Engineering Commons^™

Osmotic And Mean Activity Coefficients Of Libr And Lic In Methanol At 25, 35, And 45 Degrees C, Peggy Tomasula

Theses

Vapor pressure depression data of LiBr and LiCl in methanol at temperatures of 25,35, and 45°C were measured in the molality range 0.1-4.4m using a static method, where the difference in vapor pressure of the electrolytic solution is compared to that of pure methanol.

Osmotic coefficients were calculated from the vapor pressure data. This data was then correlated with both the one parameter Bromley equation and the three parameter Pitzer equation. For all systems at all temperatures, the data were better correlated by the Pitzer equation than with the Bromley equation. Mean activity coefficients of the two salts at the …

Face-To-Face Vs. Computerized Conferences : A Controlled Experiment, Volume Ii: Methodological Appendices, Computerized Conferencing & Communications Center, Starr Roxanne Hiltz, Kenneth Johnson, Charles Aronovitch, Murray Turroff

Computerized Conferencing and Communications Center Reports

This is volume II of research report 12. It is comprised of the methodoligical appendices that support volume I.

Face-To-Face Vs. Computerized Conferences : A Controlled Experiment. Volume I: Findings, Computerized Conferencing & Communications Center, Starr Roxanne Hiltz, Kenneth Johnson, Charles Aronovitch, Murray Turroff

Computerized Conferencing and Communications Center Reports

This is a report on the first controlled experiment conducted as part of a four year effort to explore the feasibility and effectiveness of using the computer to structure the communication for various types of group tasks. It uses a language called INTERACT, developed as part of this grant effort, to administer all instructions and conduct a group problem solving discussion in a computer conference. The experiment compares the process and outcome of face to face vs. computer mediated group problem solving discussions.

The objectives of this experiment are the following "basic research" questions:

1. To gain quantified and detailed knowledge …

Correlation Of Thixotropic Parameters And Related Tests Of Blood From Human Subjects, Walter Fabisiak

Dissertations

The flow behavior of human blood is an important facet of the circulatory system as it affects all of the organs of the body. The rheological properties of whole blood provide a means of analyzing the flow of red cells and plasma through the microcirculation. A recently observed rheological characteristic of whole human blood is thixotropy, a time-dependent phenomenon. This phenomenon is caused mainly by the redistribution of an aggregated form of erythrocytes, known as rouleaux, and the non-aggregated, single erythrocytes. In order to further define and analyze the thixotropic properties of blood, the Huang model is used to quantitatively …

Thixotropic Properties Of Whole Human Blood, Jen An Su

Dissertations

The rheological property of whole blood from various human subjects was studied with a Weissenberg Rheogonio-meter, modified with a continuously variable speed drive. Experimental data showed a hysteresis loop in the shear stress versus the shear rate plot and a torque-decay in the shear stress versus the shearing time plot which is under a constant shear rate. The rheological equation previously developed by Huang was employed to define the thixotropic parameters of each whole blood sample based upon the recorded rheograms.

The altered thixotropic parameters for the blood from patients with open heart surgery at different clinical stages were quantitatively …

The Minimum Maximal-Cube Covering Approach To Switching Theory, Yu-Tsang Gene Hwang

Dissertations

This dissertation is devoted to the construction of a new algebraic structure for the K-map so that algorithms and theorems can be derived for the minimization of Boolean functions and at the same time provide for the manipulation of Boolean functions as freely as one could on the K-map.

Computer programs have been included to demonstrate the theory and numerous examples of various complexity have been worked out in the appendices.

Impingement Of An Axi-Symmetric Jet On A Flat Surface, Amir J. Daibes

Theses

An incompressible, inviscid irrotational flow model was used to represent the normal impingement of a circular axisymmetric jet upon a flat plate. An analytical investigation was conducted to determine the free surface of the jet and the solution of the potential flow problem was obtained using finite difference techniques for jet height-to-nozzle radius ratio of 2.4.

