Engineering Commons^™

Study On The Gas Generation In Different Charging Voltage During Formation Process In Polymer Lithium-Ion Battery, Li Huang, Ming-Gang Jin, Hui-Qun Cai, Ming-Sen Zheng, Quan-Feng Dong, Jin-Kua You, Zu-Geng Lin

Journal of Electrochemistry

The gases of polymer lithium-ion battery (PLI) generated under different voltages during the first charging process were examined by means of gas chromatography (GC), and the mechanism of the gas generation was discussed. The electrolyte used in batteries was 1 mol/L LiPF₆-EC～DMC～EMC=1∶1∶1(in volume). The results showed that when the charging voltage is less than 2.5 V,  the main component of generated gases are H₂ and CO₂, and when the charging voltage is 2.5 V, EC begins to decompose. Due to the decomposition of EC, the main generated gas is C₂H₄ when the …

Application Of Hydrogen-Storage Alloy Electrode In Electrochemical Reduction Of Glucose, Hui Chen, You-Gen Tang, Zheng Tang

Journal of Electrochemistry

Electrolysis of glucose was performed at constant potential using hydrogen-storage alloy as catalytic reduction electrode. It was found that the superficial treatment and activation of hydrogen-storage alloy powder had obvious effects on improving the current efficiency of sorbitol. Under the optimums, current efficiency of sorbitol by electrolyzing glucose was over 94%. The yield of sorbitol was over 80%, the lifespan of electrode was tested and analyzed, the ways of regeneration were discussed.

Pitting Characteristics Of Cu-50/60ni Alloys In Nacl Solution, Jie Li, Yan Niu, Shi-Zhe Song

Journal of Electrochemistry

The pitting behavior of nanocrystalline Cu-50/60Ni and cast Cu-50/60Ni alloys in different concentration of NaCl solutions has been investigated using various electrochemical methods. A logarithmic dependence of the passive breakdown potential (E_b), which is established using dynamic potential scan technic, on the chloride concentration was obtained for both alloys. The study on pitting propagation of both alloys was carried out using potential step chronocurrent method. As long as pits initiate on both alloys, the pits on nanocrystalline Cu-Ni alloys develop faster than those on cast alloys.

Preparation And Properties Of The Composite Microporous Pvdf-Hfp/Sio2 Based Polymer Electrolytes, Bao-Wen Zhang, Lu Qi, Hui Hen, Xiao-Hui Zhu, Li-Yan Liu, Yun-Xiang Ci

Journal of Electrochemistry

Microporous PVDF-HFP/SiO₂ film were prepared using a solvent/nonsolvent method-phase inversion method and the volatile plasticizers DMC, DEC or PC. The conductivity of the films increased pore volume measured by a nonsolvent uptake method. The conductivity of 1.86×10^-3 S⋅m^-1 were obtained using the liquid electrolyte LiPF₆(1 M) in EC/DMC (1:1).

Study On Degradation Of Phenol By Electrochemical Oxidation, Yue-Li Liu, Hong-Hua Ge

Journal of Electrochemistry

Electrochemical oxidation of phenol was carried out by the Dimensionally Stable Anodes (DSA) electrode, which has been discarded as waste by alkali chloride factory. The result indicates that a good phenol removal can be obtained under certain phenol concentration by the DSA electrode. The key factor in effecting phenol removal of electrochemical oxidation is applied current density, the following factors are pH, electrolyte concentration and phenol concentration. After experiments, the optimal test conditions are 30 mA/cm², pH 10, electrolyte concentration 10 mg/L, phenol concentration 10 mg/L.67% CODcr removal and 90% absorbance removal are gained by electrochemical oxidation for …

Electrochemical And In-Situ Scanning Tunneling Microscopy Studies On The Sb Underpotential Deposition On Cu Single Crystal Electrodes, Ji-Hong Wu, Jia-Wei Yan, Jing Tang, Wen-Yun Hu, Bing-Wei Mao

Journal of Electrochemistry

We report electrochemical and in-situ STM studies on Sb UPD onto Cu(111) and Cu(100) electrode surfaces in HClO₄ and H₂SO₄ solutions. The results indicate that the electrode surface structure as well as anion can considerably influence Sb UPD. Sb UPD on Cu(100) forms open adlayer structures, which is accompanied by surface alloying due to the more open structure of the (100) surface, On Cu(111), a more compact Sb adlayer is formed instead. Anion adsorption influences the dynamics as well as the adlayer structure of Sb UPD. Owing to the strong adsorption of SO₄^2-, …

