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Articles 661 - 690 of 5701

Full-Text Articles in Engineering

Improving Static Cold Storage Life Of The Human Heart Before Transplant, Juan Sebastian Rodriguez Paez May 2024

Improving Static Cold Storage Life Of The Human Heart Before Transplant, Juan Sebastian Rodriguez Paez

Theses and Dissertations

Organ storage and transportation are critical steps for the success of organ transplantation. Static cold storage (SCS) of hearts for heart transplantation (HTx) remains the standard approach. However, SCS may involve damage to the tissue resulting from extended hypothermic preservation, potentially affecting organ viability. More over, the temperature distribution on and within the heart is unknown during heart transplantation. Therefore, there is an interest to study different stages of the heart transplantation process towards determining the 3D temperature distribution on and within the heart. There could be a possibility of having a hypothermic injury in different parts of the heart …

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Improved Ballistic Impact Resistance Of Nanofibrillar Cellulose Films With Discontinuous Fibrous Bouligand Architecture, Colby Caviness May 2024

Improved Ballistic Impact Resistance Of Nanofibrillar Cellulose Films With Discontinuous Fibrous Bouligand Architecture, Colby Caviness

All Theses

Natural protective materials offer unparalleled solutions for impact-resistant material designs that are simultaneously lightweight, strong, and tough. Particularly, the dactyl club of mantis shrimp features chitin nanofibrils organized in a Bouligand structure, which has been shown to effectively dissipate high-impact energy during powerful strikes. The mollusk shells also achieve excellent mechanical strength, toughness, and impact resistance with a staggered, layer-by-layer structure. Previous studies have shown that hybrid designs, by combining different bioinspired microstructures, can lead to enhanced mechanical strength and energy dissipation capabilities. Nevertheless, it remains unknown whether combining Bouligand and staggered structures in nanofibrillar cellulose (NFC) films, forming a …

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A Manufacturing-To-Response Pathway For Manufacturing Optimization Of Carbon Fiber Reinforced Polymer Composite Structures, Madhura Limaye May 2024

A Manufacturing-To-Response Pathway For Manufacturing Optimization Of Carbon Fiber Reinforced Polymer Composite Structures, Madhura Limaye

All Dissertations

Over the past decade, there has been an increased adoption of thermoplastic and thermoset based continuous carbon fiber reinforced polymer (CFRP) composites for structural applications in several industries. Among the different manufacturing methods, thermoforming process for thermoplastic based continuous CFRP’s offer a major advantage in reducing cycle times for large scale productions. Similarly, out-of-autoclave curing process for thermoset based continuous CFRP’s using heated tooling enables production of large composite structures. However, these manufacturing processes can have a significant impact on the structural performance of parts by inducing undesirable effects. These effects include inhomogeneous fiber orientations, thickness variations, and residual stresses …

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Design And Application Of Smart Systems To Address Analytical Problems, Lucas B. Ayres May 2024

Design And Application Of Smart Systems To Address Analytical Problems, Lucas B. Ayres

All Dissertations

This dissertation is a multidisciplinary effort that integrates low-cost analytical instrumentation, redox chemistry, and artificial intelligence to overcome existing limitations in the fields of wearable sensing technology, Deep Eutectic Solvents (DES), and antioxidant chemistry. The overall goal behind each implemented strategy is to enhance the accuracy, efficiency, and accessibility of analytical processes and technologies. A general overview of the thesis, along with the research outcomes is included in Chapter One. The theoretical framework of this dissertation is presented in Chapter Two. Chapter Three describes the development of a wearable platform (sensor and instrumentation) to rapidly detect (~20 minutes) S. aureus …

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Boron-Doped Diamond As A Resilient Electrode Material In Molten Salts, Hannah Katherine Patenaude May 2024

Boron-Doped Diamond As A Resilient Electrode Material In Molten Salts, Hannah Katherine Patenaude

