Engineering Commons^™

Computational Investigation Of Polymer Electrolyte Membrane Fuel Cell With Nature-Inspired Fibonacci Spiral Flow Field, Suleyman Kose

Masters Theses

"Polymer electrolyte membrane fuel cells (PEMFC) are promising clean energy devices. The flow field design has crucial role in PEMFC performance for effective distribution of reactants and removal of products. Several nature-inspired flow field designs have recently been proposed in the literature. Common characteristics of these designs were sudden changes in the flow direction through sharp bends and flow field geometries restrained to areas having corners. In this thesis, Fibonacci spiral configuration, which is found in the nature from hurricanes to seashells, was considered for flow field pattern of a PEMFC. Contrary to the bio-inspired designs proposed in previous studies, …

Designed Extrudate For Ceramic Additive Manufacturing, Devin Mcmillen

Masters Theses

"The objective of this thesis work was to design ceramic paste systems that assist in achieving a high theoretical density ( > 95%) after deposition by a novel additive manufacturing process, i.e. Ceramic On-Demand Extrusion (CODE). The work is encompassed in five main sections: Sections 1 and 2 provide an introduction and literature review of relevant topics for the following sections of experimentation. Section 3 provides an analysis of a reaction chemistry to identify three discrete materials that could be combined via CODE and result in zirconium diboride (ZrB₂) post-sintering. Section 4 describes the development of a high solids …

Quantifying On-Orbit Performance Of Cubesat Micropropulsion Systems By Observing Orbital Element Variations, Bradyn William Morton

Masters Theses

"The Advanced Propulsion Experiment mission in development by the Missouri University of Science and Technology's satellite research team (M-SAT) is a technology demonstration mission of a multi-mode propulsion system. The true test of any satellite propulsion system is the on-orbit performance. The purpose of this research is to develop methods for quantifying the on-orbit performance of the multi-mode propulsion system. This performance can be determined by observing the small variations in the orbital element parameters and using a differential corrector with the Gauss Variation of Parameter equations. Furthermore, this research could be used to determine and quantify a propulsion system's …

Research And Development Of Optically Transparent Join With Low Processing Temperatures, Eric Kevin Muskovin

Masters Theses

The purpose of this study was to investigate durable solar cell cover glass joins produced by diffusion bonding with deep eutectic solvents (DES) and to develop a novel process of joining optically transparent materials at low temperatures. A joined PV cell-glass specimen was characterized using Raman, μ-FTIR, SEM-EDS, and thin-film XRD. DESs were created with malonic acid (MAL) and choline chloride (ChCl) of varying composition factors (CF; CF=MAL/ChCl). Joining borosilicate glass coupons was attempted using DESs with CF = 0.65 and 1 at temperatures between 100-150 °C for 20 hours. Joining the glass coupons failed at all temperatures and oxygen …

Customized Multi-Group Cross Section Generation With Njoy For Discrete Ordinates Computed Tomography And Radiography Simulation, Steven Michael Wagstaff

Masters Theses

"The purpose of this work was to explore the creation of photoatomic multi-group cross section libraries to be used with a software package DOCTORS (Discrete Ordinates Computed TOmography and Radiography Simulator). This software solves the linear Boltzmann equation using the discrete ordinates method [1]. To create these libraries, NJOY2016 was used, creating both fine and broad energy multi-group cross section files. The cross section's accuracy was tested against an equivalent Monte Carlo simulation using MCNP6.

Two simulation geometries were used. The first, a cylindrical water phantom with a single source projection placed in front, simulating an X-ray radiography. The second …

Effect Of Microstructural Features On Steel Machinability, Mark C. Emmendorfer

Masters Theses

Non-metallic inclusions can have a tremendous impact on the machinability of steel. Some oxide inclusions such as alumina, spinel, and other refractory abrasive oxide inclusions can have a detrimental effect on machinability. Modification of oxide inclusions by calcium treatment can promote the formation of low melting point oxides such as anorthite and gehlenite inclusions that can assist in chip formation and form a lubricating layer on the rake surface of the machine tool. MnS is known to be beneficial to improving the machinability of steel. They assist in chip formation by being heavily deformed in the primary shear zone. Sulfide …

The Development Of A New Formulation Of Fly Ash Class C Based Geopolymer And Assessing Its Performance In Presence Of Drilling Fluid Contamination, Mohamed Saad Ahdaya

Masters Theses

"Cementing is one of the most critical steps in the drilling and completion of oil wells. Traditionally, Portland cement is used for oil cementing operations; however, geopolymer materials have recently attracted much attention because they are more cost-effective and have less environmental impacts.

