Engineering Commons^™

The Effect Of Calcium On The Properties Of Molybdenum Nitride Electrode, Yun-Gui Zhu, Xue-Liang Li, Dao-Rong Lu, Jian-Bo He, Ji-Huai Xia

Journal of Electrochemistry

The effect of calcium on the properties of molybdenum nitride film electrode wasstudied by using XRD, SEM and cyclic voltammetry. The results show that the specific electriccapacity and the voltage operating range of electrode vary with the concentration of additive in thedipping solution. At the optimum concentration of additive in the dipping solution, the specificelectric capacity of the electrode is 2.1 times as large as that of the electrode prepared in the dipping solution without additive, and the voltage operating range of electrode is increased by 0.11 V. The active mechanism of calcium on the properties of film electrode suggested …

Corrosion Behavior Of Titanium In Fgd System, J-C Lin, T-L Chang, C-T Dung, S-L Lee, S-D Chyou, S-D Guo

Journal of Electrochemistry

In-situ corrosion test of titanium in flue gas desulfurization(FGD) system has been studied. Specimens of commercial Ti alloy have been put in four different locations (i. e , cooler, pre-scruber, absorber and heater) of the FGD system for 271 days. The corrosion rate is very low (i.e.<1 mpy) in all locations. Almost no corrosion can be found in the prescruber(0 mpy), but a sensible corrosion rate is estimated in the heater (0.58 mpy). Examination through SEM, all the specimens are subject to pitting corrosion except those in the prescruber. ESCA analysis indicates that the surface film for the specimen in prescruber is calcium carbonate, but titanium nitrate for the specimen in heater. Cyclic anodic potentiodynamic polarization (CAPP) of titanium in aerated and deaerated green solution provides an interpretation on the corrosion behavior of the titanium in the FGD system.

Comparison In Surface Enhanced Raman Scattering On Salicylideneamine Between Silver And Gold Colloid And Silver Mirror Substrate, Bing Zhao, Yukihiro Ozaki

Journal of Electrochemistry

This work studied the potential difference and galvanic currents on particulate contamination of the abrasive on the patterned surface and on corrosion behaviors of TiN and W. The polarization curves of TiN and W were, respectively, obtained in 0.01mol/L KNO₃ solutions in the absence and presence of three typical oxidants (H₂O_2, KIO₃, Fe(NO₃)₃) by DC polarization technique. The corrsion potentials and galvaniccurrents were measured when TiN and W were placed in a specially designed electr-chemical cell to form electro-couple. The preliminary results revealed that the corrosionrate of TiN-W electro-couple significantly …

Performance Of A Direct Methanol Fuel Cell, Zhao-Bin Wei, Jian-Guo Liu, Ya-Guang Jiao, Wei-Jiang Zhou, Wen-Zhen Li, Li-Kang Chen, Qin Xin, Bao-Lian Yi

Journal of Electrochemistry

A direct methanol fuel cell with 9cm² active area consists of Pt-Ru/C anode ,Pt/Ccathode and Nafion 115 membrane. The effect of operating conditions: methanol solution concentration, oxygen pressure and cell temperature on the cell performances was investigated. The results show that performance of single cell was enhanced by increasing oxygen pressure and celltemperature ,and a maximum power density 75 mW/cm² was obtained in the range of 250-300mA/cm² current density, 0.2 MPa oxygen pressure, 1.0 mol/L methanol concentration and 75 ℃ cell temperature. When cell operating at room temperature, a relatively low, but a stable performance of cell …

The Effect Of Preparation Condition On The Photoelectrochemical Performance Of Both The Pani Film And Tio2-Pani Composite Film On Au, Huai-Guo Huang, Hong-Ping Zhang, Zhi-Xin Zheng, Yan-Yan Xi, Ling-Ling Wu, Zhong-Hua Lin

Journal of Electrochemistry

Both the PANI (polyaniline) film and TiO₂-PANI composite film on the PATP(paminothiophenol)/Au substrate were obtained under different preparation condition by electrochemical methods, and their photoelectrochemical performances were alo studied. The resultsshowed that the photoelectrochemical performances of the films depend deeply on the comditionsof preparation. The self-assembling of PATP favors the adhesion of PANl. The partially-oxidizedPANI has a greater photoelectrochemical response than that of the reduced PANI and oxidized PANl. There is an optimum of film thickness for the photoelectrochemical performance of PANI film. Heat treating is in favor of the photoelectrochemical performance of TiO₂, but decreases …

The Dependence Of Relative Enhancement Of Sers Bands On Temperature, Ling Huang, Jian Shen, Tsing Yu, Qing-Jin Meng

Journal of Electrochemistry

The adsorption and binding behavior of 2,5-dimercapto-1,3,4-thiadizole(DMTD) on silver surface was studied by near-infrared Fourier Transfer surface enhanced Raman scattering(NIR FT-SERS) technique. It was found that the relative intensities of the SERS bands change regularly with the increasing of temperature, which suggests the transformation of the tautomers or the re-orientation of DMTD molecules in the surface layer.

