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Articles 4561 - 4590 of 5701

Full-Text Articles in Engineering

Simulation And Characterization Of Tire Nonuniformity-Induced Steering Nibble Vibrations Through Integrated Subsystems Modeling, Derek Mangun Dec 2006

Simulation And Characterization Of Tire Nonuniformity-Induced Steering Nibble Vibrations Through Integrated Subsystems Modeling, Derek Mangun

All Theses

Periodic force variations produced by nonuniform tire/wheel assemblies are known root causes of torsional steering wheel vibrations known as 'nibble'. Previous studies have sought to investigate this issue through modeling or experimentation involving the entire vehicle or specific subsystems, however a direct link between objectively measured tire force variations and the vibration levels perceived by vehicle occupants has yet to be established. Analytical models of a nonuniform tire, double-wishbone suspension system, and rack and pinion steering system are sourced from literature and integrated into a single subsystem-level model validated against experimental data obtained as part of a collaborative effort. The …

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A Robust Conjugate Heat Transfer Methodology With Novel Turbulence Modeling Applied To Internally-Cooled Gas Turbine Airfoils, William York Dec 2006

A Robust Conjugate Heat Transfer Methodology With Novel Turbulence Modeling Applied To Internally-Cooled Gas Turbine Airfoils, William York

All Dissertations

Computational fluid dynamics and heat transfer (CFD) has become a viable, physics-based analysis tool for complex flow and/or heat transfer problems in recent years due, in large part, to rapid advances in computing power. CFD based on the Reynolds-averaged Navier-Stokes (RANS) equations is starting to enter the mainstream design environment in certain industries where rapid and reliable predictive capability is necessary. One such application is the gas turbine industry, where thermal management of airfoils at extremely high temperatures is one of the most critical components in engine design for reliability. The problem is complicated by the need for advanced airfoil …

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Investigation Of The Effects Of Subgrid-Scale Turbulence On Resolvable-Scale Statistics, Qinglin Chen Dec 2006

Investigation Of The Effects Of Subgrid-Scale Turbulence On Resolvable-Scale Statistics, Qinglin Chen

All Dissertations

The effects of the subgrid-scale (SGS) turbulence on the resolvable-scale statistics and the effects of SGS models on large-eddy simulation (LES) are studied. It is shown that the SGS turbulence evolves the resolvable-scale joint probability density function (JPDF) through the conditional means of the SGS stress, the SGS scalar flux, and their production rate, which must be reproduced by the SGS model for LES to predict correctly the one-point resolvable-scale statistics, a primary goal of LES. This necessary condition is used as the basis for studying SGS physics and for testing SGS models. Theoretical predictions, measurements data obtained in a …

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Modeling And Simulation Of Friction-Limited Continuously Variable Transmissions, Nilabh Srivastava Dec 2006

Modeling And Simulation Of Friction-Limited Continuously Variable Transmissions, Nilabh Srivastava

All Dissertations

Over the last few decades, a lot of research effort has increasingly been directed towards developing vehicle transmissions that accomplish the government imperatives of increased vehicle efficiency and lower exhaust (greenhouse gaseous) emissions. These exhaust emissions can be regulated or lowered by increasing the fuel economy of a vehicle, and CVTs (continuously variable transmissions), indubitably, play a crucial role in this plan to improve the fuel economy. A continuously variable transmission is an emerging automotive transmission technology that offers a continuum of gear ratios between desired limits. A CVT offers numerous advantages over the conventional multi-step gear transmissions such as …

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The Effects Of Viscoelastic Behavior On The Operation Of A Delayed Resonator Vibration Absorber, John Cowans Dec 2006

The Effects Of Viscoelastic Behavior On The Operation Of A Delayed Resonator Vibration Absorber, John Cowans

All Theses

Delayed resonators have proven to be effective vibration absorbers (VAs) for tracking and canceling the effects of harmonic excitations on a structure. The Delayed Resonator (DR) is selfcontained, as no information from outside of its substructure is required for proper operation. It adjusts for variations in frequency using time-delay and gain as control parameters.
This thesis examines the relationship between viscoelastic (VE) loss mechanisms in systems with DR and the choice of modeling method used to calculate control parameters and determine system stability. It is hypothesized that a VE loss mechanism approximated by a single viscous dashpot may lead to …

