Engineering Commons^™

Developing A Model System Of Liquid Lubricants For Space Applications: Multiple Alkylated Cyclopentane In Alumina Enclosed Surface, Vidit Singh

Masters Theses

"Lubricants are substances used for reducing friction wear tear and energy losses between two moving bodies. For space applications, normal lubricants cannot be used as they cannot survive the harsh and demanding conditions of space. Multiple Alkylated Cyclopentanes (MACs) have been utilized as space lubricants in recent times with tremendous results. NASA uses the MACs for their missions in space, in particular 1,3,4- tri-(2-octyldodecyl) cyclopentane sold by Nye Lubricants under the name of Pennzane^TM.

In this research, an effort has been made to identify appropriate potential models for simulating Pennzane molecules and to develop MD simulation codes to …

Experimental Characterization Of Common-Mode Sources For Prediction Of System Level Common-Mode Current On Cable Harnesses, Sameer Sudha Arun Walunj

Masters Theses

"Common-mode current on cable harnesses is often the primary source of radiated emissions below several hundred megahertz. It is difficult, however, to estimate common-mode currents that will occur in a system from component level tests because the common-mode impedances are different in the system. Research presents two methods for using simple component level tests to estimate equivalent common-mode source voltages and source impedances responsible for generating common-mode current. Key to these methods is assuming the harness can be represented with two transmission lines, one terminated with a short and one with an open. Equivalent sources are predicted for those circuits …

Multiphysics Prediction Model Of Microwave Curing For Thick Polymer Composites, Siva Dasari

Masters Theses

"Microwave curing technologies have many advantages over the traditional thermal curing methods for the manufacturing of fiber reinforced polymers, especially the processing speed and energy efficiency. Energy can be instantaneously transferred through applied electromagnetic fields and heat is generated based on dipolar rotational interactions. Microwave curing processes have been used for glass fiber composites but there are significant challenges associated with microwave curing of carbon fiber composites. Efficient heating may be difficult due to high dielectric loss associated with carbon fibers. Laminate quality will be highly dependent on the uniformity of the electromagnetic field in the material. In this work, …

Abrasion Resistant Concrete Mix Design For Cold Climates, Diane Mariah Murph

Masters Theses

“Studded tire usage in Alaska contributes to rutting damage on pavements resulting in high maintenance costs and safety issues. In this study, binary, ternary, and quaternary highly-abrasion resistant concrete mix designs using supplementary cementitious materials (SCMs) were developed. The properties of fresh concrete and mechanical, and durability properties of hardened concrete for these mix designs were then tested to determine an optimum highly-abrasion resistant concrete mixture which could be placed in cold climates to reduce rutting damage. SCMs used included silica fume, ground granulated blast furnace slag, and type F fly ash. Tests including workability, air content, drying shrinkage, compressive …

Methane Dry Reforming Reaction On Cr, V, In, And Ga Supported Sapo-34 Zeolite, Ehigiator Festus Ojo

Masters Theses

”The CO₂ reforming of methane is a significant research area in mitigating and transforming two greenhouse gases for the production of syngas. The reaction has been investigated for four different promoted catalysts to determine their reactant's conversion, product’s selectivity, and their respective syngas ratios.

The catalytic test was investigated under atmospheric conditions at 600⁰C for 6.5h with a WHSV of 4800 ml g^-1 h^-1. The conversion and selectivity of catalysts 9Al 1V-inc SAPO-34, 9Al 1Cr-inc SAPO-34, 9Al 1Ga-inc SAPO-34, and 9Al 1In-inc SAPO-34 were analyzed. The CH₄ conversion for the different catalysts are, 9Al 1Cr-inc …

Unmanned Aerial And Traversing Vehicle -- A Mobile Platform For Bridge Inspections, Clayton A. Fritsche

Masters Theses

“Unmanned aerial vehicles (UAVs), also known as drones, have been rapidly growing in popularity since their creation. This study aimed to create a robotic platform used to assist in the inspection process of the nation’s aging and deteriorating bridges. To this end, a multimodal inspection robot that utilized both flying and driving technologies, was designed, analyzed, and tested for aerial, traversing, and their transitional operability. The design, herein referred to as the “BridgeBot”, was evaluated both computationally and experimentally. A finite element model of the BridgeBot was established and analyzed under static loading scenarios to help determine stress distributions and …

