Engineering Commons^™

The Long-Term Performance Of Concrete Crack And Deck Surface Sealers, Emily A. Byl

Open Access Theses

Concrete bridge decks in the State of Indiana are undergoing continuous deterioration and loss of service life due to the use of deicing salts during winter weather conditions. As salt water penetrates the deck through cracks and the concrete surface, chlorides, water and oxygen are able to access the reinforcement to initiate corrosion. The corrosion of reinforcing steel over time creates an ongoing need for costly deck repairs and/or deck replacement. This study investigates the performance of crack sealers and deck surface sealers as a potentially cost-effective method of increasing bridge deck service life. An experimental program was developed and …

Improving Fuel Economy During High Load Diesel Engine System Operation Through Valve Train Flexibility, Xueting Lu

Open Access Theses

As emission regulations getting more stringent and the demand for fossil fuel growing, it is crucial to develop advanced technologies for internal combustion engine to lower emissions and fuel.

Strategies such as diesel oxidation catalysts (DOC) for UHC, diesel particulate filters (DPF) for PM, and selective catalytic reduction (SCR) for NOx have been developed and implemented to convert harmful emissions to innocuous species. However, the efficiencies of these after-treatment systems are heavily temperature dependent.

Heavy-duty over-the-road trucks require periodic active diesel particulate filter regeneration to clean the filter of stored particulate matter. These events require sustained temperatures between 500 and …

Development Of A Fluidic Mixing Nozzle For 3d Bioprinting, Will Hoggatt

Open Access Theses

3D bioprinting is a relatively new and very promising field that uses conventional 3D printing techniques and adapts them to print biological materials that are suited for use with cells. These bioprinters can be used to print cells encapsulated within biological "ink" (bio-ink) to create and customize complex three-dimensional tissues and organs. Our work has focused on developing a new bioprinter nozzle that addresses critical gaps with present-day bioprinters, namely, the lack of standardized, physiologically-relevant biomaterials, and their one nozzle per composition printing capacity. These shortcomings preclude printing a range of cellular and biomaterial compositions (including gradients of cells and …

Nanoparticle-Based Electrochemical Sensors For The Detection Of Lactate And Hydrogen Peroxide, Aytekin Uzunoglu

Open Access Dissertations

In the present study, electrochemical sensors for the detection of lactate and hydrogen peroxide were constructed by exploiting the physicochemical properties of metal ad metal oxide nanoparticles. This study can be divided into two main sections. While chapter 2, 3, and 4 report on the construction of electrochemical lactate biosensors using CeO2 and CeO2-based mixed metal oxide nanoparticles, chapter 5 and 6 show the development of electrochemical hydrogen peroxide sensors by the decoration of the electrode surface with palladium-based nanoparticles. First generation oxidase enzyme-based sensors suffer from oxygen dependency which results in errors in the response current of the sensors …

Control-Oriented Modeling, Validation, And Analysis Of A Natural Gas Engine Architecture, Chaitanya Panuganti

Open Access Theses

In order to improve performance and meet increasingly tight emissions regulations, engine manufacturers must improve algorithms used to control the engine. One possible strategy is to utilize centralized control algorithms that take into account the coupled interactions between inputs and outputs. Implementing a centralized control strategy often requires some kind of dynamic model of the system, which is a primary motivation for modeling efforts in this thesis. In a methodical fashion, this thesis derives a control model for a natural gas engine architecture and validates this control model against reference data in simulation. Additionally, this thesis performs control-oriented analysis on …

Analysis Of Feedback Control Applied With Command Shaping To Minimize Residual Vibration, Nicholas L. Jacobs

Open Access Theses

Joint flexibility is a physical trait that affects all robotic systems to some degree. This characteristic has been shown to be very detrimental to the performance of these robotic systems when implementing fast point-to-point motion. During such motion, the robot will induce vibrations in its structure that will extend past the completion of the move. Many techniques have been applied over the years in order to minimize these residual vibrations. One such method is known as command shaping, which will construct the input profile so as to avoid exciting the natural frequencies of the system. This work seeks to extend …