Study On Corrosion Resistance Of Electroless Nickel Composite Coatings, Tsong-Jen Yang, Meng-Feng Jou

Journal of Electrochemistry

The eletroless nickel composite coating was prepared by uniform dispersion of diamond (or PTFE) particles throughout electroless nickel deposition. Corrosion resistance of composite coating in 3.5% NaCl aqueous solution was investigated by electrochemical analysis, dipping test and salt spray test. The results showed that the corrosion resistance of composite coating was inferior to that of electroless nickel coating if small amount of particles was added to the composite coating. Microsturctural analysis by SEM, AES, XRD, and EPMA indicated that the distribution of phosphorus is not homogeneous in the composite coating. The phosphorus_rich region acts as microcathode, however, the phosphorus-lean region …

Preparation Of Ti-Based Nanocrystalline Tio2 Film Electrode With High Activity, Dao-Bao Chu, Guang-Xia Shen, Xing-Fu Zhou, Chang-Jian Lin, Hua-Shui Lin

Journal of Electrochemistry

The potentiostatic electrosynthesis of Ti(EtO)₄ was studied by anodic dissolution of metal titanium(TA1) in solution of 0.005 mol·L^-1 (EtO)₄NBr in the ethanol (AR) in the presence negligible CH₃COCH₂COCH₃. The Ti-based nanocrystalline TiO₂ Film electrode (Ti/nano-TiO₂) was prepared by sol-gel method. By TEM, SEM and XRD, it has been shown that the anatase particle of TiO₂ was 10～35 nm in diameter and the film was 0.5 μm in thickness. The nanocrystalline film was composed of a three-diminsional network of interconnected particles. Reodx behavior and electrocatalytic activities of …

New Progress In Studies Of Lithium Nickel Oxide As Positive Electrode Materials Of Lithium Ion Batteris, Han-San Liu, Yong Yang, Zhong-Ru Zhang, Zu-Geng Lin

Journal of Electrochemistry

Lithium nickel oxide as the positive electrode of lithium ion batteries has aroused more and more interests.This paper reviews the recent reserches on synthesis and element-substitution of LiNiO₂ cathode material,and summarizes the intrinsical relationship between properties and sturcture of the material.The developments of new synthesis methods and mutilsubstitution of the material are expecting to be studied in the future research.

Electrochemistry Characteristic Of Carbon Steel Under Biofilm And Sulfide Film, Ze-Hua Dong, Xing-Peng Guo, Jia-Shen Zheng, Li-Ming Xu

Journal of Electrochemistry

Wire Beam Electrode (WBE) made of Q235 carbon steel was applied to study theheterogeneous corrosion beneath biofilm formed by Sulfate Reducing Bacteria (SRB) in cultureand sulfide film in solution with 1% NaCl and 300 mg/L⋅S^2-. The potential, galvanic density mapping, as well as polarization curve and Electrochemical Impedance Spectrum (EIS) were measured to predict the localized corrosion under biofilm and sulfide film. As a result, the mappingshowed the potential fluctuation on the WBE suface decreased over time due to the conductivityof the biofilm and sulfide film. Therefore, the potential mapping could not be a criterion of localized corrosion …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 17, Number 8, May 2001, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

An eight page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Overview Of Acousto-Optic Bistability, Chaos, And Logical Applications, Monish Ranjan Chatterjee, Erol Sonmez

Electrical and Computer Engineering Faculty Publications

An overview is presented of the key results in the field of acousto-optic bistability in the past two decades. It is shown that the basic acousto-optic bistable device may be described as a nonlinear dynamical system which satisfies a quadratic map. Thereafter, details are presented of several analytical methods, computer modeling approaches, including the SPICE circuit modeling technique, and experiments that have been used to understand the phenomenon.

Extensions to logical and digital applications are also discussed.

Overview Of Fuzzy Logic, Mohamed Trabia

Mechanical Engineering Faculty Presentations

The presentation includes a brief introduction to fuzzy logic and fuzzy logic controllers. These concepts are illustrated by an example of an autonomous vehicle controller.