The velocity and pressure distributions at the plate surface and along the jet centerline were obtained.

The results from the finite difference solution are in close agreement with other most recent results from available experimental, and approximate solutions to the potential flow problem.

A Microprocessor Based Digital Logic Simulator, Kevin Dresher

Theses

It is the intent of this thesis to acquaint the reader with a tool which is available for use in the digital circuit design field. The reader is now able to totally simulate via DLS the digital logic design he creates on paper before it ever takes a hardware form. The computer program accepts a detailed description of the schematic and creates timing diagrams, loading statistics, cross references, and various lists for future documentation.

The user needs no programming knowledge and will find the requirements to run a simulation with DLS extremely user oriented. The simulation descriptions and command language …

The Characterization Of The Oxygen Transfer Capabilities Of Fermentors, Joseph Stephen Adamca

Theses

A method of characterizing the oxygen mass transfer capabilities of fermentors was developed where volumetric oxygen mass transfer coefficients are obtained using a modified sulfite oxidation method in conjunction with on line digital data processing. Carboxymethylcellulose is used in the reaction media to simulate the viscosity of typical non-Newtonian fermentation broths. Using this method, instantaneous values of volumetric oxygen mass transfer coefficients can be obtained for various combinations of agitation and airflow rates in different fermentor configurations. This data is useful in the scale up or scale down of fermentors.

Data obtained using this method have revealed that for a …

Analysis Of Unsteady-State Heat Conduction In A Cylinder With The Finite Element Method, Richard F. Bernard

Theses

Unsteady-state heat conduction in a cylinder of finite dimensions with constant physical and thermal properties was analyzed with the finite element method. Symmetry of the cylinder and application of Newman's method reduced the problem to two independent one-dimensional problems. Finite element equations for the axial and radial dimensions were developed utilizing Galerkin's method of weighted residuals. Crank-Nicholson approximations were used for time derivatives. A computer program was written for solution of the finite element equations.

Solutions obtained were conditionally stable; dependent on the value of the ratio KΔt/ρCpl². For values of the ratio less than 1/3, errors in …

The Removal And Recovery Of Fluoborate From Plating Rinse Waters, Terrence A. Hunter

Theses

Fluoborate poses a problem to electroplaters when discharged in their wastestreams. Therefore, a method for removing fluoborate from rinse waters is necessary. An ion floatation technique using a surfactant was developed at N.J.I.T. to perform this job. However, this technique requires long time periods therefore other methods were investigated.

Ultrafiltration was investigated as a replacement for the ion floatation technique. It would cut down the time required for the fluoborate removal. Also, electrolysis and the addition of excess acetic acid were tried in an attempt to separate the fluoborate and the surfactant in the ultrafiltration retentate. This system was evaluated …

An Experimental Study Of Photopolymerization In A Continuous Stirred Tank Reactor, Songvit Setthachayanon

Theses

An experimental study was carried out on the control of CSTR by on-off regulation of light intensity for the photo-sensitized polymerization of styrene. The controllability of the reaction temperature, the advantages of operating at metastable states, and the molecular weights of the polymer formed were discussed. The influence of feed temperatures, sensitizer concentrations, and residence times on the reactor performance characteristics were also discussed. Experimental results showed that polymer formed at the metastable state had a higher average chain length and narrower molecular weight distribution than that formed at the low stable state. While increasing the residence time shifted the …

Temperature Dependency Of The Group Interaction Parameters In The Agsm And Unifac Models For The Prediction Of Heats Of Mixing, Ignatius Okoronkwo Ojini

Theses

A four-parameter group-contribution model (UNIFAC) has been developed for the prediction of heats of mixing of non-electrolyte mixtures. Both the UNIFAC and AGSM models are evaluated over a wide range of temperature dependencies of the group interaction parameters. The UNIFAC model has been chosen over the AGSM model and an optimum parameter-temperature relationship has been established.

