Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics

Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 34891 - 34920 of 40921

Full-Text Articles in Engineering

Control And Characterization Of Line-Addressable Micromirror Arrays, Harris J. Hall Mar 2001

Control And Characterization Of Line-Addressable Micromirror Arrays, Harris J. Hall

Theses and Dissertations

This research involved the design and implementation of a complete line-addressable control system for a 32x32 electrostatic piston-actuated micromirror array device. Line addressing reduces the number of control lines from N2 to 2N making it possible to design larger arrays and arrays with smaller element sizes. The system utilizes the electromechanical bi-stability of individual elements to bold arbitrary bi-stable phase patterns. The control system applies pulse width modulated (PWM) signals to the rows and columns of the micromirror array. Three modes of operation were conceived and built into the system. The first was the traditional signal scheme which requires …


A Low Power Application-Specific Integrated Circuit (Asic) Implementation Of Wavelet Transform/Inverse Transform, Daniel N. Harvala Mar 2001

A Low Power Application-Specific Integrated Circuit (Asic) Implementation Of Wavelet Transform/Inverse Transform, Daniel N. Harvala

Theses and Dissertations

A unique ASIC was designed implementing the Haar Wavelet transform for image compression/decompression. ASIC operations include performing the Haar wavelet transform on a 512 by 512 square pixel image, preparing the image for transmission by quantizing and thresholding the transformed data, and performing the inverse Haar wavelet transform, returning the original image with only minor degradation. The ASIC is based on an existing four-chip FPGA implementation. Implementing the design using a dedicated ASIC enhances the speed, decreases chip count to a single die, and uses significantly less power compared to the FPGA implementation. A reduction of RAM accesses was realized …


Simulating Wet Deposition Of Radiocesium From The Chernobyl Accident, Aaron M. Kinser Mar 2001

Simulating Wet Deposition Of Radiocesium From The Chernobyl Accident, Aaron M. Kinser

Theses and Dissertations

In response to the Chernobyl nuclear power plant accident of 1986, a cesium-137 deposition dataset was assembled. Most of the airborne Chernobyl cesium was wet deposited, either via interception by falling raindrops or via absorption into cloud droplets destined to become raindrops. The Hybrid Single-Particle Lagrangian rated Transport (HYSPLIT) model, developed at Air Resources Laboratory, is used to simulate the transport and deposition of Chernobyl cesium-137. A cloud base parameterization modification is tested and appears to slightly improve the accuracy of one HYSPLIT simulation of daily Chernobyl cesium-137 deposition over the course of the accident at isolated European sites, and …


Lifecycle Energy And Air Emission Differences Between Electric And Internal Combustion Vehicles, David L. Mccleese Mar 2001

Lifecycle Energy And Air Emission Differences Between Electric And Internal Combustion Vehicles, David L. Mccleese

Theses and Dissertations

The U.S. Federal Government has encouraged shifting from internal combustion engine vehicles (ICEVs) to electric vehicles (EVs) with three objectives, reducing foreign oil dependence, greenhouse gas emissions, and criteria pollutant emissions. This thesis uses Monte Carlo simulation to predict lifecycle emissions and energy consumption differences per kilometer driven from replacing ICEVs with three EV options: lead acid, nickel cadmium (Ni-Cd), and nickel metal hydride (NiMH). All three EV options reduce U.S. foreign oil dependence by shifting to domestic coal. The probabilities that lifecycle energy consumption per km driven improve are lead acid 76%, Ni-Cd 64%, and NiMH 90%. The probabilities …


Malicious Hackers: A Framework For Analysis And Case Study, Laura J. Kleen Mar 2001

Malicious Hackers: A Framework For Analysis And Case Study, Laura J. Kleen

Theses and Dissertations

Recent years have seen an increase in the number and severity of Information Operations (IO) attacks upon DoD resources. At a higher level, the US as a whole has come under cyber attack by individuals and groups seeking thrills, monetary gain, publicity for their causes, and myriad other goals. This effort develops a first cut model of individual hacker mentality that can be utilized to improve threat assessment, mitigate Information Assurance (IA) vulnerabilities, and improve risk assessment. Further, it is a first step toward automated characterization of Information Warfare (IW) attacks based upon hacker types. All hackers are not the …


Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker Mar 2001

Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker

Theses and Dissertations

Subsurface contamination by industrial chemicals is one of the most prevalent and costly environmental problems facing the United States government. This contamination problem must be managed to protect human health and the environment. Two basic strategies are used to deal with subsurface contamination: source removal and contaminant containment. While much cost and performance data are available for individual technologies associated with each of these strategies, there have been very few studies that have examined the benefits of implementing source removal technologies in order to reduce contaminant containment (and hopefully total) costs. This study examines the tradeoff between extent of source …


A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel Mar 2001

A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel

Theses and Dissertations

Groundwater contamination by chlorinated ethenes is a widespread environmental problem. Conventional remediation technologies have shortcomings that have prompted further research into the development of novel treatment technologies. A palladium/ alumina catalyst in the presence of dissolved molecular hydrogen (referred to hereafter as a PD/H2 system) has been demonstrated to rapidly destroy chlorinated ethene contaminated groundwater. First-order kinetics have been used to model chlorinated ethene destruction in a PD/H2 reactor. However, catalyst deactivation and regeneration are important processes that also need to be modeled in order to better understand their effect on treatment efficiency. This study presents a model …


Multicast Algorithms For Mobile Satellite Communication Networks, Ryan W. Thomas Mar 2001

Multicast Algorithms For Mobile Satellite Communication Networks, Ryan W. Thomas

Theses and Dissertations

With the rise of mobile computing and an increasing need for ubiquitous high speed data connections, Internet-in-the-sky solutions are becoming increasingly viable. To reduce the network overhead of one-to-many transmissions, the multicast protocol has been devised. The implementation of multicast in these Low Earth Orbit (LEO) constellations is a critical component to achieving an omnipresent network environment. This research examines the system performance associated with two terrestrial-based multicast mobility solutions, Distance Vector Multicast Routing Protocol (DVMRP) with mobile IP and On Demand Multicast Routing Protocol (ODMRP). These protocols are implemented and simulated in a six plane, 66 satellite LEO constellation. …


Gss Technology As A Moderator Of Influence And Perceived Expertise, Kevin V. Thompson Mar 2001

Gss Technology As A Moderator Of Influence And Perceived Expertise, Kevin V. Thompson

Theses and Dissertations

Group Support System (355) research has found this content and process anonymity influence problem solving groups. However, previous studies report mixed results on how OSS technology changes social influence processes and recognition of expertise which affect group performance. This thesis explored content and process anonymity's affect on influence and perceived expertise using three treatments to derive possible explanations for the mixed results found in previous GSS research. The study developed a theoretical model of influence, perceived expertise, and performance. Using structural equation modeling the study tested the relationships between expertise and participation rates, and overall group performance. An experiment was …


Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young Mar 2001

Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young

Theses and Dissertations

Chlorinated ethenes are among the most prevalent groundwater contaminants at hazardous waste sites nationwide. In an attempt to manage the risks posed by these contaminants, while controlling costs, monitored natural attenuation (MNA) is being considered as a remediation strategy at many sites. MNA relies on naturally occurring physical, chemical, and biological processes in the subsurface to reduce the risk posed by the contamination. The implementation of MNA, however, requires a detailed understanding of these processes, and how they impact contamination at a particular site. One way to gain this understanding is through contaminant fate and transport modeling. In this study, …


Assessment Of The Effects Of Entrainment And Wind Shear On Nuclear Cloud Rise Modeling, Daniel E. Zalewski Mar 2001

Assessment Of The Effects Of Entrainment And Wind Shear On Nuclear Cloud Rise Modeling, Daniel E. Zalewski

Theses and Dissertations

The Missile Defense Agency (MDA) plans to construct, during a two-week period, an X-Band Radar (XBR) on Shemya, AK. Wind speeds must not, at any time during the construction, exceed a 25 knot limit set by the MDA for lifting the massive dome panels into place. The goal of this research was to explore the possibilities of long-range forecasts to determine the feasibility of predicting any upcoming two-week windows of opportunity, well in advance, that will ensure the successful completion of constructing the XBR on Shemya. In order to reach this goal, the following objectives were achieved; (1) a climatological …


