Engineering Commons^™

Reevaluating The Van’T Hoff And Arrhenius Equations: How Temperature And Pressure Affect Chemical Reaction Thermodynamics, Equilibrium, And Kinetics, Jianmin Wang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The van’t Hoff equation, which is used to calculate the effect of temperature on equilibrium constants, was derived from the Gibbs – Helmholtz equation that relates the molar Gibbs free energy to the molar enthalpy of a chemical reaction. However, the Gibbs – Helmholtz equation was developed for systems that do not consider contributions of Gibbs free energy from chemical species. Consequently, the van’t Hoff equation and the Arrhenius equation derived from it are technically incomplete.

By employing Hess’s law and the appropriate Gibbs free energy equation for chemical reaction systems, this investigation develops theoretical equations to calculate the effects …

An Improved Table Method For Coded Target Identification With Application To Photogrammetric Analysis Of Soil Specimen During Triaxial Testing, Xiaolong Xia, Xiong Zhang, Sara Fayek, Zhaozheng Yin

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Accurate and efficient recognition and identification of coded targets are of great importance in coded target-based photogrammetry. Recently, a deep learning-based method has been utilized to recognize the coded targets. Then, a table method has been developed to decode the coded targets, identify falsely identified coded targets, and recover missing coded targets. This method takes advantage of the geometric arrangement of the coded targets. In this paper, an improved table method has been developed to improve the coded targets recognition and identification results. Blob analysis, instead of deep learning, is utilized to recognize coded targets. Then, the RANSAC algorithm was …

Individual Design Task Final Report Security Design, Ciarrah Bell

Honors Academy

"The Environmental Services Campus project is a comprehensive development designed to support the City of Springfield’s Environmental Services operations, with a focus on functionality, sustainability, and safety. The campus includes administrative office space, staff parking, a maintenance vehicle garage, and educational facilities aimed at community outreach. A component of the project is establishing site-wide security that not only protects personnel and assets but also integrates seamlessly with the architectural and environmental goals of the facility.

The primary focus of the Security IDT is the development and implementation of a comprehensive security strategy for the entire site. This includes designing and …

Leveraging Intrinsic Properties For Classification Of Coal Seams Towards Spontaneous Combustion Proclivity And Predicting Susceptibility Using Machine Learning: Smart And Sustainable Mining Approach, Siddhartha Agarwal, Pradeep K. Gautam, Yuhao Zou, Rishabh Dwivedi, Durga C. Panigrahi, Cihan H. Dagli, A. Singh

Engineering Management and Systems Engineering Faculty Research & Creative Works

Mine fires and other hazards caused by spontaneous coal combustion are a pervasive and longstanding issue in Jharia coalfields, India. This study proposes a novel approach to classify coal seams based on their propensity to spontaneous combustion using the intrinsic properties of 30 coal samples from different seams. This method eliminates the need for expensive and time-consuming experimental determinations of susceptibility indices (SI) such as crossing point temperature (CPT), critical air blast (CAB), and differential thermal analysis (DTA). All clustering models, viz. hierarchical, k-means, and multidimensional scaling, aptly classify coal seams into three categories: highly risky, medium risky, and low …

Using Telemetry To Assess Operator Effects On Hydraulic Shovel Energy Efficiency. Part Ii: Assessing Operator Effects, Noah Adekunle Aluko, Kwame Awuah-Offei

Mining Engineering Faculty Research & Creative Works

In this second part of a two-part series, this study investigates whether operator practices significantly affect the energy efficiency of hydraulic shovels, using detailed telemetry data. Rather than assuming this relationship, the research systematically tests it through a combination of statistical and regression analyses. First, Welch's and Kruskal–Wallis ANOVA confirm that operators differ significantly in their energy efficiency (p = 0.0000). Next, correlation analysis links parameters identified in Part I to energy per unit loading rate, and difference regression analysis determines which parameters most strongly influence efficiency variations. The results show that differences in payloads are the primary driver of …

Understanding The Usefulness Of Self-Escape Technologies In Underground Mining: Perspectives Of Metal/Nonmetal Miners, Eugene A. Gyawu, Kwame Awuah-Offei, D. A. Baker

Mining Engineering Faculty Research & Creative Works

Research on mine self-escape often focuses on coal mining, while perspectives from underground metal/nonmetal miners remain understudied despite their distinct emergency response challenges and unique operating environments. Using a scenario-based survey approach, this study evaluated underground metal/nonmetal miners' perceptions of the usefulness of 18 hypothetical self-escape interventions and how these perceptions are influenced by worker characteristics. Employment type was the strongest predictor of usefulness ratings, with hourly employees rating several self-escape interventions significantly higher than salaried employees, including those related to improving self-contained self-rescuers (SCSRs) and tethered guidance systems. The data suggested potential trends where perceived usefulness increased with more …

