Engineering Commons^™

Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS) technique was employed to study the corrosion behaviour of copper painted with the anion selective, cation selective and bipolar phenolic coatings in 3% NaCl solution. From the impedance spectrum characteristics, the models of equivalent circuit for these different coating systems were established, and the methods for the analysis of experimental impedance diagrams in terms of coating and interface properties were discussed. The research results show that the composition and structure of ion selective coatings have significant influence on corrosion behaviour of copper. The bipolar coating consisting of an anion selective inner layer and a cation selective outer …

Preparation Of Pbo2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang

Journal of Electrochemistry

The perchlorate was made up of a lead dioxide plate elcetrode and an oxygen cathode. By measuring the flow capacity of cell gas in the cell, and by means of CV, SEM, XRD, the performances of the lead dioxide plate electrodes are evaluated. The influence of changes in the concentrations of electroplating solutions (F, HNO₃, Bi³⁺, Ni²⁺, Fe³⁺ and surface active agent) is investigated. The results show that the concentrations of Fe³⁺ in the solutions must be lower 0.01 g/L, and the concentrations of HNO₃ in the solutions are about 20 …

Study On The Diffusion Of Electroactive Molecules In Polymer Electrolyte By Microelectrode Voltammetry, Liming Ding, Shaojun Dong, Erkang Wang

Journal of Electrochemistry

The ten years study on the diffusion of electroactive molecules in polymer electrolyte by microelectrode voltammetry was reviewed by considering the development background of polymer electrolyte materials. The classification, fabrication, applications and electrochemical measurements of microelectrode were introduced concisely. The several important factors influencing the diffusion of electroactive molecules were stressed. In the final part of this paper, some new reports on the diffusion of labeled molecules were introduced.

Electrocatalytic Oxidation Of Methanol On The Stearate Nickel L-B Film, Benzeng Hua, Wenyan Hu, Yanzhen Chen, Yanhong Zhang

Journal of Electrochemistry

The stearate nickel L-B films is good electroacatlyst for the oxidation of methanol MeOH in alkaline. The electrochemical behaviors of stearate nickel L-B films is affected by the concentration of KOH. The rate of quantity of mickel ion and stearic acid in L-B films is 1∶1, which means that the nickel ion may exist in -COONi(OH) form. The electrocatalytic process is influenced by the concentration of OH^-, it involves the penetration of MeOH into the films. The oxidative currents of MeOH are linearly dependent on the bulk concentration.

Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅲ. Improvement Of Artificially Imposed Solid Electrolyte Film On Cell Performance, Shuhua Ma, Xiabin Jing, Fosong Wang

Journal of Electrochemistry

The improving effect of solid electrolyte film artificially imposed on carbon electrode was investigated. The result showed that both the charge/discharge capacity and first charge/discharge efficiency, to a certain extent, were enhanced, and the result also suggested the effectiveness of the substitution of the artificially imposed solid electrolyte film for the inherent passivating film which was formed on the surface of the carbon electrode while inserted in the electrolyte during charging or discharging. The Scanning Electron Microscope result displayed the compact and well-defined morphology of the artificially imposed crystalline film.

Investigation On Electro Reduction Behaviour Of Copper Anodic Products In Concentrated Naoh Solutions Ⅱ. Electro Reduction Of Cu(Ⅱ) Products, Jianbo He, Hanhe Chen, Jianxin Lin

Journal of Electrochemistry

Potentiostatic oxidation potentiodynamic or galvanostatic reduction methods have been used to study the cathodic reduction behaviour of various products anodically formed on the second stage of copper oxidation in concentrated NaOH solutions. Seven cathodic current peaks and the corresponding cathodic potential plateaus are observed on the potentiodynamic E/i curves and the galvanostatic E/t curves, respectively. In the negative potential scan, there are three couples of voltammetric peaks which have been attributed to the formation and reduction of CuO, Cu(OH)₂ and Cu(Ⅱ) ion, respectively. The complicated mechanism for the electro formation of the three Cu(Ⅱ) species are discussed.

Studies On The Failure Modes Of Stationary Vrla Batteries, Yibo Tong, Xiangming Qiu

Journal of Electrochemistry

In order to improve the reliability and the quality of stationary valve-regulated lead-acid (VRLA) batteries, the failure modes of the stationary VRLA batteries which caused by the water loss and the thermal runaway are studied. The water loss may be solved by increasing the Oxygen-recombination efficiency, choosing the suitable grid material and the additives of megative paste, decreasing the corrosion of the positive plates. The thermal runaway may be solved by decreasing the inner ohmic resistance of VRLA batteries, improving the outside condition of batteries such as putting into the absorbing-heat material between the abtteries etc..

Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li

Journal of Electrochemistry

The solid oxide fuel cells of planar type (SOFC) have been developed after successfully preparing La_0.8Sr_0.2MnO₃ cathodes and Ni-YSZ ceramic anodes on YSZ plates and solving the high temperature sealing technical problem. Examination of the single cells fabricated showed that the maximum power output at 950 ℃ for H₂ as fuel and air as oxidant reached 0.12 W/cm². It was found that the large polarization overpotential of the Ni-YSZ anode and the Ohmic losses of the cells were two main factors responsible for the relative low output power density.

Electrorheological Characters Of Polyaniline Suspensions, Guangyao Su, Deshu Gao, Changqing Zhang

Journal of Electrochemistry

Polyaniline (PAn) as the dispersive particles and insulating oil as the dispersive medium, the electrorheological fluid (ERF) is constituted. Relations between the factors of electric field strength (E), temperature (T) and the static yield stress (τ_S), current density (i) of ERF are investigated. The results show that the changes of τ_S and i with electric field intensity have emerged in the exponential relation, i.e, τ_S∝E^0.7, i∝E^2.18. Otherwise, when exert a constant voltage on ERF, owing to the polarization, the absorption of medium of ERF have taken place. Therefore, the attenuation rate …

Behavior Of Copper In Hydrogen Storage Alloy Microencapsulated By Copper, Dawei Zhang, Huatang Yuan, Huabin Yang, Zuoxiang Zhou, Yunshi Zhang

Journal of Electrochemistry

Negative electrode made from Cu microencapsulated hydrogen storage alloy was studied by using cyclic voltammetry method. The results showed that copper as a coating material was of a certain stability in 5 mol/L KOH solution within the range of charge and discharge voltage. But when expanding the sweep voltage, the CV curve showed a pair of distinct oxidation reduction current peaks of Cu₂O formation at E = -0.3 V and Cu₂O reduction at E =-0.6 V. With charging discharging cycles, copper is liable to be oxidized to Cu₂O and further oxidized into CuO_{2 …}

Study On Electrochemical Methods Of Controlled Convolution ——A Simple Electron Transfer Reaction Followed By A Homogeneous Catalytic Reaction(Ⅰ), Ming Ma, Naixian Xie, Qianlei Gao, Yue Zeng

Journal of Electrochemistry

A simple electron transfer reaction followed by a homogeneous catalytic reaction is studied in this paper by three kinds of controlled convolution electrochemical experimental methods, which are the constant semi integral (CSI), linear semi integral sweep (LSIS) and linear semi differential sweep (LSDS). According to the three methods, the following equations can be obtained. With these equations, the theoretical curves of the above three methods can be computed. Experiments of the ferrocyanide ascorbic acid catalytic system have confirmed that kinetic rate constant in catalytic reaction is in good agreement with the previously reported values.

The Electrochemical Behavior And Deposited Mechanism Of Zn-Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng

Journal of Electrochemistry

The electrochemical behavior of Zn-Ni alloy codeposition and concomitant hydrogen evolution have been studied in the chloride ammonia solution through the d-c electroplating method. Under the condition of the applied cathodic current density of 2A/dm² , the AC impedance spectra have been measured. An equivalent circuit has been presented for the impedance study on the alloy codeposition.

The Electrode Process Of Some Organic Dyes Studied By Spectroelectrochemical Technique In Situ, Yinxuan Tang, Hangsheng Yang, Baoen Shen

Journal of Electrochemistry

Spectroelectrochemistry especially with in situ measurement in a cell provides a very useful mthodology for measuring the parameters of electrode process. In this paper, we report the determination of formal potentials, the number of electron transfer, the diffusion coefficient, the heterogeneous electron transfer rate constant and the transfer coefficient of some organic dyes (Methyelene blue, Neutral red, Indigo carmine) using spectroelectro chemical technique in situ.

39th Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Preliminary program and registration information for the 39th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 3-7, 1997.