A Process For Vectoring Offensive Information Warfare As A Primary Weapon Option Within The United States Air Force, Sheila G. Bennett Mar 2001

A Process For Vectoring Offensive Information Warfare As A Primary Weapon Option Within The United States Air Force, Sheila G. Bennett

Theses and Dissertations

Consistently and comprehensively using Information Operations (IO) capabilities as primary weapon option within the Air Force is the next step to operationalizing IO within the Air Force. Doctrine and official guidance has set the variables of mission and concepts of operations, organizational structure, and IW players in place. The missing variable to operationalizing IO and probably the most difficult is the 'how' or process of the equation. This research will introduce a useable process that can be incorporated within the Air Force for integrating offensive IW activities into the current and given environment. The process is the basis for further …


Photoluminescence Of Single Quantum Well Structures In Gallium Arsenide, Christian A. Bartholomew Mar 2001

Photoluminescence Of Single Quantum Well Structures In Gallium Arsenide, Christian A. Bartholomew

Theses and Dissertations

The continued development of state-of the-art semiconductor technologies and devices by the United States Air Force and the Department of Defense requires accurate and efficient techniques to evaluate and model these new materials. Of particular interest to the Air Force are quantum well structures which can be used for small-scale laser sources in fly-by-light applications, as efficient infrared countermeasures to heat-seeking missiles, or as advanced seekers in optically guided missiles. This thesis provides the initial experimental procedures and data necessary to begin producing accurate yet robust models. Although carrier effective masses could not be evaluated using hot-electron photoluminescence, photoluminescence excitation …


Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler Mar 2001

Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler

Papers in Thermal Mechanics

Using published experimental data on the thermal conductivity, mutual diffusivity, and heats of transport, the degree of coupling between heat and mass flows has been calculated for binary and ternary nonideal liquid mixtures. The binary mixtures consist of two types: the first is six systems of six-to-eight-carbon straight and branched chain alkanes in chloroform and in carbon tetrachloride; and the second is mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and 11-octane. The ternary mixture considered is toluene-chlorobenzene-bromobenzene. The published data are available at 35°C, 30°C, and 35°C and ambient pressure. Using the linear nonequilibi-ium thermodynainics (LNET) and the …


Modeling Information Assurance, Joseph E. Beauregard Mar 2001

Modeling Information Assurance, Joseph E. Beauregard

Theses and Dissertations

The ever-increasing speed of information systems allows decision-makers around the world to gather, process, and disseminate information almost instantaneously. However, with this benefit there comes a price. Information is valuable and therefore a target to those who do not have it or wish to destroy it. The Internet has allowed information to flow freely, but it has also made information vulnerable to many forms of corruption. The U. S. military controls much of the world's most sensitive information, and since it cannot sacrifice losing the speed at which this information is currently processed and disseminated, it must find a way …


The Effects Of Budgetary Constraints, Multiple Strategy Selection, And Rationality On Equilibrium Attainment In An Information Warfare Simulation, Steven W. Tait Mar 2001

The Effects Of Budgetary Constraints, Multiple Strategy Selection, And Rationality On Equilibrium Attainment In An Information Warfare Simulation, Steven W. Tait

Theses and Dissertations

Information warfare (IW) has developed into a significant threat to the national security of the United States. Our critical infrastructures, linked together by information systems, are increasingly vulnerable to information attack. This study seeks to understand some of those factors which affect the ability of an individual to make accurate decisions in an IW environment. The study used game theory to analyze the behavior of decision-makers within an IW simulation. The IW game model is based on a set of games known as infinitely repeated games of incomplete information. It uses the Bayesian Nash equilibrium concept to determine the strategy …


Minimum Distance Estimation For Time Series Analysis With Little Data, Hakan Tekin Mar 2001

Minimum Distance Estimation For Time Series Analysis With Little Data, Hakan Tekin