Adopting the optimum temperature dependency, group inter-action parameters have been calculated using UNIFAC for the prediction of four types of mixtures: n-Alcohols/n-Alkanes; Benzene/n-Alkanes; Nitriles/n-Alkanes; Amines/n-Alkanes.

Development And Verification Of A Laboratory Model For Use In The Study Of A Continuous Flow Pressurized Activated Sludge Process, Wayne Frederick Nolte

Dissertations

Investigations concerning the responses of domestic wastewater treated at elevated pressures have demonstrated an acceleration in the rate of biological assimilation of the waste material. The literature is not extensive, but presents much conflicting data. There has been a lack of a coherent approach to the investigation of pressure in wastewater treatment. This demonstrates the need for standard testing apparatus and procedures.

A bench scale pressurized activated sludge process was designed and constructed. The apparatus was tested over a broad range of conditions and was found to give reproducible results. Kinetic responses of the pressurized process are presented.

Theory And Design Of Cyclotron-Wave Traveling-Wave Amplifiers, Arthur H. Gottfried

Dissertations

A theory and design procedure for traveling-wave tubes using cyclotron-wave interactions is developed. An analysis is presented of the energy exchange mechanism and the axial beam velocity spread induced by the r.f. interactions. The analysis of the energy spread in a realistic model of the beam with nonzero size and nonzero space-charge density shows that higher maximum efficiencies at higher power is attainable (with collector depression) in cyclotron-wave amplifiers than in synchronous-wave amplifiers.

A one-watt, and a ten-watt cyclotron-wave amplifier at 3 GHz, utilizing bifilar helix circuits, scaled from a 2 kW, 5 GHz design, were constructed. A computer was …

Adsorption Capabilities Of Adsorbents For Selected Toxic Air Pollutants, Richard Michael Vaccaro

Theses

The relative adsorption capacities of seven toxic, volatile organic air pollutants of either proven or suspected carcinogenic potential were tested on various adsorbents. Tests were run at flow velocities similar to those set in field sampling. This allows for extrapolation of test results to actual ambient air sampling systems. Experimentation was performed using a gas chromatograph (G.C.) equipped with a flame ionization detector. Sample introduction was carried out using the "displacement method" where the sample is introduced to the adsorbent cartridge as a plug.

Incipient elution volumes (V_N), normalized for bulk adsorbent packing volume, were obtained at various …

Continuous Fractionation Of Protein Mixtures By Ph-Parametric Pumping, Yuk-Wei Wong

Theses

Continuous pH-parametric pumping separations of a haemoglobin - albumin - CM Separose system were experimentally investigated. The parapump system has a feed, containing the protein mixture to be separated, introduced alternately to the top and bottom of the chromatographic column. The top and bottom products are withdrawn from the apparatus during the bottom and top feed respectively. It is shown that under certain conditions the pH-driven parametric pump has the capacity for removal of a protein component from one product fraction and large enrichment in the other fraction. Moreover, the continuous process can be operated with a large feed throughput.

Inplane And Out Of Plane Buckling Of Thick Rings Subjected To Hydrostatic Pressure, Thomas Michael Juliano

Dissertations

The problem of inplane and out of plane buckling of a thick circular ring subjected to a hydrostatic pressure is analyzed from first principals. The equations of equilibrium from nonlinear elasticity theory are used to describe two adjacent equilibrium positions, i.e., an initial and final state. The initial position problem is assumed to be governed by linear theory. The resulting incremental value equations obtained by subtracting the two equilibrium states, are also linear in nature. These problems are reduced to a one dimensional ring theory problem by the method of power series expansion of the displacements in the radial and …

Noise Performance Of The Klapper-Kratt Low Delay Fm Detector, Allan Brown Tarbell

Dissertations

In this dissertation the dual differentiator version of the Klapper-Kratt FM detector family is investigated with additive Gaussian noise. Prior analysis of this new detector family has been limited to the noiseless case.

