Engineering Commons^™

Electrocatalytic Oxidation Of Glucose On Nano Pt/C Electrode, Cui-Lian Chen, Xiao-Lan Wei, Pei Kang Shen

Journal of Electrochemistry

Nano Pt/C electrocatalysts were prepared by intermittent microwave heating method.The electrooxidation of glucose on smooth Pt and～Pt/C electrodes has been studied and compared.The results showed that the electrochemical properties on nano Pt/C were improved due to the reduction of the overpotential and the increase in the kinetic rate.The surface area would be significantly increased when the particle size of the catalyst was reduced to nano-scale,resulting in the increase in the activity.The enhancement in the resistance to poisoning could be explained that the oxygen-containing species are easier to react with poisoning species on nano Pt/C and re-active the electrode.

Effects Of Sulfide Ions On The Inhibiting Efficiency Of Eda As A Copper Corrosion Inhibitor In Dilute Hcl Solution, Wen-Juan Qu, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

The anticorrosion action of EDA on copper in dilute HCl solution and the effect of sulfide ions on the inhibiting efficiency were studied by the Tafel plot method.The corrosion potential of Cu shifted to more positive value and the corrosion current density decreased after the addition of Na₂S to the solution.The results indicated that sulphide ions could increase the inhibiting efficiency of EDA because of the synergistic inhibition effect between EDA and Na₂S,resulting from the adsorption of HS^- on the surface of Cu,facilitated the adsorption of EDA to form a highly protective adsorbed layer which …

The Complex Of Pasp And Tungstate As Inhibitors Of Cupronickel B10′S Corrosion In 3% Nacl Solution, Qun-Jie Xu, Guo-Ding Zhou, Hui-Feng Wang, Wen-Bin Cai

Journal of Electrochemistry

AC impedance and polarization curve measurements were conducted to study the effects of environ-ment-friendly inhibitors PASP,Na₂WO₄ and their complexes on the corrosion of cupronickel B10 in 3%NaCl solution.The results indicate that PASP or Na₂WO₄ alone does inhibit the corrosion of B10,and most effectiveconcentrations are 40 mg/L and 60 mg/L for PASP and Na₂WO₄,respectively.With the total concentration of 40mg/L for the complex inhibitors,the optimum complex ratio of PASP to Na₂WO₄ was 3:1.The complex of such a combination showed a significantly synergetic inhibition effect on the corrosion of B10.

The Effect Of Solution Concentration On Properties Of Ru-Ti-Ir Oxide Anode Coatings, Ke Wang, Yan Han, Jun-Tao Wang, Xiao-Ling Zhang, Yu-Pu Sun

Journal of Electrochemistry

The anode coatings of Ru-Ti-Ir oxide with various solution concentrations were prepared by thermal decomposition.The scanning electron microscope(SEM),energy dispersive X-ray detector(EDX),X-ray diffraction(XRD),accelerated life,polarization curve,cyclic voltammetry and electrochemical impedance.spectroscopy(EIS)tests were carried out.The results showed that there was an obvious effect of solution concentrations on the morphology of the coatings,but little effect on polarization of chlorine evolution.Voltammetric charges and double layer capacitances of anode coatings had a tendency to fall down firstly then increase afterwards as the solution concentration increased.

Electrochemical Reduction Behavior Of Benzaldehyde In The Ionic Liquids, Ning Zhao, Wen-Ju Dong, Qi-Zeng Shi

Journal of Electrochemistry

In this paper, the electrochemical reduction of benzaldehyde was investigated in C₄MIMBF₄, C₆MIMBF₄  and C₈MIMBF₄ ionic liquids by cyclic linear sweep voltammetry,cyclic square-wave voltammetry and chronocoulometry.Benzaldehyde exhibits two successive one-electron irreversible reduction(E_P1=-1.39 V, E_P2=1.69 V) with GC electrode in C₄MIMBF₄, the voltammetric data for benzaldehyde give diffusion coefficients of 1.5*10^-8cm²/s and 1.3*10⁸cm²/s. There is one current peak in C₆MIMBF₄  and C₈MIMBF₄ ionic liquids due to their stronger alkalinity …

Oxygen Enrichment Effect Of Ceo2 To The Cathode Performance Of Proton Exchange Membrane Fuel Cell, Xiang-Li Hou, Hong-Feng Xu, Jian-Hua Dong, Xin Sun

Journal of Electrochemistry

CeO₂ was added to Pt/C catalyst in the cathode of PEMFC by both sol and impregnation methods.The samples were evaluated by TEM,cyclic voltammogram techniques and proton exchange membrane fuel cell performance test.The addition of CeO₂ obviously improved the performance of PEMFC and represented a notable function of oxygen enrichment in the cathode side.But with the addition of CeO₂,part of the catalyst surface was covered and led to the performance drop of the PEMFC.The best content of CeO₂ is 1% when it is added by impregnation method and 3% when it is added by sol method.