Development Of Castrip Dual Phase Steel, Brenton Allen Hrebec

Masters Theses

“Thermomechanical processing necessary to produce DP 980 steel using CASTRIP hot band was investigated. The resultant steel has an ultimate tensile strength of 1038 MPa, yield strength of 744 MPa, and total elongation of 8.6%. These mechanical properties were achieved by batch annealing the hot band at 649°C for 48 hours and cold rolling to a 20% reduction. The steel was continuously annealed to simulate a galvanization cycle with an intercritical temperature of 810°C. The possibility of improving the texture of the steel by warm rolling under dynamic strain aging conditions was investigated. Dynamic strain aging in the CASTRIP hot …

Performance Of One-Part And Two-Part Class C Fly Ash-Based Alkali Activated Mortars, Cedric Chani Kashosi

Masters Theses

“Seeking an eco-friendly concrete, researchers have conducted studies to fully replace ordinary Portland cement (OPC) with fly ash (FA) producing alkali-activated concrete (AAC). Results showed better performance of AAC in terms of high early compressive strength, and durability compared to conventional concrete. However, much is still unknown about the behavior of AAC. From the type of materials used, the curing procedure, and long-term strength development of these binders; a thorough investigation is needed in order to fill the existing gap from previous studies and thus make a step forward to the safely use of AAC in the construction industry. The …

Feasibility Study For Sustainable Controlled Low-Strength Material (Clsm) Incorporating Off-Specification Fly Ash And Bottom Ash, Alexis K. Vandomelen

Masters Theses

“Controlled low-strength material (CLSM) is a self-consolidating cementitious material used in applications requiring high flowability and low strength. The primary components of this material, being cement and sand, however, negatively impact the environment. Cement is a large contributor to CO2 emissions, and the vast depletion of sand causes physical and political issues. Furthermore, over 100 million short tons of coal combustion products (CCP), including fly ash and bottom ash, are created annually in the United States, while nearly half of all CCP remain unused. No off-specification fly ash has been implemented in CLSM. This study uses coal ashes sourced from …

Laser Machining Countersinks In Carbon Fiber Reinforced Polymer, Leon James Neely Hill

Masters Theses

“Laser machining countersinks with a frequency doubled Q-switched diode pumped Nd:YAG laser is demonstrated. Tests were conducted in 0.100" thick IM7 prepreg CFRP with [0,90]3S orientation. The HAZ is minimized to avoid stress concentrations in the epoxy matrix. A chamber and filtration system was designed and built to contain the byproducts produced in the machining process. The variables investigated are the number of repetitions in the offset path, the plunge rate, and the line energy. The research was performed over one baseline study, one parameter space exercise, two full factorial experiments, and one repeatability study. Assessment was done under an …

Inclusion Engineering In Femnal Steels, Rairu Vaz Penna

Masters Theses

"Low density high Mn and Al steels, or FeMnAl steels, show great promise for military vehicles and automotive applications in which high strength and toughness is a requirement. However, these steels are subject to processing challenges including development of oxide and nitride inclusions during melting and casting as well as a large as-cast grain size and heavy interdendritic segregation. This can lead to non-uniform heat treatment response and cracking during subsequent hot rolling. Adding up to 10%Al lowers the density of these steels by as much as 15%, unfortunately, this also results in large amounts of hard and faceted AlN …

Near-Field Electrospinning Of A Polymer/Bioactive Glass Composite To Fabricate 3d Biomimetic Structures, Krishna C. R. Kolan, Jie Li, Sonya Roberts, Julie A. Semon, Jonghyun Park, D. E. Day, Ming-Chuan Leu

Biological Sciences Faculty Research & Creative Works

Bioactive glasses have recently gained attention in tissue engineering and three-dimensional (3D) bioprinting because of their ability to enhance angiogenesis. Some challenges for developing biological tissues with bioactive glasses include incorporation of glass particles and achieving a 3D architecture mimicking natural tissues. In this study, we investigate the fabrication of scaffolds with a polymer/bioactive glass composite using near-field electrospinning (NFES). An overall controlled 3D scaffold with pores, containing random fibers, is created and aimed to provide superior cell proliferation. Highly angiogenic borate bioactive glass (13-93B3) in 20 wt.% is added to polycaprolactone (PCL) to fabricate scaffolds using the NFES technique. …

Modeling Cell Line-Specific Recruitment Of Signaling Proteins To The Insulin-Like Growth Factor 1 Receptor, Keesha E. Erickson, Dipak Barua, For Full List Of Authors, See Publisher's Website.