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Internal Combustion Engine Cooling Strategies: Theory And Test, John Chastain Dec 2006

Internal Combustion Engine Cooling Strategies: Theory And Test, John Chastain

All Theses

Advanced internal combustion engine thermal management systems can enhance overall engine performance through the use of computer controlled cooling system actuators. Existing ground vehicle cooling systems generally have performance limitations due to the fixed behavior of the wax-based thermostat valve and crankshaft dependent operation of the coolant pump and radiator fan. Upgrading the traditional thermostat valve, water pump, and radiator fan with actuators permit real time computer control for improved temperature tracking and reduced power consumption. In this paper, the benefits associated with advanced automotive cooling systems are experimentally investigated. A 4.6L engine with a real-time data acquisition and control …

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Synergistic Functions Of Trimethl Phosphate And Vinylene Carbonate As Additives For The Li-Ion Batteries, Zhi-Yuan Tang, Yan-Bing He, Quan-Sheng Song, Yu-Hong Chen, Yuan-Gang Liu, Qiang Liu Nov 2006

Synergistic Functions Of Trimethl Phosphate And Vinylene Carbonate As Additives For The Li-Ion Batteries, Zhi-Yuan Tang, Yan-Bing He, Quan-Sheng Song, Yu-Hong Chen, Yuan-Gang Liu, Qiang Liu

Journal of Electrochemistry

The cooperative effects of trimethl phosphate and vinylene carbonate as additives for Li-ion batteries are investigated by using the cyclic voltammetry,electrochemical impedance spectroscopy and scanning electronic micro-photographs.The results show that the combination application of TMP and VC as additives for Li-ion batteries not only enhances safety of the batteries,but also improves their cycling performance.The reason may be ascribed to firstly VC being reduced and the reduction product polymerized to form excellent solid electrolyte interface(SEI) layer on the surface of graphite electrode during the first charge and discharge process,which prevents effectively the decomposition of TMP on the surface of the graphite …

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Facilitated Effect Of Ag To Oxygen Transportation In Pem Fuel Cell Air Cathodes, Hong-Feng Xu, Jian-Hua Dong, Xiang-Li Hou Nov 2006

Facilitated Effect Of Ag To Oxygen Transportation In Pem Fuel Cell Air Cathodes, Hong-Feng Xu, Jian-Hua Dong, Xiang-Li Hou

Journal of Electrochemistry

Silver(Ag) was deposited in the pores of Nafion membrane by ion exchange and succedent hydrogen reduction;the structures of Nafion-Ag membrane were measured by TEM and XRD,the diffusion coefficients of oxygen in Nafion-Ag was determined by electrochemical limited current method.The results showed that after deposited silver,the pores in the Nafion were enlarged by silver grains;the oxygen diffusion coefficient was increased about four times.By introducing silver in the thin Nafion film around the cathode catalyst,the performance of PEM fuel cell have a evident increasing in high current density, which shows the facilitated effects of silver to oxygen transportation in PEM fuel cell.

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Electrochemical Characterization Of Positive Electrode Material Lini1/3Co1/3Mn1/3O2 In Different Electrolytes, Jing-Jing Liu, Wei-Hua Qiu, Ling-Yan Yu, Hai-Lei Zhao, Tao Li Nov 2006

Electrochemical Characterization Of Positive Electrode Material Lini1/3Co1/3Mn1/3O2 In Different Electrolytes, Jing-Jing Liu, Wei-Hua Qiu, Ling-Yan Yu, Hai-Lei Zhao, Tao Li

Journal of Electrochemistry

Cathode materials LiNi1/3Co1/3Mn1/3O2 were prepared by low-heating solid-state reaction.The micro-structure and morphology of as-synthesized materials have been investigated by using XRD and SEM. The compatibilities of LiNi1/3Co1/3Mn1/3O2 with purchased LiPF6/ EC+DMC+DEC electrolyte and prepared LiBOB/EC+DEC+EMC electrolyte have also been studied. The Li/LiNi1/3Co1/3Mn1/3O2 batteries showed excellent electrochemical properties in the LiPF6/EC+DMC+DEC electrolyte. Reversible discharge capacities of 167, 163, 163, 157, 147mAh/g at 0.5C, 1C, 1.5C, 2C, 3C rate between 2.7~4.35 V, with stable cycling performances have …