Effects Of Srb Biofilm And Corrosion Product Films On Corrosion Behavior Of Carbon Steel, Jing Lin, Yong-Gui Yan, Guang-Zhang Chen, Guang-Zhou Liu, Qing-Fen Li

Journal of Electrochemistry

Electrochemical techniques and surface analysis techniques were applied to study corrosion characteristic of A₃ steel.The effects on corrosion behavior of A₃ steel by sulfate-reducing bacteria(SRB)(biotic media)and corrosion product(abiotic media)were studied.The results showed that biofilms and corrosion product films play different role during different stages.Biofilms were easier flaky with increasing of its thickness.Non-uniform biofilms reduced pitting corrosion of the specimens.The corrosion product films formed under abiotic conditions were more adherently to the surface of the metal than those formed in biogenic media.

In-Situ Detection Of The Effect Of Brighter In The Solution For Nickel And Phosphor Alloy, Jian Zheng, Ning Li, De-Yu Li, Guo-Feng Cui

Journal of Electrochemistry

In this work,the gold-plated mica was used for the substrate,the concentration of 5% of normal plating solution for the nickel was used as the mother solution,and the effect for the deposition by the brighter with ECSTM was in-situ detected.The solution for deposition without the brighter has no brightness,though the values of the roughness and the H_(A-V) have reduced in evidence after deposition;the solution for deposition with the complete brighter although has great brightness,the values of the roughness and the H_(A-V) have increased(after) deposition;the solution for deposition with the half brighter has a moderate effect on the H_(A-V) and (brightness).Hence,the brighter …

Numerical Simulation Of Nonlinear Elastic Wave Propagation In Piecewise Homogeneous Media, Arkadi Berezovski, Mihhail Berezovski, Juri Engelbrecht

Publications

Systematic experimental work [S. Zhuang, G. Ravichandran, D. Grady, J. Mech. Phys. Solids 51 (2003) 245–265] on laminated composites subjected to high velocity impact loading exhibits the dispersed wave field and the oscillatory behavior of waves with respect to a mean value. Such a behavior is absent in homogeneous solids. An approximate solution to the plate impact in layered heterogeneous solids has been developed in [X. Chen, N. Chandra, A.M. Rajendran, Int. J. Solids Struct. 41 (2004) 4635–4659]. The influence of the particle velocity on many process characteristics was demonstrated. Based on earlier results [A. Berezovski, J. Engelbrecht, G.A. Maugin, …

Me-Em 2006 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

Table of Contents

• Overview, Mission, and Vision
• Comments on the Strategic Plan
• Enrollment, Degrees, and Expenditure Data
• External Advisory Board
• Faculty and Staff
• Students
• Alumni
• Resources
• Graduates
• Publications

Nanoparticle-Induced Negative Differential Resistance And Memory Effect In Polymer Bistable Light-Emitting Device, Ricky J. Tseng, Jianyong Ouyang, Chih-Wei Chu, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Recently, electrical bistability was demonstrated in polymer thin films incorporated with metal nanoparticles [J. Ouyang, C. W. Chu, C. R. Szmanda, L. P. Ma, and Y. Yang, Nat. Mater. 3, 918 (2004)]. In this letter, we show the evidence that electrons are the dominant charge carriers in these bistable devices. Direct integration of bistable polymer layer with a light-emitting polymer layer shows a unique light-emitting property modulated by the electrical bistability. A unique negative differential resistance induced by the charged gold nanoparticles is observed due to the charge trapping effect from the nanoparticles when interfaced with the light-emitting layer.

In Vivo Laparoscopic Robotics, Mark E. Rentschler, Stephen R. Platt, Jason Dumpert, Shane M. Farritor, Dmitry Oleynikov

Department of Mechanical and Materials Engineering: Faculty Publications

Robotic laparoscopic surgery is evolving to include in vivo robotic assistants. The impetus for the development of this technology is to provide surgeons with additional viewpoints and unconstrained manipulators that improve safety and reduce patient trauma. A family of these robots have been developed to provide vision and task assistance. Fixed-base and mobile robots have been designed and tested in animal models with much success. A cholecystectomy, prostatectomy, and nephrectomy have all been performed with the assistance of these robots. These early successful tests show how in vivo laparoscopic robotics may be part of the next advancement in surgical technology.

