Engineering Commons^™

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …

Effects Of Aluminium And Tungsten Co-Doping On The Optical Properties Of Vo2 Based Thin Films, Cephas J Lyobha, Nuru R Mlyuka, Margaret E Samiji

Tanzania Journal of Science

Aluminium and tungsten co-doped vanadium dioxide (VO2:W:Al) thin films were deposited by DC reactive magnetron sputtering technique. In this work we report on the effects of aluminium and tungsten co–doping on the optical properties of vanadium dioxide (VO2) based thin films with a view of combining both increased luminous transmittance (Tlum) and lowered transition temperature (τc). The effect of aluminium and tungsten co-doping on semiconductor-metal transition of vanadium dioxide films was investigated and compared with tungsten doped and undopedVO2films. Spectral transmittances of the films were obtained using Shimadzu SolidSpec-3700 DUV UV-VIS-NIR spectrophotometer. The results revealed that the transmittance of tungsten …

Hall Effect Parameters Of Aluminium And Tungsten Co-Doped Vo2 Thin Films, Mohamed Mussa, Nuru R Mlyuka, Margaret E Samiji

Tanzania Journal of Science

The Hall Effect parameters of Al and W co-doped VO2 thin films were studied in order to explain the effect of co-doping on the electrical properties of thermochromic VO2 films. The carrier concentrations and conductivity of the films were found to increase with increase in temperature while carrier mobility decreased reaching a minimum around the transition temperature then slightly rose and became stable at high temperatures. Tungsten doped films displayed higher carrier concentrations and conductivity on both sides of the metal insulator transition and lower mobility compared to undoped and Al and W co-doped VO2 thin films.

Optimization Of Zinc To Tin Ratio In A Sol Gel Precursor Solution On The Growth And Properties Of Annealed Czts Thin Films, Justine John Tibaijuka, Margaret E Samiji, Nuru R Mlyuka

Tanzania Journal of Science

CZTS thin films were deposited by sol–gel spin coating method using precursor solutions prepared by dissolving copper acetate dihydrate, zinc acetate dihydrate, tin chloride and thiourea in methanol and monoethylamine then annealed in RTP furnace at 500 °C. Sol–gel precursor solutions were prepared with different Zn/Sn in a precursor solution and were annealed at different time intervals; and their effects on the optical and electrical properties of CZTS (Cu2ZnSnS4) films were investigated. The optical band-gap values were estimated to be between 1.30 and 1.88 eV while the absorption coefficients were in the range of 104 cm–1 in the visible region. …

Economic Potential For Distributed Manufacturing Of Adaptive Aids For Arthritis Patients N The U.S., Nicole Gallup, Jennifer Bow, Joshua M. Pearce

Department of Materials Science and Engineering Publications

By 2040, more than a quarter of the U.S. population will have diagnosed arthritic conditions. Adults with arthritis and other rheumatic conditions earn less than average yet have medical care expenditures that are over 12% of average household income. Adaptive aids can help arthritis patients continue to maintain independence and quality of life; however, their high costs limit accessibility for older people and the poor. One method used for consumer price reduction is distributed manufacturing with 3-D printers. In order to assess if such a method would be financially beneficial, this study evaluates the techno-economic viability of distributed manufacturing of …

Low Temperature Desiccants In Atmospheric Water Generation., Sunil Gupta

Electronic Theses and Dissertations

Surging global water demand as well as changes to weather patterns and over exploitation of natural water sources, such as ground water, has made potable water a critical resource in many parts of the World already – one rapidly heading towards a crisis situation. Desalination has been adopted as a solution – this is however energy intensive and impractical for most of the developing countries - those most in need of water. A renewable source of energy is solar thermal and solar photovoltaic. A plentiful source of water is the humidity in the atmosphere. This research is to push the …

A National Pragmatic Safety Limit For Nuclear Weapon Quantities, Joshua M. Pearce, David C. Denkenberger