An intensive laboratory work was conducted to obtain a new formulation of fly ash class C based geopolymer cement to be used as a potential alternative cementing material to Portland cement in oil and gas cementing. Twenty-four variations of fly ash class C based geopolymers were prepared, and by comparing several of their properties using API standard …

Field Implementation Of Cement-Based Composite Strengthening Technologies, Michael Andrew Janke

Masters Theses

"With infrastructure continuing to age, technologies are being developed to strengthen structures as a more sustainable option than replacement. The use of fiber-reinforced cementitious matrix (FRCM) strengthening systems is a promising new technology for adding flexural and shear capacity to existing reinforced concrete members. While cement based systems with carbon, PBO, and steel have all been implemented in a lab setting, there is not research data available for installation in the field. FRCM composites have advantages over more widely used fiber reinforced polymer (FRP) composites such as heat resistance and compatibility with concrete substrate. FRP systems have previously been field …

An Investigation Into The Effects Of Ion Tracks On Α-Quartz, Bryant Alan Kanies

Masters Theses

"The passage of a swift heavy ion through a material can cause columnar, amorphous nano-structures known as ion tracks. Swift heavy ions are present in a number of applications ranging from nuclear reactors to nuclear waste storage and onboard spacecraft. The study of ion tracks has been ongoing since the late 1950s and has led to several technological advancements. In fact, ion beams have been used to enhance material properties and aid in the production of electrical components. Ion beams, and their resultant ion tracks, can therefore be seen as a method to purposefully alter material properties such as thermal …

Characterization And Tailoring Of Powder Used In Additive Manufacturing And Plasma Spheroidization, Caitlin S. Kriewall

Masters Theses

"There are many processes that use metal powder as the starting material for the production of parts. With the growth of these manufacturing techniques, more critical part applications are being considered. In order to fully understand the process and create consistent parts, powder properties need to be well understood. Selective laser melting (SLM) is a powder bed-based additive manufacturing process. During processing, heat-affected powders are generated and can deposit within the build area. The current work investigated the characterization of heat-affected 304L stainless steel powder using techniques such as scanning electron microscopy, x-ray diffraction and x-ray photoelectron spectroscopy to detect …

Analysis And Mitigation Of Parallel-Plate Noise For High-Isolation Applications, Zachary Joel Legenzoff

Masters Theses

"Achieving highs levels of isolation between different functionalities in a PCB can be challenging. One of the major issues is that vertically adjacent planes or area fills in a PCB can form a parallel-plate waveguide with no cutoff frequency and serve as an efficient coupling mechanism between interconnects. Due to the finite size of the conductors, reflections off the edges of these parallel-plate cavities can result in the formation of standing-wave patterns with very high field strengths, resulting in high coupling at certain frequencies. This noise coupling mechanism can be suppressed by connecting the parallel plates together with an adequate …

Imaging The Subsurface In Eastern Part Of Lake Chesterfield Using A Combination Of Geophysical Tools, Jiawei Li

Masters Theses

"The Lake Chesterfield North Dam in Wildwood city, Missouri has been leaking, more or less continuously since the dam was constructed in 1986 despite mitigation efforts in 1988, 1994, 1995, 2004, and 2005. Neither the grouting efforts in 1988, 1994, 1995, 2004 or 2005, nor the placement and rehabilitation of an impervious clay liner in 2005 has solved the problem. Indeed, in June of 2017, the water level in Lake Chesterfield dropped at an alarmingly rapid rate.

Prior to authorizing additional mitigation work, the Lake Chesterfield Home Owners Association (LCHOA) decided to acquire geophysical data across the dry lake bed. …

Microstructural Development And Its Effect On Aqueous Corrosion Of A Borosilicate Glass Ceramic For Waste Vitrification, Nicholas Stephen Roberts

Masters Theses

"Waste loadings of reprocessed spent nuclear fuel vitrified into borosilicate glass can be increased by precipitating environmentally stable phases concentrated with waste components in a chemically stable glass matrix. The principal objective of this thesis was to characterize the development of crystalline powellite (CaMoO₄ and related phases) and oxyapatite (Ca₂LN₈Si₆O₂₆) in borosilicate glass-ceramics and to determine how the formation of those phases affected its chemical durability.