Evaluating Feasibility Of Incorporating Fuel Cell Drive Trains Into Existing Haul Trucks, Ayorinde Akinrinlola, Kwame Awuah-Offei, Abdullah Al Moinee

Mining Engineering Faculty Research & Creative Works

Hydrogen, as a fuel source in material handling, has become a viable option for achieving carbon reduction targets. The objective of this work was to apply vehicle drive train and energy simulation in MATLAB/Simulink to guide a discussion of the challenges and opportunities of incorporating hydrogen fuel cell drive trains into the current form factors of mine haul trucks. We built and validated a model based on the Komatsu 830-E truck and used it to estimate the hydrogen requirements for typical short-haul, medium-haul, and long-haul cycles; in the short-haul case (cycle time = 852 s) the truck consumed 23.6 L …

Cracking The Code: Harnessing Serpentinization-Driven Micro-Crack Networks For Hydrogen Generation And Subsurface Resource Recovery, U. Mutlu, G. Boitnott, A. Lisjak, J. Ha, O. Mahabadi, P. Connolly, B. N. Tunnell, T. Sherizadeh, S. Nowak, J. E. Olson

Mining Engineering Faculty Research & Creative Works

This study focuses on simulating volume-increasing processes caused by natural hydrogen-generating serpentinization, a reaction in which olivine and pyroxene typically transform into serpentine minerals. The volume increase leads to crack propagation along grain interfaces and new crack generation within unreacted crystals (aka grains). The interplay between thermo-hydro-mechanicalchemical (THMC) conditions plays a critical role in the initiation, propagation, and coalescence of various fracture surfaces, which enhances permeability and can accelerate serpentinization and hydrogen production rates. In the scenarios considered, chemical reactions between formation brine and reactive minerals result in volumetric expansion, generating stress and promoting the propagation of micro-cracks. Our results …

Aperiodically Intermittent Dynamic Event-Triggered Control For Predefined-Time Synchronization Of Stochastic Complex Networks, Lei Xue, Haoyu Zhou, Yongbao Wu, Jian Liu, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, the problem of practical predefined-time synchronization in mean square (PTSMS) of stochastic complex networks (SCNs) is investigated through dynamic event-triggered control (E-TC). Different from the existing literature, this paper considers the dynamic E-TC in an a periodically intermittent control framework and employs the average control rate, which makes it easier to satisfy the conditions of the theorem. In comparison to existing finite-time and fixed-time synchronization, by introducing the time-varying function, it can be guaranteed that all states of SCNs achieve the practical PTSMS within a preset time without calculating the convergence time. Combined with stochastic analysis theory, …

Transfection Of Ionizable Lipid Nanoparticles On Raw 264.7 And Mda-Mb-231, Lavanya Bhargava

Masters Theses

"This thesis investigates the preparation, characterization, and transfection efficiency of various ionizable lipid nanoparticles (LNPs) formulated for the delivery of mRNA encoding enhanced green fluorescent protein (EGFP) in RAW 264.7 macrophages and MDA-MB-231 breast cancer cell lines. The ionizable cationic lipid studied are ALC-035, C12-200, C14-4, PPZ-A10, DLin-MC3-DMA. The study addresses the need for effective gene delivery systems to provide a safe and versatile platform that protects and transports nucleic acids into target cells. LNPs were synthesized using microfluidic mixing methods, incorporating lipid components such as the cationic lipids, DSPE, DOPE, cholesterol and PEG lipids to achieve controlled particle sizes, …

Flexural Post-Cracking Performance Of Macro Synthetic Fiber Reinforced Super Workable Concrete Influenced By Shrinkage-Reducing Admixture, Jingjie Wei, Nima Farzadnia, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Most literature has focused on the effect of shrinkage-reducing admixture (SRA) in shrinkage mitigation resistance of concrete. This study aims to examine the impact of SRA on the efficiency of macro synthetic fibers (MSF) in enhancing the flexural post-cracking behavior of fiber-reinforced super workable concrete (FR-SWC). A comparative analysis of the influence of fiber combinations on the flexural post-cracking behavior of beams is also included. Results showed that a higher dosage of SRA, particularly at 5 % by mass of binder, had a noticeable negative impact on flexural post-cracking performance of beams while exhibiting positive effect on workability and shrinkage …