Department of Materials Science and Engineering Publications

This study determines the nuclear pragmatic limit where the direct physical negative consequences of nuclear weapons use are counter to national interests, by assuming all unknowns are conservatively optimistic. The only effect considered is nuclear winter (“nuclear autumn” in the low weapons limits) and the resultant effects on the aggressor nation. First, the ability of low nuclear weapon limits is probed for maintaining deterrence in the worst-case scenario of attacking the most-populous nation. Second, the ability of aggressor nations to feed themselves is assessed without trade and industry resultant from a nuclear attack causing “nuclear autumn” (10% global agricultural shortfall). …

A Novel Approach To Analyzing Strain Heterogeneity In Polycrystalline Quartz Specimens Deformed At High Pressure And Temperature, Nolan Ambrose Regis

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rheological studies of rocks and minerals allow researchers to study the grain-scale deformation mechanisms that govern large-scale geologic processes from mountain building to mantle mixing. Deforming rock samples with high pressure and temperature apparatuses similar to the Griggs piston cylinder apparatus allows us to simulate deformation at depth. However, many apparatuses are limited to “cook-and-look” analysis and require modeling techniques to determine the evolution of deformation patterns found in experimental samples. A previous study used two-dimensional finite element models to analyze the development of stress and strain patterns in polycrystalline rocks. The study suggested rhythmic patterns in deformed rocks develop …

Design Optimization Of Polymer Heat Exchanger For Automated Household-Scale Solar Water Pasteurizer, David C. Denkenberger, Joshua M. Pearce

Department of Materials Science and Engineering Publications

A promising approach to reducing the >870,000 deaths/year globally from unsafe water is flow-through solar water pasteurization systems (SWPs). Unfortunately, demonstrated systems have high capital costs, which limits access for the poor. The most expensive component of such systems is the heat exchanger (HX). Thus, this study focuses on cost optimization of HX designs for flow-through SWPs using high-effectiveness polymer microchannel HXs. The theoretical foundation for the cost optimization of a polymer microchannel HX is provided, and outputs are plotted in order to provide guidelines for designers to perform HX optimizations. These plots are used in two case studies: (1) …

Prerequisites For Public Acceptance Of Waste-To-Energy Plants: Evidence From Germany And Indonesia, Uwe Lahl, Barbara Zeschmar-Lahl

Makara Journal of Technology

Construction of waste incinerators often encounters resistance from the public. The minimum requirements for the ac- ceptance of these installations include modern air pollution control (APC) technology and safe disposal of residues. Confidence in the statements of government and government agencies as well as on those who support is an important point of acceptance. Independent scientific bodies such as universities can help to make this happen. In the case of the installation of waste into energy (WtE), such scientific support can be the measurement of emissions and their evalua- tion. Many products that enter the waste stream contain heavy metals, …

A Preliminary Study Of Smithport Plain Bottle Morphology In The Southern Caddo Area, Robert Z. Selden Jr.

CRHR: Archaeology

This study expands upon a previous analysis of the Clarence H. Webb collection, which resulted in the identification of two discrete shapes used in the manufacture of the base and body of Smithport Plain bottles. The sample includes the Smithport Plain bottles from the Webb collection, and four new bottles: two previously repatriated specimens in the Pohler Collection, and two from the Mitchell site (41BW4) to test whether those specimens align morphologically with the Belcher Mound or Smithport Landing specimens. Results indicate significant allometry and a significant difference in Smithport Plain body and base shapes for bottles produced at the …

Advanced Nanoscale Characterization Of Plants And Plant-Derived Materials For Sustainable Agriculture And Renewable Energy, Mikhael Soliman

