Engineering Commons^™

The Reaction Of Urea With Primary Alkyl Bromides, Ronald Lewis Stabile

Theses

The reactions between urea and the primary alkyl bromides from 1-bromobutane to 1-bromooctane were investigated. The effect of concentration, temperature, and solvents on the yield was determined. Second order reaction rate constants at temperature of 80°, 100°, and 132°C were calculated from the data for yield. The yield is defined as the percent of bromine from the alkyl bromide titrated as bromide ion.

The results indicate that the reactions of the primary alkyl bromides with urea are similar; the reaction being of the second order and the ex. tent of reaction being approximately the same for each alkyl bromide for …

Amination Of Alkyl Halides, Frank Joseph Stulb

Theses

The possibility of aminating alkyl halides with urea was the prime interest of the research undertaken in this thesis. Alkyl halides and urea react only to a slight degree. However the reaction is rapid when dimethylformamide is used as a solvent.

In working with compounds containing halogen on the aromatic ring we always found the halogen to be replaced by the amino group. With alkyl halides, however, this was not so. In the case of the reaction between an alkyl halide and urea in a solvent, a compound of composition close to that of a di-alkylurea was isolated and the …

A Method Of Process Identification Of Certain Linear Control Systems, Eugene A. Aronson

Electrical and Computer Engineering ETDs

No abstract provided.

A Study Of Electro-Magnetic Wave Propagation In Inhomogeneous Media, Thomas N. C. Wang

Electrical and Computer Engineering ETDs

The central problem of this work will be the development of several approximation methods and the application thereof to the solution of second order linear differential equations which arise in connection with the propagation of electromagnetic radiation in inhomogeneous media. Chapter I is an introduction to the problem. Maxwell’s equations are written down and it is assumed that both σ, the conductivity, and ɛ, the permittivity, are scalar functions or position. Often the above function characterizing some or the properties of matter vary in physical situations. For example, in waveguides, there may be inserted layers of dielectric material along the …

The Multi-Terminal Hall Generator, Sang S. Pak

Electrical and Computer Engineering ETDs

This thesis describes a study undertaken to maximize the Hall generator efficiency. A mathematical solution is obtained for a multi-terminal Hall generator, and an analytical technique is developed for determining the optimum values of parameters to maximize the generator efficiency. An equivalent circuit is developed for an N output-terminal Hall generator, and the efficiency expression is obtained as a function of sample dimension, conductivity and Hall coefficient of the material, and magnetic field strength. Some of the results have been checked experimentally with indium antimonide and fields up to 21.5 kilogauss. An efficiency of 40% was obtained experimentally for a …

Kentucky Rock Asphalt, Traffic-Bound Bases, George R. Laughlin

Kentucky Transportation Center Research Report

Kentucky rock asphalt (a medium-grained quartz sandstone impregnated with natural bitumen) occurs as major deposits in Edmonson, Grayson, Hardin, Breckinridge, Logan and Warren Counties. Physiographically these deposits occur along the southeastern margin of the Western Coal Field. Geologically the Caseyville formation (particularly the Bee Spring member) of the Pottsville series of the Pennsylvania strata and the Hardinsburg and Cypress sandstones of the Middle Chester series of the Mississippian strata are of interest. The areal geology of Kentucky is shown in Figure 1 and the locations of rock asphalt deposits are depicted in Figure 2.

The Control And Use Of Drag-Free Satellites, Benjamin Lange

Robert "Bob" Twiggs STEM Education Collection

A research thesis by Ben Lange for the Department of Aeronautics and Astronautics at Stanford University titled "The Control and Use of Drag-Free Satellites" from June of 1964.

The Irish Plumbing And Heating Engineer, June 1964 (Complete Issue)

Building Services Engineering

No abstract provided.

Salt Effects In Liquid-Liquid Equilibria, Edwin Otto Eisen

Dissertations

The effect of lithium chloride, sodium chloride and potassium chloride on the distribution of acetic acid, propionic acid and butyric acid between benzene and water at 25° C has been studied. The method of Hand, which has previously been used to correlate tie line data in salt-free ternary systems, has now been successfully employed to correlate distribution data for quaternary systems containing salt.

The slope and intercept of the Hand equations have been expressed as linear functions of the salt concentration in each system studied. Equations for slope and intercept possessing high statistical significance have been formulated using a linear …

Polypropylene Fibers, Anthony Vincent Galanti

Theses

One of the latest members of the rapidly growing therrnoplastic polymer family which appears capable of successfully competing with the currently saturated textile and chemical markets is polypropylene fiber. The objectives of this Thesis were to: (1) examine the effects of polymer characteristics and fiber processing conditions on the properties of polypropylene fibers, and (2) correlate all existing information on the physical, chemical, and mechanical properties of polypropylene fibers and comparatively evaluate this material with other fibers, natural and synthetic.

Polypropylene is the first member of a new group of polymers prepared by a mechanism defined as "stereospecific" polymerization. From …

Thermal Conductivity Of Solid Materials, Irwin N. Huppert

Theses

A literature search on the methods of determining the thermal conductivity of solids has been made.

