Engineering Commons^™

Phase Transitions Of Poly (L-Lactic Acid) In Bulk And In Solution, Jing Zhang

Dissertations

Poly(L-lactic acid) (PLLA) has been subject to intensive research in recent years because of its biodegradability. Applications of PLLA, such as porous tissue engineering scaffolds and excipients for controlled release, have been developed in the biomedical and pharmaceutical fields. The crystal structures and morphologies of this semicrystalline polyester are the underlying factors that determine the mechanical and degradation properties of PLLA.

A fundamental understanding of the development of crystal structures and morphologies during the phase transitions of PLLA in bulk and in solution is pursued in this dissertation. Synchrotron wide- and small-angle x-ray scattering (WAXS and SAXS) are adopted as …

Hfo2 As Gate Dielectric On Si And Ge Substrate, Reenu Garg

Dissertations

Hafnium oxide HfO₂ has been considered as an alternative to silicon dioxide SiO₂ in future nano-scale complementary metal-oxide-semiconductor (CMOS) devices since it provides the required capacitance at the reduced device size because of its high dielectric constant. HfO₂ films are currently deposited by various techniques. Many of them require high temperature annealing that can impact device performance and reliability.

In this research, electrical characteristics of capacitors with HfO₂ as gate dielectric deposited by standard thermal evaporation and e-beam evaporation on Si and Ge substrates were investigated. The dielectric constant of HfO₂ deposited by thermal evaporation …

Prediction Of Service Load Of Concrete Structures After Cracking Using Ultrasonic Technique, Xuezeng Wu

Dissertations

The objective of this study is to investigate the cracking behavior of fractured concrete structures and to introduce a new approach to assess their remaining service lives. A novel ultrasonic technique is utilized to detect crack propagation in notched beams of mortar, plain concrete and reinforced concrete. The study showed that crack growth and microcrack zone in cementitious composites can be quantitatively detected by the ultrasound technique.

To predict crack propagation during the fracture process in plain concrete, an effective compliance fracture model is proposed. A large fracture process zone is incorporated in the analytical model by means of an …

Modification Of Clays With Ionic Liquids For Polymer Nanocomponents, Neung Hyun Kim

Theses

In attempts to prepare nanofillers with enhanced compatibility with a polymer matrix, cationic and anionic clays susceptible to exchange of their interlamellar ions with a variety of other cations or anions, were selected.

In order to treat cationic clay, montmorillonite, which contains sodium ions as interlayer ions, reagents having cations differing in size and structure included three ionic liquids ([EMIM]⁺ [Br]^-, [HXMIM]⁺ [Cl]^-, and [Epty]⁺ [BF4]^-). Results indicated that cationic exchange did occur from aqueous solution as confirmed by FTIR, EDX, WAXS, TGA, and elemental analysis. WAXS indicated a significant increase …

Electrochemical Corrosion Testing Of Boronized And Unboronized Steels, Kranthi K. Pallegar

Theses

Boronizing is a thermo-chemical surface coating technique with which surface properties of materials are enhanced substantially. One of these properties is corrosion resistance. Corrosion resistance testing has been performed in many ways right from the traditional weight loss methods to the latest electrochemical techniques. These electrochemical techniques are more reliable and less time consuming and hence are widely accepted for corrosion testing in the industry.

In the present work, direct current (D.C) corrosion testing studies of both boronized and unboronized steels have been discussed. Three types of steels, AISI 1018, AISI 4340 and AISI 304 stainless steel, were considered for …

Demarcation Of Coding And Non-Coding Regions Of Dna Using Linear Transforms, Krithika Venkat

Theses

Deoxyribonucleic Acid (DNA) strand carries genetic information in the cell. A strand of DNA consists of nitrogenous molecules called nucleotides. Nucleotides triplets, or the codons, code for amino acids. There are two distinct regions in DNA, the gene and the intergenic DNA, or the junk DNA. Two regions can be distinguished in the gene- the exons, or the regions that code for amino acid, and the introns, or the regions that do not code for amino acid. The main aim of the thesis is to study signal processing techniques that help distinguish between the regions of the exons and the …