UNLV Theses, Dissertations, Professional Papers, and Capstones

Molten salt chemistry has a range of applications within nuclear technology, including for the Molten Salt Reactors (MSRs) and pyroprocessing to recover valuable actinides for energy and national security needs. However, the high-temperature, corrosive nature of molten salts makes them particularly challenging to deploy on an industrial scale and study in benchtop measurements. Material accountability and corrosion monitoring of MSR fuels are essential components to the successful deployment of MSRs, and electroanalytical techniques like cyclic voltammetry (CV) and spectroelectrochemistry (SEC) can provide a wealth of information to describe salt systems in situ. To perform such measurements, it is imperative to …

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General Hydrogeochemical Characterization Of Groundwater In Coastal Aquifers Of Kilwa Kisiwani Oceanic Island, South East Tanzania, Simon R Melchioly Apr 2024

General Hydrogeochemical Characterization Of Groundwater In Coastal Aquifers Of Kilwa Kisiwani Oceanic Island, South East Tanzania, Simon R Melchioly

Tanzania Journal of Engineering and Technology (TJET)

The main objective of this study was to determine the hydrogeochemical processes controlling the groundwater chemistry on the Island and assess its suitability for human consumption and irrigation. The methodology used in the study include hydrogeological assessment of the study area and laboratory analysis for general physico-chemical parameters of groundwater. Other parameters such as Soluble sodium percentage (SSP) or % Na+, Sodium Adsorption Ratio (SAR), Magnesium adsorption ratio (MAR), Residual sodium carbonate (RSC), hydrochemical facies classification, and Water Quality Index (WQI) were calculated using empirical formulae. The effects of salinization of groundwater were classified using the chloride-Bicarbonate (Cl/HCO3) and the …

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Enhanced Post Deposition Annealing Conditions On The Fabrication Of High Quality Thermochromic Vanadium Dioxide Films, Nuru R. Mlyuka Apr 2024

Enhanced Post Deposition Annealing Conditions On The Fabrication Of High Quality Thermochromic Vanadium Dioxide Films, Nuru R. Mlyuka

Tanzania Journal of Engineering and Technology (TJET)

Sputter deposition of thermochromic VO2 thin films for smart window applications has been faced with several challenges including the need for high deposition temperature, extremely precise and narrow range of oxygen/argon flow ratio and target poisoning during sputtering. Deposition of VO2 at room temperature without oxygen followed by post-deposition annealing has been cited as one of the potential mitigations to the challenge. In this study, the effects of post-deposition annealing conditions on the structural, electrical and optical properties of VO2 thin films are reported. The films were prepared on soda lime glass substrates using DC magnetron sputtering of metallic vanadium …

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Optimization Pump As Turbine Coupled To A Self-Excited Induction Generator Using Multi-Objective Genetic Algorithm, Emanuel J. Nyirenda Apr 2024

Optimization Pump As Turbine Coupled To A Self-Excited Induction Generator Using Multi-Objective Genetic Algorithm, Emanuel J. Nyirenda

Tanzania Journal of Engineering and Technology (TJET)

As a way of accelerating the deployment of affordable and clean renewable energy generation technologies, applying a pump working as a turbine coupled to a self-excited induction generator is gaining popularity in various areas including energy recovery and micro hydro systems. However, it is currently challenging to predict the performance of the PAT-SEIG system and there is no agreed-upon rule on the selection of the appropriate system to be installed at a particular site. This paper has presented multi-objective optimization to select the best operating point of the PAT-SEIG system. The results show that the peak efficiencies for the PAT …

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Production Of Biofertilizer From Fruit And Garden Waste, Neema Msuya Apr 2024

Production Of Biofertilizer From Fruit And Garden Waste, Neema Msuya

Tanzania Journal of Engineering and Technology (TJET)

The project focused on the production of bio-fertilizer from fruit and garden waste, with a specific emphasis on utilizing pineapple tops in the composting process. The objective was to produce and assess the properties of the bio fertilizer obtained from this process and evaluate its potential application in agriculture. In this study, the composting process was done in a 0.7 m long, 0.85 wide and 1.1 m high vessel, and 0.238 m3 pineapple top wastes, resulting in 0.35 m3 of biofertilizer. The bio fertilizer produced exhibited favorable characteristics, including a moisture content of 36%, pH of 7.1, and a total …