Electronic Theses and Dissertations

The need for nanoscale, non-invasive functional characterization has become more significant with advances in nano-biotechnology and related fields. Exploring the ultrastructure of plant cell walls and plant-derived materials is necessary to access a more profound understanding of the molecular interactions in the systems, in view of a rational design for sustainable applications. This, in turn, relates to the pressing requirements for food, energy and water sustainability experienced worldwide. Here we will present our advanced characterization approach to study the effects of external stresses on plants, and resulting opportunities for biomass valorization with an impact on the food-energy-water nexus. First, the …

Mitigation Of Environmental Hazards Of Sulfide Mineral Flotation With An Insight Into Froth Stability And Flotation Performance, Muhammad Badar Hayat

Doctoral Dissertations

"Today's major challenges facing the flotation of sulfide minerals involve constant variability in the ore composition; environmental concerns; water scarcity and inefficient plant performance. The present work addresses these challenges faced by the flotation process of complex sulfide ore of Mississippi Valley type with an insight into the froth stability and the flotation performance. The first project in this study was aimed at finding the optimum conditions for the bulk flotation of galena (PbS) and chalcopyrite (CuFeS₂) through Response Surface Methodology (RSM). In the second project, an attempt was made to replace toxic sodium cyanide (NaCN) with the biodegradable chitosan …

Energy Potentials Of Briquette Produced From Tannery Solid Waste, Olatunde Ajani Oyelaran, Faralu Muhammed Sani, Olawale Monsur Sanusi, Olusegun Balogun, Adeyinka Okeowo Fagbemigun

Makara Journal of Technology

The vast quantity of waste generated from industries is one of the serious outcomes of unplanned development, resulting into quantum of hazardous organic and inorganic waste generating daily. Proper waste management is a challenging issue that must be addressed adequately. This is, therefore, carried out with a view of assessing the energy and combustion quality of tannery solid waste with a view of converting them into briquettes for cooking, heating and small home industries and reducing the menace caused by tannery waste disposal. The results of the experiments showed that the combustion rate ranged between 0.171 and 0.217 g/min, the …

Development Of Starch-Polyvinyl Alcohol (Pva) Biodegradable Film: Effect Of Cross-Linking Agent And Antimicrobials On Film Characteristics, Aniket Satish More, Chandani Sen, Madhusweta Das

Journal of Applied Packaging Research

To satisfy the need of developing eco-friendly flexible antimicrobial packaging film with minimum use of synthetic chemical ingredients, the present study examined the efficacy of citric acid (CA) as cross-linking agent and essential oils (EOs), viz., cinnamon essential oil (CEO) and oregano essential oil (OEO) as natural antimicrobials in corn starch-polyvinyl alcohol (CS-PVA) film. Compared to film prepared from filmogenic solution (FS) containing 75 kg CS+8.75 kg PVA+24.6 kg glycerol per m³ FS, film additionally containing CA at 0.07 kg/kg CS indicated 95% higher ultimate tensile strength (UTS) and 27% lower water vapor permeability (WVP). Film developed with incorporation …

Open Source 3d Printers: An Appropriate Technology For Building Low Cost Optics Labs For The Developing Communities, Jephias Gwamuri, Joshua M. Pearce

Department of Materials Science and Engineering Publications

The recent introduction of RepRap (self-replicating rapid prototyper) 3-D printers and the resultant open source technological improvements have resulted in affordable 3-D printing, enabling low-cost distributed manufacturing for individuals. This development and others such as the rise of open source-appropriate technology (OSAT) and solar powered 3-D printing are moving 3-D printing from an industry based technology to one that could be used in the developing world for sustainable development. In this paper, we explore some specific technological improvements and how distributed manufacturing with open-source 3-D printing can be used to provide open-source 3-D printable optics components for developing world communities …

Glucose Recovery From Different Corn Stover Fractions Using Dilute Acid And Alkaline Pretreatment Techniques, D. Aboagye, N. Banadda, R. Kambugu, Jeffrey Seay, N. Kiggundu, A. Zziwa, I. Kabenge

Chemical and Materials Engineering Faculty Publications

Background: Limited availability of corn stover due to the competing uses (organic manure, animal feed, bio-materials, and bioenergy) presents a major concern for its future in the bio-economy. Furthermore, biomass research has exhibited different results due to the differences in the supply of enzymes and dissimilar analytical methods. The effect of the two leading pretreatment techniques (dilute acid and alkaline) on glucose yield from three corn stover fractions (cob, stalk, and leaf) sourced from a single harvest in Uganda were studied at temperatures 100, 120, 140, and 160 °C over reaction times of 5, 10, 30, and 60 min.