Comparison Of Two Distributed Fuzzy Logic Controllers For Flexible-Link Manipulators, Linda Z. Shi, Mohamed Trabia

Mechanical Engineering Faculty Presentations

The paper suggests that fuzzy logic controllers present a computationally efficient and robust alternative to conventional controllers. The paper presents two possible structures for the distributed fuzzy logic controller of a single-link flexible manipulator. A linear quadratic regulator method is used to prove the effectiveness of fuzzy logic controllers.

Design Of Fuzzy Logic Controllers For Optimal Performance, Mohamed Trabia

Mechanical Engineering Faculty Presentations

While fuzzy logic controllers are generally robust, the performance of a system whose behavior is not well understood, or that has a large number of coupled inputs and outputs, may be less than optimal. In this paper, nonlinear programming techniques are used to improve the performance of a fuzzy logic controller for navigating an autonomous vehicle.

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Yitung Chen, Darrell Pepper, Randy Clarksean

Fuels Campaign (TRP)

UNLV investigators will evaluate and select a process for the melt casting of metallic fuel pins that contain volatile actinides. This work will be performed with the guidance of Argonne National Laboratory (ANL) engineers to insure that their knowledge and experience benefits the project. The research to be conducted during year one will center on selecting, evaluating, and modeling potential alternatives to the traditional injection casting process used at ANL. Processing conditions will be analyzed, basic models utilized, and detailed heat and mass transfer models will be developed to analyze the most promising processes. The goal of the first year …

Observations Of Volcanic Clouds In Their First Few Days Of Atmospheric Residence: The 1992 Eruptions Of Crater Peak, Mount Spurr Volcano, Alaska, William I. Rose, Gregg J. Bluth, David J. Schneider, Gerald G. J. Ernst, Colleen M. Riley, Lydia J. Henderson, Robert G. Mcgimsey

Department of Geological and Mining Engineering and Sciences Publications

Satellite SO2 and ash measurements of Mount Spurr’s three 1992 volcanic clouds are compared with ground‐based observations to develop an understanding of the physical and chemical evolution of volcanic clouds. Each of the three eruptions with ratings of volcanic explosivity index three reached the lower stratosphere (14 km asl), but the clouds were mainly dispersed at the tropopause by moderate to strong (20–40 m/s) tropospheric winds. Three stages of cloud evolution were identified. First, heavy fallout of large (>500 μm) pyroclasts occurred close to the volcano (vent) during and immediately after the eruptions, and the cloud resembled an advected …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 17, Number 7, April 2001, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

An eight page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Santa Clara Magazine, Volume 42 Number 4, Spring 2001, Santa Clara University

Santa Clara Magazine

3 - EL SOL SHINED IN 1968 STUDENT ELECTIONS By Adam Breen. During the 1968 campus elections, an electrical engineering student felt the student body was too apathetic, so he ran for dictator to spur interest. He could have been king, but instead had himself "assassinated " for a greater cause.

12 - DOUBLE LIVES By Susan Vogel. An economic boom in Silicon Valley created opportunities, jobs, and wealth-but those who work here often can't afford to live here. What are employees and employers doing about it?

16 - THE GLACIER PRIEST By Jeff Kunkel. Bernard Hubbard, S.J., was more …

Statistical Properties Of Maximum Likelihood Estimates For Accelerated Lifetime Data Under The Weibull Model, Mahmoud A. Yousef

Doctoral Dissertations

Pipe rehabilitation liners are often installed in host pipes that lie below the water table. As such, they are subjected to external hydrostatic pressure. The external pressure leads to early deformation in the liners, which could ultimately lead to its failing or buckling before its expected service lifetime is achieved. Experiments involving long term buckling behavior of liners are typically accelerated lifetime testing procedures. In an accelerated testing procedure a liner is subjected to a constant external hydrostatic pressure and observed until it fails or for a certain time, t whichever occurs first. Liners that do not fail at time …

Mitigation Of Water Vapor Interference For Infrared Polarization-Modulated Gas Filter Correlation Radiometry, David K. Lockwood

Electrical & Computer Engineering Theses & Dissertations

Gas filter correlation radiometry (GFCR) is a high-resolution, high-specificity technique for sensing gaseous species. A variation of absorption spectroscopy, GFCR has a long-proven record on orbital platforms for quantitative measurements of atmospheric constituents, as well as common usage in ground-based sensing applications. PMGFCR (Polarization-modulated GFCR) is a recent refinement of the technique with several advantages over the traditional method, including reducing the number of photodetectors required, increased sensitivity, and elimination of moving parts.