Non-Operative Management Of Posterior Tibialis Tendon Dysfunction: Design Of A Randomized Clinical Trial [Nct00279630], Kornelia Kulig, Amy B. Pomrantz, Judith M. Burnfield, Stephen F. Reischl, Susan Mais-Requejo, David B. Thordarson, Ronald W. Smith

Department of Mechanical and Materials Engineering: Faculty Publications

Background: Posterior tibialis tendon dysfunction (PTTD) is a common cause of foot pain and dysfunction in adults. Clinical observations strongly suggest that the condition is progressive. There are currently no controlled studies evaluating the effectiveness of exercise, orthoses, or orthoses and exercise on Stage I or IIA PTTD. Our study will explore the effectiveness of an eccentric versus concentric strengthening intervention to results obtained with the use of orthoses alone. Findings from this study will guide the development of more efficacious PTTD intervention programs and contribute to enhanced function and quality of life in persons with posterior tibialis tendon dysfunction. …

Study Of Low Speed Transitional Regime Gas Flows In Microchannels Using Information Preservation (Ip) Method, Umit Kursun

Electronic Theses and Dissertations

Proper design of thermal management solutions for future nano-scale electronics or photonics will require knowledge of flow and transport through micron-scale ducts. As in the macro-scale conventional counterparts, such micron-scale flow systems would require robust simulation tools for early-stage design iterations. It can be envisioned that an ideal Nanoscale thermal management (NSTM) solution will involve two-phase flow, liquid flow and gas flow. This study focuses on numerical simulation gas flow in microchannels as a fundamental thermal management technique in any future NSTM solution. A wellknown particle-based method, Direct Simulation Monte Carlo (DSMC) is selected as the simulation tool. Unlike continuum …

Low Temperature Co-Fired Ceramics For Micro-Fluidics, John Youngsman, Brian Marx, Martin Schimpf, Scott Wolter, Jeff Glass, Amy Moll

Materials Science and Engineering Faculty Publications and Presentations

The miniaturization of analytical instruments and packaging of novel sensors is an area that has attracted significant research interest and offers many opportunities for product commercialization. Low Temperature Co-fired Ceramics (LTCC) is a materials system composed of alumina and glass in an organic binder. LTCC is a good choice for sensor development because of the ease of incorporating features in the ‘green’ or unfired state such as electrical traces, fluidic pathways and passive electrical components. After a firing cycle, what remains is a robust, monolithic device with features embedded in the package. In order for LTCC to be a successful …

Loading And Recovery Behavior Of The Human Lumbar Spine Under Static Flexion, Guntulu Selen Hatipkarasulu

LSU Doctoral Dissertations

Musculoskeletal disorders account for 32 percent of work related injuries and illnesses. Extensive studies have been conducted to understand and explore the factors that affect the development of musculoskeletal disorders to provide effective control strategies. One of the most important factors that allow effective control strategies is the biomechanical factors. Among the biomechanical risk factors, exposures to repetitive static and vibratory activities are known to result in musculoskeletal disorders. A ligamento–muscular reflex activity exists in humans and animals to stabilize the knee, shoulder, elbow, ankle joints, and spine. This reflex activity decreases over time when static loading is applied, which …

The Role Of Electrospinning In The Emerging Field Of Nanomedicine, S. Y. Chew, Y. Wen, Yuris A. Dzenis, K. W. Leong

Department of Mechanical and Materials Engineering: Faculty Publications

The fact that in vivo the extracellular matrix or substratum with which cells interact often includes topography at the nanoscale underscores the importance of investigating cell-substrate interactions and performing cell culture at the submicron scale. An important and exciting direction of research in nanomedicine would be to gain an understanding and exploit the cellular response to nanostructures. Electrospinning is a simple and versatile technique that can produce a macroporous scaffold comprising randomly oriented or aligned nanofibers. It can also accommodate the incorporation of drug delivery function into the fibrous scaffold. Endowed with both topographical and biochemical signals such electrospun nanofibrous …

Response To "Comment On Variational Approach To The Volume Viscosity Of Fluids" [Phys. Fluids 18, 109101 (2006)], Allen J. Zuckerwar, Robert L. Ash

Mechanical & Aerospace Engineering Faculty Publications

We respond to the Comment of Markus Scholle and therewith revise our material entropy constraint to account for the production of entropy. (c) 2006 American Institute of Physics.