Enzymatic Liquefaction Of Untreated Corn Stover, Neal N. Hengge

Open Access Theses

There is an ever increasing need for renewable alternatives to fossil fuels derived from petroleum. This makes feedstocks in the form of lignocellulosic biomass attractive substrates for the production of ethanol and value added chemicals. However, the economics of converting lignocellulosic materials involve high processing costs attributed with pretreatment of the biomass and the use of enzymes for saccharification. Corn stover was obtained for the examination of an upstream processing step to transform the material into a pumpable slurry for subsequent pretreatment and saccharification. Biomass liquefaction was carried out using the enzyme Depol 692L (Biocatalysts, Wales, UK) at 50°C with …

Simulation Of Flow And Water Quality From Tile Drains At The Watershed And Field Scale, Colleen Moloney

Open Access Theses

Simulation models such as the Soil and Water Assessment Tool (SWAT) have become widely used in determining the water quality impacts of various management practices. Ensuring that the algorithms accurately represent the processes simulated has become an important goal. Tile drainage is a standard practice in the Midwest, US in order to reduce risk of yield loss due to excess water. Multiple tile drainage and water table algorithms have been available in the SWAT model between the initial SWAT release and revision 638 used in this study. Testing of those algorithms is often limited. Furthermore, algorithms in the current version …

Phase Field Damage Simulations Of Debonding Between Matrix And Spherical Inclusions, Johanna B. Palsdottir

Open Access Theses

Polymer-bonded explosives (PBX) are complicated composites, and it is important for practical applications to know how they deform and fracture. PBX consists of large volume fraction of energetic particles and experiments show that the interface is a critical region for structural stability since particles are often weakly bonded to the polymer and cracks initiate there and the composite fractures. This study focuses on the interface between a particle and a binder and how the particle inclusion starts to debond from the polymer binder in compressive and tensile loading.

A phase field damage model is used to model the response of …

Development Of A Novel Polymer-Garnet Solid State Composite Electrolyte Incorporating Li-La-Zr-Bi-O And Polyethylene Oxide, Muhammed Ramazan Oduncu

Open Access Theses

Current lithium ion batteries are comprised of organic liquid electrolytes - a mixture of lithium salts and binary solvents such as ethylene carbonate (EC) and dimethyl carbonate (DMC). The main drawbacks of this liquid mixture related to safety are flammability of the organic solvents and chemical instability with the electrode materials. To date, various ceramic and polymer materials have been considered which overcome safety issues. However, a common problem of these solid state materials is that they are not able to provide high ionic conductivity at ambient temperatures. Garnet-type cubic Li7La 3Zr2O12 ceramic material has attracted much interest because of …

Cyclic Tensile Response Of A Polyurethane Material, Yizhou Nie

Open Access Theses

Polyurethane is one of the most widely used polymer materials in the world. With the increasing demand of polyurethane, its mechanical behaviors are particularly of interest. In particular, the response of the material under a quasi-static loading being subject to an impact load. To delineate the effect of rate change on the mechanical response of polyurethane, a tensile experiment was designed where the specimen is initially subjected to quasi-static tensile loading and then to high-rate cyclic tension within the same experiment. Constant strain-rate experiments at both quasi-static and high strain rates are also conducted. The analysis of the results leads …

Advanced Hydraulic Systems For Next Generation Of Skid Steer Loaders, Mrudula Uday Orpe

Open Access Theses

Fluid power systems have been extensively used in off highway applications like skid steer loaders, wheel loaders, excavators since many years. Work has been done by both industry and academia to improve efficiency, reduce noise and leakages in these systems. With increasing competition in the market, importance is now also given to operator comfort and machine productivity in off highway applications.