Results: …

Speculations On A City For Mars, Edouard Terzis

School of Architecture - Theses

This thesis proposes the reinterpretation of architectural forms as the index of the constitution of the idea of the city. “Speculations on a City on Mars” is paradoxical in a sense as it superposes both the managerial representation of a city, that is Zoning, along with the speculative aspect of an extra-terrestrial city.

A Study Of Iron-Nitrogen-Carbon Fuel Cell Catalysts: Chemistry – Nanostructure – Performance, Michael J. Workman

Nanoscience and Microsystems ETDs

Fuel cells have the potential to be a pollution-free, low-cost, and energy efficient alternative to the internal combustion engine for transportation and small-scale stationary power applications. The current state of fuel cell technology has already achieved two of these three lofty goals. The remaining barrier to wide-scale deployment is the high cost, which is primarily caused by dependence on large amounts of platinum to catalyze the energy conversion reactions. To overcome this barrier and facilitate the integration of fuel cells into mainstream applications, research into a new class of catalyst materials that do not require platinum is needed.

There has …

Mse Annual Report 2017, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Faculty and Staff News
• Faculty Research
• Student News
• Senior Design Teams
• Graduate Student News
• Outreach
• Alumni News
• By the Numbers
• Scholarships

A Concrete Water Pasteurization Device For Third World Countries, Andrea R. Murchie

Senior Honors Projects, 2010-2019

In the rural areas of South Africa, as well as many other developing countries, people cook food and sterilize their water by heating over open fires. Many times the fires are inside of homes, which more often than not are very small. Children will often be the ones to tend to the fire, out of necessity while parents and other family members are tending to other work and needs.

The purpose of my Senior Honors Project was to design a concrete vessel that can hold water and heat the water to pasteurization (149°F) when exposed to sunlight for an extended …

High-Efficiency Solar-Powered 3-D Printers For Sustainable Development, Jephias Gwamuri, Dhiogo Franco, Khalid Khan, Lucia Gauchia, Joshua M. Pearce

Michigan Tech Publications, Part 1

The release of the open source 3-D printer known as the RepRap (a self-Replicating Rapid prototyper) resulted in the potential for distributed manufacturing of products for significantly lower costs than conventional manufacturing. This development, coupled with open source-appropriate technology (OSAT), has enabled the opportunity for 3-D printers to be used for sustainable development. In this context, OSAT provides the opportunity to modify and improve the physical designs of their printers and desired digitally-shared objects. However, these 3-D printers require electricity while more than a billion people still lack electricity. To enable the utilization of RepRaps in off-grid communities, solar photovoltaic …

Corn Stover Biochar In Gypsum Board: Empirical Analysis Of Thermal Conductivity And Flexural Strength, Albena Yordanova

Dissertations and Theses @ UNI

Gypsum board, an economical and durable finish material for wall and ceiling construction in the United States and worldwide, is the component with the lowest thermal performance in a typical exterior wall assembly. It also constitutes a substantial portion of construction waste in landfills, potentially creating harmful environmental effects and dangerous gases. To minimize the negative effects of fast growing construction waste of gypsum in landfills and meet higher standards for energy efficiency in construction, there is a need to explore sustainable ways of improving thermal properties of gypsum board and recycling the material. Gypsum can be recycled and used …

