Engineering Commons^™

Preparation, Structure And Electrochemical Hydrogenation Of Carbon Nanotubes Supported Platinum Catalysts, Qing-Gang He, Xiao-Zi Yuan, Xian-Xia Yuan, Zi-Feng Ma

Journal of Electrochemistry

In this paper, Pt/CNTs catalyst was prepared and its electrocatalytic property was studied by obtaining cycling voltammetry curves (C-V) and Tafel curves. In addition, the XRD,XPS and TEM tests were carried out to determine the structure and composition of the catalysts. It can be found that the platinum loading has been increased significantly using a carbon nanotubes support. Dispersion of Platinum was better and gave more active sites. The electrochemical characteristic of Pt/CNTs was also more desirable than that of Pt/C catalys t(Johnson Matthey). In conclusion, carbon nanotubes can played a conspicuous role in "electrogenerative" processes of PEMFC hydrogenation reactor.

Study On The Electrochemical Impedance Spectroscopy (Eis) Of Al-Bronze At Different Anodic Potentials, Hui Yu, Sa-Ying Dong, Hai-Bo Xu, Ming-Xian Sun

Journal of Electrochemistry

The corrosion dissolution mechanism of Al-bronze has been investigated by Electrochemical Impedance Spectroscopy (EIS) at different anodic potentials. In the active region, the corrosion products are complex compounds of cupreous chloride and the diffusion of CuCl_2^- is the control process of electrochemical reaction. In the transition region, there exhibits two capacitance loops on EIS because CuCl and cupreous oxides films deposit on the electrode surface. In the limiting current region, an inductance loop appears on the EIS because the breakdown of the oxides film leads to serious pit corrosion.

Template Synthesis Of Highly Ordered Monocrystalline Metal Nanowire Arrays By A Two-Step Ac Electrodeposition, Juan Xiang, Jing-Hua Tian, Zi-Mian Ni, Zhi-Feng Huang, Bo Liu, Zhong-Qun Tian

Journal of Electrochemistry

The monocrystalline metal nanowire arrays were prepared by using a two-step AC electrodeposition in porous anodic aluminum oxide (AAO) template. The growth mechanism of nanowires was discussed. As a result, it has been found that the second voltage pulse has a considerable effect on the pore-filling ratio, the uniformity and the crystal structure, whereas the initial voltage pulse affects only the pore-filling ratio. Using the two-step AC electrodeposition, a highly ordered monocrystalline metal nanowire arrays with a pore-filling ration above 95% can be easily obtained.

The Interaction In Doping Lithium Of Carbonaneous Anode In Lithium Ion Battery, Chang-Guo Chen, Hong-Min Zhang, Jia Chen, Dan-Mei Yu

Journal of Electrochemistry

The quantum chemical DV-X_α method was used to calculate the lithium-doped models from one-Li-dopant to LiC₆ and LiC₂. It was found that Li⁺ has an tendency to attract electrons from the carbon plane through the C₆ hexagons lying above or below it by the graph of charge-density difference. It was shown that LiC₆ can exist steadily,while LiC₂ can not exist steadily.

Study On Determination Of Iodine Ion At Chitosan Modified Glassy Carbon Electrode, Bin Liu, Xiang-Ying Sun, Jin-Rui Xu

Journal of Electrochemistry

In this paper, a chitosan modified glassy carbon electrode was prepared by the method of covalent-bond reaction, and the anodic stripping voltammetric characteristics of iodine on the modified electrode was studied. The results showed that the modified electrode has higher adsorption and selectivity for I^- , and the sensitivity for I^-  has been much improved in 0.1 mol·L^-1 KH₂PO₄ solution (pH=4.0). The anodic stripping peak current of I^- on the modified electrode varied linearly with I^-  concentration in the range of 2.0×10^-6～2.0×10^-3 mol·L^-1, and the detection limit …