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Electrochemical Behavior Of Buprofezin On Glass-Carbon Electrode, Qi Wang, Chang-Guo Chen Nov 2006

Electrochemical Behavior Of Buprofezin On Glass-Carbon Electrode, Qi Wang, Chang-Guo Chen

Journal of Electrochemistry

Electrochemical behavior of Bup has been investigated by means of cyclic voltammetry,linear sweep voltammetry,differential pulse voltammetry and square wave voltammetry.The results indicate that the electrochemical behavior of Bup on the surface of glassy carbon electrode is corresponding to a irreversible two-protons and two-electrons process with absrption.The square wave voltammetry for determination of Bup in actual samples has been established.

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Fabrication And Characterization Of Gadolinium Hexacyanoferrate Modified Electrode, Yan-Mao Shi, Pan Du, Ping Wu, Yao-Ming Zhou, Chen-Xin Cai Nov 2006

Fabrication And Characterization Of Gadolinium Hexacyanoferrate Modified Electrode, Yan-Mao Shi, Pan Du, Ping Wu, Yao-Ming Zhou, Chen-Xin Cai

Journal of Electrochemistry

A new electroactive polynuclear inorganic compound of rare earth metal hexacyanoferrate,gadolinium hexacyanoferrate(GdCHF),was prepared by electrochemically deposition on the surface of a glassy carbon electrode with a potential cycling procedure.The result of SEM indicated that the GdHCF was in the form of particles adhered on the surface of electrode.There were two different shapes and sizes of GdHCF forming on the surface of electrode.FTIR spectrum of GdHCF showed a very strong and sharp peak,which located at 2062.5 cm-1 and corresponded to the stretching vibration of the C≡N group in the GdHCF.The cyclic voltammetric results indicated that the GdHCF/GC electrode exhibited two …

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Synthesis Of Monolithic Carbon/Nickel Oxide Composite Electrode Material And Cyclic Voltammetry Characteristics, Tian-Ying Guo, Jing-Wei Zhu, Mou-Dao Song, Bang-Hua Zhang Nov 2006

Synthesis Of Monolithic Carbon/Nickel Oxide Composite Electrode Material And Cyclic Voltammetry Characteristics, Tian-Ying Guo, Jing-Wei Zhu, Mou-Dao Song, Bang-Hua Zhang

Journal of Electrochemistry

Monolithic carbon/nickel oxide composite materials were synthesized by carbonization of phenol formaldehyde gels that were ion-exchanged with Ni2+.Atomic absorption spectroscopy and powder X-ray diffraction technique were used to characterize the chemical composition and physical structure of the materials.The nickel dope amount for this method can reach 5.9 %(by mass).Subsequent cyclic voltammetry experiments indicate that the materials exhibit best capacitive performance at the nickel content of 4.4 %.

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Fabrication Of Gold Electrode Array Based On Co2 Laser Ablation, Wei Zhang, Jiang-Qun Xiao, Yong-Liang Zhou Nov 2006

Fabrication Of Gold Electrode Array Based On Co2 Laser Ablation, Wei Zhang, Jiang-Qun Xiao, Yong-Liang Zhou

Journal of Electrochemistry

A rapid process is described to produce single or multiple electrodes of any shape based on CO2 laser ablation for microfluidic chip.The method is as follow: coating a kind of material as sacrifice layer on a piece of glass with sputtered Cr and Au;designing the needed pattern on a computer;selecting proper parameters and ablating with CO2 laser;wiping of Au/Cr and sacrifice layer,and obtain electrodes at last.The microfluidic chip was gotten by reversely bonding with a piece of PDMS,and sealing around with PDMS prepolymer.The mask' effect is the main factor that influencing electrode quality.The width of electrodes could be …

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Novel Electrochemical Method For Synthesis Of Nanostructured Materials Of Noble Metals Based On Poly(N-Vinylpyrrolidone) (Pvp), Wei Pan, Xiao-Kai Zhang, Ming-Hu Huang, Shao-Xin Huang, Xing-Li Feng, Hou-Yi Ma Nov 2006