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Assessment Of Risk Factors Related To Body Pain Complaints In Tanzania Construction Industry, Fatma K. Mohamed Apr 2024

Assessment Of Risk Factors Related To Body Pain Complaints In Tanzania Construction Industry, Fatma K. Mohamed

Tanzania Journal of Engineering and Technology (TJET)

The construction industry is associated with risks that can result in musculoskeletal diseases. Although young male workers who are presumed to be healthy dominate the industry in Tanzania, body pain complaints have been widely reported. The aim of this study is to assess the prevalence and causes of body pains in workers. A cross-sectional study involving 396 workers was conducted. A chi square test was used for testing association of independent categorical variables and binary logistic regression analysis was used to determine predictors for body pain complaints. The results show that all study participants complained of at least one form …

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Comparison Of Meteorological Drought Indices In Tanzania Using The Meteorological Drought Monitoring Software Package, Paul Ts Limbu Apr 2024

Comparison Of Meteorological Drought Indices In Tanzania Using The Meteorological Drought Monitoring Software Package, Paul Ts Limbu

Tanzania Journal of Engineering and Technology (TJET)

Low precipitation, substantial evaporation, and an unequal distribution of precipitation throughout the area are the characteristics of drought, a climatic abnormality. This study used the Meteorological Drought Monitoring (MDM) software and monthly rainfall data from the Tanzania Meteorological Authority (TMA) to examine and compare the Deciles Index (DI), Standardised Precipitation Index (SPI), Percent of Normal Index (PNI), Rainfall Anomaly Index (RAI), Z-Score Index (ZSI), China-Z Index (CZI), and Modified China-Z Index (MCZI) for drought monitoring in Tanzania from 1988 to 2017. It was found that ZSI represented the dry years better than other indices, followed by DI, RAI, PNI, SPI, …

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Causes And Consequences Of Inefficient Drilling And Blasting In Mine Development Headings: A Case Study Of Hard Rock Gold Mining Operations In Northern Tanzania, George Bennett Apr 2024

Causes And Consequences Of Inefficient Drilling And Blasting In Mine Development Headings: A Case Study Of Hard Rock Gold Mining Operations In Northern Tanzania, George Bennett

Tanzania Journal of Engineering and Technology (TJET)

Despite the introduction of the perimeter blasting technique at the Tulawaka Gold Mine, the mine continued to suffer from an overbreak of mine development headings, with an average overbreak of 24% every 22 m, which is approximately twice the acceptable 10% overbreak. The causes of this problem include ineffective drilling practices and uneven and excessive charging of explosives, resulting in a slightly high powder factor of 3.94 kg/m3 instead of 3.8 kg/m3, as per the design. The problem of overbreak resulted in ore dilution, a longer mine development cycle time and additional costs of approximately US$ 45 per cut, especially …

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Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu Apr 2024

Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu

Journal of Electrochemistry

The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.

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Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng Apr 2024

Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng

Journal of Electrochemistry

Aryl-substituted benzothiophene and phenanthrene are important structural units in medicinal chemistry and materials science. Although extensive effort has been devoted to prepare these compounds and a variety of approaches have been developed to construct the 2-substituted benzothiophene core structure, environmental-friendly and efficient synthetic means are still desired. Based on our previous electrochemical Minisci-type arylation reaction with aryl diazonium salt as the aryl precursor, as well as the work from König’s group, herein, we described the use of paired electrolysis to achieve 2-aryl benzothiophenes and 9-aryl phenanthrenes employing benzenediazonium salts as the aryl radical precursors. Initially, 2-methylthiobenzendiazonium salt 1a and 4-methylbenzene …

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Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu Apr 2024

Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu

Journal of Electrochemistry

Zero-emission of desulfurization wastewater is one of the main demands for coal-fired power plants. As typical high salinity wastewater, it is hard to purify the desulfurization wastewater from coal-fired power plants through traditional physicochemical treatment or biochemical treatment, e.g., COD and Cl–. A high concentration of Cl– ion in desulfurization wastewater restricts wastewater reuse and zero-emission. Electrochemical technology is an attractive method for high salinity wastewater zero-emission, which provides a versatile, efficient, cost-effective, easily automatable, and clean industrial process. For advanced treatment of effluent after triple box process treatment in power plants, this paper reports an electrochemical …

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Thermal Performance Investigation Of Thermoelectric Cooling System With Various Hot-Side Cooling Methods, Bowo Y. Prasetyo, Parisya P. Rosulindo, Fujen Wang Apr 2024

Thermal Performance Investigation Of Thermoelectric Cooling System With Various Hot-Side Cooling Methods, Bowo Y. Prasetyo, Parisya P. Rosulindo, Fujen Wang

Makara Journal of Technology

Thermoelectric devices have been widely used in various applications, including cooling and power generation. The potential application of thermoelectric cooling systems has been studied. However, these systems still face challenges in achieving optimal performance compared with other cooling systems. Several factors, including the hot-side cooling method, influence the performance of thermoelectric systems. This study aimed to investigate the effects of different hot-side cooling methods on the thermoelectric performance and thermal behavior of thermoelectric cooling systems. The testing methods involved the combination of the thermoelectric module with five hot-side heat exchangers, including a square heatsink, a round heatsink, a two-pipe heat …

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Towards A Study Protocol: A Data-Driven Workflow To Identify Error Sources In Direct Ink Write Mechatronics, Hein Htet Aung, Quynh D. Tran, Pawan K. Tripathi, Roger H. French, Laura S. Bruckman Apr 2024

Towards A Study Protocol: A Data-Driven Workflow To Identify Error Sources In Direct Ink Write Mechatronics, Hein Htet Aung, Quynh D. Tran, Pawan K. Tripathi, Roger H. French, Laura S. Bruckman

Faculty Scholarship

Using Direct Ink Write (DIW) technology in a rapid and large-scale production requires reliable quality control for printed parts. Data streams generated during printing, such as print mechatronics, are massive and diverse which impedes extracting insights. In our study protocol approach, we developed a data-driven workflow to understand the behavior of sensor-measured X- and Y-axes positional errors with process parameters, such as print velocity and velocity control. We uncovered patterns showing that instantaneous changes in the velocity, when the build platform accelerates and decelerates, largely influence the positional errors, especially in the X-axis due to the hardware architecture. Since DIW …

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Injectable And Rapidly Expandable Thrombin-Decorated Cryogels Achieve Rapid Hemostasis And High Survival Rates In A Swine Model Of Lethal Junctional Hemorrhage, Syed Muntazir Andrabi, S.M. Shatil Shahriar, Al-Murtadha Al-Gahmi, Benjamin L. Wilczewski, Mark A. Carlson, Jingwei Xie Apr 2024

Injectable And Rapidly Expandable Thrombin-Decorated Cryogels Achieve Rapid Hemostasis And High Survival Rates In A Swine Model Of Lethal Junctional Hemorrhage, Syed Muntazir Andrabi, S.M. Shatil Shahriar, Al-Murtadha Al-Gahmi, Benjamin L. Wilczewski, Mark A. Carlson, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Effective therapies are urgently needed to stabilize patients with marginally compressible junctional hemorrhage long enough to get them to the hospital alive. Herein, we report injectable and rapidly expandable cryogels consisting of polyacrylamide and thrombin (AT cryogels) created by cryo-polymerization for the efficient management of lethal junctional hemorrhage in swine. The produced cryogels have small pore sizes and highly interconnected porous architecture with robust mechanical strength. The cryogels exhibit rapid shape memory properties and prove to be resilient against fatigue. These cryogels also show high water/blood absorption capacity, fast blood clotting effect, and enhanced adhesion of red blood cells and …

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A Feasibility Study Of Drilling Fluid Slippage For Wellbore Displacement, John Johnson Apr 2024

A Feasibility Study Of Drilling Fluid Slippage For Wellbore Displacement, John Johnson