A compilation of the various methods of determining the thermal conductivity of solids presented in the literature is given in the report. In general, the literature is lacking in correlations of thermal conductivity with other properties of solid materials. A review of the correlations found is presented. A summary of data presented in the literature is presented in the text.

A method of determining the thermal conductivity of solid materials without measuring the heat flow through the test specimen is presented. The use of …

Mass Transfer Into Cylindrical Liquid Films Measurement Of Liquid Diffusivities, Ronald Francis Lovenguth

Theses

This thesis was undertaken to augment and validate the previous work of Ratcliff and Reid⁽⁷⁾ in the area of diffusion of immiscible liquids. Their novel approach to this particular problem of liquid diffusion led the author to consider an experimental technique that has been used in gas-liquid studies. A short vetted-wall column was used to determine the rate of mass transfer of benzene and toluene into thin cylindrical films of water. A general analytical solution for the rate of mass transfer has been derived and is given below. This solution was checked using the system benzene-water.

G=3.63(Π(ρ_ω-ρ …

The Virial Equation Of State Based On Critical Constants, Ghanshyam R. Patel

Theses

Results obtained from the Epstein equation of state¹⁵ i.e. equation (8), which is theoretically valid up to the critical density, are compared with the experimental values of the compressibility factor. The calculated values of compressibility factor or ethylene, ethane, propane, and n-butane were obtained using two methods of evaluation for the second and third virial coefficients. In addition, using these two methods and excluding fourth, fifth, and sixth virials in the Epstein equation of state, compressibility factors were calculated for all the four compounds to test the effect of higher virial terms. In the proposed method-(A) and method-(C), the …

Esterification Of Oleic Acid With Oleyl Alcohol, Robert Persurance

Theses

The esterification of oleic acid with oleyl alcohol was studied. A literature search showed that the chemical kinetics for this reaction had not been studied previously.

In the temperature range of 150 to 200°C. and up to a conversion of about 85 per cent, the esterification was found to be a second order reaction when the water of reaction was removed from the system by simple distillation.

Para-toluenesulfonic acid is an effective catalyst for this system, and the observed specific rate constant is a linear function of the catalyst concentration.

The effect of temperature on the specific rate constant for …

An Experimental Investigation Of The Effect Of A Constant Body Force Field Upon The Drag Coefficient Of A Sphere, Brent Evans Boyack

Theses and Dissertations

The object of this thesis was to present the method and results of an experimental determination and correlation of the drag coefficients of accelerating spheres.

A Kerr Cell System For Measuring The Amplitude Of High-Voltage Nonrecurring Pulses, Donald C. Wunsch

Electrical and Computer Engineering ETDs

There are at present several conventional techniques and systems to measure the peak amplitude of high-voltage pulses. Three of the prin­cipal techniques are:

1. Potential dividers in conjunction with some type of low-voltage recording system.

2. High-voltage oscilloscopes with low sensitivity.

3. Sphere gaps with predetermined breakover voltages.

Potential dividers of many types have been developed. These include resistive voltage dividers, capacitive voltage dividers, and combination resistive and capacitive dividers. The different designs have usually been developed to eliminate some error in measurement. Different types of resistive windings have been designed to minimize self-inductance. Shields have been designed to reduce …

Effects Of Oxygen Content Of Admitted Gases In Sulfide Flotation, Brian J. Boyle

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Methods Of Studying The Effects Of Frothers, Frank L. Bazzanella

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Performance Of Initial Treatments, Constructed During 1963, James H. Havens, Robert L. Florence

Kentucky Transportation Center Research Report

Seventeen initial bituminous treatment projects were advertised for bids during 1963, which permitted bituminous concrete Class I Surface (hot-mix) as an alternate to Class C-1 Surface (road-mix). The hot-mix surface course was to contain a minimum of 6 percent PAC-9. Eleven of the contracts, totaling 38.841 miles in length, were awarded as hot-mix; and the remaining six contracts, totaling 18.12 miles in length, were awarded as road-mix.

Final Construction And Interim Performance Report: Experimental Use Of Thermoplastic Pavement-Striping Materials, James H. Havens, John W. Scott

Kentucky Transportation Center Research Report

The purposes and objectives of this study are: 1) to evaluate the application and performance characteristics of hot-melt plastic, pavement-striping materials which are presently prominent and known commercially as "Catatherm" and "Perma-Line"; 2) to compare the performance of these materials with the performance of painted stripes applied and re-newed according to the current practices of the Kentucky Department of Highways; and 3) to evaluate the economics of these striping materials in terms of cost-per-pile per-day-of-useful-life. The project is described more fully in the "Proposal..." (approved by Division Engineer, September 7, 1962) and in Report No. 1 (Pre-Construction Report) submitted September …

Simplified Approach To The Problem Of Stability Of Soil Slopes Under Horizontal Earthquake And Pore Pressure, Dalim Kumar Majumdar

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A problem that has confronted engineers for a great number of years is that of determining the stability of soil slopes. Many factors introduce complications into stability analysis. Most embankments contain heterogeneous soils, often of several types. This and other complications usually necessitate the use of a simplified cross section. At the same time, it is often necessary to adopt simplified average soil characteristics which represent actual characteristics as best as possible. Those steps which bear on the choice of the simplified section and the simplified soil characteristics are always important in stability analysis work. These steps are independent, however, …

Point Flow Measurements In Irrigation Furrows, David Ernest Mortin

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A new flow measurement concept is needed to facilitate the study of intake characteristics of the soil under furrow irrigation. Knowledge of the flow rate at various points throughout the furrow length is required but measurement must be made without altering the normal flow regime. Conventional water measuring devices such as weirs, orifices or flumes which require a loss of head in their operation, are usually unsatisfactory because to create a measuring head would alter the normal flow depth upstream thus changing the intake pattern.