Novel Electrochemical Method For Synthesis Of Nanostructured Materials Of Noble Metals Based On Poly(N-Vinylpyrrolidone) (Pvp), Wei Pan, Xiao-Kai Zhang, Ming-Hu Huang, Shao-Xin Huang, Xing-Li Feng, Hou-Yi Ma

Journal of Electrochemistry

Gold nanocrystals with controllable size were synthesized through a simple electroreduction method using poly(N-vinylpyrrolidone)(PVP) of different polymerization degree as both stabilizer and shape-controller for gold nanoclusters.Individual gold nanoparticles spontaneously assembled into the wire-and ring-shaped nanoparticle aggregates depending on the PVP's dynamic stretching and curling,and precursor nanoparticles grew into flat,single-crystalline nanoprisms with thickness of dozens of nanometers based on the oriented aggregation between particles.Besides,core-shell Au/Ag nanoparticles were conveniently synthesized through two-step electroreduction of noble metal ions in the presence of PVPK30.The electrochemical synthetic method based on PVP provides a new path for preparation of noble metal nanostructured materials with different shape …

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Study Of The Electrooxidation Of Glycerol On Oxide And Pd/C Composite Catalysts, Zhi-Yuan Yan, Chang-Wei Xu, Pei-Kang Shen Nov 2006

Study Of The Electrooxidation Of Glycerol On Oxide And Pd/C Composite Catalysts, Zhi-Yuan Yan, Chang-Wei Xu, Pei-Kang Shen

Journal of Electrochemistry

Oxide and Pd on carbon composite catalysts have been prepared by intermittent microwave heating(IMH) method.The performance of the catalysts for glycerol oxidation in alkaline solution is studied by electrochemical techniques.It is shown that the Pd/C catalyst is active for glycerol electrooxidation.However,the oxide-Pd/C catalysts are even better in terms of the onset potential that is more negative and peak current density.The ratio of oxide to Pd is optimized according to the electrochemical measurement.The results reveal that the addition of oxide into the Pd/C induces the synergistic effect for glycerol electrooxidation.

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Deep Treatment Of Pulping Wastewater Using Three Phase Fluidized Bed Electrode Reactor, Dan Wu, Qi-Cai Shi, Ji-Ti Zhou, Bao-Jun Jia Nov 2006

Deep Treatment Of Pulping Wastewater Using Three Phase Fluidized Bed Electrode Reactor, Dan Wu, Qi-Cai Shi, Ji-Ti Zhou, Bao-Jun Jia

Journal of Electrochemistry

Treatment of pulping wastewater by using a novel electrochemical reactor,i.e.the three phase fluidized bed electrode,reactor were invesigated.The effects of air flow rate,applied voltage,pH value and FeSO4 concentration on electrolysis efficiency were investigated.It was clearly shown that the 20 V of voltage,0.3 m3·h-1 of air flow rate,1000 mg L-1 of FeSO4 concentration and pH≈2.5 were its best conditions.COD removal could be 70.1% under these conditions.

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Electrochemical Properties Of The Modified Carbon Nanotubes, Chun-An Ma Nov 2006

Electrochemical Properties Of The Modified Carbon Nanotubes, Chun-An Ma

Journal of Electrochemistry

Powder micro-electrodes were prepared from raw carbon nanotubes and carbon nanotubes modified by carboxyl.The electro-reduction properties of both the raw and open-ended carbon nanotubes in p-Nitrophenol solution were investigated.The FTIR spectrum result indicated that the functional groups are successfully fixed on the surface of the carbon nanotubes after nitric acid treatment.The cyclic voltammetry results show that the electrochemical activity of carboxyl-modified carbon nanotubes was improved.The mechanism of electro-(reduction) for the carbon nanotubes after acid treatment was discussed.