Theses and Dissertations

Minimum distance estimate is a statistical parameter estimate technique that selects model parameters that minimize a good-of-fit statistic. Minimum distance estimation has been demonstrated better standard approaches, including maximum likelihood estimators and least squares, in estimating statistical distribution parameters with very small data sets. This research applies minimum distance estimation to the task of making time series predictions with very few historical observations. In a Monte Carlo analysis, we test a variety of distance measures and report the results based on many different criteria. Our analysis tests the robustness of the approach by testing its ability to make predictions when …


Numerical Study Of Optical Delay In Semiconductor Multilayer Distributed Bragg Reflector And Tunable Microcavity Structures, Michael I. K. Etan Mar 2001

Numerical Study Of Optical Delay In Semiconductor Multilayer Distributed Bragg Reflector And Tunable Microcavity Structures, Michael I. K. Etan

Theses and Dissertations

The Air Force has a growing need for the greater bandwidth, speed, and flexibility offered by optical communication links. Future space systems and airborne platforms will most likely use optical signals for efficient power transmission and to minimize the possibility of spoofing and eavesdropping. Tunable optical delays play an important role in the implementation of free space optical communication links. The primary challenge in implementing these systems is the active maintenance of coherent wave fronts across the system's optical aperture. For space applications, this aperture may he hundreds of meters in diameter. Spatial segmentation of a large aperture into smaller …


The Applications Of Confocal Raman Micro-Spectroscopy For Study Of Practical Electrode Materials, Yong Yang, Wei Chu, Jun-Min Nan, Xun-Guang Chen, Zu-Geng Lin Feb 2001

The Applications Of Confocal Raman Micro-Spectroscopy For Study Of Practical Electrode Materials, Yong Yang, Wei Chu, Jun-Min Nan, Xun-Guang Chen, Zu-Geng Lin

Journal of Electrochemistry

Some recent research work about applications of confocal Raman micro spectroscopy for study of practical electrode materials carried out in our lab has been briefly introduced. The examples include study of electrochemical Li+ intercalation process, characterization of surface oxide film on AB5 type electrodes and passive film and pitting corrosion of Rebar electrodes.


Confocal Microprobe Raman Spectroscopy For Investigating The Electrochemical Interface, Bin Ren, Feng-Ming Liu, Xu-Feng Lin, Zhong-Qun Tian Feb 2001

Confocal Microprobe Raman Spectroscopy For Investigating The Electrochemical Interface, Bin Ren, Feng-Ming Liu, Xu-Feng Lin, Zhong-Qun Tian

Journal of Electrochemistry

The invention of the surface enhanced Raman spectroscopy (SERS) in the mid of 1970s, opened an entirely new and very promising area. However, it was found that SERS of practical application in electrochemistry can only be found on noble metal surfaces, such as Ag, Au and Cu that exhibit huge surface enhancement. This greatly limits the application of SERS in electrochemistry.


Raman And Afm Characterization Of Au And Cu Nanorod And Nanowire Arrays, Jing Tang, Jian-Lin Yao, Kuan-Hong Xue, De-Yin Wu, Long-Gang Lin, Yu-Xiong Jiang, Bin Ren, Xin Xu, Bing-Wei Mao, Zhong-Qun Tian Feb 2001

Raman And Afm Characterization Of Au And Cu Nanorod And Nanowire Arrays, Jing Tang, Jian-Lin Yao, Kuan-Hong Xue, De-Yin Wu, Long-Gang Lin, Yu-Xiong Jiang, Bin Ren, Xin Xu, Bing-Wei Mao, Zhong-Qun Tian

Journal of Electrochemistry

Recently metal nanowires (nanorods) have aroused tremendous interest because of their novel properties and potential applications in wide fields Many two-dimensional nanowire arrays of semiconductors and metals with different diameter and length have been made by using template synthesis method.


Surface-Enhanced Raman Spectroscopy Of Metallotetraphenyl Porphyrins Adsorbed On Ag2O And Silver Colloids, Ying-Hui Zhang, Dong-Ming Chen, Tian-Jing He, Fan-Chen Liu Feb 2001

Surface-Enhanced Raman Spectroscopy Of Metallotetraphenyl Porphyrins Adsorbed On Ag2O And Silver Colloids, Ying-Hui Zhang, Dong-Ming Chen, Tian-Jing He, Fan-Chen Liu

Journal of Electrochemistry

The biological significance of porphyrins and metalloporphyrins has stimulated intensive investigations on these compounds for many years. On the other hand, porphyrins and metalloporphyrins also have extensive applications in many other fields such as chemical modified electrodes, organic photovoltaic devices and biomimetic catalysis. The adsorption behavior and chemical reactions of metalloporphyrins on surfaces or interfaces are very important for these applications.


