Engineering Commons^™

Electrohydrodynamic Enhancement Of Heat Transfer And Mass Transport In Gaseous Media, Bulk Dielectric Liquids And Dielectric Thin Liquid Films, Seyed Reza Mahmoudi

Electronic Thesis and Dissertation Repository

Controlling transport phenomena in liquid and gaseous media through electrostatic forces has brought new important scientific and industrial applications. Although numerous EHD applications have been explored and extensively studied so far, the fast-growing technologies, mainly in the semiconductor industry, introduce new challenges and demands. These challenges require enhancement of heat transfer and mass transport in small scales (sometimes in molecular scales) to remove highly concentrated heat fluxes from reduced size devices. Electric field induced flows, or electrohydrodynamics (EHD), have shown promise in both macro and micro-scale devices.

Several existing problems in EHD heat transfer enhancements were investigated in this thesis. …

Derivation Of Correction Terms To The Eikonal Approximations In The Formulation Of Analytical Abrasion-Ablation Model, Santosh Bhatt

Doctoral Dissertations

Analytical models for the quantitative predictions of spectra from the neutrons and light ions produced from the high energy, heavy ion (HZE) reactions are extremely important in assessment of the radiation damage during long duration deep space missions, and for various accelerator applications. The fundamental physics of the secondary particle production and transport from these HZE reactions is described using the abrasion-ablation model. The abrasion part of the model is based on the Glauber multiple scattering theory while the ablation process is based on statistical decay based on an evaporation model. The current formulations for the abrasion process are based …

Mott Transition And Electronic Structure In Complex Oxide Heterostructures, Jian Liu

Graduate Theses and Dissertations

Strongly correlated electron systems, particularly transition metal oxides, have been a focus of condensed matter physics for more than two decades since the discovery of high-temperature superconducting cuprates. Diverse competing phases emerge, spanning from exotic magnetism to unconventional superconductivity, in proximity to the localized-itinerant transition of Mott insulators. While studies were concentrated on bulk crystals, the recent rapid advance in synthesis has enabled fabrication of high-quality oxide heterostructures, offering a new route to create novel artificial quantum materials.

This dissertation details the investigation on ultrathin films and heterostructures of 3d⁷(t_2g⁶e_g¹) systems with …

Use Of Ultra High Vacuum Plasma Enhanced Chemical Vapor Deposition For Graphene Fabrication, Shannen Adcock

Graduate Theses and Dissertations

Graphene, what some are terming the "new silicon", has the possibility of revolutionizing technology through nanoscale design processes. Fabrication of graphene for device processing is limited largely by the temperatures used in conventional deposition. High temperatures are detrimental to device design where many different materials may be present. For this reason, graphene synthesis at low temperatures using plasma-enhanced chemical vapor deposition is the subject of much research. In this thesis, a tool for ultra-high vacuum plasma-enhanced chemical vapor deposition (UHV-PECVD) and accompanying subsystems, such as control systems and alarms, are designed and implemented to be used in future graphene growths. …

Investigation Of Negative Differential Resistance Phenomena In Quantum Well Heterostructures, Nazariy Andrushchak

Graduate Theses and Dissertations

Increasing interest in entirely new possibilities for quantum mechanical description of carriers transport is becoming more evident with the developing advancements in epitaxial growth technique. Consequently, molecular beam epitaxy (MBE) technique is considered to be the most precise technique that allows the growth of ultra-thin layers of different compositions.

Those structures can be designed to investigate the wave-nature of carriers, which broadens the possibilities in device design and fabrication for a specific area. In this thesis the fundamental study of the real space charge transfer (RST) mechanism that took place in quantum well heterostructures and led to the negative differential …

A High-Energy Neutron Flux Spectra Measurement Method For The Spallation Neutron Source, Nicholas Patrick Luciano

Masters Theses

The goal of this work was to develop a foil activation method to measure high-energy (∼1-100 MeV) neutron flux spectra at the Spallation Neutron Source by researching the scientific literature, assembling an experimental apparatus, performing experiments, analyzing the results, and refining the technique based on experience. The primary motivation for this work is to provide a benchmark for the neutron source term used in target station and shielding simulations Two sets of foil irradiations were performed, one at the ARCS beamline and one at the POWGEN beamline. The gamma radiation of the foil activation products was measured with a high …