Medical Equipment Planning And Construction Of A Interventional Neuroradiology Suite, Furqan Elahi

Theses

New York-Presbyterian Hospital is one of the most comprehensive university hospitals in the world, with leading specialists in every field of medicine. It is composed of two renowned medical centers, New York-Presbyterian Hospital/Columbia University Medical Center and New York-Presbyterian Hospital/Weill Cornell Medical Center. The hospital's strategic planning group identified the need to expand the Interventional Neuroradiology service that the hospital provides. This brought upon the need to form a committee to plan the construction of an Interventional Neuroradiology. The problem statement of this thesis is to prepare a best practices guideline from a clinical engineering perspective on constructing the three …

Doppler Ultrasound Technique Used To Determine The Blood Flow Viscosity In The Middle Cerebral Artery Of A Canine Animal Model, Raj P. Ganpath

Theses

The cerebral blood flow velocity in the middle cerebral artery of an canine animal model was measured using the Doppler Ultrasound technique. A transducer was designed with a 20 MHz piezoelectric crystal and used for the application. An in vitro calibration system was designed and machined for the purpose of testing and calibrating every transducer before using it in vivo. Preliminary tests included experiments on the in vitro system and measurement of blood flow velocity in the human wrist artery (metacarpal artery). The effect of using different transmission media (agarose and gelatin) was determined through the many in vitro and …

Impact Of Missed Beats On Heart Rate Variability Using Time-Frequency Analysis, Kilbrom T. Hailu

Theses

ECG recordings, especially during an exercise stress test, are exposed to artifacts. The source of artifacts can be due to technical problems, biological events and errors in the automatic detection. As a result missed beats, extra beats and ectopic beats can occur. In this study analysis of missed beats is performed using time-frequency analysis. Some of the patient's data had missed beats.

Fourier spectral analysis was first applied to the missed beats during the resting state. The impact of missed beats using Fourier spectral analysis is significant, especially, when the missed beats are in a row. The Fourier spectral analysis …

Online Clustering With Single-Pass Topology Based Fuzzy Clustering Algorithm, Abhishek Jaiantilal

Theses

Online clustering is of significant interest for real-time data analysis. Generic offline clustering methods such as K-Means, C-Means and others are computationally expensive. The computational burden of these methods increases non-linearly with the size of the data set. In addition these methods usually require a good amount of supervised knowledge yielding a non-unique solution. For real-time data analysis, there is an important tradeoff between accuracy and computational efficiency. An unsupervised one-pass clustering method that efficiently adapts to data distribution and evaluation is proposed. This method, Topology-Based Fuzzy Clustering (TFC), uses the topology of data to discover clusters. TFC uses the …

New Hybrid Automatic Repeat Request (Harq) Combining With Space Time Block Coding (Stbc) In Invariant And Variant Fading Channel, Guillem Ernest Malagarriga Vilella

Theses

Hybrid Automatic Repeat reQuest (HARQ) combining for space time block coding Multiple Input Multiple Output (MIMO) system consisting of N transmit antennas and M receive antennas (NxM) in a time invariant channel and in a time varying channel is proposed and its performance is analyzed. Based on the measured channel matrix, the receiver chooses the best retransmission order and communicated it to the transmitter.

The scheme, where this algorithm is performed, is a combination of a precombining HARQ scheme and the Multiple Alamouti Space-Time Block Coding (MASTBC), which is suitable for more than 2 transmit antennas. The combination of this …

Non-Invasive Monitoring Of Bone Health Using Ultrasound, Nashit Jahan Meem

Theses

Bone fractures are estimated to afflict everyone at least once in his/her lifetime. Monitoring this becomes crucial especially when it comes to athletes in order for them to safely resume their regular activities as soon as possible. Technologies currently employed are either very expensive or use harmful radiation.