Active Phytoextraction Of Toluene Shifts The Microbiome And Enhances Degradation Capacity In Hybrid Poplar, Michael Benisrael, Dasiel Obregon, Philipp Wanner, Jeremy Fernandes, Joel G. Burken, Ramon Aravena, Beth L. Parker, Elizabeth A. Haack, David T. Tsao, Kari E. Dunfield

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Hybrid poplars are widely recognized for their effectiveness in remediating subsurface aromatic hydrocarbon contaminants, including benzene, toluene, ethylbenzene, and xylene isomers (BTEX). While BTEX compounds are frequently found in the transpiration streams of poplars at contaminated sites, the microbial dynamics within these trees, particularly in response to hydrocarbon exposure, remain underexplored. This study utilized high-throughput amplicon sequencing to investigate the trunk microbiome in hybrid poplars at a field-scale toluene phytoremediation site. Across the plant growth season (spring to late summer), we observed a significant seasonal increase in bacterial diversity and richness, particularly in trees located in areas with the highest …

Innovative Air Convection Embankment For Cold/Arctic Region Low-Volume Roads, Hanli Wu, Jenny Liu, Xiong Zhang, Steve Saboundjian

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Roadbed thaw settlement is a unique challenge for the durability of low-volume roads (LVRs) in permafrost regions. Air convection embankment (ACE) is an effective technique that acts as a semi-heat-transfer system to control temperature variation and reduce the thaw depth of subsoil. However, limited by the shortage of the necessary crushed rocks within a short distance, building an ACE in Alaska, U.S., is prohibitively expensive. Previous studies identified the feasibility of using cellular concrete for ACE and determined the optimized thickness of the cellular concrete aggregate interlayer for ACE. However, the economic efficiency and thermal and mechanical performance of the …

Improving The Operator-Swarm Dynamic Under Mental Fatigue Constraints In Search And Rescue Operations, Jordan Morrow

Masters Theses

"Human-robot applications that allow for work to be done remotely are largely dependent on the lassitude of the operators. The exhaustion of these operators is a result of work completion and duration. Previous research attempts to evaluate the impact on reaction by quantiying human weariness. This paper examines how human weariness affects the human-robot dynamic in UAV-assisted search and rescue missions. An explanation of the connection between mental exhaustion and operator responsiveness over prolonged durations is provided by the search and rescue operations using UAV swarms (SAROUS) model. Through the use of artificial intelligence, SAROUS is modernized. This allows the …

Computation Of Natural Relative Trajectories In The Elliptic Restricted Three-Body Problem, Dane Huck

Masters Theses

"Humankind’s presence in deep space is certain to increase throughout future decades. Future missions will continue to exploit the complex dynamics making use of liberation point orbits. Along with this trend is the rise of small satellites ("small sats") and fractionated spacecraft in general. Compared to traditional monolithic spacecraft, small sats can often have higher maneuverability, be a fraction of the cost, and be more expendable in nature. The growing interest in these two areas drives the need for improvements in the area of relative motion in deep space. One obvious use of small sats in deep space is for …

Advanced 3d Lidar-Based Systems For Urban Traffic And Pedestrian Monitoring: Integrating Elevated Lidar, Data Collection, And Deep Learning For Precise Detection And Activity Classification, Nawfal Guefrachi

Masters Theses

"Accurate and real-time monitoring of urban traffic and pedestrian activities is crucial for intelligent transportation systems (ITS) and smart cities. Traditional camera-based methods struggle with issues like lighting and privacy. This research leverages advanced three-dimension light detection and ranging (3D LiDAR) technology and computational frameworks to address these challenges, providing transformative solutions for urban traffic management and pedestrian safety. By strategically deploying elevated LiDAR sensors, detailed 3D point cloud data is captured, enabling precise monitoring of urban environments. Enhancements to LiDAR-based frameworks, such as fine-tuning the Point Voxel Region-Based Convolutional Neural Network (PV-RCNN), improve the detection of vehicles and pedestrians …

Bond Behavior Of Magnesium Potassium Phosphate Cement (Mkpc) Coating For Steel Reinforcement, Eric Williams

Masters Theses

"This research investigates the bond behavior of magnesium potassium phosphate cement (MKPC) coated mild steel deformed bars in conventional concrete and concrete repair materials. For typical steel reinforcement in concrete, a thin “passive layer” develops around the reinforcement, which protects the reinforcement from corrosion. The concrete carbonates over time, reducing the protection of the passive layer and allowing chlorides, which corrode the reinforcement, to penetrate at an increasing rate. In some cases, to combat this corrosion, a protective layer is added to the reinforcement prior to installation. Common protective layers include epoxy coatings or zinc galvanization. MKPC is a novel …