A Method To Measure The Detective Quantum Efficiency Of Radiographic Systems In Clinical Setting, Michael C. Mcdonald

Electronic Thesis and Dissertation Repository

The risks associated with exposure to radiation make it critical that digital imaging systems give the best possible images for a given dose to the patient. The DQE is the most widely accepted measure of performance and dose efficiency for digital radiography systems, however it is not commonly measured in a clinical environment as part of routine quality assurance. The primary reason for this is that the data provided to the user by clinical systems has typically undergone image processing and therefore may have a non-linear characteristic response. This is a problem because the Fourier metrics of the DQE require …

Functional Magnetic Nanoparticles, James Gass

USF Tampa Graduate Theses and Dissertations

Nanoparticle system research and characterization is the focal point of this research and dissertation. In the research presented here, magnetite, cobalt, and ferrite nanoparticle systems have been explored in regard to their magnetocaloric effect (MCE) properties, as well as for use in polymer composites. Both areas of study have potential applications across a wide variety of interdisciplinary fields.

Magnetite nanoparticles have been successfully dispersed in a polymer. The surface chemistry of the magnetic nanoparticle proves critical to obtaining a homogenous and well separated high density dispersion in PMMA. Theoretical studies found in the literature have indicated that surface interface energy …

Laser Processing Of Metals And Polymers, Senthilraja Singaravelu

Physics Theses & Dissertations

A laser offers a unique set of opportunities for precise delivery of high quality coherent energy. This energy can be tailored to alter the properties of material allowing a very flexible adjustment of the interaction that can lead to melting, vaporization, or just surface modification. Nowadays laser systems can be found in nearly all branches of research and industry for numerous applications. Sufficient evidence exists in the literature to suggest that further advancements in the field of laser material processing will rely significantly on the development of new process schemes. As a result they can be applied in various applications …

Optimization Framework For A Radio Frequency Gun Based Injector, Alicia S. Hofler

Electrical & Computer Engineering Theses & Dissertations

Linear accelerator based light sources are used to produce coherent x-ray beams with unprecedented peak intensity. In these devices, the key parameters of the photon beam such as brilliance and coherence are directly dependent on the electron beam parameters. This leads to stringent beam quality requirements for the electron beam source. Radio frequency (RF) guns are used in such light sources since they accelerate electrons to relativistic energies over a very short distance, thus minimizing the beam quality degradation due to space charge effects within the particle bunch. Designing such sources including optimization of its beam parameters is a complex …

Multidimensional Spectroscopy Of Semiconductor Quantum Dots, Jason Michael Bylsma

USF Tampa Graduate Theses and Dissertations

The coherent properties of semiconductor nanostructures are inherently difficult to measure and one-dimensional spectroscopies are often unable to separate inhomogeneous and homogeneous linewidths. We have refined and improved a method of performing multidimensional Fourier transform spectroscopy based on four-wave

mixing (FWM) experiments in the box geometry. We have modified our system with broadband beamsplitters in all interferometer arms, high-resolution translation stages and the ability to work in reflection geometry. By improving the phase-stability of our setup and scanning pulse delays with sub-optical cycle precision, we are able to

reproduce 2DFT spectra of GaAs multiple quantum wells. With the FWM signal …

Vertical Field Switching Blue Phase Liquid Crystals For Field Sequential Color Displays, Hui-Chuan Cheng

Electronic Theses and Dissertations

Low power consumption is a critical requirement for all liquid crystal display (LCD) devices. A field sequential color (FSC) LCD was proposed by using red (R), green (G) and blue (B) LEDs and removing the lossy component of color filters which only transmits ~30% of the incoming white light. Without color filters, FSC LCDs exhibit a ~3X higher optical efficiency and 3X higher resolution density as compared to the conventional color filters-based LCDs. However, color breakup (CBU) is a most disturbing defect that degrades the image quality in FSC displays. CBU can be observed in stationary or moving images. It …

Non-Reciprocal Wave Transmission In Integrated Waveguide Array Isolators, Tony Yatming Ho