Mobile, off – highway vehicles like Skid-steer loaders are widely used in labour saving applications like loading earth into a truck, dig and move material on construction sites to, clean roads, clear snow from roads etc. To carry out …

Analyzing The Opinion Of Industry Professionals On Model-Based Definition Datasets To Determine The Most Efficient Method, Shawn P. Ruemler

Open Access Theses

Model-based definition (MBD) has the engineering and manufacturing industries moving towards a model-based enterprise (MBE) where traditional two-dimensional (2D) drawings may one day no longer be needed. With MBD, the product data will be contained in the three-dimensional (3D) computer aided design (CAD) model itself. MBD provides a wealth of benefits to users, including reduced time-to-market, product quality, and task efficiency. Even with all the benefits of MBD, there is still no best practice when it comes to implementing MBD. Different strategies of MBD datasets exist, however none have been compared to see which method is more efficient. This project …

Exploratory Study Of Students' Representational Fluency And Competence Of Electric Circuits, William Fernando Sandchez Cossio

Open Access Theses

Electric circuits are extensively used in today’s devices as computers, phones, cameras and others. This makes them a crucial topic in engineering because almost every engineering branch could be related of used them at different levels. Even though their importance, students often struggle during the learning process of circuit analysis topics. Additionally, other very important abilities for engineering students are the capacities to create, use, express and think about models and representations of technical concepts; and the capacities to translate and map from one representation to another. These abilities are known as representational competence and representational fluency respectively.

The purpose …

Solution Based Processing Of Garnet Type Oxides For Optimized Lithium-Ion Transport, Derek K. W. Schwanz

Open Access Theses

Current lithium based portable electrochemical storage devices are limited by the inherent instability and volatility of conventional electrolytes materials. Ceramic materials show much promise for use in advanced lithium based battery systems due to their inhibition of dendritic growth and high thermal and chemical stability. The main drawback of solid materials is their low ionic conductivity, relying on lattice hopping to transport ions between electrodes during cycling. Garnet type oxides, specifically of the base compositions Li7La3Zr2O12 and Li5L a3Bi2O12 have been synthesized through Pechini method solution based processing by the dissolution of reagent salts into nitric acid and creation of …

Polymerizable Lipids For Controlled Functionalization Of Layered Materials, Kortney Kaye Rupp

Open Access Theses

Self-assembled monolayers (SAM’s) offer a straightforward approach to tailoring the interfacial properties of metals, metal oxides and semiconductors. Noncovalent functionalization of single-layer graphene offers the possibility to finely tune surface chemistry for future applications in electronics. Polymerization of photochemically reactive molecules in a lying-down phase has been used to increase the strength of intermolecular interactions between long alkanes and HOPG substrates. Long-chain fatty acid derivatives with internal diyne groups yield a conjugated ene-yne polymer upon UV irradiation. Diyne lipids with phosphocholine (diyne PC) and phosphoethanolamine (diyne PE) groups offer a charged form of the head group that is robust towards …

Applications Of The Homotopy Analysis Method To Optimal Control Problems, Shubham Singh

Open Access Theses

Traditionally, trajectory optimization for aerospace applications has been performed using either direct or indirect methods. Indirect methods produce highly accurate solutions but suer from a small convergence region, requiring initial guesses close to the optimal solution. In past two decades, a new series of analytical approximation methods have been used for solving systems of dierential equations and boundary value problems.

The Homotopy Analysis Method (HAM) is one such method which has been used to solve typical boundary value problems in nance, science, and engineering. In this investigation, a methodology is created to solve indirect trajectory optimization problems using the Homotopy …

High-Throughput Mechanical Characterization Methods For Composite Electrodes And In-Situ Analysis Of Li-Ion Batteries, Luize Scalco De Vasconcelos

Open Access Theses

Electrodes in commercial rechargeable batteries are microscopically heterogeneous materials. The constituents often have large variation in their mechanical properties, making the characterization process a challenging task. In addition, the mechanical properties and mechanical behaviors of electrodes are closely coupled with the electrochemical processes of lithium insertion and extraction. There is an urgent need to develop an experimental platform to characterize the chemomechanical response of electrodes under the in-situ conditions of charge and discharge.

