Engineering Commons^™

Prediction And Correlation Of The Salt-Effect In Vapor-Liquid Equilibrium, Enrique M. Bekerman

Theses

The feasibility of developing a method of correlation and prediction, for mixtures of two solvents containing a dissolved salt has been studied. The procedure consisted of arriving at the interaction parameters for the three binary systems (solvent 1-solvent 2, solvent 1-salt, solvent 2-salt) and using these to calculate the ternary results. Attempts to generate interaction parameters for the solvent-salt binaries by means of the Wilson equation were unsuccessful, whereas, use of the NRTL equation resulted in a very good fit of the binary data.

In correlating the ternary results, it became necessary to redefine the liquid phase mole fractions and …

Reaction Kinetics For The Synthesis Of Benzyl Benzoate From Benzyl Chloride And The Triethylamine Salt Of Benzoic Acid, Michael A. Kolakowski

Theses

The reaction kinetics for the synthesis of benzyl benzoate from benzyl chloride and the triethylamine salt of benzoic acid has been studied over the temperature range of 70-105°C and a mole ratio of benzyl chloride to triethylamine of 0.5 - 10.0.

A reaction mechanism which is consistent with the experimental data has been derived. The experimental data was analyzed by means of the integral method of analysis. The temperature dependency of the reaction was determined from Arrhenius' Law and the activation energy was calculated to be 15,064 cal/g-mole. An empirical equation which explains the effects of the reactant mole ratio …

Computerized Conferencing And The Homebound Handicapped, Computerized Conferencing & Communications Center, Murray Turoff, Howard Gage

Computerized Conferencing and Communications Center Reports

Computer conferencing is a relatively new technique which can be applied to improve both the efficiency of education, and communication services available to the homebound handicapped. A system is currently being implemented at the New Jersey Institute of Technology which allows such individuals to engage in a written form of conversation with other individuals or groups. Here the computer stores the discus­sion and keeps track of what everyone has or has not seen, so participants can communicate at a time and pace of their choosing. There is also provision for a range of ancillary facilities such as voting, word processing, …

A Study Of The Effect Of An Electric Potential On The Saponification Of Ethyl Acetate, Michael Maciupa

Theses

A reactor of rectangular cross-sectional, area was constructed of plexiglass to study the effect of an electric potential on the saponification of ethyl acetate with sodium hydroxide. Three different laminar region flow rates were used and the applied voltage was varied up to four kilovolts in one kilovolt increments for each flow rate. It was found that the apparent rate constant for the reaction was either increased or decreased depending on the voltage and flow rate used. The largest increase was a 4.2 percent change from zero voltage steady state conditions with an applied voltage of one kilovolt at a …

Adsorption On Activated Flyash, John William Kubarewicz

Theses

An experimental study was undertaken to compare the adsorptive characteristics of activated carbon, flyash, and activated flyash. Due to the contradictory evidence available in the literature, emphasis was placed on the effect of acid activation on the physical properties of the adsorbent. The experiment consisted of two parts; batch isotherm studies, and continuous column operations. An artificial sewage composed of a mixture of deionized water and beef broth was used as the adsorbate. This solution was prepared daily and exerted a COD of 225 ± 30 mg/l. Flyash activation was found to increase the degree of adsorption indirectly rather than …

An Analysis Of The Passenger Vehicle Interface Of Street Transit Systems With Applications To Design Optimization, Walter H. Kraft

Dissertations

This research analyzes the Passenger Vehicle Interface of the street transit systems and presents applications for design optimization. The Passenger Vehicle Interface (PVI) is defined as the interaction between the passenger and vehicle elements of the street transit system.

Human observer and photographic studies were conducted in 17 cities in the United States and Canada to measure the time for queues of passengers to board various transit vehicles. The data were analyzed by considering seven factors that affect the Passenger Vehicle Interface: Human Factor, Modal Factor, Operating Practices, Operating Policies, Mobility, Climate and Weather, and Other System Elements. Those effects …

The Chemical Effect Of Ultrasound On Cyanide Solutions, Nabil R. Zaki

Theses

An experimental study was undertaken to investigate the chemical effects of high intensity ultrasonic radiation on cyanide solutions. The effects of aeration, concentration of cyanide and temperatures on the reaction rate are investigated. The experiment was preformed in a 30 mm pyrex tube immersed at a fixed height in a constant volume water bath. Ultrasonic energy was applied through the use of a transducer epoxied at the bottom of the water bath. The power inputs to the transducer were 40W (27KHz) and 100W (21KHz).