To date, no infrared remote sensors have successfully measured nitric oxide (NO) in vehicle exhaust due to spectral overlap by strong water vapor (H₂O_{v …}

Unsteady Flow Model For An Irrigation Canal Network, Talaat Taher El Gamel

Civil & Environmental Engineering Theses & Dissertations

A mathematical model is developed to route unsteady flow through an irrigation canal network. The model is designed to handle branches, lateral inflow and outflow, sluice gates, and various boundary conditions. The model is developed for use on a personal computer. A specific irrigation canal network in Egypt is used as a case study to verify the model, and the results are presented. Full documentation is included in the appendix.

Coherent Differential Absorption Lidar For Combined Measurement Of Wind And Trace Atmospheric Gases, Grady James Koch

Electrical & Computer Engineering Theses & Dissertations

A lidar system was developed for making combined range-resolved measurements of wind speed and direction, water vapor concentration, and carbon dioxide concentration in the atmosphere. This lidar combines the coherent Doppler technique for wind detection and the differential absorption lidar (DIAL) technique to provide a multifunctional capability. DIAL and coherent lidars have traditionally been thought of and implemented as separate instruments, but the research reported here has shown a demonstration of combining the coherent and DIAL techniques into a single instrument using solid-state lasers. The lasers used are of Ho:Tm:YLF, which operates at a wavelength of 2 μm. This wavelength …

2001 - The Sixth Annual Symposium Of Student Scholars

Symposium of Student Scholars Program Books

The full program book from the Sixth Annual Symposium of Student Scholars, held on March 30, 2001. Includes abstracts from the presentations and posters.

Modeling The Transient Rate Behavior Of Bandwidth Sharing As A Hybrid Control System, Kang Li, Molly H. Shor, Jonathan Walpole, Calton Pu

Computer Science Faculty Publications and Presentations

This paper uses hybrid control to model a problem of computer network systems, the dynamic behavior of bandwidth sharing among competing TCP traffic. It has been well known in the computer network community that well-behaved (TCP-friendly) congestion control mechanisms are crucial to the robustness of the Internet. Congestion control determines the transmission rate for each flow. Right now, most TCP-friendly research focuses only on the average throughput behavior without considering how the data is sent out in the short-term (e.g. bursty or smooth). However, recent experimental results show that short-term rate adjustments can change the bandwidth sharing result. Therefore, it …

Infosphere Project: An Overview, Calton Pu, Jonathan Walpole

Computer Science Faculty Publications and Presentations

We describe the Infosphere project, which is building the systems software support for information-driven applications such as digital libraries and electronic commerce. The main technical contribution is the Infopipe abstraction to support information flow with quality of service. Using building blocks such as program specialization, software feedback, domain-specific languages, and personalized information filtering, the Infopipe software generates code and manage resources to provide the specified quality of service with support for composition and restructuring.

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 17, Number 6, March 2001, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

An eight page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Bistable Operation Of A Two-Section 1.3-Mm Inas Quantum Dot Laser—Absorption Saturation And The Quantum Confined Stark Effect, Xiaodong Huang, A. Stintz, Hua Li, Audra Rice, G. T. Liu, L.F. Lester, Julian Cheng, K.J. Malloy

Faculty Publications

Room temperature, continuous-wave bistability was observed in oxide-confined, two-section, 1.3- m quantum-dot (QD) lasers with an integrated intracavity quantum-dot saturable absorber. The origin of the hysteresis and bistability were shown to be due to the nonlinear saturation of the QD absorption and the electroabsorption induced by the quantum confined Stark effect.

Moving Towards Massively Scalable Video-Based Sensor Networks, Wu-Chi Feng, Jonathan Walpole, Calton Pu, Wu-Chang Feng

Computer Science Faculty Publications and Presentations

Networking and computing technologies are becoming advanced enough to enable a wealth of diverse applications that will drastically change our everyday lives. Some past examples of these developments include the World Wide Web and wireless data networking infrastructures. As is quite obvious, the World Wide Web has enabled a fundamental change in the way many people deal with day-to-day tasks. Through the web, one can now make on-line reservations for travel, pay bills through on-line banking services, and view personalized on-line newscasts. More recently, developments in wireless technologies have enabled anywhere, anytime access to information over wireless medium. As wireless …

An Objective Evaluation Of Four Sar Image Segmentation Algorithms, Jason B. Gregga

Theses and Dissertations

Because of the large number of SAR images the Air Force generates and the dwindling number of available human analysts, automated methods must be developed. A key step towards automated SAR image analysis is image segmentation. There are many segmentation algorithms, but they have not been tested on a common set of images, and there are no standard test methods. This thesis evaluates four SAR image segmentation algorithms by running them on a common set of data and objectively comparing them to each other and to human segmentors. This objective comparison uses a multi-metric a approach with a set of …