Engineering Commons^™

The Electrochemical Characteristics Of Cpo-Pll/Gc Electrode, Wen Zhao, Xia-Qin Wu, Zhong-Qing Lu, Wen-Jing Hou, He-Xing Li

Journal of Electrochemistry

Poly-L-lysine(PLL) was electropolymerized onto the surface of glassy carbon(GC) electrode.1[(3-dimethylamino)propyl]-3-ethylcarbodiimide hydrochloride(EDC) was used as a Cross-linking agent to immobilized Chloroperoxidase(CPO) onto the PLL/GC electrode.A pair of well-defined redox peaks was observed at CPO-PLL/GC electrode,which clearly suggested that PLL can promote the direct electron transfer between the CPO and the GC electrodes.The cyclic voltammetry results also showed that the electron transfer at CPO-PLL/GC is a surface adsorption-controlled quasi-reversible process,which is accompanied with proton transfer.The CPO-PLL/GC electrode exhibited a good electrochemical stability and excellently electrocatalytic activity for electrochemical reduction of O₂.

Electrosynthesis Of P-Aminobenzenearsenic Acid, Chun-An Ma, Qin-An Zheng, Qiang Zhou, Ying-Hua Xu

Journal of Electrochemistry

The electrochemical reduction of p-nitrophenyl arsonit acid to p-aminobenzenearsenic acid was studied using controlled-current electrolysis.The results showed that the yield of p-aminobenzenearsenic acid was determinated by the following factors:the concentrations of sulphuric acid,the amount of additive,temperature and the concentrations of p-nitrophenyl arsenic acid.The optimum electrolytic conditions were obtained to be is 10% H₂SO₄,1% NaCl,80 ℃,25 g/350 mL p-nitrophenyl arsenic acid and 10 A·dm^-2.The yield of arsanilic acid could be reached 64.7% under the optimum electrolytic conditions.

Electrochemical Corrosion Behavior Of Tio2/Ha Composite Coating On Medical Titanium In Tyrode's Physiological Solution, Li-Li Kong, Long-Xiang Lin, Rong-Gang Hu, Fan Zhang, Chang-Jian Lin

Journal of Electrochemistry

Titanium and its alloys have been widely used as medical implant materials because of their good mechanical properties and biocompatibility.However,the physiological corrosion of metal will release metal ions,resulting in toxic and side effects.In this paper,in order to improve the corrosion resistance of titanium,and to enhance its bioactivity and osseointegration,the surface modification of titamum were performed.Using eletrochemical methods Tafel polarization and electrochemical impedance spectroscopy(EIS) were applied to study the electrochemical corrosion behavior of TiO₂ /HA composite coating.It is indicated that the corrosion resistance of the prepared TiO₂ /Ti material in Tyrode's physiological solution is improved because of the enhanced …

Electrocatalytic Reduction Of L-Cystine At Pb/Nanotio2 Film Electrode, Dao-Bao Chu, Feng Wang, Ying Xiao, Xue-Jiao Zhang

Journal of Electrochemistry

The nanoporous Ti-based TiO₂ films electrodes modified with Pb particles(Pb/nanoTiO₂) were prepared by using anodization and potentiostatic electro-deposition.The optimum deposition conditions were determined by comparing with various deposition potentials and time.The SEM analyses indicated that the TiO₂ films were homogeneous nanoporous structure,and the Pb particles well dispersed on the TiO₂ films.The L-cystine electrocatalytic activity reduction on the Pb/nanoTiO₂ film electrodes was investigated by cyclic voltammetry and Chronoamperometric curves.The results showed that this type of the electrode posseses high acticity and stability.

Cobalt-Doped Todorokite Prepared By Refluxing At Atmospheric Pressure As Lithium-Ion Battery Cathode, Rui-Qi Li, Chun-Hua Song, Chao Xu, Li-Xing Tu, Guo-Hong Qiu, Fan Liu

Journal of Electrochemistry

Cobalt-doped todorokites were prepared by refluxing at atmospheric pressure,and then charactered by X-ray diffraction(XRD),thermogravimetry(TG) and the analysis of chemical compositions.These measurements showed that all of the refluxing products were single phase of todorokites and the structure formulas were Mg_xCo_yMnO_z·nH₂O,where 0.18 ≤ x ≤ 0.22,0 ≤ y ≤ 0.24,2.10 ≤ z ≤ 2.53,and 0.35 ≤ n ≤0.73.The electrochemical characteristics of cobalt-doped todorokites were examined as lithium insertion hosts for cathodes in rechargeable lithium batteries.The first discharge capacity of undoped todorokite electrode was 211 mAh/g and the discharge capacity became 37 mAh/g after 30 …