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Reaction Mechanism Of V(Ⅳ)/V(Ⅴ) Redox Couple At Graphite Felt Composite Electrode Bonded With Conductive Carbon Plastic, Xiao-Gang Li, Ke-Long Huang, Su-Qin Liu, Ning Tan, Li-Quan Chen Nov 2006

Reaction Mechanism Of V(Ⅳ)/V(Ⅴ) Redox Couple At Graphite Felt Composite Electrode Bonded With Conductive Carbon Plastic, Xiao-Gang Li, Ke-Long Huang, Su-Qin Liu, Ning Tan, Li-Quan Chen

Journal of Electrochemistry

The rate-determining step of V(Ⅳ) /V(Ⅴ) redoxreaction was investigated at graphite felt(GF)composite electrode by various techniques: cyclic voltammetry,polarization curve and impedance spectroscopy.Cyclic voltammetry analysis indicated that V(Ⅳ) /V(Ⅴ) redox reaction at GF electrode is quasi reversible.Acertain chemical reaction step is suspected to follow the electron transfer step of this reaction.The Tafel slopevalue(0.124) obtained from the polarization curve agrees well with theoretical value(0.12),which supposingthe electron transfer step was the rate-determining step.Impedance Spectroscopies at various potentials werestudied and simulated by equivalentcircuits.The impedance value of the electron transfer step modified is greatlyhigher than the others,which shows that the electron transfer step is the …

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The Synthesis, Structure And Electrochemical Performances Of Lithium Iron Phosphate, Hui Xie, Zhen-Tao Zhou Nov 2006

The Synthesis, Structure And Electrochemical Performances Of Lithium Iron Phosphate, Hui Xie, Zhen-Tao Zhou

Journal of Electrochemistry

The lithium iron phosphate cathode materials were synthesized by solid-state reaction combined high-rate ball milling under the temperature ranging from 400 ℃ to 700 ℃.The crystalline structure, morphology of particles, and electrochemical performance of the sample were investigated by X-ray diffraction, scanning electron microscopy and charge-discharge test. The results showed that the sintering temperature had great influences on the crystal structure, morphology and electrochemical performances of LiFePO4. The sample synthesized under 600℃ showed the best charge-discharge performances with the first specific discharge capacity of(128.8) mAh/g and the 15th specific discharge capacity of 129.1 mAh/g at 0.1C rate, …

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Structure And Electrochemical Characteristics Of Lifepo4 Prepared By The Polyacrylates-Pyrolysis-Reduction Method For Li-Ion Batteries, Li-Hong Yu, Yu-Liang Cao, Xiao-Fei Zhang, Han-Xi Yang, Xin-Ping Ai Nov 2006

Structure And Electrochemical Characteristics Of Lifepo4 Prepared By The Polyacrylates-Pyrolysis-Reduction Method For Li-Ion Batteries, Li-Hong Yu, Yu-Liang Cao, Xiao-Fei Zhang, Han-Xi Yang, Xin-Ping Ai

Journal of Electrochemistry

The cathode material of olivine LiFePO4 was prepared by a novel method of polyacrylate-pyrolysis-reduction.XRD demonstrates that the material have the olivine structure.SEM photo shows an average particle-size of about 100 nm with a well distribution.Electrochemical test of cycling at a constant current reveals the discharge capacity of 138 mAh/g and a good cycling stability.It is a novel practicable technology to prepare LiFePO4 by using polyacrylate-pyrolysis-reduction method.

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Some Aspects Of The Mechanical Response Of Pmr-15 Neat Resin At 288°C: Experiment And Modeling, Christina M. Falcone Sep 2006

Some Aspects Of The Mechanical Response Of Pmr-15 Neat Resin At 288°C: Experiment And Modeling, Christina M. Falcone

Theses and Dissertations

The mechanical response of PMR-15 neat resin was investigated at 288?C. Monotonic loading/unloading tests performed at several constant stress rates revealed considerable rate dependence, especially on the unloading path. Effect of prior stress rate on creep behavior was evaluated in creep tests preceded by uninterrupted loading to a target stress. Creep response was dependent on the prior stress rate. Effect of loading history was studied in stepwise creep tests, where specimens were subjected to a constant stress rate loading followed by unloading to zero stress with intermittent creep periods during both loading and unloading. Comparison of creep strains accumulated during …

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Effects Of Polishing Shot-Peened Surfaces On Fretting Fatigue Behavior Of Ti-6al-4v, Kasey S. Scheel Sep 2006

Effects Of Polishing Shot-Peened Surfaces On Fretting Fatigue Behavior Of Ti-6al-4v, Kasey S. Scheel