Chemical and Biochemical Engineering Faculty Research & Creative Works

Receptor tyrosine kinases (RTKs) typically contain multiple autophosphorylation sites in their cytoplasmic domains. Once activated, these autophosphorylation sites can recruit downstream signaling proteins containing Src homology 2 (SH2) and phosphotyrosine-binding (PTB) domains, which recognize phosphotyrosine-containing short linear motifs (SLiMs). These domains and SLiMs have polyspecific or promiscuous binding activities. Thus, multiple signaling proteins may compete for binding to a common SLiM and vice versa. To investigate the effects of competition on RTK signaling, we used a rule-based modeling approach to develop and analyze models for ligand-induced recruitment of SH2/PTB domain-containing proteins to autophosphorylation sites in the insulin-like growth factor 1 …

Effects Of Mixing Methods Of Bifunctional Catalysts On Catalyst Stability Of Dme Synthesis Via Co₂ Hydrogenation, Shoujie Ren, Shiguang Li, Naomi Klinghoffer, Miao Yu, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The effects of three different mixing methods of CuO/ZnO/Al₂O₃ (CZA) and HZSM-5 bifunctional catalyst on the stability for dimethyl ether (DME) synthesis from carbon dioxide (CO₂) hydrogenation were investigated. When the bifunctional catalyst was prepared by method A (mixing powder without pelletization), there was no significant change in DME production and catalyst stability when the HZSM-5 loading was varied between 0.1 g and 0.5 g with a fixed CZA loading of 0.5 g,. When the bifunctional catalysts were prepared by method B (pressed into pellets of CZA and pellets of HZSM-5 and then mixed) and …

In Situ Mechanical Characterization Of The Mixed- Mode Fracture Strength Of The Cu/Si Interface For Tsv Structures, Chenglin Wu, Congjie Wei, Yanxiao Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In situ nanoindentation experiments have been widely adopted to characterize material behaviors of microelectronic devices. This work introduces the latest developments of nanoindentation experiments in the characterization of nonlinear material properties of 3D integrated microelectronic devices using the through-silicon via (TSV) technique. The elastic, plastic, and interfacial fracture behavior of the copper via and matrix via interface were characterized using small-scale specimens prepared with a focused ion beam (FIB) and nanoindentation experiments. A brittle interfacial fracture was found at the Cu/Si interface under mixed-mode loading with a phase angle ranging from 16.7° to 83.7°. The mixed-mode fracture strengths were extracted …

Smart Building And Construction Materials, Donglu Shi, Julian Wang, Wen Deng

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Advances and innovations in materials science and engineering have always played a substantial role in civil engineering, building structural design, and construction. In recent years, extensive effort has been devoted to the applications of stimuli-responsive smart materials and nanostructures in buildings. These smart materials used in the built environment can be defined as those offering specific functional and adaptable properties in response to thermal, optical, structural, and environmental stimuli. Not only do these materials enhance the overall performance of new building construction but also promise safer structures, longer durability of building elements, efficient building energy savings, greater environmental sustainability, and …

Melt Property Variation In Gese2-As2se3-Pbse Glass Ceramics For Infrared Gradient Refractive Index (Grin) Applications, Anupama Yadav, Andrew Buff, Myungkoo Kang, Laura Sisken, Charmayne Smith (Lonergan), Jason Lonergan, Cesar Blanco, Michael Antia, Megan Driggers, Andrew Kirk, Clara Rivero-Baleine, Theresa Mayer, Andrew Swisher, Alexej Pogrebnyakov, A. R. Hilton, Greg Whaley

Materials Science and Engineering Faculty Research & Creative Works

Melt size-dependent physical property variation is examined in a multicomponent GeSe₂-As₂Se₃-PbSe chalcogenide glass developed for gradient refractive index applications. The impact of melting conditions on small (40 g) prototype laboratory-scale melts extended to commercially relevant melt sizes (1.325 kg) have been studied and the role of thermal history variation on physical and optical property evolution in parent glass, the glass' crystallization behavior and post heat-treated glass ceramics, is quantified. As-melted glass morphology, optical homogeneity and heat treatment-induced microstructure following a fixed, two-step nucleation and growth protocol exhibit marked variation with melt size. These attributes …

Column Flotation Performance Prediction: Pca, Ann And Image Analysis-Based Approaches, Fardis Nakhaei, Mehdi Irannajad, Sima Mohammadnejad