In the first part of this thesis, instrumented grid indentation is employed to determine the elastic modulus and hardness of the constituent phases of a composite cathode. …

Numerical Methods For Low-Thrust Trajectory Optimization, Robert E. Pritchett

Open Access Theses

The spacecraft trajectory design process frequently includes the optimization of a quantity of importance such as propellant consumption or time of flight. A variety of methods for trajectory optimization are available, however the efficiency of an approach is dependent on the problem scenario it is applied to. Indirect and direct trajectory optimization methods are examined in this investigation with the goal of assessing the characteristics of each approach, and thereby determining the problem scenarios each is best suited for. Insight is gained from application of each optimization method to three sample problems; a circular-to-circular orbit transfer as well as two …

Using Ubiquitous Data To Improve Smartwatches' Context Awareness, Yuankun Song

Open Access Theses

Nowadays, more and more data is being generated by various software applications, services and smart devices every second. The data contains abundant information about people’s daily lives. This research explored the possibility of improving smartwatches’ context awareness by using common ubiquitous data. The researcher developed a prototype system consisting of an Android application and a web application, and conducted an experiment where 10 participants performed several tasks with the help of a smartwatch. The result showed a significant improvement of the smartwatch’s context awareness running the prototype application, which used ubiquitous data to automatically execute proper actions according to contexts. …

Mapping And Analyzing Energy Use And Efficiency In A Modified Hydroponic Shipping Container, Rachel E. Sparks

Open Access Theses

In urban centers today, vertical farming is becoming a popular alternative to conventional agriculture in an effort to increase local food production and improve urban food security by growing crops using hydroponic methods in controlled environment spaces. More specifically, one vertical method involves growing crops inside refurbished shipping containers, or a “farm-in-a-box” concept, which offers a flexible, mobile, and scalable means of year-round food production in a variety of climates. Despite benefits of producing food locally, some of the concerns associated with these vertical farming systems include high energy consumption from climate control and electric lighting systems as well as …

Test Cell Set-Up To Enable Drive-Cycle Testing Of A Variable Valve Actuation Enabled Camless Diesel Engine, Alexander Harrison Taylor

Open Access Theses

The previous facility which was used for engine testing at Purdue's Ray W. Herrick Laboratories utilized an eddy current dynamometer which is only suited for steady-state testing and throttle snaps. To better utilize a pre-existing camless diesel engine, which is is enabled via variable valve actuation, it was desired to perform transient drive-cycle tests. To accomplish this goal, a variable frequency drive AC dynamometer was required. Given that a brand new facility was constructed, the team was presented with an opportunity for ground up design of a test cell.

The new test cell's operation was proved out using a cammed …

Novel Gain Enhancement Technique For Microstrip Patch Antennas Based On Multi-Pronged Feed Network Synthesis, Brian J. Vaughn

Open Access Theses

Developing antennas with enhanced gain has always been an important pursuit within the antenna community, as a higher gain leads to an increase in the received power for any given wireless link. In general, when a higher gain is needed for an application, only certain types of antennas can be used. The goal of this thesis project was to develop a method for increasing the gain of antennas that already exist by applying modifications to them, expanding the design flexibility for wireless applications. In this thesis, a novel method for increasing the gain of microstrip patch antennas by synthesizing specialized …

Fast Voxel Line Update For Time-Space Image Reconstruction, Xiao Wang

Open Access Theses

Recent applications of model-based iterative reconstruction(MBIR) algorithm to time-space Computed Tomography (CT) have shown that MBIR can greatly improve image quality by increasing resolution as well as reducing noise and some artifacts. Among the various iterative methods that have been studied for MBIR, iterative coordinate descent(ICD) has been found to have relatively low overall computational requirements due to its fast convergence. However, high computational cost and long reconstruction times remain as a barrier to the use of MBIR in practical applications. This disadvantage is especially prominent in time-space reconstruction because of the large volume of data. This thesis presents a …

Command Shaping With Constrained Peak Input Acceleration To Minimize Residual Vibration In A Flexible-Joint Robot, Yumeng Wu