Formation And Characterization Of Water-Repellent Nano Tio2 Coating And Studying Its Anticorrosion Property, Guang-Xia Shen, Yi-Cong Chen, Chang-Jian Lin

Journal of Electrochemistry

Using ethyl acetoacetate (EAcAc) as a chelating agent, ultra fine TiO₂ sol is prepared. Nano-TiO₂ coatings are deposited on the 316L stainless steel by the dip-coating. Hydrothermal post-treatment leads to crack-free coatings. Meanwhile, the surface struture and properties was optimized. Self-assembly of Hetadecafluorodecyltrimethoxysilane (FSA-13) fabricates hydrophobic layers on the surface of the nano-TiO₂ coatings. Particle sizes of TiO₂ sol was analysed by zeta pals potential analysis, and surface morphology, structure and properties was characterized by contract angle instrument, XRD, and SEM technologies. The results have shown that the surface of coatings is porous, with approx. 375 …

Study Of Electrochemical Properties Of The Hydride Alloy Electrode Zrcr0.4Mn0.2V0.1Co0.1Ni1.2 At High Temperature, Song Li, Shi-Jun Ji, Jun-Cai Sun

Journal of Electrochemistry

Electrochemical properties of the hydride alloy electrode ZrCr_0.4Mn_0.2V_0.1Co_0.1Ni_1.2 at the different temperature have been investigated. The results showed that the alloy electrodes possessed the maximum discharge capacities 336 mAh/g and 298 mAh/g at 25 ℃ and 70 ℃ respectively. The activation process of the alloy at 70 ℃ became faster, and the alloy reached its maximum capacity in less than 4 cycles, while in 13 cycles at 25 ℃. The high rate capability increased from 55 % at 25 ℃ to 71% at 70 ℃ at 300 mA/g. It was worth …

Electrochemical Synthesis Of Ferrate(Vi) By Anodic Oxidation, Jia-Ju Xu, Jian-Ming Wang, Wei-Hua Yang, Cheng Chen, Jian-Qing Zhang

Journal of Electrochemistry

The ferrate(Ⅵ) was synthesized by electrochemical anodic oxidation. The effects of preparation conditions on the current yield of ferrate(VI) synthesis have been studied in this work. The experimental results showed that grey cast iron as an anodic material is suitable for electrochemical synthesis and NaOH solution as an electrolyte results in a higher current yield than KOH solution. The highest current yield was obtained at a current density (4.54) mA·cm^-2, temperature 20 ℃ and 14 mol·dm^-3 NaOH. In this case, a current yield of 68.5% was obtained by electrolysis for 1 h.

Substrates Made By Electrodeposition For Measuring Electrical Properties Of One Dimensional Nanomaterials, Jin-Xuan Liu, Juan Xiang, Zhong-Qun Tian, Bing-Wei Mao

Journal of Electrochemistry

A method to prepare alternating conducting/insulating substrates by electrodeposition-oxidation was established to facilitate I-E measurements of one-dimensional nanomaterial by CT-AFM. The prepared Au/CuO and HOPG/CuO substrates showed low roughness as well as high uniformity of the alternating conducting/insulating structure, Qualitative I-E measurements were performed on a single carbon nanotube attached to the two above-mentioned substrates, both showing metallic characteristics at room temperature and in air.

Studies On The Mechanism Of Electroreduction Of Oxalic Acid, Yu-Zhan Li, Xin Liu, Rui-Sheng Hu, Deng-Ping Gu

Journal of Electrochemistry

The electroreduction mechanism of oxalic acid on Pb electrode in Na₂SO₄ solution were investigated using high scan rate cyclic voltammetry and chronoamperometry. The dynamic parameters for the first step electron transter reaction of oxalic acid electroreduction by were determined. The corresponding reduction peak potentials of oxalic acid, glyoxylic acid and glycolic acid in the cyclic voltammogranis obtained in the same condition were compared, and the intermediate reduction products of oxalic acid were suggested. The results showed that oxalic acid is weakly absorbed on the lead electrode.