Study Of Electrodes Modified With Hybrid Copper Cobalt Hexacyanoferrate-Mwcnts Composites, Shan Jiang, Yun Zhang, Xiao-Yan Wang, Xiao-Fei Yao

Journal of Electrochemistry

The hybrid modified electrodes were obtained by electrochemical deposition of copper-cobalt hexacyanoferrate(CuCoHCF) /multi-walled carbon nanotubes(MWCNTs) on the surface of glassy carbon electrode.The effects of the amount of MWCNTs and composition of electrolyte on the properties of modified electrode had been researched.The copper cobalt hexacyanoferrate-MWCNTs modified electrodes show excellent electrochemical properties compared with that modified only copper-cobalt hexacyanoferrate.The CuCoHCF-MWCNTs/GCE exhibits obvious electrocatalytic activity towards oxidation of hydrogen peroxide.The oxidation peak current increased linearly with the concentration of hydrogen peroxide in the range of 3.16 × 10^-5 ～ 2.92 × 10^-3 mol· L^-1.The linear equation is given up …

Fabrication And Characterization Of The Ni-Scsz Composite Anodes With A Lscm-Ceo2 Catalyst Layer In Thin Film Sofc, Yun-Yun Wang, Bo Huang, Xin-Jian Zhu, Wan-Qi Hu, Qing-Chun Yu

Journal of Electrochemistry

Solid oxide full cell(SOFC) running directly on hydrocarbon fuels has attracted much attention in recent years. In this paper, a dual-layer structure anode was fabricated by tape casting and screen printing method. The addition of a LSCM-CeO₂ catalyst layer to the supported anode surface yielded better performance in ethanol fuel. The maximum power density reached 710 and 669 mW/cm² at 850 ℃ running on hydrogen gas steam and ethanol steam,respectively. No significant degradation in performance has been observed after 216 h of cell testing when the Ni-ScSZ13 anode was exposed to the ethanol steam at 700 ℃. Very …

Multiscale Transformation Field Analysis Of Progressive Damage In Fibrous Laminates, Yehia Bahei-El-Din, Ritesh Khire, Prabhat Hajela

Centre for Advanced Materials

As part of an ongoing effort to model uncertainty propagation across multiple scales in fibrous laminates, this paper presents a deterministic transformation field analysis for modeling damage progression under membrane forces and bending moments. In this approach, equivalent eigenstresses are computed in the phases and/or plies such that their respective stress components that satisfy the underlying failure criteria are reduced to zero. Superposition of the solutions found for the undamaged laminate under applied loads and under the eigenstress field provide the entire response. Failure criteria are based on stress averages in the fiber and matrix. Damage mechanisms considered are frictional …

Modified Sandwich Structures For Improved Impact Resistance Of Wind Turbine Blades, Yehia Bahei-El-Din, Mostafa Shazly, I. El-Habbal, Y. Elbahy

Centre for Advanced Materials

Wind turbine blades are susceptible to damage due to fatigue as well as impact by flying objects and parts broken off failed blades of nearby wind towers. Localized, permanent compression of the foam core and delamination of the fibrous composite face sheets are typical damage modes and can lead to progressive structural failure. Sandwich structures modified by inclusion of flexible polyurethane (PU) layers within the cross section are examined under both impact and dynamic loads. Finite element models of sandwich structures with conventional and modified designs show that sandwich designs modified with PU interlayes exhibit reduced foam core crushing and …

Me-Em 2010 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

Table of Contents

• First Year to First Career
• Faculty & Staff
• Alumni
• Resources
• Graduates
• Publications

Luminescence Enhancement Of Cdte Nanostructures In Laf3:Ce/Cdte Nanocomposites, Mingzhen Yao, Xing Zhang, Lun Ma, Wei Chen, Alan G. Joly, Jinsong Huang, Qingwu Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Radiation detection demands new scintillators with high quantum efficiency, high energy resolution, and short luminescence lifetimes. Nanocomposites consisting of quantum dots and Ce³⁺ doped nanophosphors may be able to meet these requirements. Here, we report the luminescence enhancement of LaF₃:Ce/CdTe nanocomposites which were synthesized by a wet chemistry method. CdTe quantum dots in LaF₃:Ce/CdTe nanocomposites are converted into nanowires, while in LaF₃ /CdTe nanocomposites no such conversion is observed. As a result, the CdTe luminescence in LaF₃:Ce/CdTe nanocomposites is enhanced about five times, while in LaF₃ /CdTe nanocomposites no enhancement was …