Borosilicate glasses provided by PNNL were re-melted and quenched at rates from over 300⁰C/s to ~0.05⁰C/s. Isothermal heat treatment experiments were conducted by quenching melts …

Practical Dwell Times For Switched System Stability With Smart Grid Application, William Roy St. Pierre

Masters Theses

"Switched systems are encountered throughout many engineering disciplines, but confirming their stability is a challenging task. Even if each subsystem is asymptotically stable, certain switching sequences may exist that drive the overall system states into unacceptable regions. This thesis contains a process that grants stability under switching to switched systems with multiple operating points. The method linearizes a switched system about its distinct operating points, and employs multiple Lyapunov functions to produce modal dwell times that yield stability. This approach prioritizes practicality and is designed to be useful for large systems with many states and subsystems due to its ease …

3d Dubins Curves For Multi-Vehicle Path Planning, Yiheng Wang

Masters Theses

"This thesis proposes a unified algorithm for target assignment and path planning in 3D space for multiple Autonomous Underwater Vehicles (AUVs) to visit multiple targets. The multi-target assignment and path planning problem is modeled as a multiple Traveling Salesmen Problem (mTSP) and is usually solved by two separate algorithms: the multiple task assignment problem is first solved by the Genetic Algorithm (GA) using Euclidean distances between the targets; then the 3D path planning problem is solved for each assignment by selecting Dubins curves or other continuity curves. In contrast, this paper embeds the 3D Dubins curve selection into the target …

Tvs Transient Behavior Modeling Method, And System-Level Effective Esd Design For Usb3.X Interface, Pengyu Wei

Masters Theses

"This research proposal presents a methodology whereby a protection device can be modeled in SPICE compatible platforms with respect to the transient behaviors during Electrostatic Discharge (ESD) events. This methodology uses an exclusively "black-box" approach to characterize the parameters of the protection device, thereby allowing it to be implemented without intimate knowledge of the DUT. Results of this methodology can be used to predict the transient response (conductivity modulation and snapback delay) of the ESD protection devices, and thereby predicts how much current could flow into the device (typically a digital IO pin) under protection. The transient behavior modeling methodology …

Spatial Resolution Study For Magnetic Near-Field Probe, Xin Yan

Masters Theses

"Spatial resolution is an important factor of near-field probe, which represents the ability to distinguish two close radiation sources. Traditional definition of spatial resolution is the distance between peak point and -6dB point when measuring microstrip line. The definition has disadvantage and limitation. In this topic, spatial resolution for magnetic near-field probe is studied, and three dimensions of spatial resolution are put forward. An optimized measurement setup is presented to reflect spatial resolution of probe properly. Then, an example is given to show how spatial resolution affects field distribution in near-field measurement"--Abstract, page iv.

Distributed Fiber Optic Sensors For Monitoring Spatially Continuous Strain And Quasi-Distributed Refractive Index Using Optical Frequency Domain Reflectometry, Sasi Jothibasu

Masters Theses

"This thesis is comprised of two papers and they describe distributed fiber optic sensing using an optical frequency domain reflectometry (OFDR) instrumentation system.

The first paper presents about distributed fiber optic sensor embedded within the layers of a composite laminates to monitor the continuous profile of strain using the optical frequency domain reflectometry (OFDR) system. The OFDR system was used to analyze the Rayleigh backscattered signal. The shift in the Rayleigh backscattered spectrum (RBS) was observed to be linearly related to the change in strain of the composite material. The continuous strain sensing using OFDR was demonstrated by an INSTRON …

Limit Analysis On Seismic Stability Of Anisotropic And Nonhomogeneous Slopes With Anti-Slide Piles, Wei Bing Gong, Jing Pei Li, Lin Li

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study employs the limit analysis method to evaluate the seismic stability of anisotropic and nonhomogeneous slopes stabilized with anti-slide piles. The pseudo-static approach is used to simplify the earthquake load. The yield seismic acceleration factor is obtained from the optimization procedure and the results are verified with the published data. Then, the seismically unstable slope is reinforced with anti-slide piles, and the seismic stability of the reinforced slope is explored. The results show that the anisotropy and Non homogeneity of soils have significant effects on the stabilizing force required from the anti-slide piles and the optimal location of the …