An Electrochemical Study Of The Effects Of Chelating Agents And Additives On Electroless Copper Plating, Xin Gu, Zhou-Cheng Wang, Chang-Jian Lin

Journal of Electrochemistry

In this study, ethylenediaminetetraacetic acid disodium salt (Na₂EDTA), triethanolamine(TEA), and 2,2′-dipyridine were adopted as chelating agents or additives in the electrolyte for electroless copper plating, and formaldehyde (HCHO) was as the reducting agent. Linear sweep voltammetry was applied to analyze the polarization behavior. The peak current of formaldehyde oxidation which increased by the addition of 2,2′-dipyridine is beneficial to formaldehyde oxidation in a specific range of concentration, While TEA decreased the peak current of formaldehyde oxidation. Two cathodic peaks due to copper(Ⅱ)reduction of TEA chelatation and copper(Ⅱ)reduction of EDTA chelatation were examined. EDTA increased the reduction peak current …

Electrodeposition Nanolaminated Growth Of Zinc, Ying Cao, Tian-Hui Shen, Jing-Yuan Yao, Gui-Fu Ding

Journal of Electrochemistry

Nanolaminated growth of the electrodeposition of zinc was studied. The structure and size of crystalline in zinc coatings were investigated by using FEG-TEM and XRD. The corrosion tests of the zinc deposition and the Coatings-Neutral salt spray test were performed, the capability in corrosion resistance of the nanolaminated growth was better than that of others.

Electrochemical Character Of Water Containing Gel Electrolyte And Its Preliminary Examination In Lithium Water Cell, Jing-Dong Liu, Wen-Ji Wang, Xin-Zheng Yi

Journal of Electrochemistry

AC impedance technique has been used to characterize the system of poly(methyl acrylic acid)-poly(methyl acrylic lithiumate)-glycerol (referred to as GPE).The results showed that the conductivity of GPE increased with increasing both temperature and its water content.The glass transition temperature of GPE polymer could be lowered by water. Its conducting characteristic was just like liquid electrolyte,The electrolysis of GPE was almost the same as the electrolysis of water. Its composition voltage was about 1.50V. The GPE has been used to manufacture lithium water cell. When the graphite was used as cathode, the cell could discharge continuously for 2 hours under constant …

Yucca Mountain Climate Technical Support Representative, Saxon E. Sharpe, Dick Reinhardt, Eric Smistad, Don Baepler, Amy J. Smiecinski

Publications (YM)

The principal investigator (PI), Saxon Sharpe, for Task ORD-FY04-012, DOE Cooperative Agreement DE-FC28-04RW12232, will serve as Yucca Mountain Climate Technical Support Representative for the Department of Energy (DOE) in a series of activities related to past, present, and future climate for the Yucca Mountain Project (YMP) climate program.

As stated in the Viability Assessment of a Repository at Yucca Mountain: “Climate and its changes over time directly affect system performance at Yucca Mountain.” Currently, information from climate studies is used in models that support the Total System Performance Assessment and Licensing Application. It is a model component of all key …

Proposal For No-Cost Extension And Re-Scope For Unlv Trp Project: Neutron Multiplicity Measurements For The Afci Program (Advanced Fuel Cycle Initiative), Denis Beller

Transmutation Sciences Physics (TRP)

The U.S. Advanced Fuel Cycle Initiative (AFCI) is a program to develop economic and environmental methods to reduce the impact of waste from commercial nuclear fuel cycles. One concept for near-complete destruction of waste isotopes from used nuclear fuel is accelerator-driven transmutation. High-power accelerators would be used to produce high-energy charged particles, which then collide with heavy metal targets to create a cascade of neutrons. These neutrons then cause a nuclear chain reaction in subcritical systems. Fission neutrons then transmute fissile waste isotopes as well as other problematic isotopes such as technetium-99 and iodine-129. To design these systems, complex reactor …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 20, Number 4, February 2004, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