Mining Engineering Faculty Research & Creative Works

The flotation froth surface appearance includes remarkable information, which can be employed as a helpful index for the qualitative evaluation of the process efficiency. Image analysis is a practical technology for the sake of achieving process related information that can be employed in expert controllers in order to amend flotation performance. In this paper, the intelligent modelling of relationship between froth characteristics and the metallurgical performance in a pilot column flotation of iron ore was established. Column flotation tests were carried out at a wide range of operating conditions and the froth features along with the metallurgical performances were specified …

Impulse Measurements Of Electric Solid Propellant In An Electrothermal Ablation-Fed Pulsed Plasma Thruster, Matthew S. Glascock, Joshua L. Rovey, Kurt A. Polzin

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in the ablative pulsed plasma thruster. In this paper, the performance of an electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated using an inverted pendulum micro-Newton thrust stand. The impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration test runs of 100 pulses and longer-duration runs to end-of-life, at energy levels of 5, …

Thermodynamic And Transport Properties Of Hydroxylammonium Nitrate-Based Electric Solid Propellant Vapor, Matthew S. Glascock, Patrick D. Drew, Joshua L. Rovey

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Electric solid propellants are advanced solid chemical rocket propellants controlled by electric current. Electric solid propellants may also be used in an electric propulsion system, specifically, an ablative pulsed plasma thruster. Previous experiments with the electric solid propellant HIPEP suggest its ablation processes are similar to traditional propellant polytetrafluoroethylene (C2F4). Better understanding of the ablation and resulting propulsion performance of HIPEP requires a model of its vapor composition and transport properties. This paper reports on the development of such a model. The model was validated by comparing results for C2F4 with literature, which showed agreement with multiple models described. Transport …

Influence Of A Backward-Facing Step On Swept-Wing Boundary-Layer Transition, Jenna L. Eppink, Richard W. Wlezien, Rudolph A. King, Meelan Choudhari

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Experimental measurements were performed on a swept flat-plate model with an airfoil leading edge and imposed chordwise pressure gradient to determine the effects of a backward-facing step on transition in a low-speed stationary crossflow-dominated boundary layer. Detailed hot-wire measurements were performed for three step heights ranging from 36 to 49% of the boundary-layer thickness at the step and corresponding to subcritical, nearly critical, and critical cases. In general, the step had a small, localized effect on the growth of the stationary crossflow vortex, whereas the unsteady disturbance amplitudes increased with increasing step height. Intermittent spikes in instantaneous velocity began to …

Corrigendum To ‘Zinc Oxide As An Active N-Layer And Antireflection Coating For Silicon Based Heterojunction Solar Cell’ [Sol. Energy Mater. Sol. Cells 139 (2015) 95–100](S0927024815001324)(10.1016/J.Solmat.2015.03.017), Babar Hussain, Abasifreke Ebong, Ian Ferguson

Electrical and Computer Engineering Faculty Research & Creative Works

The authors regret that permanent email address of the corresponding author is "[email protected]". The authors would like to apologize for any inconvenience caused.

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …

Transient Multiphase Flow Simulation For Unloading Of Frac Hit Gas Wells, Miguel Angel Cedeno Moreno

Doctoral Dissertations

"This work seeks to develop a fully step-by-step transient multiphase flow simulation valid for unloading gas wells using nitrogen. It studies the behavior of nitrogen for unloading horizontal gas wells with gas injection in the annulus. The work investigates unloading non-Newtonian fluids such as those which invade offset wells when a frac hit occurs during hydraulic fracturing operations in unconventional wells. The effect of varying tubing depth and injection pressure are included in the study.

Results show that as the plastic viscosity increases, the nitrogen volume and time to unload will be increased. As tubing depth increases, the nitrogen volume …

The Effects Of Low Aspect Ratio And Heat Exchanging Internals On The Bubble Properties And Flow Regime In A Pilot-Plant Bubble/Slurry Bubble Column For Fischer-Tropsch Synthesis, Hayder Al-Naseri

Doctoral Dissertations

"Fischer-Tropsch synthesis (F-T) is a process utilized to convert the syngas mixture of CO and H₂ to synthetic fuel and chemicals that executed commercially by using the bubble/slurry bubble column reactor. The experimental results reveal that the investigated parameters, in terms the presence of internals, and reducing the aspect ratio and the solids loading, increase the local gas holdup, interfacial area, bubble passage frequency, and decrease the bubble rise velocity, bubble chord length. Meanwhile, the aspect ratio H/D = 4, and 5 provide enough height to established the fully developed flow regime. As a result of the variation in …