Electrochemical Impedance Spectroscopy Studies On Inhibitive Performance Of Aluminum Triphosphate Pigment, Yong-Gui Liao, Zhi-Jun Gu, Zhi-Gang Zhang, Qi-Long Guo, Fang-Teng Su Feb 2001

Electrochemical Impedance Spectroscopy Studies On Inhibitive Performance Of Aluminum Triphosphate Pigment, Yong-Gui Liao, Zhi-Jun Gu, Zhi-Gang Zhang, Qi-Long Guo, Fang-Teng Su

Journal of Electrochemistry

The epoxy coatings on A3 steel sheets containing calcite or aluminum triphosphate (AlTP), were investigated by Electrochemical Impedance Spectroscopy (EIS). The results showed that calcite pigment is not an inhibitor, but an extender pigment, and that AlTP pigment can considerably enhance the protective performance of epoxy coating. The triphosphate ion at the interface between the steel substrate and the coating can complex with the corrosion product, such as ferric and ferrous ions, and form a compact protective film which effectively separates the steel substrate from the aggressive media.


A Study On The Performance Of Matrix Prepared By Tape Cast And Its Molten Carbonate Fuel Cells (Mcfcs), Hua-Xin Lin, Bao-Lian Yi, Li Zhou, Chang-Qing He, Lian-Ying Kong, En-Jun Zhang Feb 2001

A Study On The Performance Of Matrix Prepared By Tape Cast And Its Molten Carbonate Fuel Cells (Mcfcs), Hua-Xin Lin, Bao-Lian Yi, Li Zhou, Chang-Qing He, Lian-Ying Kong, En-Jun Zhang

Journal of Electrochemistry

The matrix prepared with γ-LiAlO2 powder and by tape cast displayed higher ability of preventing from gas cross over and lower ohmic polarization. The voltages of the stack (three cells, 122 cm2) stacked with the matrix were 2.02 and 1.78 V at 200 and 246 mA/cm2, respectively, and the output power reached 53.4 W. The cell (28 cm 2) voltages were 0.85 and 0.75 V at 200 and 300 mA/cm2, respectively, and the output power was about 6.6 W. Compensating the shrinkage of matrix in stacking cells promoted the enhancement of the …


Rhodium As A Ubiquitous Substrate For Surface Enhanced Raman Spectroscopy, Bin Ren, Xu-Feng Lin, Zhong-Qun Tian Feb 2001

Rhodium As A Ubiquitous Substrate For Surface Enhanced Raman Spectroscopy, Bin Ren, Xu-Feng Lin, Zhong-Qun Tian

Journal of Electrochemistry

Raman Spectroscopy is a powerful technique in characterizing the molecular structure at the molecular level. However, only after the discovery of surface enhanced Raman scattering (SERS) effect, has it become one of the most widely used technique in surface sciences. The limitation that only Ag, Au and Cu can produce prominent SERS signal of practical significance, greatly hinders the application of this technique. Recently our group has made great progress in extending SERS to pure transition metal surfaces, such as Pt, Ni, Fe, Co etc.


Two-Dimensional Surface Raman Imaging Of A Roughened Iron Electrode In Saline Water, Pei-Gen Cao, Jian-Lin Yao, Jun-Wei Zheng, Bin Ren, Ren-Ao Gu, Zhong-Qun Tian Feb 2001

Two-Dimensional Surface Raman Imaging Of A Roughened Iron Electrode In Saline Water, Pei-Gen Cao, Jian-Lin Yao, Jun-Wei Zheng, Bin Ren, Ren-Ao Gu, Zhong-Qun Tian

Journal of Electrochemistry

The analysis of the composite and distribution of iron oxide due to pit corrosion in saline solutions (3.4% NaCl) is of great importance. Many electrochemical methods, XPS, and other photoelectronic techniques have been applied to this domain. Surface enhanced Raman scattering (SERS) spectroscopy can provide the vibrational information of surface species with high sensitivity and is very useful in the study of surface chemistry of iron. Notwithstanding, the application of SERS in iron corrosion is hampered for its SERS-inactivity. Efforts have been devoted to extend the use of SERS to the study of iron.