LSU Master's Theses

In the ideal plug-flow mode viscoplastic drilling fluids display uniform frontal velocity due to wall slippage (at very low flowrate limited by the fluid’s yield strength). The flow rate could be increased by raising the yield strength that would make the fluid best candidate for frontal displacement. Based on this concept the study qualifies wall slippage effect for wellbore displacement. Using a conceptual model of fluid motion between two parallel plates defines maximum velocity as a function of shearing rate and yield stress. Conversion to coaxial geometry gives practical formulas for fluid testing with rotational viscometer. A new analysis of …

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Numerical Analysis Of Flow Fields For The Different Models Of The Shrouded Savonius Rotor, Alsaied Khalil Mahmoud, Mohamed Mahgoub Bassuoni, Mohamed Fawzy Obiaa, Ahmed Mostafa Khaira Mar 2024

Numerical Analysis Of Flow Fields For The Different Models Of The Shrouded Savonius Rotor, Alsaied Khalil Mahmoud, Mohamed Mahgoub Bassuoni, Mohamed Fawzy Obiaa, Ahmed Mostafa Khaira

Journal of Engineering Research

In this study, the effect of three different lengths (short, medium, and long) of flanged shrouded Savonius wind turbines is investigated three-dimensional (3-D) numerically by ANSYS-FLUENT. The 3-D numerical model of a simple rotor is validated by comparing the results with previous published experimental ones at the same operating conditions and geometry. The numerical and experimental results indicate a good agreement with each other when using the SST K-ω model with a time step size of 0.0025 s.The analysis of the numerical results of the three flanged shrouded models shows an enhancement of the torque coefficient at tip speed ratio …

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Recent Advances In Solar Photo(Electro)Catalytic Nitrogen Fixation, Jun-Bo Ma, Sheng Lin, Zhiqun Lin, Lan Sun, Chang-Jian Lin Mar 2024

Recent Advances In Solar Photo(Electro)Catalytic Nitrogen Fixation, Jun-Bo Ma, Sheng Lin, Zhiqun Lin, Lan Sun, Chang-Jian Lin

Journal of Electrochemistry

Ammonia (NH3) is an essential chemical in modern society. It is currently produced in industry by the Haber-Bosch process using H2 and N2 as reactants in the presence of iron-based catalysts at high-temperature (400–600 oC) and extremely highpressure (20–40 MPa) conditions. However, its efficiency is limited to 10% to 15%. At the same time, a large amount of energy is consumed, and CO2 emission is inevitably. The development of a sustainable, clean, and environmentally friendly energy system represents a key strategy to address energy crisis and environmental pollution, ultimately aiming to achieve carbon neutrality. …

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Technology Assessment For Cybersecurity Organizational Readiness: Case Of Airlines Sector And Electronic Payment, Sultan Ayed Alghamdi, Tugrul Daim, Saeed Mohammed Alzahrani Mar 2024

Technology Assessment For Cybersecurity Organizational Readiness: Case Of Airlines Sector And Electronic Payment, Sultan Ayed Alghamdi, Tugrul Daim, Saeed Mohammed Alzahrani

Engineering and Technology Management Faculty Publications and Presentations

Payment processing systems have advanced significantly in the airline business. Because e-payments are easy, they have captured the attention of many companies in the aviation industry and are quickly becoming the dominant means of payment. However, as technology advances, fraud grows at a comparable rate. Over the years, there has been a surge in payment fraud incidents in the airline sector, reducing the platform's trustworthiness. Despite attempts to eliminate epayment fraud, decision-makers lack the technical expertise required to use the finest fraud detection and prevention assessments. This research recognizes the lack of an established decision model as a hurdle and …

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A General Materials Data Science Framework For Quantitative 2d Analysis Of Particle Growth From Image Sequences, Sameera Nalin Venkat, Thomas G. Ciardi, Mingjian Lu, Preston C. Deleo, Jube Augustino, Adam Goodman, Jayvic Cristian Jimenez, Anirban Mondal, Frank Ernst, Yinghui Wu, Roger H. French, Laura S. Bruckman Mar 2024