Ultrasound can monitor bone fractures in a non-invasive manner, as discussed in United States Patent # 5143069. Three transducers are mounted over the test specimen. A pulse generator excites the transmitting receiver. The second receiver is mounted next to the transmitter and acts as a reference receiver that displays the response across …

A Study Of Steganography And Steganalysis, Nisant Nalla

Theses

Steganography is the art of hiding the fact that communication is taking place, by hiding information in other information. Steganalysis is the study of methods to detect the presence of hidden messages. The Steganography and Steganalysis are very much interdependent. The people in the Steganography domain try to develop stronger methods to hide data in different media. This spurs the discovery of new steganalysis methods which can break these Steganography methods. This is vital for the development of these fields. The internet has been growing by leaps and bounds. There is an increasing need for information security. It has been …

Qt Variability Calculation Using A Template Matching Algorithm And Power Spectral Analysis, Theodore Sami Rizkalla

Theses

ECG interval measurement and variability analysis has proven to be a useful tool in investigating autonomic nervous system function. Traditionally, the R to R interval has been the thrust of research conducted in this field. QT variability is another topic on which little research has been done.

This thesis uses an algorithm proposed by Dr. Berger, published in 2003. The algorithm stretches the template in the time domain, and composes a sum-squared error function, which is minimized to find the scaling factor for that beat. These scaling factors are compiled into an array, and an interpolated signal is generated of …

Boron Induced Surface Modification Of Transition Metals, Raghasudha Vangaveti

Theses

Boronizing is a thermo-chemical surface treatment of metals in which boron atoms diffuse into the metal substrate and form hard metallic borides. As a result of boronizing, several properties such as hardness, wear resistance, corrosion resistance, and high temperature oxidation resistance improve which make the metal substrate more suitable for industrial applications. These boronized parts are used in many industrial applications like ingot moulds, crucibles, biomedical implants, die-casting moulds, magnetic head applications, drawing dies etc.

The objective of this work was to investigate the influence of boronizing on the properties of transition metals. Three transition metals, tantalum, niobium and tungsten …

Direct Application Of The Least Action Principle To Solve (Human) Movement Dynamics Without Using Differential Equations Of Motion, Amitha Kumar

Theses

This thesis explores the numerical feasibility of solving motion 2-point boundary value problems (BVPs) by direct numerical minimization of the action without using the equations of motion (EOM) as an intermediate step. The proposed direct least action (DLA) approach using the downhill simplex method (DSM) is applied to both the single and double pendulum systems as beginning test problems. The solutions so obtained are compared to numerical solutions of the corresponding Lagrange BOM solved using a first order Euler algorithm for the same mechanical problems. The output path obtained by both of the methods essentially superimpose on each other.

Future …

Heavy Metal Adsorption On Iron Oxide And Iron Oxide-Coated Silica : Macroscopic, Spectroscopic, And Modeling Studies, Ying Xu

Dissertations

To accurately model metal mobility and bioavailability in soils and sediments, systematic sorption studies are needed using representative and well-characterized minerals. Two important surfaces are iron oxide and silica, which are ubiquitous and associated with one another in the environment playing important roles in metal distribution. The objectives of this research are to develop models for predicting speciation and mobility of toxic trace metal ions in groundwater, soils, and sediments when competing ions are present. A model system for soils and sediments, iron oxide-coated silica, was synthesized; the degree of coatings was highly sensitive to the particle size of silica …

Study Of Si/Sio2 Interface Passivation And Sio2 Reliability On Deuterium Implanted Silicon, Tias Kundu

Dissertations

One of the major defects that contribute to the interface states in the silicon band gap is the dangling bond, which degrades performance of MOS devices. Passivation of these bonds with hydrogen had been found to diminish their effect but the improvement degrades the operation due to hot electron effect. Passivation with deuterium annealing has proven to improve the lifetime of the metal oxide semiconductor devices but this technique is not very effective for a multi-level metal-dielectric structure. This work investigates and optimizes incorporation of deuterium by ion implantation into the silicon substrate before the growth of 6.5 nm thin …