Ferrite Characterization Techniques & Particle Simulations For Semiconductor Devices, Nicholas Erickson

Doctoral Dissertations

"This dissertation is divided into three papers, covering two major topics. The first topic, techniques for ferrite characterization, is discussed over the course of two papers. The second topic, particle simulations for semiconductor devices, is discussed in the last paper. In the first paper, the method for extracting permeability from ferrite materials is discussed for the Keysight 16454A permeability extraction fixture, where the ferrite material to be characterized is assumed to be homogeneous. Then the method is updated to account for layered materials. The updated method is verified through full-wave simulations. In the second paper, a planar printed circuit board …

Hardware Architectures For Compact Microwave And Millimeter Wave Cameras, Matthew Jared Horst

Doctoral Dissertations

"Millimeter wave SAR imaging has shown promise as an inspection tool for human skin for characterizing burns and skin cancers. However, the current state-of-the-art in microwave camera technology is not yet suited for developing a millimeter wave camera for human skin inspection. Consequently, the objective of this dissertation has been to build the necessary foundation of research to achieve such a millimeter wave camera. First, frequency uncertainty in signals generated by a practical microwave source, which is prone to drift in output frequency, was studied to determine its effect on SAR-generated images. A direct relationship was found between the level …

Assessment And Prediction Of Surface Water Vulnerability From Non-Point Source Pollution In Midwestern Watersheds, Fadhil K. Jabbar

Doctoral Dissertations

"Non-point source pollution is the leading cause of impairment in surface water in the Midwest. In this research, we seek to predict which watersheds are most vulnerable to point source pollution without field sampling using publically available GIS databases. Watersheds with higher vulnerability ratings can then be targeted for water quality monitoring, and funds used to improve watershed health can be distributed with greater efficacy. To better understand and target watershed vulnerability, we used three different approaches. In the first project, 35 sub-watersheds were sampled in the Lower Grand Watershed, which is a highly agricultural watershed in northern Missouri/southern Iowa. …

Laser Welding Of Metallic Glass To Crystalline Metal In Laser-Foil-Printing Additive Manufacturing, Yingqi Li

Doctoral Dissertations

"The application of metallic glasses has been traditionally limited to parts with small dimensions and simple geometries, due to the requirement of fast cooling during the conventional process of casting. In addition, joining metallic glass to crystalline metal is of interest for many applications that require locally tailored functions and properties, but it is challenging. This research describes a promising additive manufacturing technology, i.e., laser-foil-printing, to make high-quality metallic glass parts with large dimensions and complex geometries and to fabricate multi-material components from metallic glass and crystalline metal. In this research, Zr_52.5Ti₅Al₁₀Ni_14.6Cu …

Freeform Extrusion Fabrication Of Advanced Ceramics And Ceramic-Based Composites, Wenbin Li

Doctoral Dissertations

"Ceramic On-Demand Extrusion (CODE) is a recently developed freeform extrusion fabrication process for producing dense ceramic components from single and multiple constituents. In this process, aqueous paste of ceramic particles with a very low binder content ( < 1 vol%) is extruded through a moving nozzle to print each layer sequentially. Once one layer is printed, it is surrounded by oil to prevent undesirable water evaporation from the perimeters of the part. The oil level is regulated just below the topmost layer of the part being fabricated. Infrared radiation is then applied to uniformly and partially dry the top layer so that the yield stress of the paste increases to avoid part deformation. By repeating the above steps, the part is printed in a layer-wise fashion, followed by post-processing. Paste extrusion precision of different extrusion mechanisms was compared and analyzed, with an auger extruder determined to be the most suitable paste extruder for the CODE system. A novel fabrication system was developed based on a motion gantry, auger extruders, and peripheral devices. Sample specimens were then produced from 3 mol% yttria stabilized zirconia using this fabrication system, and their properties, including density, flexural strength, Young's modulus, Weibull modulus, fracture toughness, and hardness were measured. The results indicated that superior mechanical properties were achieved by the CODE process among all the additive manufacturing processes. Further development was made on the CODE process to fabricate ceramic components that have external/internal features such as overhangs by using fugitive support material. Finally, ceramic composites with functionally graded materials (FGMs) were fabricated by the CODE process using a dynamic mixing device"--Abstract, page iv.