Open Access Theses

Rapid point-to-point motion is limited when flexibilities exist in the system. In order to minimize the vibrations related to joint flexibilities, much work has been done, including modifying the system so that vibrations can be damped out more quickly, calculating the inverse dynamics of the system and constructing shaped input profiles that avoid system natural frequencies. In this work, the earlier fixed-time command shaping method has been extended to a peak-acceleration-constrained approach with two basis functions, the ramped sinusoid function and the versine function, such that the maximum acceleration is guaranteed without overconstraining the input profiles. The approach is developed …

Vhf Lumped-Element Reconfigurable Filters Design And Applications In Field-Programmable Filter Array, Wei Yang

Open Access Theses

The increasing demand for limited space in crowded frequency spectrum is creating new challenges to RF frontend communication systems. High gain tunable antennas, tunable filter with high selectivity and isolation, large signal-to-noise ratio tunable low noise amplifiers are demanded. This thesis demonstrates novel tunable filter synthesis that may help in developing solutions for future RF frontend filter applications. The proposed coupling scheme enable the tuning of center frequency, order, response shape, bandwidth, and transmission zero spectral location. Also, this coupling scheme can be used to implement a field-programmable filter arrays (FPFAs) design.

Experimental Characterization Of Scroll Expander For Small-Scale Power Generation In An Organic Rankine Cycle, Felipe Airoldi Accorsi

Open Access Theses

Organic Rankine Cycles (ORC) are thermodynamic power cycles designed to generate work from low temperature sources. The low temperature heat input, typically between 80 °C to 270 °C, allows them to recover energy from industrial waste heat, exhaust gas from diesel, engines, solar systems, geothermal systems, and others. This technology already is commercialized in large-to-medium-scale power plants; however, it is still in development for small-to-micro scale.

The operating principle of ORC comprises four major steps. First, the working fluid evaporates at high pressure using the heat transfer from the low temperature heat source. Then, the working fluid reduces its enthalpy …

Algorithms For Lidar Based Traffic Tracking: Development And Demonstration, Vamsi K. Bandaru

Open Access Theses

The current state of the art of traffic tracking is based on the use of video, and requires extensive manual intervention for it to work, including hours of painstaking human examination of videos frame by frame which also make the acquisition of data extremely expensive. Fundamentally, this is because we do not have observability of the actual scene from a camera which captures a 2D projection of the 3D world. Even if video were to be automated, it would involve such algorithms as RANSACK for outlier elimination while matching features across frames or across multiple cameras. This results in algorithms …

Enhancing Silymarin Fractionation Via Molecular Modeling Using The Conductor-Like Screening Model For Real Solvents, Emma C. Brace

Open Access Theses

The market for bio-based products from plant sources is on the rise. There is a global challenge to implement environmentally clean practices for the production of fuels and pharmaceuticals from sustainable resources. A significant hurdle for discovery of comparable plant-derived products is the extensive volume of trial-and-error experimentation required. To alleviate the experimental burden, a quantum mechanics based molecular modeling approach known as the COnductor-like Screening Model for Real Solvents (COSMO-RS) was used to predict the best biphasic solvent system to purify silymarins from an aqueous mixture. Silymarins are a class of flavonolignans present in milk thistle ( Silybum marianum …

Efficient Inelastic Scattering In Atomistic Tight Binding, James A. Charles

Open Access Theses

In this thesis, the coherent and incoherent transport simulation capabilities of the multipurpose nanodevice simulation tool NEMO5 are presented and applied on transport in tunneling field-effect transistors (TFET). A gentle introduction is given to the non-equilibrium Green's function theory. The comparison with experimental resistivity data confirms the validity of the electron-phonon scattering models. Common pitfalls of numerical implementations such as current conservation, energy mesh resolution, and recursive Green's function stability and the applicability of common approximations of scattering self-energies are discussed. The impact of phonon-assisted tunneling on the performance of TFETs is exemplified with a concrete Si nanowire device. The …