Nanomechanical Testing Of Ods Steels Irradiated With 1 Mev/Amu Heavy Ions, Kateryna Kornieieva, Vladimir Skuratov, Alexander Sohatsky, Jacques O'Connell, Yuri Golovin, Victor Korenkov, Jan Neethling

Nanomechanical Testing in Materials Research and Development V

Heavy ion beams with high damage production rate are widely used to evaluate radiation tolerance of promising nuclear reactor materials, such as oxide dispersion strengthened (ODS) alloys, including their mechanical properties. Since typical ion projected ranges do not exceed 1 micron, nanoindentation technique is the most convenient method for examination of irradiated materials.

In present work we report data on radiation hardening of several ODS steels irradiated with 107 MeV Kr and 167 MeV Xe ions. Some samples were irradiated trough the special Al-foil filter in order to obtain the unfolding damage profile on the surface. The post-irradiation testing steels …

Transmission Electron Microscopy Characterization Of High-Temperatur Oxidation Of Fe-20cr-5al Alloy Prepared By Focused Ion Beam Technique, Mohammad Dani, Pudji Untoro, Teguh Yulius Surya Panca Putra, Parikin Parikin, Joachim Mayer, Arbi Dimyati

Makara Journal of Technology

The Focused Ion Beam (FIB) technique was applied for cross section preparation of the oxidized alloy for Transmission Electron Microscopy (TEM) study. Prior to preparation, the specimens of Fe-20Cr-5Al alloy sheet were oxidized in air at 1200 oC for 2 minutes, 10 minutes, 2 hours, and 100 hours. The microstructure and elemental composition of the samples were characterized using TEM equipped with an Energy Dispersive X-Ray Spectroscopy (EDX). The Electron Energy Loss Spectroscopy (EELS) was used to determine of the light elements. The TEM investigation reveals remarkable microstructure evolution of the specimens during oxidation which generally exhibit a typical multi-layer …

Consumer Perceptions Towards Package Designs: A Cross Cultural Study, Romica Chandra Lal, Fritz Yambrach, Lucy Mcproud

Journal of Applied Packaging Research

The choice of one package or the other can be an economic decision or can be influenced by cultural acceptance or perception of individual convenience. Product package systems can be designed for one-time use or multiple-use purposes. Package perceptions in different countries typically develop from a variety of factors, including climate, lifestyle, and cultural acceptance with regard to particular products. In an increasingly global economy with multinational firms marketing products worldwide, it is important to understand the differences between consumer needs and consumer responses to product-package systems.

The objective of this research was to examine consumer perceptions of different product …

Section Abstracts: Astronomy, Mathematics And Physics With Material Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics, and Physics with Material Science Section for the 93rd Annual Meeting of the Virginia Academy of Science, May 21-23, 2015, James Madison University, Richmond, Virginia

Suitability Of Geoscan-M Elemental Analyser For Phosphate Rock, H. Kurth, Derek Griffiths

Beneficiation of Phosphates VII

No abstract provided.

Phosphate Beneficiation With Novel Collectors For Direct And Reverse Flotation: Beyond Low Cost Fatty Acids, Pablo Dopico

Beneficiation of Phosphates VII

No abstract provided.

A Tailor Made Approach For The Beneficiation Of Phosphate Rock, Leonid Lisiansky, Mike Baker, Keren Larmour-Ship, Olga Elyash

Beneficiation of Phosphates VII

Tenova Bateman Technologies (TBT), part of Tenova Mining & Minerals is known as a provider of advanced process technologies in solvent extraction, phosphate beneficiation and fertilizer production.

TBT has participated in a number of phosphate projects and offers a comprehensive range of phosphate treatment technologies: from beneficiation to the production of purified phosphoric acid and downstream salts.

The beneficiation of phosphate rock can often be simplified and made more economic by taking into account the distribution of P₂O₅ and impurities as a function of their deportment between the size fractions resulting from mined and comminuted sedimentary phosphates. …