Robust Techniques And Applications In Fuzzy Clustering, Amit Banerjee

Dissertations

This dissertation addresses issues central to frizzy classification. The issue of sensitivity to noise and outliers of least squares minimization based clustering techniques, such as Fuzzy c-Means (FCM) and its variants is addressed. In this work, two novel and robust clustering schemes are presented and analyzed in detail. They approach the problem of robustness from different perspectives. The first scheme scales down the FCM memberships of data points based on the distance of the points from the cluster centers. Scaling done on outliers reduces their membership in true clusters. This scheme, known as the Mega-clustering, defines a conceptual mega-cluster which …

Variable Permittivity Dielectric Material Loaded Stepped-Horn Antenna, Ozgur Ozdemir

Dissertations

Stepped-horn antenna loaded with dielectric material of variable permittivity is proposed to improve radiation characteristics and/or to increase the electrical dimensions of the radiating structure compared to unloaded empty one. A hybrid numerical technique is used to analyze such an antenna. The tapered section of the horn antenna is modeled by multi-stepped waveguide structures filled with variable dielectric constant material. Generalized scattering matrix representation of the tapered section of the horn antenna is obtained using mode matching technique. The radiating aperture problem is solved by the method of moments, under the assumption that the horn is terminated by an infinite …

On The Design For Flexibility Of Manufacturing Systems : A Stochiastic Approach, Nathapol Areeratchakul

Dissertations

Flexibility has emerged as one of the most strategic imperatives for company viability in today's fast paced economy. This realization has stimulated extensive research efforts in this area most of which have focused mainly on defining flexibility and its attributes, the need for flexibility and how to measure it. Nevertheless, despite the considerable amount of publications regarding flexibility and its related subjects, insufficient attention has been given to the optimality of the design for flexibility and the inherent needs to meet uncertainty. Bridging this gap is the intent of this work.

In this dissertation, developed analytical models are for the …

Opportunistic Transmission Scheduling For Next Generation Wireless Communication Systems With Multimedia Services, Chengzhou Li

Dissertations

The explosive growth of the Internet and the continued dramatic increase for all wireless services are fueling the demand for increased capacity, data rates, and support of different quality of service (QoS) requirements for different classes of services. Since in the current and future wireless communication infrastructures, the performances of the various services are strongly correlated, as the resources are shared among them, dynamic resource allocation methods should be employed. With the demand for high data rate and support of multiple QoS, the transmission scheduling plays a key role in the efficient resource allocation process in wireless systems. The fundamental …

Energy Efficient Organization And Modeling Of Wireless Sensor Networks, Jin Zhu

Dissertations

With their focus on applications requiring tight coupling with the physical world, as opposed to the personal communication focus of conventional wireless networks, wireless sensor networks pose significantly different design, implementation and deployment challenges. Wireless sensor networks can be used for environmental parameter monitoring, boundary surveillance, target detection and classification, and the facilitation of the decision making process. Multiple sensors provide better monitoring capabilities about parameters that present both spatial and temporal variances, and can deliver valuable inferences about the physical world to the end user.

In this dissertation, the problem of the energy efficient organization and modeling of dynamic …

Optimal Speed Limit For Shared-Use Roadways, Yongqiang Yang

Dissertations

Motor vehicle crashes are a serious social problem in the United States. Each year a large number of motor vehicle crashes occur and many people are killed or injured, resulting in substantial economic costs. To minimize economic costs, it is necessary to determine optimal speed limits on roadways because of the strong relationship among posted speed limit, crash frequency, and crash injury severity.