Lidar From The Skies: A Uav-Based Approach For Efficient Object Detection And Tracking, Baya Cherif

Masters Theses

"Recently, there has been a growing interest in deploying the Light Detection and Ranging (LiDAR) technology to gain traction in the autonomous vehicle industry, its applications are expanding into areas like smart cities, agriculture, and renewable energy. This work proposes an advanced approach to enhance aerial traffic monitoring using Li- DAR. We aim to provide accurate, real-time object detection and tracking from an aerial perspective by integrating Unmanned Aerial Vehicle (UAV) with LiDAR, culminating in a smart UAV-integrated LiDAR (A-LiD) sensor for traffic surveillance. We introduce an adapted version of one of the newest methods of the cutting-edge 3D object …

Fetal Acidosis Prediction Using Attention Enhanced Convolutional Neural Networks, Anusha Adhikari

Masters Theses

This study explores the integration of spectral mixtures of fetal heart rate (FHR) and uterine contraction (UC) signals to enhance the prediction of fetal acidosis, utilizing the CTU-CHB dataset. Several classification models were trained using two distinct oversampling techniques and inputs, demonstrating that models incorporating spectral mixtures significantly outperform those using raw signals. These models, particularly when combined with convolutional neural networks (CNNs) and attention mechanisms, achieved a notable F1-score of 0.98, with the highest model achieving an area under the Receiver Operating Characteristic (ROC) curve of 0.95. The research employs a variety of techniques including short-time Fourier transform and …

Modeling Of Slot-Backed Microstrip Line For Emi Applications, Jongsuk Hyun

Masters Theses

Radiated emissions from printed circuit boards (PCBs) are a significant concern in electromagnetic interference (EMI) and radio frequency interference (RFI). Shielding cans are widely used to mitigate these emissions but evaluating requires accurate characterization of equivalent noise sources. Slot-backed microstrip antennas are employed for this purpose due to their near-zero height, low parasitic radiation, and PCB-compatible structure, offering a practical alternative to conventional loop antennas. This paper presents a physics-based analytical model that integrates both the discontinuity effects and radiated characteristics of slot-backed microstrip structures within a unified circuit framework. An analytical expression for the dipole moment is proposed based …

Long Short-Term Memory (Lstm) -Based Neural Network Model For Optimizing Composite Manufacturing Process Using Autoclave, Sourav P. Bolar

Masters Theses

The combination of high pressure and controlled heat plays a critical role in ensuring the uniform curing of composite materials, leading to parts with superior mechanical properties. In this study, three composite samples of IM7/CYCOM 5320-1, each cut into 12x12-inch squares, were placed in an autoclave at three different locations, spaced 6 inches apart. Sixteen thermocouples were randomly distributed across the setup to monitor the curing process as the autoclave temperature was systematically ramped up and down while maintaining constant pressure, creating a fully controlled curing environment. The primary objective was to optimize the curing locations to reduce machine runtime …

Characterization Of The Microstructural Changes Of Zrb2 Under Heavy Ion Irradiation For Molten Salt Reactor Applications, Narrie Loftus

Masters Theses

A primary challenge in finding suitable materials for Molten Salt Reactors (MSRs) lies in identifying those that concurrently exhibit high corrosion resistance, stability at elevated temperatures, resistance to radiation, and chemical compatibility with molten salts. 11B-enriched zirconium diboride (ZrB₂) is a potential candidate for applications in MSRs due to its unique combination of properties, including high melting point, high thermal conductivity, and resistance to corrosion in harsh environments. This ultra-high temperature ceramic (UHTC) has exhibited stability under extreme conditions, making it an attractive material for components within MSRs.

The microstructural response of ZrB₂ under heavy ion irradiation …

On Optimizing Sensor Data Collection, Processing, And Storage For Industrial Additive Manufacturing, Steven Thompson

Masters Theses

The widespread adoption of digital data management methods for transformative technologies, such as additive manufacturing (AM), within the aerospace industry is impeded by poor interoperability between AM component manufacturing processes. Moreover, data quality may be compromised due to sensor failures or other corruptions. Additionally, massive amounts of data are collected during these processes, often needing to remain accessible for decades. These storage costs can place a significant financial burden on smaller suppliers. This work aims to make digital data management methods more affordable and, therefore, approachable for smaller suppliers.