Electronic Theses and Dissertations

Non-reciprocal wave transmission is a phenomenon witnessed in certain photonic devices when the wave propagation dynamics through the device along one direction differs greatly from the dynamics along the counter-propagating direction. Specifically, it refers to significant power transfer occurring in one direction, and greatly reduced power transfer in the opposite direction. The resulting effect is to isolate the directionality of wave propagation, allowing transmission to occur along one direction only. Given the popularity of photonic integrated circuits (PIC), in which all the optical components are fabricated on the same chip so that the entire optical system can be made more …

Injection-Locked Semiconductor Lasers For Realization Of Novel Rf Photonics Components, Nazanin Hoghooghi

Electronic Theses and Dissertations

This dissertation details the work has been done on a novel resonant cavity linear interferometric modulator and a direct phase detector with channel filtering capability using injection-locked semiconductor lasers for applications in RF photonics. First, examples of optical systems whose performance can be greatly enhanced by using a linear intensity modulator are presented and existing linearized modulator designs are reviewed. The novel linear interferometric optical intensity modulator based on an injection-locked laser as an arcsine phase modulator is introduced and followed by numerical simulations of the phase and amplitude response of an injection-locked semiconductor laser. The numerical model is then …

Third Order Nonlinearity Of Organic Molecules, Honghua Hu

Electronic Theses and Dissertations

The main goal of this dissertation is to investigate the third-order nonlinearity of organic molecules. This topic contains two aspects: two-photon absorption (2PA) and nonlinear refraction (NLR), which are associated with the imaginary and real part of the third-order nonlinearity (χ (3)) of the material, respectively. With the optical properties tailored through meticulous molecular structure engineering, organic molecules are promising candidates to exhibit large third-order nonlinearities. Both linear (absorption, fluorescence, fluorescence excitation anisotropy) and nonlinear (Z-scan, two-photon fluorescence, pump-probe) techniques are described and utilized to fully characterize the spectroscopic properties of organic molecules in solution or solid-state form. These properties …

Direct Write Fabrication Of Waveguides And Interconnects For Optical Printed Wiring Boards, Joseph Carl Dingeldein

Dissertations, Master's Theses and Master's Reports - Open

Current copper based circuit technology is becoming a limiting factor in high speed data transfer applications as processors are improving at a faster rate than are developments to increase on board data transfer. One solution is to utilize optical waveguide technology to overcome these bandwidth and loss restrictions. The use of this technology virtually eliminates the heat and cross-talk loss seen in copper circuitry, while also operating at a higher bandwidth. Transitioning current fabrication techniques from small scale laboratory environments to large scale manufacturing presents significant challenges. Optical-to-electrical connections and out-of-plane coupling are significant hurdles in the advancement of optical …

Translation Studies On An Annular Field Reversed Configuration Device For Space Propulsion, Carrie Suzanne Hill

Dissertations, Master's Theses and Master's Reports - Open

This research investigated annular field reversed configuration (AFRC)devices for high power electric propulsion by demonstrating the acceleration of these plasmoids using an experimental prototype and measuring the plasmoid's velocity, impulse, and energy efficiency.

The AFRC plasmoid translation experiment was design and constructed with the aid of a dynamic circuit model. Two versions of the experiment were built, using underdamped RLC circuits at 10 kHz and 20 kHz. Input energies were varied from 100 J/pulse to 1000 J/pulse for the 10 kHz bank and 100 J/pulse for the 20 kHz bank. The plasmoids were formed in static gas fill of …

Raman Spectroscopy And Diffuse Reflectance Spectroscopy For Diagnosis Of Human Cancer And Acanthosis Nigricans, Suneetha Devpura

Wayne State University Dissertations

Cancer and diabetes are common chronic diseases in today's world causing numerous deaths in adults as well as children. Most common types of cancers in adults include prostate, lung, breast, colorectal and head and neck squamous cell carcinoma, while among children; leukemia, and brain and central nervous system cancers are quite common. In each of these cases, early detection of the cancer or disease dramatically increases the chances of successful treatment. In recent years, there has been much interest in using Raman spectroscopy and diffuse reflectance spectroscopy as analytical optical spectroscopic methods for early diagnosis of diseases. Raman spectroscopy can …

An Apparatus For Verification Of Absolute Calibration Of Quantum Effiency For Charge-Coupled Devices, Rebecca Ann Coles

Wayne State University Theses

The LBNL Microsystems Laboratory produces backside illuminated, high resistivity, p-channel, charge-coupled devices (CCDs). A system was developed to test the quantum efficiency (QE) of the CCDs; the percentage of electrons that are emitted from the CCD surface per amount of light that it's exposed to.