An eight page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Camrit: Control-Based Adaptive Middleware For Real-Time Image Transmission, Xiaorui Wang, Huang-Ming Huang, Venkita Subramonian, Chenyang Lu, Christopher Gill

All Computer Science and Engineering Research

Real-time image transmission is crucial to an emerging class of distributed embedded systems operating in open network environments. Examples include avionics mission re-planning over Link-16, security systems based on wireless camera networks, and online collaboration using camera phones. Meeting image transmission deadlines is a key chal-lenge in such systems due to unpredictable network condi-tions. In this paper, we present the design, modeling, and analysis of CAMRIT, a Control-based Adaptive Middleware framework for Real-time Image Transmission in distributed real-time embedded systems. CAMRIT features a distributed feedback control loop that meets image transmission dead-lines by dynamically adjusting the quality of image tiles. …

Mapping Surface Polarization In Thin Films Of The Ferroelectric Polymer P(Vdf-Trfe)., Bradley W. Peterson, Stephen Ducharme, Vladimir M. Fridkin, Timothy J. Reece

Stephen Ducharme Publications

Pyroelectric Scanning Microscopy (PSM) has been developed to enable mapping of surface polarization in ferroelectric thin films, in particular the copolymer polyvinylidene fluoride trifluororethylene, or P(VDF-TrFE). The Chynoweth method for dynamically measuring pyroelectric current is employed in conjunction with a micropositioning system to construct two-dimensional images of the film polarization. These images have revealed enhancement of the polarization near the edges of the film below the average coercive field, with the center's polarization increasing thereafter to meet the edge value at saturation.

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 20, Number 3, January 2004, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

A ten page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Nebraska Summary: S508 Challenger Mt545b, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Using Web Services To Integrate Heterogeneous Simulations In A Grid Environment, J. Mark Pullen, Ryan Brunton, Don Brutzman, David Drake, Michael Hieb, Katherine L. Morse, Andreas Tolk

Computational Modeling & Simulation Engineering Faculty Publications

The distributed information technologies collectively known as Web services recently have demonstrated powerful capabilities for scalable interoperation of heterogeneous software across a wide variety of networked platforms. This approach supports a rapid integration cycle and shows promise for ultimately supporting automatic composability of services using discovery via registries. This paper presents a rationale for extending Web services to distributed simulation environments, including the High Level Architecture (HLA), together with a description and examples of the integration methodology used to develop significant prototype implementations. A logical next step is combining the power of Grid computing with Web services to facilitate rapid …

Santa Clara Magazine, Volume 46 Number 3, Winter 2004, Santa Clara University

Santa Clara Magazine

8 - AN ARTIST WITH A MISSION By Elizabeth Kelley Gillogly '93. In his latest series, Howard Anderson '71 created paintings of the 21 California missions.

10 - THE SPIRITUALITY OF GIFT GIVING By Tom Beaudoin. Is it possible to turn our gift giving into a spiritual exercise?

14 - RAISING ARIZONA By Susan Shea. Arizona Governor Janet Napolitano '79, a rising political star, uses the lessons learned at SCU to serve her state.

20 - LEAVING COMMUNISM BEHIND By Jane Curry. An SCU professor and Fulbright Scholar researches forgiveness and justice in post-communist Poland.

Operator-Based Semantics For Logic Programs, Pascal Hitzler

Computer Science and Engineering Faculty Publications

The question how knowledge can be represented by means of logic programs with negation has been a driving force for the field of non-monotonic reasoning. Implemented systems, known as answer set programming systems, have emerged recently and are currently being used in various application domains like the semantic web.

Intuitively, logic programs are being used for encoding commonsense reasoning, in particular the phenomenon that human reasoning tends to ”jump to conclusions” under incomplete knowledge. Formally, this kind of reasoning is described by interpreting the first-order syntax of logic programs in a more sophisticated way. This, in turn, is most easily …

A Book Management System Elibrary, Shanpeng Song

Theses Digitization Project

"eLibrary" is a book management software application that runs on Microsoft Windows platforms. The software incorporates a Windows Explorer like interface and XML/XSL to display book details. The purpose of this project is to build a full-featured, commerical-quality software package to help people manage their books (either printed or electronic). The goal is for eLibrary to be a complete solution for people who wish to build their own personal electronic library catalog.