First, the design and initial implementation of an affordable and adaptable …

Emi Mitigation, Material Characterization, Transformer Equivalent Circuit Modeling, Reza Vahdani

Masters Theses

Modern high-frequency electronic systems demand precise characterization and modeling techniques to ensure signal integrity and electromagnetic compatibility. This thesis presents three core studies focused on real-world challenges in high-speed and power electronics: EMI mitigation using 3D printed absorbers, wideband liquid dielectric characterization, and accurate transformer modeling.

The first study demonstrates a targeted approach to mitigating electromagnetic interference (EMI) in a commercial router. By using holography imaging to identify radiation hotspots, custom absorber structures were designed with commercially available materials, fabricated via 3D printing, and applied directly to emission sources. Radiated emission tests in a reverberation chamber showed up to 9 …

Investigation Of Arm Stiffness Modulation During Overground Physical Human-Human Interaction, Henry Tien

Masters Theses

The vision of advancing robots capable of direct physical engagement with humans begins with an understanding of how humans interact with each other. Even rudimentary interactive tasks, such as shaking hands, provides tremendous challenges for modern robotics and current research into the biomechanics of such interactions is limited. Thus, further analysis of physical Human-Human Interaction (pHHI) will bolster efforts to enhance collaborative robot capabilities. To this end, a custom Force Perturbation Handle (FPH) was developed, including the requisite mechanical, electrical, and software systems, to investigate the unique role of arm stiffness modulation in haptic communication between humans. The novel device …

System Design For Highly Accurate And Efficient Target Detection In Triaxial Testing, Qingqing Fu

Masters Theses

Accurate and automated recognition of coded targets is crucial for high-precision photogrammetry-based measurements in triaxial testing. Traditional recognition methods, including those based on deep learning and table decoding, often struggle with issues such as perspective distortion, rotation, and variable lighting, leading to unreliable results. While deep learning approaches offer some improvements, they remain computationally intensive and sensitive to environmental factors.

This thesis introduces an innovative system that replaces deep learning algorithms with a blob analysis-based method for efficient and robust recognition of coded targets. The system also employs newly designed solid points of varying sizes and patterns, eliminating the need …

Development Of A Method To Measure Blast Overpressure Exposure Using Orthogonal Sensor Orientations, Nicholas Kuehl

Masters Theses

Measuring and recording blast exposure to military personnel from shoulder-fired weaponry or improvised explosive devices to correlate health outcomes like mild traumatic brain injury has been a goal for many years. As such, many wearable sensors have been developed and tested for accuracy and reliability. Despite this, knowing the sensor orientation in relation to the blast source is important to fully correlate the actual personnel exposure to clinical outcomes. This research investigates whether pressures recorded at three independent orientations in the x, y and z planes can be combined to a representative pressure that is independent of orientation. Important metrics …

Power Flow Control Of The Triple Active Bridge Converter, Lauryn Reece Morris

Masters Theses

With the rise of renewable energies, electric vehicles, and microgrids, the development of power electronic topologies that can seamlessly integrate these systems into the grid is crucial. The triple active bridge is an extension of the dual active bridge topology and is capable of energy storage or renewable energy integration into a power electronic converter and thus the power grid. Consisting of three H-Bridge converters, the triple active bridge topology is an expanding area of research to meet these growing demands. With the addition of the third bridge, the system has additional nonlinear characteristics which introduce complexity in solving for …

Ground Testing Of Cryogenic Environments In Vacuum Conditions, Lucas A. Scott

Masters Theses

The environment in the vacuum of space is unforgiving and ever-changing. Not only facing the lack of a protective atmosphere, but powerful radiation and extreme temperature ranges as well. Equipment destined for space must be hardened to withstand them. Just launching satellites that are theoretically able to survive these conditions is unfeasibly costly in the event of failure. Because of this, spacecraft must be tested in a simulated environment that can match the harsh climate in space. Therefore, it is the goal of the Gas and Plasma Dynamics Lab's (GPDL) to test and prove specific methods of recreating these conditions. …

Overpressure Waveform Comparison Of High Explosive, Methane, And Coal Dust Explosions, Frank James Schott

Masters Theses

Methane and coal dust explosions remain a leading cause of catastrophic mining accidents, making it critical to understand their overpressure characteristics for better hazard modeling, mitigation, and regulation. Although high explosives (HE), flammable gases, and dusts have been studied separately, direct waveform comparisons in identical environments are rare. This study addresses that gap by comparing overpressure waveforms from HE, methane-air mixtures, and coal dust explosions to assess differences in peak pressure, impulse, rise time, and phase duration. Twenty-seven tests were conducted using standardized instrumentation and sensor arrays. Results showed that HE generated the highest peak pressures with short positive phases …