At a power of 40W, ultrasound had no chemical effect on cyanide solutions. At 100W, hydrogen …

Communications And Group Decision-Making : Experimental Evidence On The Potential Impact Of Computer Conferenging, Computerized Conferencing & Communications Center, Starr Roxanne Hiltz

Computerized Conferencing and Communications Center Reports

This paper is a selective review of small group experiments in the area of the relationship between communication (modes, structures, processes) and group decision-making or problem solving. There are literally hundreds of these experiments; the purpose of this effort has been to isolate and summarize the results of those experimental traditions which may have the most bearing upon:

1. our understanding of the probable social effects of computer conferencing as a communication mode;
2. the identification of possible experiments utilizing computer conferencing which appear to be potentially most fruitful in terms of evaluating the strengths and weaknesses of computer conferencing in facilitating …

Deposition Of Suspensions In Laminar Flow In The Entrance Region Ofa Channel And In A Diffuser, Shawki Mahmoud Eldighidy

Dissertations

In this investigation, the deposition of suspensions in laminar flow in the entrance region of a channel and a diffuser was considered.

The particulate phase was considered to he under the action of the electric field force clue to electrostatic charges. In addition, a lift force acting on each particle at the wall arising from the fluid shear near the wall and an adhesive force between each particle and the wall due to the difference of the material properties for both particle and walls were considered as surface forces.

The suspension flow was assumed to be incompressible, laminar, dilute, and …

Computer Program For Binary Distillation Using The Method Of Pochon-Savarit With Enthalpy Data Calculated By Lagrange Interpolation, Joseph J. Rogus

Theses

This thesis presents a Fortran Computer Program to solve binary distillation problems. The solution is obtained by the method of Pochon-Savarit which is based upon graphical use of an enthalpy-concentration diagram. The enthalpy data in this program is calculated using Lagrange interpolation. This is accomplished by utilizing the Lagrange interpolation to get values for the enthalpy of the vapor until we find that value which lies on the same line as the enthalpy of the liquid from the preceding tray and its corresponding del point.

The required input data consist of liquid-vapor equilibrium data, heat of solution data with the …

Initial Specifications Electronic Information Exchange System (Eie), Computerized Conferencing & Communications Center, Murray Turoff

Computerized Conferencing and Communications Center Reports

This document is intended as a SPECIFICATIONS MANUAL to guide the development of the EIE System. It does not represent a User Manual although it contains the specification of the user abilities on the system. It is written in a highly segmented style which reflects the potential use of the material in the on-line EXPLANATION file which will be available as part of the EIE System and which will allow users to retrieve just enough information to satisfy a specific question on system use and options.

This comprehensive specification document is much harder to utilize for learning the system than …

An Investigation Of The Optical Absorption Properties Of Silicon As Related To Its Electrical Conductivity, Onofrio Louis Russo

Dissertations

The purpose of this study is to demonstrate the feasibility of obtaining the electrical conductivity of band gap semiconductors, by considering the absorption of radiation in the visible region. The experimental evidence confirmed predictions that the conductivities of the silicon samples are related to the horizontal displacement of energy in the absorption curves. The material used in this study was p-doped silicon, although the approach should be valid in general for either elemental or compound semiconductors.

The absorption coefficient for silicon was measured in the radiation region between 2.0 and 3.0 ev. This region above the indirect band gap (= …

Optimal Control And Identification Of Stochastic Systems Using Differential Game Theory, Harry Marvin Burbank

Dissertations

This dissertation deals with linear systems subjected to stochastic disturbances. The class of stochastic processes considered is the class of second order stochastic processes characterized by having finite continuous covariance. The properties of the covariance provide means to formulate optimization problems without the difficulties present when the covariance is not finite or continuous.

The first aspect studied was several classes of optimal control problems. The effects of the stochastic processes were approximated by the effects of its first two moments. This procedure resulted in allowing optimal system controls to be found whatever the first two moments of the stochastic input …

The Thermal Dehydration Of Magnesium Sulfate Hexahydrate (Mgso3.6h2o) And Magnesium Sulfite Trihydrate (Mgso3.3h2o), Raafat F. Abdel-Malek

Theses

The thermal dehydration of MgSO₃.3H₂O and MgSO₃.6H₂O have been studied by differential thermal analysis, differential scanning calorimetry and thermal gravimetric analysis.

Similar studies by other groups led to contradictory conclusions. In this investigation, these results were reconciled and it was concluded that MgSO₃.6H₂O, under equilibrium conditions, dehydrates in two steps through the intermediate formation of MgSO₃.3H₂O.