Theses and Dissertations

The research of this thesis was done to investigate the effects of polishing a shot-peened specimen of Ti-6Al-4V on the fretting fatigue life of that specimen. The shot-peening process, though one of the most beneficial techniques in prolonging fretting fatigue life, creates a textured surface that may lead to problems on the micro level. This research was done in an attempt to further improve the peening process by examining the effects of another surface treatment to be used in conjunction, surface polishing. The rough peened surface may contain abrupt changes in surface geometry that act as stress risers, which are …

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Rate Dependence Of Tensile Properties And Stress-Strain Behavior Of An Oxide/Oxide Ceramic Matrix Composite At Elevated Temperature And The Effects Of Low-Magnitude Sustained Loading On Composite Microstructure, Andrew T. Radzicki Sep 2006

Rate Dependence Of Tensile Properties And Stress-Strain Behavior Of An Oxide/Oxide Ceramic Matrix Composite At Elevated Temperature And The Effects Of Low-Magnitude Sustained Loading On Composite Microstructure, Andrew T. Radzicki

Theses and Dissertations

Advanced aerospace structures and components require materials that exhibit high strength at high operating temperatures. Nextel ™ 720/Alumina (N720/A) is an oxide/oxide, porous-matrix ceramic-matrix composite developed for load bearing applications at elevated temperatures. The current research investigates the rate dependence of tensile properties of the N720/A CMC at 1200°C as well as the creep behavior of this composite under applied stresses in the 1-25 MPa range. In addition, influence of prior loading rate on the creep response of N720/A under applied stresses above 50 MPa was evaluated at 1200°C. Tensile tests conducted at loading rate of 0.0025 and 25 MPa/s …

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Effects Of Environment On Creep Behavior Of Two Oxide-Oxide Ceramic Matrix Composites At 1200°C, Pavlos Koutsoukos Sep 2006

Effects Of Environment On Creep Behavior Of Two Oxide-Oxide Ceramic Matrix Composites At 1200°C, Pavlos Koutsoukos

Theses and Dissertations

Previous studies by the advisor and graduate students examined creep behavior of the Nextel720/Alumina CMC in air and in 100% steam environments at 1200 and 1330°C. Results showed that while this oxide/oxide system exhibits an exceptionally high fatigue limit at 1200°C it also experiences substantial strain accumulation under sustained loading conditions. Furthermore, these earlier investigations revealed a significant degrading effect of 100% steam environment on material performance under both static and cyclic loadings. The present effort will investigate creep rupture behavior of Nextel720/Alumina composite in the inert gas environment. In addition, creep rupture behavior of Nextel720/Aluminosilicate CMC will be investigated …

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Effects Of Phase Difference Between Axial And Contact Loads On Fretting Fatigue Behavior Of Titanium Alloy, Mohammad Almajali Sep 2006

Effects Of Phase Difference Between Axial And Contact Loads On Fretting Fatigue Behavior Of Titanium Alloy, Mohammad Almajali

Theses and Dissertations

Fretting fatigue is the surface damage that occurs at the interface between two components that are undergoing a small amplitude oscillatory movements. It results in a reduction of the material life as compared to the plain fatigue. Most of the previous works were accomplished under a constant applied normal load and a little effort was done under a variable contact load, while none of these studies has considered the phase difference between the axial load and the contact load. The primary goal of this study is to investigate the effect of phase difference between axial and contact loads on fretting …

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Research Of Explosion Mechanism Of Lithium-Ion Battery, Yu-Hong Chen, Zhi-Yuan Tang, Yan-Bing He, Qiang Liu Aug 2006

Research Of Explosion Mechanism Of Lithium-Ion Battery, Yu-Hong Chen, Zhi-Yuan Tang, Yan-Bing He, Qiang Liu

Journal of Electrochemistry

The heat character of Lithium-ion battery materials and explosion mechanism of Lithium-ion cells under the overcharge,short-circuit and other abuse behavior are tested by C80 calorimeter, DSC and charge-discharge instrument.SEI reactions, LixC6/electrolyte and LixC6/PVDF reactions take place at the anodes. Electrolyte and solvent reactions happen after 178℃ and Li1-xCo1/3Ni1/3Mn1/3O2 decomposes after 230℃. The batteries explode at 150℃ oven test or 1.5C, 5.5 V overcharge and do not explode at short-circuit.