Design And Performance Evaluation Of An Integrated Miniature Single Stage Centrifugal Compressor And Permanent Magnet Synchronous Motor, Dipjyoti Acharya

Electronic Theses and Dissertations

An attempt has been made in this present work to design, fabricate and performance evaluate an integrated single stage centrifugal compressor and permanent magnet synchronous motor which is a key component of the reverse brayton cycle cryocooler. An off the shelf compressor – the driven and electric motor – the driver was not available commercially to suffice the requirements of the reverse brayton cryocooler. The integrated compressor-motor system was designed and tested with air as the working fluid at mass flow rate of 7.3 grams per sec, with a compression ratio of 1.58 and driven by a 2 KW permanent …

Commissioning Of A Dynamic Mechanical Analyzerfor The Characterization Of Low Temperature Nitife Shape Memory Alloys, Maruthi Diwakar Nandiraju

Electronic Theses and Dissertations

NiTiFe shape memory alloys can undergo transformations between cubic, trigonal and monoclinic phases at low temperatures. The low hysteresis associated with the trigonal R-phase transformation make them candidates for actuator applications at low temperatures. However, the literature available on these alloys is limited and there is a need to establish processing structure-property correlations. This study was undertaken with the objective of determining and understanding such correlations in a Ni46.8Ti50Fe3.2 alloy. First, a dynamic mechanical analyzer (DMA) was successfully commissioned to facilitate mechanical testing between -150 and 600ºC. The experiments performed over selected ranges of stress and temperature probed a range …

A Micromechanical Approach For Predicting The Complex Shear Modulus And Accumulated Shear Strain Of Asphalt Mixtures From Binder And Mastics, Cristian Druta

LSU Doctoral Dissertations

Asphalt mixtures are particulate composite materials consisting of uniformly distributed mineral aggregates, asphalt binder and air voids. Mixtures of asphalt binder and filler, also called mastics, are often assumed to behave as simple viscoelastic materials, where the binders are stiffened by the filler. Because the workability and performance of bituminous mixes are known to be affected by the filler-asphalt mixture (or mastic) properties, this study is intended for performing rheological tests on asphalt binder and mastics and use the results in order to estimate performance parameters of asphalt mixture. The present work uses the PG64-22 asphalt binder test data initially …

Design And Fabrication Of Micro Transducers Using Cured Su-8 Polymer As Main Structural Material, Wen Dai

LSU Doctoral Dissertations

Polymer based micro-transducers have many advantages over the traditional silicon based micro-transducers, such as easy integration with metal structures, design flexibility, and low fabrication costs. The characteristics of micro-transducers include converting electrical signals to/from mechanical response, the ability to sustain loading, sensitivity to external excitation, and etc. Some of the difficulties in realizing these characteristics include: characterizing material mechanical properties, techniques for producing electrically conductive polymer structures, and reliable fabrication procedures. In this dissertation, research addressing these difficulties is presented. The developed techniques are demonstrated in the design and fabrication of a SU-8 polymer based comb-drive micro-actuator. The micro-actuator used …

Ultra-Violet Lithography Of Thick Photoresist For The Applications In Biomems And Micro Optics, Ren Yang

LSU Doctoral Dissertations

UV lithography of thick photoresist is widely used in microelectromechanical systems (MEMS) and micro-optoelectromechanical systems (MOEMS). SU-8 is a typical negative tone thick photoresist for micro systems, and can be used for both structural material and pattern transfer. This dissertation presents an effort to comprehensively study these important subjects. The first part, and the most fundamental part of this dissertation concentrated on the numerical analysis and experimental study of the wavelength dependent absorbance of SU-8 and the diffraction effects on the sidewall profiles of the microstructures made using UV lithography of SU-8. This study has laid the foundation for all …

Thermal Sprayed Surface Coatings And Optical Characterisation, Yueqiang Xue

Masters

This research work aims to establish the potential of defect detection of thermal sprayed surface coatings by using a newly developed optical non-destructive interferometric technique – Electronic Speckle Pattern Shearing Interferometry (ESPSI), rather than using mechanical destructive testing methods and other non-destructive methods. This technique has been used in many industries for non-destructive testing (NDT). However, it is innovative to use this technique for NDT of thermal sprayed metal alloy coatings, especially those that are produced by flame powder spraying process. Investigations were carried out by the SUPERJET spray process, which was the flame powder spray process utilised in this …