Study On Electrochemical Behavior Of Sus316l Stainless Steel After Surface Modification, Cheng-Hao Liang, Liang Guo, Wan Chen, Jing-Xiao Liu

Journal of Electrochemistry

The surface modification for SUS316L stainless steel was carried out by electroplating Rh, ion beam assisted deposition Ta₂O₅ and sol-gel-derived TiO₂. In Tyrode's stimulated body fluid, the surface modified samples had been investigated with electrochemical techniques. The results indicated that the electrochemical stability and dissolution were improved significantly after surface modification. Moreover, as to ion beam assisted deposition Ta₂O₅ and Sol-gel-derived TiO₂ film, the metal's d orbit electron holes filled up by the oxygen electrons made against the adsorption of hydrogen. Thus the cathode process, which is controlled by the hydrogen …

The Study Of Green Corrosion Inhibitors For Mild Steel 907 In Natural Seawater Environment, Ping Gong, Min Du, Qing-Zhang Wang, Zhen-Jun Mu

Journal of Electrochemistry

Nine green compounds, including calcium gluconate, zinc gluconate, zinc sulfate, garlic, ACUSOL 445N, OS-15, APG, OCTA and STPP were selected according to the methods of molecule design and function groups prune. The functions of combined corrosion inhibitors mixed by the compounds mentioned above for mild steel in seawater were studied in this work using the methods of polarization curve and weight-loss.The best weight ratio and distinct synergistic effect of calcium gluconate, zinc sulfate and OCTA were studied by Latin experiment. The afgereffects of the best weight ratio corrosoin inhibitor were studied by subsection experiment. In this way, a kind of …

Optimizing Catalyst Layer Composition Of Pemfc By Orthogonal Method, Ming-Hua Wang, Xin-Jian Zhu, Guang-Yi Cao, Sheng Sui, Qing-Chun Yu, Ming-Ruo Hu, Zheng-Yu Fan

Journal of Electrochemistry

The optimal composition of catalyst layer in a PEMFC electrode was studied through orthogonal method. It was showed that the performance of hydrophilic electrodes, in which there is no PTFE in the catalyst layer, were more favorable than that of hydrophobic electrodes. According to this condition, the power density of PEMFC attained 0.37 w·cm^-2 when the Nafion loading was 1.4 mg·cm^-2, and the Pt loading was 0.4 mg·cm^-2 in the catalyst layer, using H₂ as fuel and air as oxidant both at atmospheric pressure. Additionally, the results showed that increasing Pt loading in Pt/C catalyst …

The Study On Carbon Nanotube-Loaded Pt Catalysts For Proton Exchange Membrane Fuel Cells, Hong Zhu, Feng-Juan Ge, Xiao-Hong Kang, Yu-Guo Yang, Yun-Hua Xu

Journal of Electrochemistry

Carbon nanotube-supported-platinum (Pt/CNTs) and carbon-supported-platinum (Pt/C) catalysts were synthesized by in-situ chemical reduction. They were analyzed using TEM and XRD, then made into electrodes to be part of assemable PEMFC for the performence tests. The resulted show that Pt clusters in both catalysts are of small particle size (about 4nm), and Pt/CNTs exhibits a higher catalytic activity than Pt/C.

Effect Of Dspp Al2O3 On Electrical Properties Of Polymer Electrolyte, Hai-Fen Xie, Xiao-Xiang Sun, Yi-Pin Wang, Guang-Yuan Li

Journal of Electrochemistry

The PEO-NaSCN polymer solid electrolytes by adding dispersed second phase particles (DSPP) of Al₂O₃ were studied. The characteristics of solid electrolytes and conductivity values are dependent on DSPP Al₂O₃ sizes and its contents. It was found that when the Al₂O₃ sizes are less than 1 μm, which is a criticle size, the sample conductivities were larger than those of the pure PEO-NaSCN samples and when the Al₂O₃ sizes are larger than 1 μm then the sample conductivities are less then those of the pure samples. The maximum conductivity …

The Current Fluctuations Of Carbon Steel In Nano2-Nacl Solutions, Yu-Ming Tang, Yu Zuo