The Characterization Of Leadership Within Undergraduate Engineering Design Teams Through Case Study Analysis, Gary Palmer Ii

All Theses

The purpose of this research is to clearly define leadership that exists within engineering project teams. Leadership can be applicable to any field of study and is heavily researched in business management. Sources which review leadership classify this topic in reference to managerial styles, leadership types and styles, emotional intelligence, and work climate. However, there are few sources which define leadership specifically within engineering environments. The motivation of this research is driven by the absence of defining and observing consistency in engineering leadership through the research‟s experience in engineering teams. Existing leadership is defined in this research through conducting two …

Effects Of Bondline Thickness On Nonlinear Interfacial Fracture Of Bonded Adhesive Joint, Gefu Ji

LSU Doctoral Dissertations

A number of existing and emerging industrial applications are dependent on layered substrates through adhesive bonding. The interfacial fracture of adhesively bonded structures is a critical issue for its extensive applications to a variety of modern industries. In the recent two decades, cohesive zone models (CZMs) have been receiving intensive attentions for fracture problems of adhesively bonded joints due to its fairly simple and accurate predictive ability. In CZMs the nonlinear interfacial fracture behaviors are described by the traction-separation laws (also referred to as cohesive laws). The cohesive laws represent the local constitutive behavior, instead of the global parameter, such …

Phase Change Materials For Thermal Regulation Of Building Integrated Photovoltaics, Ahmad Hassan

Doctoral

In outdoor deployed photovoltaics (PV), standard test conditions (STC) of 25 °C PV temperature, 1000 Wm-2 solar radiation intensity and 1.5 air-mass rarely prevail. PV temperature can rise 40-100 °C above STC inducing a power drop in crystalline silicon PV with a coefficient of -0.4 to -0.65 %/K above STC. Increased operating temperature also results in accelerated PV degradation due to cell delamination allowing moisture ingress. vConventional building integrated photovoltaics (BIPV) cooling techniques using passive
or active heat removal by air or water flow are limited by (i) very low heat transfer or (ii) large capital as well as maintenance …

Dynamic Model Of Ecological Factors Impacting The Gulf Of Mexico Dead Zone, Jimmie Arnold Brumfield Ii

LSU Doctoral Dissertations

The industrial agriculture complex of the Mississippi River Drainage Basin has the positive effect of feeding more individuals with less land via the use of chemical nutrients, pesticides and drainage. The negative effects of the agricultural nutrient load are carried by the Mississippi River to the Gulf of Mexico. After the flood of 1927 the Flood Control Act of 1928 began changing the Mississippi River into a navigation and flood control project. While successful, the river was turned into a channel where nutrient input was discharged into the Gulf of Mexico. Nitrogen compounds discharged from the Mississippi are claimed to …

Investigation Into The Impact Of Grain Boundaries, Film Interface, And Crystallographic Orientation On The Ionic Conductivity Of Thin Film Gadolinium-Doped Ceria, Matthew M. Swanson

Dissertations, Master's Theses and Master's Reports - Open

The research reported in this dissertation investigates the impact of grain boundaries, film interface, and crystallographic orientation on the ionic conductivity of thin film Gd-doped CeO2 (GDC).

Chapter 2 of this work addresses claims in the literature that submicron grain boundaries have the potential to dramatically increase the ionic conductivity of GDC films. Unambiguous testing of this claim requires directly comparing the ionic conductivity of single-crystal GDC films to films that are identical except for the presence of submicron grain boundaries. In this work techniques have been developed to grow GDC films by RF magnetron sputtering from a GDC target …

Measuring The Elastic Modulus Of Polymers Using The Atomic Force Microscope, Daniel Hoffman

Dissertations, Master's Theses and Master's Reports - Open

Testing a new method of nanoindentation using the atomic force microscope (AFM) was the purpose of this research. Nanoindentation is a useful technique to study the properties of materials on the sub-micron scale. The AFM has been used as a nanoindenter previously; however several parameters needed to obtain accurate results, including tip radius and cantilever sensitivity, can be difficult to determine. To solve this problem, a new method to determine the elastic modulus of a material using the atomic force microscope (AFM) has been proposed by Tang et al. This method models the cantilever and the sample as two springs …

An Ab-Initio Study Of The Elastic Properties Of Important Group Iv Diborides At High Temperatures, Manny Gonzales

Open Access Theses & Dissertations

Presented is an ab-initio Molecular Dynamics (MD) study, employing the Density Functional Theory (DFT), of the lattice parameter, thermal expansion coefficients and elastic constants of ZrB₂, TiB₂ and HfB₂ as a function of temperature. The MD trajectories provide the equilibrium lattice parameters at finite temperatures, and the gradient of the energy from these equilibrium solutions is then used to calculate the components of the stiffness tensor. The results for ZrB₂ are shown to agree well with reported experimental results for the lattice parameters and elastic constants as a function of temperature.