A General Materials Data Science Framework For Quantitative 2d Analysis Of Particle Growth From Image Sequences, Sameera Nalin Venkat, Thomas G. Ciardi, Mingjian Lu, Preston C. Deleo, Jube Augustino, Adam Goodman, Jayvic Cristian Jimenez, Anirban Mondal, Frank Ernst, Yinghui Wu, Roger H. French, Laura S. Bruckman

Faculty Scholarship

Phase transformations are a challenging problem in materials science, which lead to changes in properties and may impact performance of material systems in various applications. We introduce a general framework for the analysis of particle growth kinetics by utilizing concepts from machine learning and graph theory. As a model system, we use image sequences of atomic force microscopy showing the crystallization of an amorphous fluoroelastomer film. To identify crystalline particles in an amorphous matrix and track the temporal evolution of the particle dispersion, we have developed quantitative methods of 2D analysis. 700 image sequences were analyzed using a neural network …

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Properties Of Portland Cement Concrete Incorporating Basalt-Based Pozzolanic Cement, Rana Khalil Feb 2024

Properties Of Portland Cement Concrete Incorporating Basalt-Based Pozzolanic Cement, Rana Khalil

Theses and Dissertations

Over the last decade, the world's population has increased dramatically. Due to this growth, the demand for concrete and Portland cement, in return, have increased. Manufacturing of Portland cement is an energy-intensive process that, alone, contributes to about 8% of global CO2. For decades, efforts have been exerted to reduce the harmful environmental impacts of Portland cement by reducing its use in concrete as well as considering alternate binders that may fully or partially replace it. This study aims to assess the properties of concrete incorporating a novel basalt-based pozzolanic cement. To meet this objective, four sets of concrete mixtures …

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The Behavior Of ½⟨111⟩ Screw Dislocations In W–Mo Alloys Analyzed Through Atomistic Simulations, Lucas A. Heaton, Kevin Chu, Adib J. Samin Feb 2024

The Behavior Of ½⟨111⟩ Screw Dislocations In W–Mo Alloys Analyzed Through Atomistic Simulations, Lucas A. Heaton, Kevin Chu, Adib J. Samin

Faculty Publications

Analyzing plastic flow in refractory alloys is relevant to many different commercial and technological applications. In this study, screw dislocation statics and dynamics were studied for various compositions of the body-centered cubic binary alloy tungsten–molybdenum (W–Mo). The core structure did not appear to change for different alloy compositions, consistent with the literature. The pure tungsten and pure molybdenum samples had the lowest plastic flow, while the highest dislocation velocities were observed for equiatomic, W0.5Mo0.5 alloys. In general, dislocation velocities were found to largely align with a well-established dislocation mobility phenomenological model supporting two discrete dislocation mobility regimes, …

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Joint Time-Frequency Analysis: Taking Charge Penetration Depth And Current Spatial Distribution In The Single Pore As An Example, Nan Wang, Qiu-An Huang, Wei-Heng Li, Yu-Xuan Bai, Jiu-Jun Zhang Feb 2024

Joint Time-Frequency Analysis: Taking Charge Penetration Depth And Current Spatial Distribution In The Single Pore As An Example, Nan Wang, Qiu-An Huang, Wei-Heng Li, Yu-Xuan Bai, Jiu-Jun Zhang

Journal of Electrochemistry

In recent years, joint time-frequency analysis has once again become a research hotspot. Supercapacitors have high power density and long service life, however, in order to balance between power density and energy density, two key factors need to be considered: (i) the specific surface area of the porous matrix; (ii) the electrolyte accessibility to the intra-pore space of porous carbon matrix. Electrochemical impedance spectra are extensively used to investigate charge penetration ratio and charge storage mechanism in the porous electrode for capacitance energy storage. Furthermore, similar results could be obtained by different methods such as stable-state analysis in the frequency …

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Automated Workflow For Redox Potentials And Acidity Constants Calculations From Machine Learning Molecular Dynamics, Feng Wang, Jun Cheng Feb 2024