One consequence of this work is the development of a simple analytical procedure, using TGA, for the quantitative determination of both hydrates in mixtures and in the presence …

The Thermodynamics Of Electrolytic Solutions, Eric Robert Bixon

Theses

The thermodynamic properties of solutions of electrolytes may be accurately determined by the measurement of the activity of the s6lvent. when the. solute is nonvolatile, this quantity may be obtained from measurements of the lowering of the vapor pressure caused by the presence of the dissolved solute.

An experimental method has been devised to measure this effect using a semi-conventional Othmer Still. The experimental apparatus has been constructed. and evaluated. Data has been-obtained for the vapor pressure lowering of methanol due to the presence of dissolved electrolyte for five different electrolyte-methanol systems. An extrapolation technique was developed to make use …

Separation Of Isomers Via Thermal Parametric Pumping, Vincent J. D'Emidio

Theses

Continuous and semicontinuous thermal parametric pumps for separating isomers were experimentally investigated using the model system glucose-fructose-water on a cation exchange resin adsorbent. A comparison was made between the experimental data and the calculated results by a method based on an equilibrium theory. The method invokes the assumptions that a multicomponent mixture contains a series of pseudo binary systems. Each binary system consists of one of the solutes as one component and the common inert solvent as the other component. It has been shown that under certain conditions, the pump with feed at the enriched end has the capacity for …

A Preliminary Study Of The Thermodynamic Limitations Of The Nrtl/Lemf Equations, Robert Petrie

Theses

Analytical evaluations of the second and third derivatives of the molar Gibbs energy of mixing for the NRTL/LEMF equations indicate distinct zones of miscible and inmiscible prediction.

These calculations for a number of different α's have produced approximate miscibility limits for both NRTL/LEMF energy parameters and infinite dilution activity coefficients of a given system.

Transient Phenomena Of Polymer Solutions, Nikolaus Zwetkow

Theses

With the aid of a rotational viscometer, several transient phenomena were studied with different polymer solutions. In order to be acquainted with the operations of the rotational viscometer, viscosity measurements were made on polystyrene solution of a 7.14 wt. % NBS-2-35967 in a 35 - 65 mixture of aroclor and TCP, polyisobutylene (16.5% in mineral spirits), Indopol H-1900 (polyisobutylene) and 4.5% polyisobutylene in Primol 355. All these were done at a temperature of 77°F, except for Indopol H-1900 which was done at different temperatures. The results are listed in the section of tables and graphs.

Viscosity was measured with a …

A Kinetic Study Of Lysine And Lysine Derivatives, Stephen Joseph Stanley

Theses

The kinetics of the reaction of iodoacetamide with lysine, polylysine, N-α-Acetyl lysine, and N-ε-Acetyl lysine, have been studied. The investigation was done at 23° C ± 123° C, as a function of pH, and concentration. In all cases it was noted that the rate of reaction increased as the pH increased. The rate data was analyzed in order to obtain the second order rate constants. In addition, the effects of the reactive site's environment on the rate was demonstrated.

Steady State Heat Transfer From A Double Ring Of Identical Spheres In A Regular Orientation, Evelio A. Melo

Theses

Solutions to Laplace's equation are obtained by the method of reflections for the problem of heat transfer from two parallel rings of spheres arranged in regular polygonal arrays. The mathematical models developed describe the rate of heat transfer and spatial temperature distribution due to an arbitrary number of identical spheres of equal surface temperature correcting Fourier's heat transfer equation for the interference caused by a multiparticle array. Although the method of solution is quite rigorous and can be used to obtain as accurate a solution as desired, only the second reflection was obtained, yielding a first order correction. The model …

Soluble Surfactant Effects On Gas Absorption Of Organic Compounds, Angelo C. Morresi

Theses

A literature search dating back to the beginning of this century turned up no previous work similar to ours. We discuss several methods and experiments involving the scrubbing of air streams.

The objective of this work was the determination of surfactant affects on the solubility of certain organic compounds of varying solubility in water. A means of simulating a packed tower was devised to allow for bench scale evaluation and thus enabled a greater number of organic compounds to be examined with a greater variety of surfactants.

Curves were plotted based on organic vapor concentration, surfactant concentration, organic type, surfactant …

A Study Of The Vibrational Spectra Of Some Monosubstituted Benezene Derivatives Of Group Via Of The Periodic Table, Fawzi S. Rasheed

Theses

The vibrational frequencies for (C₆H₅)₂Se, (C₆H₅)₂Te, (C₆H₅)₂Se₂, (C₆H₅)₂Te₂, (C₆H₅)₂Hg, and (C6H5-Se)₂Hg are completely assigned and are consistent with the vibrational assignments for (C₆H₅)₂O, (C₆H₅)₂S, and (C₆H₅)₂S₂ previously reported. Further, whereas (C₆H₅)₂O and to a lesser extent (C₆H …

Reactions Of Para-Nitroaniline With Acid Chlorides, Stephen Alan Zapoticzny

Theses

Para-nitroaniline was reacted with acid chlorides forming amides. Their structures were elucidated by the performance of various spectral analyses.