The investigation was conducted both analytically and experimentally. First, the dual differentiator version of the Klapper-Kratt detector was mathematically analyzed, assuming an unmodulated carrier plus additive Gaussian noise. This analysis was verified by assembling the detector and measuring its performance in the laboratory.

It was discovered that the Klapper-Kratt detector without limiter performs identically to the conventional limiter discriminator in the linear improvement region. When compared to …

The Use Of Natural Sorbents For The Treatment Of Industrial Sludge Leachate, Mung Shium Jack Sheih

Dissertations

A sorbent treatment process has been developed which uses natural clay soils and fly ashes as sorbents in the treatment of the hazardous contaminants of potential sludge leachate emanating from industrial landfills. Natural sorbents (i.e., vermiculite, illite, kaolinite, zeolite, acidic and basic fly ashes) were evaluated for the removal of specific cations, anions, and organics from leachates generated from three industrial sludges (i.e., calcium fluoride, metal finishing, and petroleum). The laboratory results indicate that, rather than a single sorbent, a combination of acidic and basic sorbents in a layered system is required to reduce for the measurable contaminants present in …

Signal Processing Techniques For Analysis Of Heart Sounds And Electrocardiograms, Alan D. Bernstein

Dissertations

Audible heart sounds represent less than 5% of the vibrational energy associated with the cardiac cycle. In this study, experiments have been conducted to explore the feasibility of examining cardiac vibration by means of a single display encompassing the entire bandwidth of the oscillations and relating components at different frequencies. Zero-phase-shift digital filtering is shown to be required in producing such displays, which extend from a recognizable phonocardiogram at one frequency extreme to a recognizable apexcardiogram at the other. Certain features in mid-systole and early diastole, observed by means of this technique, appear not to have been previously described.

Frequency …

Synthesis Of Multiarea Grid Power Systems, Bharat C. Patel

Dissertations

This dissertation presents improved development in the formation of a generalized transmission loss (B)-matrix for a multiarea grid power system. In the procedure, the individual tie powers of each area are replaced by the net interchange, sneak and circulating powers. The latter two variables are directly eliminated in the power reference frame using actual impedances, unlike current methods that require the elimination of sneak and circulating currents, the formation of complex tie current model and the complex tie power model. Consequently, manipulation of large complex current, power and impedance matrices is avoided reducing both computer time and memory requirement. Further, …

Axisymmetric Air Jet Impinging On A Convex Hemispherical Plate, David C. Chan

Theses

Experimental investigation was conducted on an axisymmetric, submerged air jet impinging normally on a smooth convex hemisphere. Three nozzle diameters of 0.5" (12.7mm), 0.375" (9.525mm) and 0.25" (6.35mm) were used and tests were run at Reynolds number range of 14,700 to 84,000.

The results obtained in the free jet and deflection zones were found to confirm the works of previous investigators. As for the fully developed wall jet region, the following points are noted:

1. The maximum wall-velocity decay was found to possess a slightly higher rate than that of either the flat plate or the concave hemisphere.

2. The mean velocity …

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Calculations Of Isobaric Phase Enthalpy Differences For Binary Systems From Vapor-Liquid Equilibrium Data, Steven Merrill Harvey

Theses

Equations relating isobaric vapor-liquid equilibrium data to heats of vaporization are useful in testing the thermodynamic consistency of experimental VLE data and in the design of distillation equipment. Several researchers have proposed such equations based on the Gibbs-Duhem equation. At low pressures, simplified versions of these equations were successfully used to test the consistency of published VLE and enthalpy data. At high pressures, equilibrium phase enthalpy differences were calculated from rigorous equations using a modified form of the Redlich-Kwong equation to calculate fugacity coefficients. As expected, the relative error of using the simplified equations was found to increase with increasing …

The Preparation, Spectra, And Conformations Of Cis, Cis-, Cis, Trans-, And Trans, Trans- Dipropenyl Ethers, Helen C. Hollein