Journal of Electrochemistry

The characteristics of current fluctuations of A3 carbon steel in NaNO₂-NaCl solutions were studied with potentiostatic and potentiodynamic polarization methods. The steel remained stable passivation in 0.1 mol/L NaNO₂ solution without Cl^-. After NaCl was added in to the solution, current fluctuations with a characteristic of quick increase and slow decrease occurred, indicating quick dissolution and slow re-passivation of the metastable pits. The metastable pitting may cause accumulated corrosion damage around certain area and result in observable pits. With the increase of chloride concentration, the occurring potential for metastable pits Em rised, and peak values …

Adsorption And Oxidation Of Phenol Electrode Processes, Bao-Cheng Wang, Yan-Ping Sun, Jin-Hua Zhu

Journal of Electrochemistry

The electrochemical behaviors of platinum electrode were studied by cyclic voltammetry in 1mol/L sulfuric acid solution and 1mol/L sulfuric acid solution contained phenol. The adsorption characteristics of phenol and the intermediat on electrode surface have been discussed. The reactive reversibility and oxidation mechanism of phenol on electrode process have been investigated.The potential of characteristic adsorption was suggested. The various products woud be formed when the electrode potential was greater than the one of characteristic adsorption.

Hardware-Based Dynamic Storage Management For High-Performance And Real-Time Systems, Victor H. Lai

All Computer Science and Engineering Research

Most modern application programs depend on dynamic storage management to handle allocation and deallocation of memory. Unfortunately conventional software-based storage managers are relatively low performance due to the latency associated with accessing DRAM memory. Consequently, developers of programs with very specialized memory requirements, such a real-time systems, often choose to manage memory manually at the application-code level. This practice can greatly increase performance but it can also significantly complicate the development process. In this thesis we present the design, VHDL implementation and performance evaluation of hardware-based storage manager called the Optimized Hardware Estranged Buddy System (OHEBS). The OHEBS implements four …

Bomb-Pulse Chlorine-36 At The Proposed Yucca Mountain Repository Horizon: An Investigation Of Previous Conflicting Results And Collection Of New Data, Klaus J. Stetzenbach, Fred Phillips, Drew Coleman, Don Baepler, Amy J. Smiecinski

Publications (YM)

Previous studies by scientists at Los Alamos National Laboratory (LANL) and the United States Geological Survey (USGS) quantified ³⁶Cl/Cl to test for the presence of fast pathways at the proposed Yucca Mountain high-level nuclear waste repository. The goal of these studies was to determine whether or not fluids containing bomb-pulse ³⁶Cl/Cl traveled along fast travel pathways and reached the repository horizon, however, the two groups followed somewhat different procedures and produced conflicting results. The objective of this study is to attempt to determine the cause of the conflicting results and to obtain additional data to determine whether or …

Slides: Encana, John Moran

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: John Moran, Reservoir Engineer, Encana Oil & Gas

23 slides

Abstract: For companies doing directional drilling, what are the direct and indirect costs and benefits? When is it economical and what factors does industry take into account in making the decision to utilize directional drilling?

Notes From The Directional Drilling Workshop, University Of Colorado Boulder. Natural Resources Law Center

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

20 pages

"These notes were taken by one of our law students attending the workshop. They are not a verbatim transcript and they were not supplied by, and may not have been reviewed by, the speakers. There may be errors or gaps in the notes and for these we apologize in advance. Where the speaker provided an abstract of their talk, these are included and noted as such."

Slides: Directional Drilling: The Promise And The Peril, Alfred W. Eustes Iii

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Dr. Bill Eustes, Ph.D., P.E., Department of Petroleum Engineering, Colorado School of Mines, Golden, CO

63 slides

Abstract: What is it, where can it be done and how does it fit into full field development for oil and gas? This segment will set the foundation and bring everyone up to a basic level of understanding of the technology of directional drilling.

Slides: Untitled [British Petroleum], Rusty Riese

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Dr. Rusty Riese, Consulting Geologist, BP American Production Co.

6 slides

Abstract: For companies doing directional drilling, what are the direct and indirect costs and benefits? When is it economical and what factors does industry take into account in making the decision to utilize directional drilling?

Slides: Untitled [Western Resource Advocates], Mike Chiropolos

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Mike Chiropolos, Attorney, Western Resource Advocates

10 slides

Abstract: What are the environmental considerations involved with directional drilling? How should the NEPA analysis take this technology into account? When should it be analyzed as an alternative to conventional vertical drilling?

Slides: Untitled [Colorado Attorney General's Office], Carol Harmon

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Carol Harmon, Colorado Attorney General's Office

8 slides

Abstract: When does the State require directional drilling? Can landowners require it in Surface Use Agreements? What does Colorado's version of the accommodation doctrine mean for directional drilling?