Experimental Investigation Of Nonlinear Dynamics In Single Mode Semiconductor Laser Diodes With Phase Conjugate Feedback, Gordon T. Hengst

Theses and Dissertations

The semiconductor laser diode offers a unique system to investigate nonlinear dynamics when optical feedback is applied. Although there is extensive research of laser diodes with optical feedback from normal dielectric mirrors, very little has been done experimentally to analyze the effects of degenerate phase conjugate feedback from a BaTiO₃ crystal. This research experimentally investigated the dynamics of a single-mode laser diode with weak phase conjugate feedback using both the self-pumped and double phase conjugate geometries. The experimental results validated a mathematical model which numerically evaluates the Lang-Kobayahsi coupled differential equations. The model simulated the nonlinear behavior of a …

An Improved Analytical Model For Wormhole Routed Networks With Application To Butterfly Fat-Trees, Ronald I. Greenberg, Lee Guan

Computer Science: Faculty Publications and Other Works

A performance model for wormhole routed interconnection networks is presented and applied to the butterfly fat-tree network. Experimental results agree very closely over a wide range of load rate. Novel aspects of the model, leading to accurate and simple performance predictions, include (1) use of multiple-server queues, and (2) a general method of correcting queuing results based on Poisson arrivals to apply to wormhole routing. These ideas can also be applied to other networks.

Detection Of Volcanic Ash Clouds From Nimbus 7/Total Ozone Mapping Spectrometer, C. J. Seftor, N. C. Hsu, J. R. Herman, P. K. Bhartia, O. Torres, William I. Rose, David J. Schneider, N. Krotkov

Department of Geological and Mining Engineering and Sciences Publications

Measured radiances from the Version 7 reprocessing of the Nimbus 7/total ozone mapping spectrometer (TOMS) 340- and 380-nm channels are used to detect absorbing particulates injected into the atmosphere after the El Chichon eruption on April 4, 1982. It is shown that while the single-channel reflectivity determined from the 380-nm channel is able to detect clouds and haze composed of nonabsorbing aerosols, the spectral contrast between the 340- and 380-nm channels is sensitive to absorbing particulates such as volcanic ash, desert dust, or smoke from biomass burning. In this paper the spectral contrast between these two channels is used to …

Santa Clara Magazine, Volume 39 Number 2, Summer 1997, Santa Clara University

Santa Clara Magazine

6 - THE BEST TEST SCORE MONEY CAN BUY If you can afford it, taking a cram course can make a difference. But does a higher score indicate the breadth of your knowledge or just the thickness of your wallet? By Jeff Brazil '85

12 - THE FUTURE OF HISTORY MAJORS Studying the past can lead to present-day success. By Kathryn Bold '81

16 - BITTER HARVEST Researchers witness the impact of civil war, famine, and Islamic militants on life in a Sudanese village. By Susan Frey

Dynamic Load Distribution In Mist, K. Al-Saqabi, R. M. Prouty, Dylan Mcnamee, Steve Otto, Jonathan Walpole

Computer Science Faculty Publications and Presentations

This paper presents an algorithm for scheduling parallel applications in large-scale, multiuser, heterogeneous distributed systems. The approach is primarily targeted at systems that harvest idle cycles in general-purpose workstation networks, but is also applicable to clustered computer systems and massively parallel processors. The algorithm handles unequal processor capacities, multiple architecture types and dynamic variations in the number of processes and available processors. Scheduling decisions are driven by the desire to minimize turnaround time while maintaining fairness among competing applications. For efficiency, the virtual processors (VPs) of each application are gang scheduled on some subset of the available physical processors.

Fixpunktsemantik Logischer Programme, Pascal Hitzler

Computer Science and Engineering Faculty Publications

No abstract provided.

The Study Of Wave-Blocking And Current Effects On Nonlinear Interactions Of Shallow-Water Waves Using Advanced Boussinesq Models, Qin Chen

Civil & Environmental Engineering Theses & Dissertations

The first part of this work focuses on the derivation of enhanced Boussinesq-type equations for the combined motion of waves and currents in shallow water areas.

The strategy proposed in this work is to couple two known methods which are the sponge layer concept suitable for short waves and Sommerfeld radiation condition for currents. This coupling method provides satisfactory non-reflective boundaries for the simulation of fully coupled wave/current motion as demonstrated by the numerical experiments. We verify the model against the well known solutions based on the existing theories and good agreement has been observed. The numerical results confirm the …

High-Order Finite-Difference Schemes And Their Application To Computational Acoustics, Joe Leo Manthey

Mathematics & Statistics Theses & Dissertations

The primary focus of this study is upon the numerical stability of high-order finite-difference schemes and their application to duct acoustics. Since acoustic waves are known to be non-dissipative and non-dispersive, high-order schemes are favored for their low dissipation and low dispersion relative to the low-order schemes. The primary obstacle to the the development of explicit high-order finite-difference schemes is the construction of boundary closures which simultaneously maintain the formal order of accuracy and the numerical stability of the overall scheme. In this thesis a hybrid seven-point, fourth-order stencil for computing spatial derivatives is presented and the time stability is …