Theses

Cis,cis-dipropenyl ether was prepared by potassium t-butoxide catalyzed rearrangement of diallyl ether in diglyme solution. Pyrolysis was used in an attempt to produce an isomeric dipropenyl ether mixture with a high percentage of the less stable trans,trans isomer; 21.6% trans,trans-dipropenyl ether was produced by pyrolysis at 395°C, but formation of an azeotropic byproduct in significant quantities negated the feasibility of this synthesis. A mixture of 45.7% cis,cis-, 43.6% cis,trans-, and 10.7% trans,trans-dipropenyl ether was produced by mercuric acetate catalyzed isomerization at 80°C, and the mixture was separated on a Nester/Faust spinning band column of two hundred theoretical plates.

Physical properties, …

A Three-Dimensional Kinematic Model Of The Human Knee, Wayne Ke-Wung Li

Theses

This thesis describes two kinematic models of human knee which may be used to study the motion of the knee and the forces in the ligaments of the knee. In one model, the ligaments are simulated by rigid links connected to links representing the articulating bones at the centroids of the areas of insertion of the ligaments. The condylar higher pair connections are simulated by equivalent linkages connected by resolutes. In an advanced model, the rigid ligament links are replaced by springs.

The IMP procedure, a powerful kinematic linkage analysis method, is employed to study the motion and forces in …

A Study On The Growth And Asparaginase Production Of Vibrio Succinogenes In A Chemostat, Preston David Krautheim

Theses

A continuous fermentation assembly was constructed and studies on the growth of the organism, Vibrio succinogenes, and its production of asparaginase was conducted. Results were compared with that already performed on a batch system and showed that a continuous fermentation produced 31.83 I.U. enzymes/mM ammonium formate compared to 17.4 I.U. enzyme/mM formate for batch.

Some of the runs performed indicated that the organism was washing out or giving very low specific growth rates. It was decided that this was not due to operational parameters of the chemostat, but possible chemical contamination in the medium. With all things considered, a continuous …

An Equilibrium Theory Of The Ph-Parametric Pump, Charles Omotayo Kerobo

Theses

Parametric pumping, both batch and continuous, and cycling zone adsorption are theoretically scrutinized for various operating conditions by using the concept of equilibrium stages. The model system is Haemoglobin-Albumin-CM sepharose, a physical system in which a local equilibrium between liquid and sorbent in the layers of the separating medium in the column is characterized. For the batch process, the steady-state concentrations in both top and bottom reservoirs are found to be independent of the number of equilibrium stages, provided that a = 1 (i.e., number of transfer steps/number of stages).. For continuous parapump process, separation is enhanced with decreasing top …

A New Mathematical Model For Nephron Macromolecular Selectivity, John Anthony Domiter

Theses

A mathematical model describing the displayed selectivity of the kidney nephron to macromolecules of varying particle size is presented. Diffusion and electrical forces are considered to be the sole mechanisms of transfer. The mass transfer principles responsible for selectivity are considered to occur within the capillary structure, and not within the membrane wall. A charge is assumed to be characteristic of the macromolecule and the membrane wall. Models describing both charged and uncharged solutes are developed.

A non-linear least squares technique, developed by Marquardt, is used to curve fit the derived functions to data relating fractional clearances of dextran and …

Effect Of Concentration And Ph On Parametric Pumping Separations, Tsu-Kun S. Hsieh

Theses

The technique of parametric pumping represents a new and valuable development in the separation science of proteins. Many conventional protein separation are often processed batchwise. However, parametric pumping offers the possibility of continuous processing; the continuous process provides both the advantages of decreasing the processing time and of minimizing degradation.

Preliminary step testing experiments were conducted to study the equilibrium of protein between the stationary and mobile phase of the sephadex ion exchanger.

It was the purpose of this research to study the feasibility of operating a semi-continuous parametric pump with a sephadex ion exchanger for the separation of a …