The QE system was designed and constructed to test CCDs of a much smaller size then what is currently produced. To continue testing, I redesigned the QE apparatus to make room for the new, larger size, CCDs while still preserving measurement accuracy. I removed the photodiode that formally sat alongside the CCD in the Dewar, …

A Study Of Wo3 And W0.95ti0.05o3 Thin Films Using Comparative Spectroscopy, James Heyward Howard

Open Access Theses & Dissertations

Tungsten oxide (WO3) is important and well-studied in materials science, particularly for sensor applications. In this research work, we consider the innovation of adding Ti to thin films of this material. Since the characteristics of any such material are strongly dependent on the conditions and methods used in its deposition, the main objective of this project is to provide a detailed spectroscopic characterization by Raman scattering, infrared absorption, and X-ray photoelectron spectroscopy (XPS) of WO3 and of W0.95Ti0.05O3. This characterization will be based on comparison of the morphology and composition of WO3-based thin films, grown by radio frequency magnetron reactive …

High Pressure Synchrotron X-Ray Diffraction Studies Of Superprotonic Transitions In Phosphate Based Solid Acids, Juan Daniel Hermosillo

Open Access Theses & Dissertations

Certain phosphate based solid acids, such as CsH2PO4 and RbH2PO4, have been shown to exhibit an abrupt, several-order-of-magnitude increase in their proton conductivity when heated above a temperature threshold. This so called superprotonic behavior allows the above-mentioned materials to function as fuel cell electrolytes at temperatures between 150C and 300C, a remarkable application that attracted significant interest especially from the automobile industry. Yet, the microscopic structures and dynamic mechanisms responsible for this behavior are not fully understood. In fact, until very recently, the very nature of the superprotonic behavior has been debate, with some groups attributing the steep proton enhancement …

Submillisecond-Response Blue Phase Liquid Crystals For Display Applications, Kuan Ming Chen

Electronic Theses and Dissertations

With exploding growth of information exchanges between people, display has become indispensable in our daily lives. After decades of intensive research and development in materials and devices, and massive investment in manufacturing technologies, liquid crystal display (LCD) has overcome various obstacles and achieved the performance we need, such as wide viewing angle, high contrast ratio, and high resolution, etc. These excellent performances make LCD prevailed in every perspective. Recently, with the demands of energy conservation, a greener LCD with lower power consumption is desired. In order to achieve this goal, new energy-effective driving methods, such as field sequential color display, …

High-Efficiency Blue Phase Liquid Crystal Displays, Yan Li

Electronic Theses and Dissertations

Blue phase liquid crystals (BPLCs) have a delicate lattice structure existing between chiral nematic and isotropic phases, with a stable temperature range of about 2 K. But due to short coherent length, these self-assembled nano-structured BPLCs have a fast response time. In the past three decades, the application of BPLC has been rather limited because of its narrow temperature range. In 2002, Kikuchi et al. developed a polymer stabilization method to extend the blue-phase temperature range to more than 60 K. This opens a new gateway for display and photonic applications. In this dissertation, I investigate the material properties of …

Laser Filamentation Interaction With Materials For Spectroscopic Applications, Matthew Weidman

Electronic Theses and Dissertations

Laser filamentation is a non-diffracting propagation regime consisting of an intense core that is surrounded by an energy reservoir. For laser ablation based spectroscopy techniques such as Laser Induced Breakdown Spectroscopy (LIBS), laser filamentation enables the remote delivery of high power density laser radiation at long distances. This work shows a quasiconstant filament-induced mass ablation along a 35 m propagation distance. The mass ablated is sufficient for the application of laser filamentation as a sampling tool for plasma based spectroscopy techniques. Within the scope of this study, single-shot ablation was compared with multi-shot ablation. The dependence of ablated mass on …

