or epidermal growth factor). The production of CBD fusions was examined using batch and fed-batch culturing of Escherichia coli to express the fusion proteins, and affinity chromatography to isolate the final product.

Different medium formulations, feeding strategies, and induction methods were tested in order …

Iii-V Bismide Optoelectronic Devices, Dongsheng Fan

Graduate Theses and Dissertations

This dissertation explores modeling, molecular beam epitaxy growth, and fabrication of III-V bismide optoelectronic devices, which are of great importance in modern applications of telecommunication, gas sensing, environment monitoring, etc. In the current room-temperature continuous-wave operational GaSb-based type-I InGaAsSb/AlGaInAsSb quantum well laser diodes in 3-4 um mid-wavelength range, the lasing wavelength and performance of the devices are limited due to the lack of hole confinement in the active regions. In this dissertation, a novel GaSb-based GaInAsSbBi material is proposed to replace the conventional InGaAsSb material in the quantum well region, which enables the laser diodes achieve up to 4 µm …

Design, Layout, And Testing Of A Silicon Carbide-Based Under Voltage Lock-Out Circuit, Michael Dalan Glover

Graduate Theses and Dissertations

Silicon carbide-based power devices play an increasingly important role in modern power conversion systems. Finding a means to reduce the size and complexity of these systems by even incremental amounts can have a significant impact on cost and reliability. One approach to achieving this goal is the die-level integration of gate driver circuitry with the SiC power devices. Aside from cost reductions, there are significant advantages to the integration of the gate driver circuits with the power devices. By integrating the gate driver circuitry with the power devices, the parasitic inductances traditionally seen between the gate driver and the switching …

Synthesis Of Optimized Inp/Zns Core/Shell Nanocrystals And Tio2 Nanotubes For Quantum Dot Sensitized Solar Cells, Seungyong Lee

Graduate Theses and Dissertations

Synthesis of InP/ZnS core/shell nanocrystals and TiO₂ nanotubes and the optimization study to couple them together were explored for quantum dot sensitized solar cells. Its intrinsic nontoxicity makes the direct band gap InP/ZnS core/shell be one of the most promising semiconductor nanocrystals for optoelectric applications, with the advantage of tuning the optical absorption range in the desired solar spectrum region. Highly luminescent and monodisperse InP/ZnS nanocrystals were synthesized in a non-coordinating solvent. By varying the synthesis scheme, different size InP/ZnS nanocrystals with emission peaks ranging from 520 nm to 620 nm were grown. For the purpose of ensuring air …

Device Characterization And Compact Modeling Of The Sige Hbt In Extreme Temperature Environments, Beth Olivia Woods

Graduate Theses and Dissertations

The silicon germanium heterojunction bipolar transistor, SiGe HBT, has very high frequency response but limited voltage range. Commercial communication applications in wireless and system integration have driven the development of the SiGe HBT. However, the device's excellent electrical performance goes beyond the commercial environment. The SiGe HBT performs exceptionally at low temperatures. The device DC current gain and AC small-signal gain significantly increase in the cryogenic temperature range. Applications at low temperatures with expansive temperature range specifications need an HBT compact model to accurately represent the device's performance.

In this work, a compact model referenced at 300K was developed to …

Enhanced Tribological Properties Of Surfaces Patterned With Su8/Dlc Microstructures, Luke Osborn

Inquiry: The University of Arkansas Undergraduate Research Journal

In tribology (the study of friction, wear, and lubrication), it is known that micro-textured surfaces can reduce friction due to decreased contact area between two surfaces. The problem with many micro-textures, however, is their inability to withstand significant amounts of wear, thus limiting their potential uses and overall effectiveness. In this study, connected and isolated microstructures of SU8, a negative tone photoresist, coated with and without diamond-like carbon (DLC), were designed to investigate the effects of these microstructures and DLC coating on the tribological performance of a surface. Friction and wear studies were conducted using a tribometer; surface topography and …

Preparation Of New Versatile And Implantable Titanate Nanofiber-Bioscaffolds Via Efficient Cation Exchanges, Keaton Piper

Inquiry: The University of Arkansas Undergraduate Research Journal

For the first time in the implantable biomaterials field, efficient hydrothermal cation exchange methods were developed suitable for mass-production of implantable material. The cation exchange conditions were performed by various methods of temperature, pressure, and time exposure. To confirm both chemical and physical alteration of the scaffold, XRD shift analysis, EDX atomic composition, and SEM imaging were conducted. The optimal results are to use aqueous solutions of 0.5 M chloride salts in sealed heated containers at 180 ̊C for eight hours. Cation exchange capacities are determined for K+, Na+, Li+, Ca2+, and Sr2+; future studies demanding durable, highly specific composition …