The purpose of this study is to develop a simple, reliable method of measuring small …

The Irish Plumbing And Heating Engineer, May 1964 (Complete Issue)

Building Services Engineering

No abstract provided.

Evaporation And Potential Evapotranspiration In Central Iraq, Ala H. Al-Barrak

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The principal objectives of this study were to compare several formulas for estimating pan evaporation and evapotranspiration and to derive new formulas or modify existing formulas that will better fit the data for central Iraq. Computed evaporation was compared with measured evaporation by determining the differences and the ratios. The pan evaporation formulas were also compared by expressing them all in the form
Ev = K C_RC_TC_WC_HC_DTC_SC_M

Three pan evaporation formulas were modified. For the Meyer and Utah formulas, the constants were changed and expressions were derived …

The Purification, Analysis And Growth Of Single Crystals Of Organic Semiconductors, Melvin Leonard Druin

Theses

The purpose of this investigation was to design and construct a furnace for growing large single crystals of organic compounds by slow crystallization from the melt by the Bridgman technique. The crystals obtained by this furnace will be used in a later investigation of the intrinsic electrical and optical properties of organic semiconductors.

The methods describe have been used width success to produce large single crystals of anthracene and ethyl-p aminobenzoate with diameters of 1/2 inch.

The most promising methods of purification of anthracene, which were chemical synthesis, washing, recrystallization from solvents, sublimation, dimerization, co-distallatian and zone refining have been …

Predicting Current Gain Degradation In Npn Silicon Transistors After Irradiation By High-Energy Neutrons, Jerry A. Hood

Electrical and Computer Engineering ETDs

The damage discussed in this report is permanent and remains after all transient ionization has decayed. The damage which predominantly affects the electrical characteristics of a transistor is the creation of "vacancies" and "interstitials" in the lattice structure. These defects are created when an atom is knocked from its position and leaves a vacancy in the lattice. The atom comes to rest in a position out of the lattice structure and is known as interstitial. These atoms are knocked from their positions by the irradiating neutrons or by an interstitial traveling through the crystal. These defects occur in localized clusters …

Temperature Distribution And Thermal Stresses In Radiation-Cooled Circular Cylinders, William E. Putman Jr.

Mechanical Engineering ETDs

This study involves the determination of the transient temperature distribution and thermal stresses in a solid circular cylinder cooled by thermal radiation. The analytical solutions are presented in dimensionless form. Theoretical results are shown for temperature distribution and thermal stresses in the nondimensional form. Certain of these results are given in the dimensional form for the model cylinder used in this investigation.

The uranium-zirconium prototype element was thought to be undesirable for this investigation. Therefore, similitude was used to select a model which could be used for the experimental work. A solid, cylindrical, epoxy model was constructed, and thermocouples were …

The Design Criteria Of A Phoswich Transducer., Richard L. Crawford

Electrical and Computer Engineering ETDs

This dissertation is an experimental and theoretical treatise on the design criteria of a phoswich transducer. The major emphasis is on the application in a gamma-ray spectrometer. The conversion efficiency, gamma-ray cross sections, response to charged particles, luminescence decay time, spectral response and physical qualities are discussed, in considerable detail, in making the optimum choices for the inorganic crystal and the organic phosphor which will act as the charged particle anticoincident shield. The effect of the thickness of the anticoincident shield on resolution, the percentage of gamma-rays absorbed, the percentage of gamma-rays that are atten­uated in energy and the lower …

Electric Fields From Airborne Vertical And Horizontal Dipoles At Very-Low Frequencies, A. H. Garry Gibson

Electrical and Computer Engineering ETDs

A gap exists in present-day knowledge of the electric fields in the earth which are radiated from elevated antenna structures in the earth-air-ionosphere waveguide. It is the purpose of this paper to present a method of estimating the electric field at the earth-air boundary, caused by elevated antenna structures, and to show the existence of new phenomena that may lead to an improved design of communication systems.

Weighing Vehicles In Motion [1964], College Of Engineering, University Of Kentucky

Kentucky Transportation Center Research Report

This report describes the construction, installation, testing and performance analysis of three types of dynamic electronic scales; the Taller-Cooper, a commercially developed four load cell scale, the Broke Bridge, an adaptation of a German prototype employing two load cells and the Bean Type Scale, an experimental prototype that uses a pair of instrumented aluminum beams as the weight sensors.