Investigation Of Drag Reduction On A Two-Dimensional Circular Cylinder By Ejecting Jet From The Rear Stagnation Region, Satoshi Atsuchi

Mechanical & Aerospace Engineering Theses & Dissertations

Extensive work in the field of drag reduction has been done in the past. However, this field of study is highly desirable today because of various high-speed research programs. The present study attempts to investigate the feasibility of drag reduction on a cylinder by flow injection from the rear stagnation region. A two-dimensional circular cylinder at Reynolds number l x10⁵with a jet ejected from its tail is selected as a physical model. To tackle this problem, a numerical simulation as well as an experimental approach were used. Despite the recent development of computational fluid dynamics (CFD), computing a …

Specification And Verification Of Generic Cell Rate Algorithms In Pvs, Huseyin Ozgungor

Electrical & Computer Engineering Theses & Dissertations

Formal verification methods have been considered as a powerful complementary approach to define standards and to prove correctness of the systems. In this work, formal specification of Generic Cell Rate Algorithms are defined and proved. The specification process enables standardization for constructing Generic Cell Rate Algorithms. Standardization is an important process in the Asynchronous Transfer Mode (ATM) networks. By employing formal methods, the necessary standards could be constructed to allow different algorithms to be employed which still meet system requirements. Those system requirements are quantified in the Quality of Service (QOS).

Congestion management is a vital concept for networks in …

The Detoxification Of Petroleum Contaminated Coastal Plain Sandy Soil Using An Amended Vermicomposting Approach, John Charles Kraemer

Health Services Research Dissertations

This study explores the feasibility of utilizing an amended vermicomposting treatment approach for detoxifying petroleum hydrocarbon contaminated sandy soil. The bench-scale testing of gasoline and diesel contaminated soil using three test soil vessels and one control soil vessel was performed in a laboratory setting for a six week time period. The control soil received no treatment other than distilled water to maintain soil moisture. Treatment 1 consisted of direct application of liquid municipal biologic sludge on a weekly basis. Treatment 2 consisted of the addition of 30 Eisenia foetida earthworms and distilled water. Treatment 3 consisted of direct application of …

Correlation Of Finite Element Prediction And Experimental Measurements Of Aircraft Panel Structural Vibration, Olaf L. Storaasli

Mechanical & Aerospace Engineering Theses & Dissertations

With the rapid development of computational capabilities and the implementation of complex tools for commercial finite element programs, predicting structural dynamics and related acoustics of complex structures is presently achievable. Structural finite element modeling is a design tool widely utilized for analysis of problems of all kinds. However, high frequency vibration of complex structures, such as the reinforced aircraft panel used for this study, currently does not correlate well with experimental measurements using conventional modeling methods. An investigation into the commonly used modeling techniques as well as the new tools of commercial finite element analysis packages for the prediction of …

A Synthesized Methodology For Eliciting Expert Judgment For Addressing Uncertainty In Decision Analysis, Richard W. Monroe

Engineering Management & Systems Engineering Theses & Dissertations

This dissertation describes the development, refinement, and demonstration of an expert judgment elicitation methodology. The methodology has been developed by synthesizing the literature across several social science and scientific fields. The foremost consideration in the methodology development has been to incorporate elements that are based on reasonable expectations for the human capabilities of the user, the expert in this case.

Many methodologies exist for eliciting assessments for uncertain events. These are frequently elicited in probability form. This methodology differs by incorporating a qualitative element as a beginning step for the elicitation process. The qualitative assessment is a more reasonable way …

Reverse Engineering Of Aircraft Wing Data Using A Partial Differential Equation Surface Model, Jacalyn M. Huband

Mathematics & Statistics Theses & Dissertations

Reverse engineering is a multi-step process used in industry to determine a production representation of an existing physical object. This representation is in the form of mathematical equations that are compatible with computer-aided design and computer-aided manufacturing (CAD/CAM) equipment. The four basic steps to the reverse engineering process are data acquisition, data separation, surface or curve fitting, and CAD/CAM production. The surface fitting step determines the design representation of the object, and thus is critical to the success or failure of the reverse engineering process. Although surface fitting methods described in the literature are used to model a variety of …

The River Association Approach To Privatization Of Federal Hydro Projects, Michael K. Block

Dams: Water and Power in the New West (Summer Conference, June 2-4)

15 pages.

Greener And More Equitable: A Vision For Dams And Other Western Water Issues, Bruce C. Driver

Dams: Water and Power in the New West (Summer Conference, June 2-4)

10 pages.

Contains 1 page of references.