Automated Workflow For Redox Potentials And Acidity Constants Calculations From Machine Learning Molecular Dynamics, Feng Wang, Jun Cheng

Journal of Electrochemistry

Redox potentials and acidity constants are key properties for evaluating the performance of energy materials. To achieve computational design of new generation of energy materials with higher performances, computing redox potentials and acidity constants with computational chemistry have attracted lots of attention. However, many works are done by using implicit solvation models, which is difficult to be applied to complex solvation environments due to hard parameterization. Recently, ab initio molecular dynamics (AIMD) has been applied to investigate real electrolytes with complex solvation. Furthermore, AIMD based free energy calculation methods have been established to calculate these physical chemical properties accurately. However, …

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A Study On High-Frequency Bending Fatigue, Microhardness, Tensile Strength, And Microstructure Of Parts Made Using Atomic Diffusion Additive Manufacturing (Adam) And Additive Friction Stir Deposition (Afsd), Hamed Ghadimi Feb 2024

A Study On High-Frequency Bending Fatigue, Microhardness, Tensile Strength, And Microstructure Of Parts Made Using Atomic Diffusion Additive Manufacturing (Adam) And Additive Friction Stir Deposition (Afsd), Hamed Ghadimi

LSU Doctoral Dissertations

This dissertation reports the findings of several studies on the mechanical and microstructural properties of parts made using atomic diffusion additive manufacturing (ADAM) and additive friction stir deposition (AFSD). The design of a small-sized bending-fatigue test specimen for an ultrasonic fatigue testing system is reported in Chapter 1. The design was optimized based on the finite element analysis and analytical solution. The stress–life (S–N) curve is obtained for Inconel alloy 718. Chapter 2 presents the findings of ultrasonic bending-fatigue and tensile tests carried out on the ADAM test specimens. The S-N curves were created in the very high-cycle fatigue regime. …

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Residual Stress Generation In Additive Manufacturing Of Complex Lattice Geometries, Katie Bruggeman, Nathan Klingbeil, Anthony N. Palazotto Feb 2024

Residual Stress Generation In Additive Manufacturing Of Complex Lattice Geometries, Katie Bruggeman, Nathan Klingbeil, Anthony N. Palazotto

Faculty Publications

Residual stresses developed during additive manufacturing (AM) can influence the mechanical performance of structural components in their intended applications. In this study, thermomechanical residual stress simulations of the laser powder bed fusion (LPBF) process are conducted for both simplified (plate and cube-shaped) geometries as well as five complex lattice geometries fabricated with Inconel 718. These simulations are conducted with the commercial software package Simufact Additive©, which uses a nonlinear finite element analysis and layer-by-layer averaging approach in determining residual stresses. To verify the efficacy of the Simufact Additive© simulations, numerical results for the plate and cube-shape geometries are analyzed for …

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Modeling At The Nanometric Scale Of Interfacial Defects Of A Semiconductor Heterostructure In The Isotropic And Anisotropic Cases For The Study Of The Influence Of Stresses, Ahmed Boussaha, Rafik Makhloufi, Rachid Benbouta, Mourad Brioua Feb 2024

Modeling At The Nanometric Scale Of Interfacial Defects Of A Semiconductor Heterostructure In The Isotropic And Anisotropic Cases For The Study Of The Influence Of Stresses, Ahmed Boussaha, Rafik Makhloufi, Rachid Benbouta, Mourad Brioua

Emirates Journal for Engineering Research

This work aims to determine the effect of stresses caused by dislocation networks placed at the interface of a semiconductor heterostructure of the thin GaAs/Si system. In this case, we use a mathematical modeling by Fourier series expansion to numerically simulate the stresses for the two cases of isotropic and anisotropic elasticity in order to predict the mechanical behavior of the heterostructure in the presence of interfacial dislocations while respecting well-defined stress boundary conditions. The elastic stress relaxation is reached for a layer thickness threshold of the GaAs deposit on the Si substrate not exceeding 5 nm.

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