Technology And Mathematics Standards: An Integrated Approach, Chris Merrill, Mark Comerford

Publications

The article focuses on the use of standards-based teaching and learning that has been gaining significant attention in the education world. State and national associations now base their specific subject area or discipline solely on standards, i.e., International Technology Education Association (ITEA), National Council of Teachers of Mathematics (NCTM), National Science Education Association (NSEA). Moreover, at the public school level, state boards of education are holding school districts accountable for teaching standards-based curricula. It is with the latter definition in mind that the authors created a standards-based, integrated technology and mathematics lesson using the design and construction of stair systems.

Land For Maine's Future Program: Increasing The Return On A Sound Public Investment, Richard Barringer, Hugh Coxe, Jack Kartez, Catherine Reilly, Jonathan Rubin

Economics and Finance

Maine is nowhere a more special place than in the quality of its landscape and the traditions of its land use. Among the mo st privately-owned of all the states, Maine’s natural diversity and beauty combine with its traditions of resource stewardship, open access, and appreciation of nature to distinguish it in the public mind and national imagination. In recent decades, however, these traditions have come under assault from the forces of economic and social change; and the people of Maine have responded. In 1986, Governor Joseph Brennan’s Special Commission on Outdoor Recreation recognized the growing threats to Maine’s natur …

Virtual Exploration Of A Cardiovascular System, Elke Moritz, Thomas Wischgoll, Joerg Meyer

Computer Science and Engineering Faculty Publications

No abstract provided.

Accuracy And Interferences For Enzyme-Linked Immunoassay Tests For Atrazine, Craig D. Adams, Hua Jiang, Michael Mcguire, Nicole Graziano, Alan Roberson, Michelle Frey

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Atrazine is one of the most commonly used herbicides in the United States, therefore it is a regulatory concern and is extensively monitored in the environment, especially in drinking water. Because of the higher costs of gas chromatography (GC) methods, utility managers and regulators are considering the increased use of enzyme-linked immunosorbent assay (ELISA) methods for monitoring atrazine. an ELISA test kit was recently approved by the US Environmental Protection Agency. the research in this article points out potential biases and inaccuracies that may occur with such test kits. ELISA test kits for atrazine are typically precise (repeatable) but often …

Adaptive Intelligent User Interfaces With Emotion Recognition, Fatma Nasoz

Electronic Theses and Dissertations

The focus of this dissertation is on creating Adaptive Intelligent User Interfaces to facilitate enhanced natural communication during the Human-Computer Interaction by recognizing users' affective states (i.e., emotions experienced by the users) and responding to those emotions by adapting to the current situation via an affective user model created for each user. Controlled experiments were designed and conducted in a laboratory environment and in a Virtual Reality environment to collect physiological data signals from participants experiencing specific emotions. Algorithms (k-Nearest Neighbor [KNN], Discriminant Function Analysis [DFA], Marquardt-Backpropagation [MBP], and Resilient Backpropagation [RBP]) were implemented to analyze the collected data signals …

Thermal Management, Beam Control,And Packaging Designs For High Power, Te-Yuan Chung

Electronic Theses and Dissertations

Several novel techniques for controlling, managing and utilizing high power diode lasers are described. Low pressure water spray cooling for a high heat flux system is developed and proven to be an ideal cooling method for high power diode laser arrays. In order to enable better thermal and optical performance of diode laser arrays, a new and simple optical element, the beam control prism, is invented. It provides the ability to accomplish beam shaping and beam tilting at the same time. Several low thermal resistance diode packaging designs using beam control prisms are proposed, studied and produced. Two pump cavity …