A Simple Model For Elastic-Plastic Contact Of Granular Geomaterials, Jian Wang, Qimin Li, Changwei Yang, Yidan Huang, Caizhi Zhou

Materials Science and Engineering Faculty Research & Creative Works

We propose a simple elastic-plastic contact model by considering the interaction of two spheres in the normal direction, for use in discrete element method (DEM) simulations of geomaterials. This model has been developed by using the finite element method (FEM) and nonlinear fitting methods, in the form of power-law relation of the dimensionless normal force and displacement. Only four parameters are needed for each loading-unloading contact process between two spheres, which are relevant to material properties evaluated by FEM simulations. Within the given range of material properties, those four parameters can be quickly accessed by interpolating the data appended or …

Femtosecond Laser-Matter Interactions In Ternary Zinc Phosphate Glasses, J. Hernandez-Rueda, N. W. Troy, P. Freudenberger, Richard K. Brow, D. M. Krol

Materials Science and Engineering Faculty Research & Creative Works

We investigate the interaction of ultrashort laser pulses with ternary zinc phosphate glasses. We explore the viability of ten different glass compositions with different levels of alumina to inscribe optical waveguides via the fs-laser direct writing technique, finding that only samples with [O]/[P] ratios of 3.25 are suitable candidates. We also test a zinc magnesium phosphate glass to fabricate waveguide Bragg gratings in order to generate filters and mirrors with specific spectral properties. Confocal Raman spectroscopy inspection shows that laser-damaged material exhibits a relative intensity decrease and a subtle blue-shift on the 1209 cm-1 Raman peak, which implies a relative …

Effect Of Thickness On The Structure And Corrosion Performance Of Sputtered Ce-Al-O Coatings On Al 2024-T3 Alloy Substrates, Yuanyuan Liu, Jiamu Huang, Lilu Qin, James B. Claypool, Matthew J. O'Keefe, Yiming Jiang

Materials Science and Engineering Faculty Research & Creative Works

Ce-Al-O coatings with thicknesses between ca. 136 nm and 1094 nm were deposited on Al 2024-T3 alloy substrates using magnetron co-sputtering of independent Al and CeO2 targets. The Ce-Al-O coatings with thicknesses from ca. 136 nm to 490 nm were compact, dense, and did not have distinct X-ray diffraction peaks. The ca. 1094 nm thick Ce-Al-O coating exhibited a columnar-textured outer layer ∼700 nm thick and a dense, ∼390 nm thick inner layer. X-ray photoelectron spectroscopy analysis revealed that the Ce-Al-O coatings contained Ce (III) species, and that the Al/Ce atomic ratio decreased with increasing coating thickness. Electrochemical corrosion data …

Set-Theoretic Model Reference Adaptive Control Of A Generic Transport Model, Ehsan Arabi, Tansel Yucelen, Nhan T. Nguyen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper illustrates an application of a recently developed set-theoretic model reference adaptive control architecture on a generic transport model developed by NASA. The set- theoretic model reference adaptive control allows the system error bound between the state of an uncertain dynamical system and the state of a given reference model to be less than a-priori, user-defined worst-case performance bound. Thus, it has the capability to enforce strict performance guarantees to the adaptively controlled uncertain dynamical systems. specifically, after designing set-theoretic adaptive controllers for both longitudinal and lateral-directional dynamics here, the efficacy of this architecture is illustrated on the NASA …

Linear Burn Rate Of Monopropellant For Multi-Mode Micropropulsion, Alex J. Mundahl, Steven P. Berg, Joshua L. Rovey

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Multi-mode micro propulsion is a technology that can enable rapidly composable small satellites with unprecedented mission flexibility. To maximize mission flexibility a multi-mode micro propulsion monopropellant must be shared between the chemical and electric propulsion modes. Previous research has identified a promising monopropellant that is both readily catalytically exothermically decomposed (chemical mode) and electro sprayable (electric mode). In this work the linear burn rate of this monopropellant is determined and used to aid the design of a microtube catalytic chemical thruster. Experiments with a pressurized fixed volume reactor are used to determine the linear burn rate. Benchmark experiments use a …

Electrospray Mass Spectroscopy Of A Han-Based Monopropellant, Mitchell J. Wainwright, Joshua L. Rovey, Shawn W. Miller, Benjamin D. Prince, Steven P. Berg