Raman And Infrared Study Of Electrospun Plla/Pcl Nanofiber Blends For Use In Tissue Engineering, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

Recently, the biomedical engineering field has developed at a very fast pace as improved techniques and materials become available to promote its growth. Consequently, the research in polymeric biomaterials has been highly stimulated by this trend. The goal of the current research is to demonstrate the usefulness of the Raman scattering, Raman mapping, and infrared absorption spectroscopies to tissue engineering, by spectroscopically characterizing blends of PLLA and PCL polymers, which were prepared by electrospinning with and without cell addition. The proposed use of these blends is as primary biomaterials in biodegradable scaffolds used in tissue engineering. Both Raman and infrared …

Applications Of Density Functional Theory In Materials Science And Engineering, Manuel Alvarado

Open Access Theses & Dissertations

Density Functional Theory (DFT) is a powerful tool that can be used to model various systems in materials science. Our research applies DFT to two problems of interest. First, an organic/inorganic complex dye system known as a Mayan pigment is modeled to determine chemical binding sites, verifying each model with physical data such as UV/Vis spectra. Preliminary studies on palygorskite-based mayan pigments (mayacrom blue, mayacrom purple) show excellent agreement with experimental studies when using a dimer dye geometry binding with tetrahedrally-coordinated aluminum impurity sites in palygorksite. This approach is applied to a sepiolite-based organic/inorganic dye system using thioindigo attached to …

An Investigation Of The Relationship Between Visual Effects And Object Identification Using Eye-Tracking, Jonathan Rosch

Electronic Theses and Dissertations

The visual content represented on information displays used in training environments prescribe display attributes as brightness, color, contrast, and motion blur, but considerations regarding cognitive processes corresponding to these visual features require further attention in order to optimize the display for training applications. This dissertation describes an empirical study with which information display features, specifically color and motion blur reduction, were investigated to assess their impact in a training scenario involving visual search and threat detection. Presented in this document is a review of the theory and literature describing display technology, its applications to training, and how eye-tracking systems can …

Random Transformations Of Optical Fields And Applications, Thomas Kohlgraf-Owens

Electronic Theses and Dissertations

The interaction of optical waves with material systems often results in complex, seemingly random fields. Because the fluctuations of such fields are typically difficult to analyze, they are regarded as noise to be suppressed. Nevertheless, in many cases the fluctuations of the field result from a linear and deterministic, albeit complicated, interaction between the optical field and the scattering system. As a result, linear systems theory (LST) can be used to frame the scattering problem and highlight situations in which useful information can be extracted from the fluctuations of the scattered field. Three fundamental problems can be posed in LST …

Applications Of Volume Holographic Elements In High Power Fiber Lasers, Apurva Jain

Electronic Theses and Dissertations

The main objective of this thesis is to explore the use of volume holographic elements recorded in photo-thermo-refractive (PTR) glass for power scaling of narrow linewidth diffraction-limited fiber lasers to harness high average power and high brightness beams. Single fiber lasers enable kW level output powers limited by optical damage, thermal effects and non-linear effects. Output powers can be further scaled using large mode area fibers, however, at the cost of beam quality and instabilities due to the presence of higher order modes. The mechanisms limiting the performance of narrow-linewidth large mode area fiber lasers are investigated and solutions using …

Optical Fluid-Based Photonic And Display Devices, Su Xu

Electronic Theses and Dissertations

Conventional solid-state photonic devices exhibit an ultra-high optical performance and durability, but minimal adaptability. Recently, optical fluid-based photonic and display devices are emerging. By dynamically manipulating the optical interface formed by liquids, the optical output can be reconfigured or adaptively tuned in real time. Such devices exhibit some unique characteristics that are not achievable in conventional solid-state photonic devices. Therefore, they open a gateway for new applications, such as image and signal processing, optical communication, sensing, and lab-on-a-chip, etc. Different operation principles of optical fluidbased photonic devices have been proposed, for instance fluidic pressure, electrochemistry, thermal effect, environmentally adaptive hydrogel, …