The Charge Transfer Effect Of Sers Induced By The Electrochemical Hydrogen Evolution Reaction, Feng-Ming Liu, Qi Han, Yan-Xia Chen, Qi-Ling Zhong, Bin Ren, Zhong-Qun Tian Feb 2001

The Charge Transfer Effect Of Sers Induced By The Electrochemical Hydrogen Evolution Reaction, Feng-Ming Liu, Qi Han, Yan-Xia Chen, Qi-Ling Zhong, Bin Ren, Zhong-Qun Tian

Journal of Electrochemistry

As one of the important mechanisms of SERS, the charge transfer (CT) enhancement requires the strong interaction of the adsorbed species with the substrate in order to permit the transition of charge between the metal Fermi level (energy state) and the molecular orbital. The high enhancement needs the match of the energy gap between the Fermi level (or surface state) and the orbital energy level of the adsorbed molecules with the energy of the incident light. The electrode Fermi level is usually adjusted by the applied potential to satisfy the CT resonance. For the electrochemical reaction process, the frontier orbital …


How Can Direct Mthanol Fuel Cell Benefit From Carbonate Media, Lin Zhuang, Yang Wang, Jun-Tao Lu Feb 2001

How Can Direct Mthanol Fuel Cell Benefit From Carbonate Media, Lin Zhuang, Yang Wang, Jun-Tao Lu

Journal of Electrochemistry

The kinetics of methanol oxidation and oxygen reduction in 0.5 mol/L K2CO3 were compared with those in 0.5 mol/L H2SO 4. Experiments revealed that carbonate media could be more beneficial to direct methanol fuel cell(DMFC). Firstly, both electrode reactions show better performance in the carbonate than in the acid; secondly, materials other than noble metals become possible to be used as the anodic and cathodic catalysts; thirdly, the potential dectease caused by methanol crossover could be depressed by using metal oxide catalysts not stable in acid, such as MnO2.


Synthesis Of Limn2O4-ΔClΔ Cathode Material By Like-Sol-Gel Methode, Zhao-Yong Chen, Yi He, Xing-Quan Liu, Zhi-Jie Li, Zuo-Long Yu Feb 2001

Synthesis Of Limn2O4-ΔClΔ Cathode Material By Like-Sol-Gel Methode, Zhao-Yong Chen, Yi He, Xing-Quan Liu, Zhi-Jie Li, Zuo-Long Yu

Journal of Electrochemistry

LiMn2O4-δClδ was synthesized by like sol gel methode, with calculated LiOH·H2O, Mn(No3)2⋅6H2O and LiCl·H2O, and made electrochemical test with these compounds as positive materials. Result demostrated that LiMn2O4-δClδ cathode material has exellent stability and nearly no capacity loss after reaching stability.


Raman Spectroelectrochemical Study On Bioactive Molecules, Xiao-Wei Cao, Hai-Feng Yang, Zhe Su Meng Xiao Yun Wang, Xia-Qin Wu, Zong-Rang Zhang Feb 2001

Raman Spectroelectrochemical Study On Bioactive Molecules, Xiao-Wei Cao, Hai-Feng Yang, Zhe Su Meng Xiao Yun Wang, Xia-Qin Wu, Zong-Rang Zhang

Journal of Electrochemistry

Electron-transfer reaction is known to be one of the key reactions for generating biological functions. Mechanism revelation at a molecular level of such kind reactions is to be very helpful for us to understand life essence. In fact, surface enhanced Raman scattering (SERS) is one of the most powerful tools for the study on metal-electrolyte and metal-vacuum interfaces since 1970's. Moreover, Raman spectroscopic study in enzymology has provided attractive results during last twenty-five years.