Lattice Boltzmann Modeling For Shallow Water Equations Using High Performance Computing, Kevin Tubbs

LSU Doctoral Dissertations

The aim of this dissertation project is to extend the standard Lattice Boltzmann method (LBM) for shallow water flows in order to deal with three dimensional flow fields. The shallow water and mass transport equations have wide applications in ocean, coastal, and hydraulic engineering, which can benefit from the advantages of the LBM. The LBM has recently become an attractive numerical method to solve various fluid dynamics phenomena; however, it has not been extensively applied to modeling shallow water flow and mass transport. Only a few works can be found on improving the LBM for mass transport in shallow water …

Experimental And Numerical Analysis Of Fuel Cells, Abul Bashar Mahmud Hasan

LSU Doctoral Dissertations

Fuel Cells are attractive power source for use in electronic applications. Physical phenomena (water generation, saturation effect in fuel cell, poisoning, and thermal stress) are studied that governs the operation of a Proton Exchange Membrane Fuel Cell (PEMFC) and Solid Oxide Fuel cell (SOFC). Additionally, experimental studies and numerical simulations on PEMFC gas flow channel, the determination of the impact of the single channel fuel cell are presented. Furthermore, preliminary study is done for the application of APS (Air Plasma Spray) to SOFC and adhesion of anode and cathode with electrolytes for the determination of parameters involved in manufacturing the …

Sensitivity Analysis Of The Johnson-Cook Plasticity Model For Hypervelocity Impacts: A Hydro-Code Study, Carlos David Castellanos

Open Access Theses & Dissertations

Computer simulations have been in use for decades in the modeling of hypervelocity impacts and general large deformation problems. Several computer codes have been developed to simulate this type of problems under a variety of geometric configurations and for any number of materials. These codes make use of several constitutive material models to simulate the response of the material under a variety of thermo-mechanical conditions. The Johnson-Cook constitutive model is widely used in the simulation hypervelocity impacts for the simulation of crater formation and even perforation of target structures. This thesis presents the results of a sensitivity study of this …

Selection Process, Modified Impact Testing And Failure Analysis Of An Electron-Beam-Melted Ti-6al-4v 3d Tessellation Based On The Eulerian Path Of The First Stellation Of The Rhombic Dodecahedron Open Unit Cell, Hugo Lopez

Open Access Theses & Dissertations

Ti-6Al-4V lattice block structures manufactured through the electron beam melting (EBM) process are a promising field in design and research due to great advantages that the alloy, the process and the final product offer. Three lattice block structures were manufactured through the electron beam process using an ARCAM A2 machine. The structures were designed using the MATERIALIZE^TM software and were designed around different types of unit cells. Compression testing was performed and one unit cell was selected due to its anisotropic behavior for modified impact testing. The same unit cell was used and it was scaled up to add …

Processing Of Zrb2-Zrc-Zrxsiy Ceramic By Reactive Metal Penetration, Nischel B. Maheswaraiah

Open Access Theses & Dissertations

The processing of ZrB2-ZrC-ZrxSiy composite by reactive metal penetration was investigated as a successor to the ZrB2-SiC composites for hypersonic vehicles application, which cannot be used for extended time at temperatures greater than 1600C due to formation of SiO and CO gases. Zirconium (Zr), zirconium disilicide (ZrSi2), and boron carbide (B4C) were reacted in graphite crucibles for 60, 120, 180, and 240 minutes. Microscopy and x-ray diffraction (XRD) deduced the formation of a heterogeneous microstructure of ZrB2-ZrC-ZrxSiy precipitates surrounded by a solidified Zr-Si melt. Unreacted boron carbide was observed in samples held at 1860C for 60 minutes and 120 minutes, …

Microstructure Investigation Of Al-Rich Titanium Aluminum Alloys, David Pham

Open Access Theses & Dissertations

The microstructures of Ti-Al alloys with 70-80 wt% Al were investigated. Aluminum wire (99.999%) and TiH₂ powder (99.7%) were used to produce the sample compositions inside a vertical tube furnace at 1600^oC in an Ar atmosphere. Argon is purified through a dehumidification and deoxidation system. Magnesium perchlorate Mg(ClO₄)₂ acts as a desiccant and titanium sponge pulls oxygen from the Ar in furnaces operating at 800^oC and 750^oC. X-ray diffraction and an optical microscope are used to identify phases and compositions

Spectroscopic Study Of The Inhibition Of Calcium Oxalate Calculi By Larrea Tridentata, Luis Alonso Pinales

Open Access Theses & Dissertations

The causes of urolithiasis include such influences as diet, metabolic disorders, and genetic factors which have been documented as sources that aggravate urinary calculi depositions and aggregations, and, implicitly, as causes of urolithiasis. This study endeavors to detail the scientific mechanisms involved in calcium oxalate calculi formation, and, more importantly, their inhibition under growth conditions imposed by the traditional medicinal approach using the herbal extract, Larrea tridentata. The calculi were synthesized without and with Larrea tridentata infusion by employing the single diffusion gel technique. A visible decrease in calcium oxalate crystal growth with increasing amounts of Larrea tridentata herbal infusion …

The Reactivity Of A Zr-Si Melt With B4c At Ultrahigh Temperatures, Alvaro Vega Sandate

Open Access Theses & Dissertations

Surfaces with exceptional properties are needed for next generation materials. Hypersonic re-entry space vehicles or turbines are subjected to both oxidizing and neutral environments and nose-caps or wings on such vehicles could easily reach operating temperatures of over 2000°C. Ultrahigh temperature ceramics like ZrB2 and HfB2 have melting temperatures of 3245°C and 3380°C respectively. However, these materials need to be protected from oxidation, usually with an oxide layer. Zirconium is more affordable and will be used to study its reaction with B4C and ZrSi2.

Experimentation was conducted by melting Zr slugs into a B4C and ZrSi2 packed bed at 1860°C …

Resistive Switching Of Tin Dioxide (Sno2) For Memristor Applications, Sergio Fabian Almeida

Open Access Theses & Dissertations

In the last decades new electrical devices have been investigated in order to overcome problems caused by integrated circuit shrinking. Within these devices there is one that has attracted much attention due to its high scalability and simple structure. This device was proposed theoretically by Leon Chua in 1971 who gave it the name of "Memristor". In the recent years thin films structures composed of a metal/oxide/metal (MOM) stack have been linked to this new device, also known as "Resistive switching". There are several applications for the memristor; one of the most important is for resistive random access memory (ReRAM) …

Hybrid Manufacturing: Integrating Stereolithography And Direct Print Technologies, Amit Lopes

Open Access Theses & Dissertations

The focus of this research was the development of a hybrid manufacturing system that integrates stereolithography (SL) and direct print (DP) technologies to fabricate three dimensional (3D) structural electronic devices within a single set-up. The capabilities of this new additive manufacturing (AM) technology was explored in the context of fabricating and prototyping complex electronic devices in which conformal shape, rugged and light-weight integration, and a natural resistance to reverse engineering are all of paramount importance. Consequently, electronic components can be tightly integrated together in a rugged, light-weight 3D structure of arbitrary form. This research is a continuing advancement of the …

Surface Modification Of Carbon Structures For Biological Applications, Elizabeth Irene Maurer

Browse all Theses and Dissertations

Carbon substrates have a wide variety of applications, many of which are enabled by appropriate surface modifications. In particular, the use of carbon-based substrates for biological devices can be quite advantageous due to their relative inertness and biocompatibility. Moreover, graphitic carbon can take many forms ranging from flat sheets to foams, fibers, and nanotubes. In this project, larger carbon substrates such as microcellular foam and flat graphite have been modified with carbon nanotubes, and their potential use in two types of biological applications was tested. The first study involved an investigation of the growth and proliferation of osteoblast cells on …

A Critical Assessment Of The High Cycle Bending Fatigue Behavior Of Boron-Modified Ti-6al-4v, Casey M. Holycross

Browse all Theses and Dissertations

Boron-modified Ti-6Al-4V alloys have shown increased performance in mechanical properties over unmodified alloys and are currently of interest for use in turbine engine applications. These alloys offer up to 40% increase in ultimate tensile strength, up to 30% increase in stiffness, and favorable damage characteristics while maintaining a ductility greater than 10%. These attractive properties are attributed to small additions of boron that refine the microstructure and form strong and stiff TiB whiskers. Previous research has found that these modified alloys compare favorably in fatigue. Samples machined from a powder-metallurgy forging with nominal composition Ti-6Al-4V-1B, were tested in fully-reversed bending …