Design Of A Yig-Tuned Oscillator, Tien Liang Jin

Theses

A technique for designing YIG (yttrium-iron garnet) tuned transistor oscillators, tunable over the range of frequencies from 500 to 950 MHZ, is presented. The approach taken differs appreciably from that used in the design of conventional LC-tuned oscillators. One major difference is that the YIG tuning mechanism is electrically controlled. The YIG tuning element is treated as a single unit and is not resolved into an equivalent LC circuit. Instead, a direct method using reflection coefficients measured at network terminals to characterize various design stages is applied. The transistor is also characterized by reflection and transmission coefficients, i.e., S-parameters. Thus …

Design And Analysis Of An Instrument System For Rheological Testing Of Whole Blood Samples, Robert Rimvydas Sinusas

Dissertations

The dissertation covers the conceptual design of a rheometer for testing whole blood samples through to the clotting state. While the design aims at increased measurement accuracy, the design employs well known technologies and available components.

The main reason for preoccupation with blood testing is that recent investigations have indicated that physiological disorders can be correlated with rheological properties of blood. The pursuit of an improved means of correlation is initiated with a survey of the rheological properties of blood. The relevance of these blood properties is then discussed. From this discussion a broader blood model is developed as a …

Characterization Of Thixotropic Materials And Modification Of The Weissenberg Rheogoniometer, Paul Joseph Orosz

Dissertations

A Weissenberg Rheogoniometer, Model R-18, was modified to give complete rheological curves without resetting the gearbox and generate hysteresis loops for time-dependent, non-Newtonian materials. This modified instrument was used to analyze a number of materials. Standard Newtonian and known time-independent, non-Newtonian materials were studied to insure the accuracy of the instrument. Results indicated that the instrument would reproduce known viscosities of these materials, give consistent results, and not display inherent hysteresis loops with non-thixotropic materials. Materials known and suspected to be thixotropic: silicone grease-oil mixture, montmorillonite clay, and blood were tested. All displayed the characteristic hysteresis loop usually associated with …

Engineering A Primary Waste Treatment Plant, Edwin O. Onwawoma

Theses

This thesis deals with the design and construction of a primary waste treatment plant. The scope of work covered here, includes waste sampling and characterization, process design data gathering, process and mechanical design, cost estimate, and a general discussion of the construction and start-up.

In the development of this work, it is assumed that a decision has been made to build the waste treatment plant, using a known process. Therefore, economic evaluations designed to determine return on investment and selection of a process, will not be discussed. The impact the capital investment associated with the waste treatment facility has on …

The Resource Interruption Monitoring System : Basic Reporting Procedures And Sample Reports, United States. General Services Administration. Office Of Preparedness.

Computerized Conferencing and Communications Center Reports

This RIMS training manual was originally prepared by Mrs. Helen R. Nixon for use in her' office, Region 7, Dallas, Texas. It has subsequently been used for training at each OP Regional Office and at the Central Office in Washington. In anticipation of requirements for training of new users of RIMS under crisis reporting conditions, the manual is being issued for library reference and quantity reproduction.

The Interpretation Of Infrared And Raman Spectra Using Pattern Recognition, John Martin Comerford

Dissertations

An automatic classification of chemical compounds by computer processing of digitized spectral data is presented. The classification system is based on a branch of artificial intelligence known as supervised learning, and used binary linear classifiers to identify compounds as alcohols, esters, ethers, ketones or compounds containing double bonds.

Each of the 1117 spectra in volume one of Sadtler's Standard Raman Spectra was coded using a scale from 0 to 9 in the range from 4000 to 200 cm^-1. One hundred and twelve readings were taken on each spectrum. These data were then examined using pattern recognition techniques, and …

Effect Of Mixing On Polymerizations In Batch Reactors, John Guy Steenrod

Theses

The effects of mixing on polymerizations in batch reactors are examined theoretically for initiations by thermal decomposition of catalyst and by absorption of ionizing radiation. Mathematical expressions for predicting the first three moments of the dead polymer size distribution are presented. Two extreme mixing states. perfect and no mixing. are considered. It is shown that in batch reactors mixing in any direction in which nonuniform initiations exist increases the polymerization reaction rate and the number average molecular weight, and decreases the weight average and the polydispersity.

Experimentally, the effects of mixing were studied in a solution polymerization system, in a …