Infrastructure For Performance Tuning Mpi Applications, Kathryn Marie Mohror

Dissertations and Theses

Clusters of workstations are becoming increasingly popular as a low-budget alternative for supercomputing power. In these systems, message-passing is often used to allow the separate nodes to act as a single computing machine. Programmers of such systems face a daunting challenge in understanding the performance bottlenecks of their applications. This is largely due to the vast amount of performance data that is collected, and the time and expertise necessary to use traditional parallel performance tools to analyze that data.

The goal of this project is to increase the level of performance tool support for message-passing application programmers on clusters of …

Melanoma And Seborrheic Keratosis Differentiation Using Texture Features, Srinivas V. Deshabhoina, Scott E. Umbaugh, William V. Stoecker, Randy Hays Moss, Subhashini K. Srinivasan

Chemistry Faculty Research & Creative Works

Purpose: To explore texture features in two-dimensional images to differentiate seborrheic keratosis from melanoma.

Methods: A systematic approach to consistent classification of skin tumors is described. Texture features, based on the second-order histogram, were used to identify the features or a combination of features that could consistently differentiate a malignant skin tumor (melanoma) from a benign one (seborrheic keratosis). Two hundred and seventy-one skin tumor images were separated into training and test sets for accuracy and consistency. Automatic induction was applied to generate classification rules. Data analysis and modeling tools were used to gain further insight into the feature space. …

Task Allocation Via Multi-Agent Coalition Formation: Taxonomy, Algorithms And Complexity, Hoong Chuin Lau, L. Zhang

Research Collection School Of Computing and Information Systems

Coalition formation has become a key topic in multiagent research. In this paper, we propose a preliminary classification for the coalition formation problem based on three driving factors (demands, resources and profit objectives). We divide our analysis into 5 cases. For each case, we present algorithms and complexity results. We anticipate that with future research, this classification can be extended in similar fashion to the comprehensive classification for the job scheduling problem.

Developing A Sensing System For The Measurement Of Oxygen Concentration In Liquid Pb-Bi Eutectic: Quarterly Progress Report (Aug. 01 – Oct. 31, 2003), Yingtao Jiang, Bingmei Fu

Transmutation Sciences Materials (TRP)

The experimental setup designed and manufactured in UNLV was shipped to LANL in early Aug. One student has been working in LANL to conduct the experiment since then. In the meantime, one new Ph. D. student has started to run the simulation for transport in oxygen mixing. In Oct., a professional has been hired to work in both experimental and the theoretical studies pertaining to the proposed work.

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Quarterly Progress Report (June 1 – August 31, 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

As indicated in the original proposal, the primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate target materials for applications in spallationneutron- target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including Alloy HT-9, Alloy EP 823 and Type 422 stainless steel. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these materials are being evaluated in aqueous environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Quarterly Progress Report (June 01 – Aug 31, 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This Alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this Alloy. The test material will be thermally treated prior to the evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (June 01 – August 31, 2003), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV), the Idaho State University (ISU), and the Los Alamos National Laboratory (LANL) is to evaluate the feasibility of determining residual stresses in cold-worked, plastically-deformed (bent), and welded materials using a nondestructive method based on positron annihilation spectroscopy (PAS). This technique uses γ-rays from a small MeV electron Linac to generate positrons inside the sample via pair production. This method is known to have capabilities of characterizing defects in thick specimens that could not be accomplished by conventional positron technique or other nondestructive methods. The generated …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Annual Progress Report (September 2002 – August 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading structural target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the molten lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this martensitic alloy. Three different heats of this material, produced by vacuum induction melting, were thermally treated to produce fully-tempered martensitic microstructure without any retained austenite (Table I). Cylindrical specimens were fabricated from the heat-treated round bars …

Storage Coalescing, Delvin C. Defoe

All Computer Science and Engineering Research

Typically, when a program executes, it creates objects dynamically and requests storage for its objects from the underlying storage allocator. The patterns of such requests can potentially lead to internal fragmentation as well as external fragmentation. Internal fragmentation occurs when the storage allocator allocates a contiguous block of storage to a program, but the program uses only a fraction of that block to satisfy a request. The unused portion of that block is wasted since the allocator cannot use it to satisfy a subsequent allocation request. External fragmentation, on the other hand, concerns chunks of memory that reside between allocated …