Valence-Length Correlations For Chemical Bonds From Atomic Orbital Exponents, F. D. Hardcastle

Journal of the Arkansas Academy of Science

Pauling’s empirical bond valence-length correlation has proven valuable because it offers a quick and convenient way of checking and evaluating molecular structures and determining oxidation states from measured bond lengths. In this study, a simplified quantum-mechanical approach was used to derive Pauling’s empirical bond valence-length relationship by considering overlap of hydrogen-like orbitals. An expression for the b “empirical” fitting parameter was derived in terms of atomic-orbital exponents. A new set of orbital exponents is presented using published atomic/covalent radii and a continuous function for the effective principal quantum. The b parameters calculated from the orbital exponents are consistent with bond …

Trajectory Generation For Stair Ascent Walking Using Rayleigh Oscillator, T. Afzal, Andrew B. Wright, Kamran Iqbal

Journal of the Arkansas Academy of Science

This paper describes a trajectory generation technique for stair-ascent walking. The knee, hip and ankle joint trajectory during stair ascent are generated using mutually coupled, nonlinear oscillators. The parameters of the oscillators are tuned using the harmonic balance method, which converts the nonlinear differential equations to a set of algebraic equations. Fourier analysis of data generated by stair-ascent walking is performed to extract the amplitude and the phase of the dominant frequency components for each joint trajectory. The solution for the oscillator is assumed to be a sinusoidal wave and then by harmonic balance method the parameters of the oscillator …

Titanium-Oxygen Bond Length -Bond Valence Relationship, D. Dodd, F. D. Hardcastle, S. Laffoon

Journal of the Arkansas Academy of Science

A bond length–bond valence correlation is a simple method of checking and evaluating molecular structures and is of great interest in chemistry, biology, geology, and material science. Recently, we used quantum-mechanical arguments to derive Pauling’s bond length-valence relationship and to define the adjustable fitting parameter b in terms of atomic-orbital exponents. Improved orbital exponents were generated for elements 1-103 using published atomic radii and single-bond covalent radii as well as a continuous function for effective principal quantum number. In this study, we use orbital exponents for titanium (Ti) and oxygen (O) to generate a bond length-valence relationship for Ti-O bonds. …

Prestress Losses In Lightweight Self-Consolidating Concrete, Jared Bymaster

Graduate Theses and Dissertations

While much research has been performed on lightweight concrete and self-consolidating concrete (SCC), the knowledge of prestress losses in lightweight self-consolidating concrete (LWSCC) is still limited. LWSCC has the benefits of increased flowability, reduced placement labor, and decreased shipping cost compared to conventional concrete. This research program included the study of 14 SCC beams cast with expanded clay, expanded shale, and limestone aggregates. Strains in the beams were measured with vibrating-wire strain gages, and the measured prestress losses were compared with current AASHTO methods for calculating prestress losses. The AASHTO approximate method better predicted actual losses than did the AASHTO …

Silica Nanoparticle-Based Coatings With Superhydrophilic And Superhydrophobic Properties, Robert Andrew Fleming

Graduate Theses and Dissertations

Superhydrophilic and superhydrophobic surfaces have potential for implementation into a variety of fields, including self-cleaning surfaces, anti-fogging transparent materials, and biomedical applications. In this study, sandblasting, oxygen plasma treatments, silica nanoparticle films, and a low surface energy fluorocarbon film were employed to change the natural surface wettability of titanium, glass, and polyethylene terephthalate (PET) substrates, with an aim to produce superhydrophilic and superhydrophobic behavior. The effects of these surface modifications are characterized by water contact angles (WCAs), surface wetting stability, surface morphology and roughness, surface elemental composition, and optical transmittance measurements. The results show that stable superhydrophilic and superhydrophobic surfaces …

Development Of Mems-Based Corrosion Sensor, Feng Pan

Graduate Theses and Dissertations

This research is to develop a MEMS-based corrosion sensor, which is used for monitoring uniform, galvanic corrosion occurring in infrastructures such as buildings, bridges. The corrosion sensor is made up of the composite of micro/nano metal particles with elastomers. The mechanism of corrosion sensor is based on the mass transport of corrosive species through the sensor matrix. When the metal particles in the matrix corrode, the electrical resistivity of the material increases due to increasing particle resistances or reduction of conducting pathways. The corrosion rate can be monitored by detecting the resistivity change in sensing elements. The life span of …