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A mixture of [Emim][EtSO4]-HAN is a potential propellant suitable in a multi-mode chemical-electric microtube-electrospray micro propulsion system. This paper reports experimental mass spectrum results for this liquid when electro sprayed in a 50 μm capillary emitter. Mass spectra from 0-600 amu were obtained over a variety of angles and flow rates from 2 pL/sec to 3 nL/sec in both cation and anion extraction mode. Effects of flow rate and angular orientation on the spectra agree well with literature. Results show at least three of the four monomer species are emitted, along with numerous other species, some of which have been …

Application-Adaptable Chipless Rfid Tag, Katelyn Brinker, Reza Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

Chipless RFID has gained prominence due to its application versatility and cost and complexity advantages over traditional RFID. However, chipless RFID tags are typically designed for a specific application instead of being deployable for a multitude of applications. In this paper, a new approach to adaptable chipless RFID tag is proposed that can be optimized for a variety of applications, including materials characterization with tags as embedded sensors. Additionally, the designed approach renders tags that can be interrogated with a linearly polarized probe and achieves bit densities up to 27.57 bits/cm 2,

Synchrotron Radiation X-Ray Absorption Spectroscopy And Spectroscopic Ellipsometry Studies Of Insb Thin Films On Gaas Grown By Metalorganic Chemical Vapor Deposition, Yingda Qian, Yuanlan Liang, Xuguang Luo, Kaiyan He, Wenhong Sun, Hao Hsiung Lin, Devki N. Talwar, Ting Shan Chan, Ian Ferguson, Lingyu Wan, Qingyi Yang, Zhe Chuan Feng

Electrical and Computer Engineering Faculty Research & Creative Works

A series of ultrathin InSb films grown on GaAs by low-pressure metalorganic chemical vapor deposition with different V/III ratios were investigated thoroughly using spectroscopic ellipsometry (SE), X-ray diffraction, and synchrotron radiation X-ray absorption spectroscopy. The results predicted that InSb films on GaAs grown under too high or too low V/III ratios are with poor quality, while those grown with proper V/III ratios of 4.20-4.78 possess the high crystalline quality. The temperature-dependent SE (20-300°C) and simulation showed smooth variations of SE spectra, optical constants (n, k, e1, and ϵ2), and critical energy points (E1, E1+Δ1, E′0, E2, and E′1) for InSb …

A Two-Dimensional Simulation Of Grain Structure Growth Within Substrate And Fusion Zone During Direct Metal Deposition, Jingwei Zhang, Lei Yan, Wei Li, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In this chapter, a predictive multiscale model based on a cellular automaton (CA)-finite element (FE) method has been developed to simulate thermal history and microstructure evolution during metal solidification for direct metal deposition (DMD) process. The macroscopic FE calculation that is validated by the thermocouple experiment is developed to simulate the transient temperature field and cooling rate of single layer and multiple layers. In order to integrate the different scales, a CA-FE coupled model is developed to combine with thermal history and simulate grain growth. In the mesoscopic CA model, heterogeneous nucleation sites, grain growth orientation and rate, epitaxial growth, …

The Effect Of Overloading On Reliability Of Wheel Loader Structural Components, Eric Raymond Achelpohl

Doctoral Dissertations

"This research attempts to provide a fundamental understanding into the relationship between the productivity of material handling equipment, specifically wheel loaders, and their ability to operate reliably when subjected to high overload conditions. The overall aim is to determine the effect of overloading the bucket on wheel loader reliability. The specific objectives of the research are to: 1) evaluate the effect of overloading the bucket on wheel loader productivity; 2) examine the effect of overloading the bucket on hydraulic pressures in the hoist cylinders (used as a proxy for forces on a wheel loader); and 3) investigate the effect of …

Torsional Behavior Of Rc Beams Strengthened With Pbo-Frcm Composite, Meyyada Y. Alabdulhady

Doctoral Dissertations

"Externally bonded fiber reinforced cementitious matrix (FRCM) composites have been investigated recently as an alternative to fiber reinforced polymer (FRP) composites to overcome certain shortcomings such as the inability to install on wet surfaces or in low temperatures, low fire resistance, low glass transition temperature, low reversibility, and lack of vapor permeability. This study includes an inclusive investigation of the torsional behavior of RC beams strengthened with externally bonded polyparaphenylene benzo-bisoxazole (PBO)-FRCM composite material. A comprehensive review and discussion of the previous experimental, analytical, and numerically-simulated torsional behavior of RC beams strengthened with FRP composite was introduced to gain a …