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Studies On Performance And Electrode Materials For All Vanadium Flow Battery, Jun Yuan, Qing-Chun Yu, Yi-Feng Liu, Liang-Liang Ma, Yi-Hua Wu Aug 2006

Studies On Performance And Electrode Materials For All Vanadium Flow Battery, Jun Yuan, Qing-Chun Yu, Yi-Feng Liu, Liang-Liang Ma, Yi-Hua Wu

Journal of Electrochemistry

In this paper,cyclic voltammetry has been used to study the electrochemical performance of the treated and untreated graphite,soft graphite and PAN-carbon cloth in vanadium sulfate solution.The results show that: the reversibility of reaction can be improved on the surface of treated electrode,and the current can also increase;the electrochemical performance of treated electrode is remarkably enhanced;in the process of charge/discharge,the charge current can reach up to 20 mA/cm2,and discharge current up to 15 mA/cm2;surface morphology of the treated and untreated graphite show that the treatment can change the surface structure of electrode and also add the reaction …

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Immobilization Of Cytochrome C On The Surface Of Single-Wall Carbon Nanotube And Its Direct Electron Transfer And Electrocatalysis, Ya-Jing Yin, Ya-Fen Lv, Ping Wu, Pan Du, Yan-Mao Shi, Chen-Xin Cai Aug 2006

Immobilization Of Cytochrome C On The Surface Of Single-Wall Carbon Nanotube And Its Direct Electron Transfer And Electrocatalysis, Ya-Jing Yin, Ya-Fen Lv, Ping Wu, Pan Du, Yan-Mao Shi, Chen-Xin Cai

Journal of Electrochemistry

Cytochrome c(Cyto c) was immobilized on the surface of the single-wall carbon nanotube(SWNT) by using the method of adsorption.Infrared spectroscopy indicated that the Cyto c remained in its original structure and did not undergo structural change after its immobilization on the SWNT.The direct electrochemistry of cyto c,which was adsorbed on the surface of the SWNT,was studied by cyclic voltammetry.The voltammetric results demonstrated that the SWNT had promoting effects on the direct electron transfer of Cyto c and also indicated that the immobilized Cyto c retained its bioelectrocatalytic activity to the reduction of H2O2.This modified electrode might …

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Investigation Of The Direct Electrochemical Reduction Of Cr2O3 Powder In Molten Cacl2 By A Metallic Cavity Electrode, Guo-Hong Qiu, Di-Hua Wang, Xian-Bo Jin, Xiao-Hong Hu, Zheng Chen Aug 2006

Investigation Of The Direct Electrochemical Reduction Of Cr2O3 Powder In Molten Cacl2 By A Metallic Cavity Electrode, Guo-Hong Qiu, Di-Hua Wang, Xian-Bo Jin, Xiao-Hong Hu, Zheng Chen

Journal of Electrochemistry

A metallic cavity electrode is used for further investigation of the electrochemical behaviour of Cr2O3 powder in molten CaCl2(Na: ~0.02% by mass,Mg: < 0.005% by mass) at 900 ℃.The Cr2O3 powder reduction mechanism was confirmed in line with EDX and SEM analysis of the potentiostatic electrolysis products.The correlations between the particle size of metallised product and the electrolysis potential,or electrolysis time were analysed.

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Studies On Synthesis And Electrochemical Performance Of LiXNi1/3Mn1/3Co1/3O2 As Cathode Material For Lithium Ion Batteries, Xiao-Jian Guo, Jie Li, Yi-Xiao Li, Yong Yang Aug 2006

Studies On Synthesis And Electrochemical Performance Of LiXNi1/3Mn1/3Co1/3O2 As Cathode Material For Lithium Ion Batteries, Xiao-Jian Guo, Jie Li, Yi-Xiao Li, Yong Yang

Journal of Electrochemistry

A series of LiNi1/3Mn1/3Co1/3O2 were synthesized by a combined hydroxides coprecipitation and calcination method.Effects of synthesizing temperature of coprecipitations and the Li∶M ratios on structure and electrochemical performance of the materials were studied.The results showed that materials synthesized with coprecipitation at room temperature(~20 ~(o)C) delivered the best electrochemical performance.Another series of cathode materials LiXNi1/3Mn1/3Co1/3O2 with different Li∶M ratios were synthesized with this method.The results showed that sintering at high temperature could cause loss of LiOH,thus more LiOH should be added.It is demonstrated that Li …

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