Shear Band Evolution In Zr/Hf-Based Bulk Metallic Glasses Under Static And Dynamic Indentations, Hongwen Zhang

Dissertations, Master's Theses and Master's Reports - Open

Bulk metallic glasses (BMGs) exhibit superior mechanical properties as compared with other conventional materials and have been proposed for numerous engineering and technological applications. Zr/Hf-based BMGs or tungsten reinforced BMG composites are considered as a potential replacement for depleted uranium armor-piercing projectiles because of their ability to form localized shear bands during impact, which has been known to be the dominant plastic deformation mechanism in BMGs. However, in conventional tensile, compressive and bending tests, limited ductility has been observed because of fracture initiation immediately following the shear band formation. To fully investigate shear band characteristics, indentation tests that can confine …

Variational Approach To The Volume Viscosity Of Fluids, Allan J. Zuckerwar, Robert L. Ash

Mechanical & Aerospace Engineering Faculty Publications

The variational principle of Hamilton is applied to develop an analytical formulation to describe the volume viscosity in fluids. The procedure described here differs from those used in the past in that a dissipative process is represented by the chemical affinity and progress variable (sometimes called "order parameter") of a reacting species. These state variables appear in the variational integral in two places: first, in the expression for the internal energy, and second, in a subsidiary condition accounting for the conservation of the reacting species. As a result of the variational procedure, two dissipative terms appear in the Navier-Stokes equation. …

Fabrication Of Oxide Superconducting Thin Films Using Colloid Of Nanoparticles As Precursor, Vamsee K. Chintamaneni

Browse all Theses and Dissertations

This thesis reports the development of a new approach for the fabrication of superconducting thin films. Among the liquid phase methods of fabricating high temperature superconductors having critical current density about 1 MA/cm², metalorganic deposition using metal trifluoroacetates (TFA-MOD) is the best known method. In this project, detailed spectroscopic and microscopic analysis was performed at every stage of the TFA-MOD process to understand the evolution of crystalline superconducting film. It was observed that the TFA-MOD has some inherent disadvantages such as long process time, evolution of HF gas and results porosity in films. A new liquid phase process …

Efficient Inverted Polymer Solar Cells, G. Li, C.-W. Chu, V. Shrotriya, Jinsong Huang, Y. Yang

Department of Mechanical and Materials Engineering: Faculty Publications

We investigate the effect of interfacial buffer layers—vanadium oxide (V₂O₅) and cesium carbonate (Cs₂CO₃)—on the performance of polymer solar cells based on regioregular poly-(3-hexylthiophene) and [6,6]-phenyl C₆₀ butyric acid methyl ester blend. The polarity of solar cells can be controlled by the relative positions of these two interfacial layers. Efficient inverted polymer solar cells were fabricated with the structure of indium tin oxide (ITO)/Cs₂CO₃/polymer blend/vanadium oxide (V₂O₅)/aluminum (Al). Short-circuit current of 8.42 mA/cm2, open-circuit voltage of 0.56 V, and power conversion efficiency of …

Improving The Power Efficiency Of White Light-Emitting Diode By Doping Electron Transport Material, Jinsong Huang, Wei-Jen Hou, Juo-Hao Li, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Highly efficient white light emission was realized via the partial energy transfer from blue host polyfluorene (PF) to orange light emission dopant rubrene. A more balanced charge transport was achieved by adding an electron transport material, 2-(4-biphenylyl)-5-(4-tertbutylphenyl)-1,3,4-oxadiazole (PBD), into the PF-rubrene system to enhance the electron transportation. Efficiency improvement by as much as a factor of 2 has been observed through the addition of PBD. These devices can easily reach high luminance at low driving voltages, thus achieving high power efficiency at high luminance (14.8, 13.5, and 12.0 lm/W at the luminances of 1000, 2000, and 4000 cd/m², …

Piezoelectromagnetic Waves In A Ceramic Plate Between Two Ceramic Half-Spaces, S. N. Jiang, Q. Jiang, X. F. Li, S. H. Guo, H. G. Zhou, J. S. Chang

Department of Mechanical and Materials Engineering: Faculty Publications

We analyze the propagation of piezoelectromagnetic waves guided by a plate of polarized ceramics between two ceramic half-spaces. An exact dispersion relation is obtained, which reduces to a few known elastic, electromagnetic, and quasistatic piezoelectric wave solutions in the literature as special cases. Numerical solutions to the equation that determines the dispersion relation show the existence of guided waves. The results are useful for acoustic wave and microwave devices.