A comprehensive literature review about the relationship among posted speed limit, crash frequency, and crash injury severity level was conducted. Crash frequency prediction models and crash injury severity models are developed to obtain crash frequency and injury …

Synthesis And Characterization Of Polymer Nanocomposites, Nirav S. Patel

Theses

Polymer nanocomposites were produced by solution mixing of a commercial flexible acrylic polymer paint, with nanofillers of different size, shape, aspect ratio and purity such as hydrotalcite (HT), sodium montmorillonite (MMT), single wall carbon nanotubes (SWNT) and fullerenes (FUL), at 5 and 10 wt% loading. Structural characteristics and mechanical, thermal and barrier properties of the nanocomposites were characterized by different techniques and compared to those of the unfilled polymer.

The presence of partially exfoliated and intercalated nanoplatelets in the polymer resulted in increased 2% secant tensile modulus, and decreased tensile strength and elongation at break, to different extents. While the …

Investigation Of Solid Polymeric Hollow Fiber Heat Exchange Devices For Use In Thermally-Driven Desalination Processes, Saskia Christian

Theses

The heat exchange between hot brine (4 wt% NaCl) and cold water as well as between condensing steam and cold water without direct fluid-fluid contact using modules made out of solid polymeric hollow fibers of polypropylene (PP) and polyetheretherketone (PEEK) has been studied. The solid hollow fiber dimensions were 425μm/575μm (ID/OD) for PP and 420μm/570μm (ID/OD) for PEEK. Extensive heat transfer measurements have been performed and the experimentally-determined overall heat transfer coefficients utilized to isolate the wall heat transfer coefficient, the inside heat transfer coefficient and the outside heat transfer coefficient. The heat exchange between hot brine and cold water …

Haptic Induced Motor Learning And The Extension Of Its Benefits To Stroke Patients, Adrienne M. Coppa

Theses

In this research, the Haptic Master robotic arm and virtual environments are used to induce motor learning in subjects with no known musculoskeletal or neurological disorders. It is found in this research that both perception and performance of the subject are increased through the haptic and visual feedback delivered through the Haptic Master. These system benefits may be extended to enhance therapies for patients with loss of motor skills due to neurological disease or brain injury.

Force and visual feedback were manipulated within virtual environment scenarios to facilitate learning. In one force feedback condition, the subject is required to maneuver …

Growth Behavior Of Fibroblasts Influenced By Small Changes In Polymer Structure, Saraswathi Doddi

Theses

Polymers are a promising class of biomaterials that can be engineered to meet specific end use requirements. The order and processing history of the polymer, which would alter the molecular orientation of the material could have a significant contribution towards cellular attachment and in turn, cell growth on the particular polymer. Surface properties of the material were considered to directly influence the properties of the adherent cells including cellular growth and reorganization. The present study is aimed at comparing cell growth on polyarylates with that of polylactic acid in their original state or by introducing small changes in the surface …

An Analytical Model Of Mac Protocol Dependant Power Consumption In Multi-Hop Ad Hoc Wireless Sensor Networks, Komlan Egoh

Theses

Power efficiency is the most constraining requirement for viable operation of battery-powered networked sensors. Conventionally, dynamic power management (DPM) is used to put sensor nodes into different states such as active, idle, and sleep, each consuming a certain level of power. Within the active state, communication operational states, such as receive and transmit consume different levels of nodal power. This thesis shows how DPM states and protocol operational states can be combined into a single stochastic model to finely evaluate the power consumption performance of a medium access control (MAC) protocol. The model is formulated as a semi-Markov decision process …

Enhancing End-To-End Quality Of Service Provisioning In Wireless Ad Hoc Networks Using Service Vectors, Didem Gozupek

Theses

A cross-layer architecture that achieves significant power savings, while enhancing the end-to-end QoS provisioning and granularity in wireless ad hoc networks is proposed in this thesis. Recently, a new concept called service vector has been introduced, which enables an end host to choose different service classes along its data path. This scheme enhances the user benefits from the network services and network resource utilization, while maintaining the simplicity and scalability of the current Differentiated Services (DiffServ) network architecture. This thesis explores the application of this concept on wireless ad hoc networks and provides a cross-layer architecture based on the combination …