Distribution Map Of Multi-Walled Carbon Nanotubes In A Refrigerant/Oil Mixture Within A 2.5 Ton Unitary Air-Conditioner, Warren Russell Long

Graduate Theses and Dissertations

In recent years, nanoparticles have received considerable attention as a potential additive to heat transfer fluids (i.e. refrigerant) in order to increase the heat transfer capabilities of these fluids. The potential of carbon nanotubes (CNTs) to exit the compressor, migrate throughout a vapor compression air conditioning system, and possibly foul the components of such a system was experimentally investigated in this research. Six grams of CNTs were dispersed in the polyol ester oil used by a 2.5 ton (8.79 kW) unitary air conditioning system, which was continuously operated for 168 hours. After this time, the unit was shut down and …

Design, Fabrication, Testing Of Cnt Based Isfet And Characterization Of Nano/Bio Materials Using Afm, Zhuxin Dong

Graduate Theses and Dissertations

A combination of Carbon Nanotubes (CNTs) and Ion Selective Field Effect Transistor (ISFET) is designed and experimentally verified in order to develop the next generation ion concentration sensing system. Micro Electro-Mechanical System (MEMS) fabrication techniques, such as photolithography, diffusion, evaporation, lift-off, packaging, etc., are required in the fabrication of the CNT-ISFET structure on p-type silicon wafers. In addition, Atomic Force Microscopy (AFM) based surface nanomachining is investigated and used for creating nanochannels on silicon surfaces. Since AFM based nanomanipulation and nanomachining is highly controllable, nanochannels are precisely scratched in the area between the source and drain of the FET where …

Performance And Cost Analysis Of A Structured Concrete Thermocline Thermal Energy Storage System, Matt Nicholas Strasser

Graduate Theses and Dissertations

Increasing global energy demands and diminishing fossil fuel resources have raised increased interest in harvesting renewable energy resources. Solar energy is a promising candidate, as sufficient irradiance is incident to the Earth to supply the energy demands of all of its inhabitants. At the utility scale, concentrating solar power (CSP) plants provide the most cost-efficient method of harnessing solar energy for conversion to electrical energy. A major roadblock to the large-scale implementation of CSP plants is the lack of thermal energy storage (TES) that would allow the continued production of electricity during the absence of constant irradiance. Sensible heat TES …

Comprehensive Drainage Study Of The Upper Reach Of College Branch In Fayetteville, Arkansas, Kathryn Lea Mccoy

Graduate Theses and Dissertations

College Branch is a stream with headwaters located on the University of Arkansas campus. The stream flows through much of the west side of campus, gaining discharge and enlarging its channel as it meanders to the south. College Branch has experienced erosion and flooding issues in recent years due to increased urbanization of its watershed and increased runoff volume.

The purpose of this project was to develop a comprehensive drainage study of College Branch on the University of Arkansas campus. Storm runoff and flood flow patterns were evaluated in order to understand the hydraulics and hydrology of the watershed and …

Implementing Conductive Concrete With Photovoltaic Energy To Develop Anti-Icing Airfield Runways, Adam Benjamin Osweiler

Graduate Theses and Dissertations

Snow and ice accumulation on airport runways force airports to cancel or significantly delay flights. Winter weather can also drastically affect airport safety during times of aircraft takeoff and landing. During these times, countless dollars are used to remove snow and return airports to their functional conditions. In this thesis, a conductive concrete solar energy system will be examined in order to prevent snow and ice accumulation. The objective of this research is to implement a conductive concrete overlay system on airport runways in conjunction with photovoltaic energy so that no frost precipitation accumulates on the runway surface.

Modeling, Fabrication And Characterization Of Scalable Electroless Gold Plated Nanostructures For Enhanced Surface Plasmon Resonance, Gyoung Gug Jang

Graduate Theses and Dissertations

The scientific and industrial demand for controllable thin gold (Au) film and Au nanostructures is increasing in many fields including opto-electronics, photovoltaics, MEMS devices, diagnostics, bio-molecular sensors, spectro-/microscopic surfaces and probes. In this study, a novel continuous flow electroless (CF-EL) Au plating method is developed to fabricate uniform Au thin films in ambient condition. The enhanced local mass transfer rate and continuous deposition resulting from CF-EL plating improved physical uniformity of deposited Au films and thermally transformed nanoparticles (NPs). Au films and NPs exhibited improved optical photoluminescence (PL) and surface plasmon resonance (SPR), respectively, relative to batch immersion EL (BI-EL) …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …